WO2011001631A1 - 透明導電膜 - Google Patents
透明導電膜 Download PDFInfo
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- WO2011001631A1 WO2011001631A1 PCT/JP2010/004174 JP2010004174W WO2011001631A1 WO 2011001631 A1 WO2011001631 A1 WO 2011001631A1 JP 2010004174 W JP2010004174 W JP 2010004174W WO 2011001631 A1 WO2011001631 A1 WO 2011001631A1
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- transparent conductive
- conductive film
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- zinc oxide
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
- C23C14/3414—Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
Definitions
- the present invention relates to a transparent conductive film.
- the transparent conductive film is a window electrode of a photoelectric conversion element of a solar cell, an electromagnetic shielding film of an electromagnetic shield, an electrode of an input device such as a transparent touch panel, a liquid crystal display, an electroluminescence (EL) light emitter, an electrochromic (EC) display. Widely used for transparent electrodes such as body.
- the transparent conductive film is required to have good conductivity and high transparency in order to increase conversion efficiency in solar cell applications and not to impair visibility in display device applications.
- the transparent conductive film for example, indium tin oxide (ITO), indium zinc oxide, Al-doped zinc oxide (AZO), or the like is used.
- Patent Document 2 indium zinc oxide is crystallized into bixbite by heat treatment in a nitrogen atmosphere to improve the transmittance.
- the transmittance has been improved only to the extent of heat treated ITO.
- An object of the present invention is to provide a transparent conductive film having good conductivity and excellent transparency.
- the present inventors have found an indium zinc oxide film having a specific structure with further improved transmittance.
- the following transparent conductive film is provided.
- a transparent conductive film having good conductivity and excellent transparency can be provided.
- FIG. 2 is an X-ray diffraction chart of a transparent conductive film obtained in Example 1.
- FIG. 3 is an X-ray diffraction chart of a transparent conductive film obtained in Example 2.
- 4 is an X-ray diffraction chart of a transparent conductive film obtained in Example 3.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Example 4.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Example 5.
- FIG. 6 is an X-ray diffraction chart of a transparent conductive film obtained in Example 8.
- 10 is an X-ray diffraction chart of a transparent conductive film obtained in Example 9.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Example 10.
- 3 is an X-ray diffraction chart of a transparent conductive film obtained in Comparative Example 1.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Comparative Example 2.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Comparative Example 3.
- 6 is an X-ray diffraction chart of a transparent conductive film obtained in Comparative Example 4.
- the X-ray diffraction peak of the Cuk ⁇ ray at any one or more of ⁇ 67.8 °, and the peak intensities of the peaks at 2 ⁇ 30.2 ° -30.8 ° and 54.0-57.0 ° , Each of which is 20% or less of the peak intensity of the main peak.
- the main peak means a peak having the highest X-ray diffraction peak of Cuk ⁇ rays.
- the peak intensity of 20% or less of the peak intensity of the main peak means that the peak height of the X-ray diffraction peak of the Cuk ⁇ ray is 20% or less of the peak height of the main peak.
- a transparent conductive film having high transparency and low resistance can be obtained.
- the peak at 2 ⁇ 66.5 ° to 67.8 ° of the X-ray diffraction peak preferably has a peak at 66.7 ° to 67.5 °, and more preferably 66.9 ° to 67.67. It has a peak at 3 °.
- the content of ZnO is preferably 2 to 20% by weight, more preferably 5 to 15% by weight.
- the ZnO content in the film is less than 2% by weight, crystals having a bixbite structure may be formed during film formation.
- the content of ZnO in the film exceeds 20% by weight, the ratio of bixbite structure crystals in the transparent conductive film may increase.
- the Sn element content is preferably 1000 ppm by weight or less, more preferably 800 ppm by weight or less.
- the resistance of the film may be increased.
- the content of ZnO in the transparent conductive film of the present invention can be measured by a known method. For example, measurement is possible by using an ICP (High Frequency Inductively Coupled Luminescence Analyzer).
- the content of Sn element in the transparent conductive film of the present invention can be measured by a known method. For example, measurement can be performed by using an ICP-MS (high frequency inductively coupled mass spectrometer).
- the transparent conductive film of the present invention can contain other components as long as transparency and conductivity are not impaired.
- the transparent conductive film of the present invention may contain Ga and / or a positive tetravalent metal element.
- the transparent conductive film of the present invention may consist essentially of the indium oxide, zinc oxide and tin. “Substantially” means that 95% by weight to 100% by weight (preferably 98% by weight or more and 100% by weight or less) of the transparent conductive film is the above-mentioned component, or other within the range not impairing the effect of the present invention. This means that it may contain only inevitable impurities.
- the film thickness of the transparent conductive film of the present invention is preferably 35 nm to 1000 nm from the viewpoint of obtaining a low specific resistance and high light transmittance, and preferably 1000 nm or less from the viewpoint of production cost.
- the transparent conductive film of the present invention is manufactured by forming an indium zinc oxide amorphous film on a substrate using a sintered body containing In 2 O 3 and ZnO, and annealing the indium zinc oxide amorphous film. To do. At this time, by adjusting both the ZnO concentration and the annealing substrate temperature, atmosphere, and temperature, the peak intensity of 30.2 ° to 30.8 ° can be reduced or eliminated. Usually, the annealing treatment is performed at 200 to 750 ° C. in an atmosphere not containing oxygen.
- the film obtained by sputtering is crystallized by annealing, and is any one or more of 35.5 ° to 37.0 °, 39.0 ° to 40.5 °, and 66.5 ° to 67.8 °. A peak can be seen.
- the transparent conductive film of the present invention is an indium zinc oxide amorphous film formed on a substrate by sputtering at a substrate temperature of 100 to 500 ° C. using a sintered body containing 3 to 20% by weight of ZnO in In 2 O 3.
- the indium zinc oxide amorphous film can be obtained by annealing at a temperature of 200 to 700 ° C. in an oxygen-free atmosphere.
- the preferred conditions for the sintered body containing In 2 O 3 and ZnO used for film formation are the same as the preferred conditions for the transparent conductive film of the present invention. That is, the sintered body containing In 2 O 3 and ZnO preferably has a ZnO content of preferably 3 to 20% by weight, and more preferably 5 to 15% by weight. The sintered body containing In 2 O 3 and ZnO preferably has a Sn element content of 1000 ppm by weight or less, and preferably 100 ppm by weight or less. Note that the composition of the indium zinc oxide amorphous film generally matches the composition of the sintered body used for film formation.
- the substrate is not particularly limited, and a known substrate can be used.
- glass substrates such as alkali silicate glass, non-alkali glass, and quartz glass, silicon substrates, sapphire substrates, acrylic, polycarbonate, polyethylene naphthalate (PEN), etc.
- a resin film substrate, a polymer film substrate such as polyethylene terephthalate (PET), and polyamide can be used.
- the thickness of the substrate is generally 0.1 to 10 mm, preferably 0.3 to 5 mm.
- a glass substrate those chemically or thermally reinforced are preferred.
- a glass substrate and a resin substrate are preferable, and a glass substrate is particularly preferable.
- a resin substrate or a polymer base material is preferable.
- the indium zinc oxide amorphous film can be formed using, for example, a sputtering method, a vapor deposition method, an ion beam method, or the like.
- the substrate temperature is preferably 100 ° C. to 300 ° C., more preferably 150 ° C. to 300 ° C.
- the oxygen partial pressure is preferably 0 to 5%
- the film formation pressure is preferably 0.1 to 0.8 Pa
- the distance between the substrates is preferably 500 mm to 5000 mm.
- the power source can be DC or RF.
- the transparent conductive film of the present invention can be obtained by crystallizing an indium zinc oxide amorphous film by annealing in an atmosphere not containing oxygen.
- the atmosphere containing no oxygen is an atmosphere having an oxygen partial pressure of 1% or less, preferably an atmosphere having an oxygen partial pressure of 0.5% or less, more preferably an atmosphere having an oxygen partial pressure of 0.1% or less. It is.
- the oxygen-free atmosphere examples include an inert gas atmosphere and a vacuum atmosphere.
- an inert gas in an inert gas atmosphere a gas such as nitrogen or argon can be used.
- the vacuum atmosphere is an atmosphere having a pressure of 1 Pa or less, preferably an atmosphere of 0.5 Pa or less, and more preferably an atmosphere of 0.2 Pa or less.
- the annealing temperature of the indium zinc oxide amorphous film is 200 ° C. to 750 ° C., preferably 400 to 700 ° C., and more preferably 500 to 700 ° C.
- the content of ZnO contained in the sintered body used for film formation is desirably 5 to 8% by weight. If the annealing temperature is less than 200 ° C., crystallization may not be possible. On the other hand, when the annealing temperature exceeds 750 ° C., the ratio of bixbite crystals may increase.
- the annealing treatment time is preferably 5 to 10 minutes when the annealing temperature is 500 to 750 ° C. Further, when the annealing temperature is 200 ° C. or higher and 400 ° C. or lower, it is preferably 60 minutes to 240 minutes.
- the transparent conductive film of the present invention has a transmittance of, for example, 80% or more for light with a wavelength of 350 nm to 450 nm when the film thickness is 50 to 300 nm, and is a liquid crystal display, light emitting diode (LED), organic light emitting diode (OLED). ), And can be suitably used as a transparent electrode for solar cells and the like. That is, the present invention includes a liquid crystal display, a light emitting diode (LED), an organic light emitting diode (OLED), and a transparent electrode provided with the indium zinc oxide film of the present invention.
- Example 1 Using a magnetron sputtering apparatus, a target (IZO (registered trademark), manufactured by Idemitsu Kosan Co., Ltd.) containing 10.7% by weight of ZnO in In 2 O 3 was sputtered at a substrate temperature of 200 ° C., and indium having a film thickness of 300 nm was formed on the glass substrate. A zinc oxide amorphous film was formed. This glass substrate with an indium zinc oxide amorphous film was annealed in vacuum at 500 ° C. for 10 minutes to obtain an indium zinc oxide film. In addition, about the atmosphere at the time of sputtering, argon gas containing 3% of oxygen was adjusted so that the inside of a system might be set to 0.1 Pa. The film formation was performed with the distance between the glass substrate and the target being 100 mm.
- IZO registered trademark
- the obtained indium zinc oxide film was subjected to X-ray diffraction measurement. The results are shown in FIG. Further, the average transmittance and specific resistance of the obtained indium zinc oxide film were evaluated. The results are shown in Table 1.
- the average transmittance is an average value of the transmittance of the indium zinc oxide film every 1 nm between wavelengths of 350 to 450 nm.
- the conditions for the X-ray diffraction measurement are as follows.
- the conditions for measuring the average transmittance are as follows. Equipment: UV-3600 manufactured by SHIMAZU Scanning speed: Medium sampling pitch: 1nm For measuring the transmittance, glass of the same thickness and material was used on the reference side.
- the specific resistance of the obtained indium zinc oxide film was measured using Loresta EP manufactured by Mitsubishi Chemical Analytech.
- the specific resistance was calculated by multiplying the resistance value measured by Loresta by a correction coefficient of 0.4532 and further by the film thickness.
- Examples 2 to 10 and Comparative Examples 1 to 5 According to the conditions of Table 1, an indium zinc oxide film was formed and evaluated in the same manner as in Example 1. The results are shown in Table 1. However, as for Comparative Example 2, a sapphire substrate was used instead of the glass substrate in order to prevent deformation of the substrate. Similarly, the results of X-ray diffraction measurement of the indium zinc oxide films of Examples 2 to 5 and Examples 8 to 10 are shown in FIGS. 2 to 8, respectively, and X of the indium zinc oxide films of Comparative Examples 1 to 4 are shown. The results of the line diffraction measurement are shown in FIGS. 9 to 12, respectively.
- the relative intensity means the relative value of the peak height of each peak when the background is subtracted from each peak and the peak height of the main peak is 100.
- the blank of relative intensity indicates that no peak was detected.
- the specific resistance “ ⁇ ” indicates that the specific resistance is not measurable, that is, the specific resistance is 10 8 ⁇ cm or more.
- the transparent conductive film of the present invention has good conductivity and excellent transparency, and is suitably used as a transparent electrode for liquid crystal displays, light emitting diodes (LEDs), organic light emitting diodes (OLEDs), solar cells, and the like. it can.
- LEDs light emitting diodes
- OLEDs organic light emitting diodes
- solar cells and the like. it can.
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Abstract
Description
上記透明導電膜には、例えばインジウム錫酸化物(ITO)、インジウム亜鉛酸化物、Alドープ酸化亜鉛(AZO)等が用いられている。
1.In2O3結晶を含むインジウム亜鉛酸化物膜であって、
2θ=35.5°~37.0°、39.0°~40.5°及び66.5°~67.8°のいずれか1つ以上でCukα線のX線回折ピークを有し、
2θ=30.2°~30.8°及び54.0°~57.0°に有するピークのピーク強度が、それぞれ主ピークのピーク強度の20%以下である透明導電膜。
2.ZnOの含有量が2~20重量%である1に記載の透明導電膜。
3.Sn元素の含有量が1000重量ppm以下である1又は2に記載の透明導電膜。
上記X線回析ピークの2θ=39.0°~40.5°にあるピークは、好ましくは39.4°~40.3°にピークを有し、さらに好ましくは39.6°~40.1°にピークを有する。
上記X線回析ピークの2θ=66.5°~67.8°にあるピークは、好ましくは66.7°~67.5°にピークを有し、さらに好ましくは66.9°~67.3°にピークを有する。
尚、上記ピーク強度が主ピークのピーク強度の20%以下であることは、2θ=30.2~30.8°又は54.0°~57.0°にピークが検出されないことも含む。
上記X線回析ピークの2θ=54.0°~57.0°のピークとは、好ましくは54.5°~55.7°のピークであり、さらに好ましくは55.0°~55.2°のピークである。
透明導電膜中にビックスバイト構造の結晶が存在すると、透過率の減少、又は抵抗の上昇を起こすおそれがある。即ち、本発明の透明導電膜はビックスバイト構造の割合が少ないために、透明度を高く、且つ抵抗を低くすることができる。
膜中のZnOの含有量が2重量%未満の場合、成膜時にビックスバイト構造の結晶が生成するおそれがある。一方、膜中のZnOの含有量が20重量%超の場合、透明導電膜中のビックスバイト構造の結晶の割合が増えるおそれがある。
膜中のSn元素の含有量が1000重量ppm超の場合、膜の抵抗が高くなるおそれがある。
本発明の透明導電膜中のSn元素の含有量は、周知の方法で測定可能である。例えば、ICP-MS(高周波誘導結合質量分析装置)を使用することで、測定可能である。
しかしながら、本発明の透明導電膜は、実質的に上記酸化インジウム、酸化亜鉛及び錫のみからなってもよい。「実質的」とは、透明導電膜の95重量%以上100重量%以下(好ましくは98重量%以上100重量%以下)が上記の成分であること、又は本発明の効果を損なわない範囲で他に不可避不純物のみを含んでいてもよいことを意味する。
本発明の透明導電膜は、In2O3中にZnOを3~20重量%含む焼結体を用いて、基板温度100~500℃でスパッタリングすることで、基板上にインジウム亜鉛酸化物アモルファス膜を成膜し、当該インジウム亜鉛酸化物アモルファス膜を酸素を含まない雰囲気下で200~700℃の温度でアニール処理をすることにより得ることができる。
尚、インジウム亜鉛酸化物アモルファス膜の組成は、通常、成膜に用いる焼結体の組成とほぼ一致する。
スパッタ法でインジウム亜鉛酸化物アモルファス膜を成膜する場合、基板温度は好ましくは100℃~300℃であり、より好ましくは150℃~300℃である。
酸素を含まない雰囲気とは、酸素分圧が1%以下の雰囲気であり、好ましくは酸素分圧が0.5%以下の雰囲気であり、より好ましくは酸素分圧が0.1%以下の雰囲気である。
不活性ガス雰囲気の不活性ガスとしては、窒素、アルゴン等のガスを用いることが可能である。
また、真空雰囲気とは、圧力が1Pa以下の雰囲気であり、好ましくは0.5Pa以下の雰囲気であり、より好ましくは0.2Pa以下の雰囲気である。
特に、アニール温度が200℃以上300℃未満の場合、成膜に用いる焼結体に含まれるZnOの含有量を5~8重量%とすることが望ましい。
アニール温度が200℃未満の場合、結晶化できないおそれがある。一方、アニール温度が750℃超の場合、ビックスバイト結晶の割合が多くなるおそれがある。
即ち、本発明には、本発明のインジウム亜鉛酸化物膜を備える液晶ディスプレイ、発光ダイオード(LED)、有機発光ダイオード(OLED)及び透明電極も含まれる。
マグネトロンスパッタ装置を用いてIn2O3中にZnOを10.7重量%含むターゲット(IZO(登録商標)、出光興産製)を基板温度200℃でスパッタリングし、ガラス基板上に膜厚300nmのインジウム亜鉛酸化物アモルファス膜を成膜した。このインジウム亜鉛酸化物アモルファス膜付きガラス基板を、真空中500℃で10分間アニール処理をし、インジウム亜鉛酸化物膜を得た。
尚、スパッタリング時の雰囲気については、酸素を3%含むアルゴンガスを系内が0.1Paとなるように調整した。また、成膜は、ガラス基板とターゲットの間隔を100mmにして行った。
尚、上記平均透過率とは、波長350~450nm間の1nm毎のインジウム亜鉛酸化物膜の透過率の平均の値である。
装置:Rigaku製 MiniflexII
線源:Cukα
電圧:30kV
電流:15mA
サンプリング間隔:0.05°
スキャンスピード:2°/min
装置:SHIMAZU製 UV-3600
スキャンスピード:中速
サンプリングピッチ:1nm
透過率の測定には、リファレンス側には同じ厚み及び材質のガラスを用いた。
表1の条件に従って、実施例1と同様にしてインジウム亜鉛酸化物膜を成膜して評価した。結果を表1に示す。
ただし、比較例2に関しては、基板の変形を防ぐためにガラス基板の代わりにサファイア基板を用いた。
同様に、実施例2~5並びに実施例8~10のインジウム亜鉛酸化物膜のX線回折測定の結果を、それぞれ図2~8に示し、比較例1~4のインジウム亜鉛酸化物膜のX線回折測定の結果を、それぞれ図9~12に示す。
また、比抵抗の「∞」とは、比抵抗が測定不能つまり、比抵抗が108μΩcm以上であったことを示す。
この明細書に記載の文献の内容を全てここに援用する。
Claims (3)
- In2O3結晶を含むインジウム亜鉛酸化物膜であって、
2θ=35.5°~37.0°、39.0°~40.5°及び66.5°~67.8°のいずれか1つ以上でCukα線のX線回折ピークを有し、
2θ=30.2°~30.8°及び54.0°~57.0°に有するピークのピーク強度が、それぞれ主ピークのピーク強度の20%以下である透明導電膜。 - ZnOの含有量が2~20重量%である請求項1に記載の透明導電膜。
- Sn元素の含有量が1000重量ppm以下である請求項1又は2に記載の透明導電膜。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011520767A JP5662933B2 (ja) | 2009-06-30 | 2010-06-23 | 透明導電膜 |
EP10793805.2A EP2450466A4 (en) | 2009-06-30 | 2010-06-23 | TRANSPARENT CONDUCTIVE FILM |
CN201080027935.9A CN102803547B (zh) | 2009-06-30 | 2010-06-23 | 透明导电膜 |
US13/381,403 US8568621B2 (en) | 2009-06-30 | 2010-06-23 | Transparent conductive film |
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PCT/JP2010/004174 WO2011001631A1 (ja) | 2009-06-30 | 2010-06-23 | 透明導電膜 |
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US (1) | US8568621B2 (ja) |
EP (1) | EP2450466A4 (ja) |
JP (1) | JP5662933B2 (ja) |
KR (1) | KR20120031185A (ja) |
CN (1) | CN102803547B (ja) |
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WO (1) | WO2011001631A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014024819A1 (ja) * | 2012-08-06 | 2014-02-13 | 積水ナノコートテクノロジー株式会社 | 光透過性導電性フィルム及び光透過性導電性フィルムを含有するタッチパネル |
JP2014067701A (ja) * | 2012-09-05 | 2014-04-17 | Semiconductor Energy Lab Co Ltd | 導電性酸化物膜、表示装置、及び導電性酸化物膜の作製方法 |
JP2022176332A (ja) * | 2017-09-29 | 2022-11-25 | 日東電工株式会社 | エレクトロクロミック調光部材、光透過性導電ガラスフィルムおよびエレクトロクロミック調光素子 |
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TW201408803A (zh) * | 2012-06-18 | 2014-03-01 | Oc Oerlikon Balzers Ag | 用於方向性材料沉積的pvd設備、方法及工件 |
KR20150018728A (ko) | 2013-08-09 | 2015-02-24 | 삼성디스플레이 주식회사 | 액정 표시 장치 및 이의 제조 방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000067657A (ja) * | 1998-08-26 | 2000-03-03 | Internatl Business Mach Corp <Ibm> | 赤外線透過に優れた透明導電膜及びその製造方法 |
JP2001155549A (ja) * | 1999-11-26 | 2001-06-08 | Alps Electric Co Ltd | 酸化物透明導電膜と酸化物透明導電膜形成用ターゲットおよび先の酸化物透明導電膜を備えた基板の製造方法と電子機器および液晶表示装置 |
JP2004076094A (ja) * | 2002-08-19 | 2004-03-11 | Okura Ind Co Ltd | 透明導電膜、及びその製造方法 |
WO2007058066A1 (ja) * | 2005-11-21 | 2007-05-24 | Idemitsu Kosan Co., Ltd. | 透明導電膜並びにそれを用いた基板、電子機器及び液晶表示装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58209809A (ja) | 1982-05-31 | 1983-12-06 | 株式会社東芝 | 透明導電膜の形成方法 |
JP4233641B2 (ja) * | 1998-08-31 | 2009-03-04 | 出光興産株式会社 | 透明導電膜用ターゲットおよび透明導電ガラスならびに透明導電フィルム |
EP2610230A2 (en) * | 1998-08-31 | 2013-07-03 | Idemitsu Kosan Co., Ltd. | Target for transparent electroconductive film, transparent electroconductive material, transparent electroconductive glass, and transparent electroconductive film |
JP2002118960A (ja) | 2000-03-10 | 2002-04-19 | Mark Tec:Kk | 電気料金管理装置およびその記録媒体 |
JP3945395B2 (ja) * | 2002-07-05 | 2007-07-18 | 住友金属鉱山株式会社 | 透明導電性薄膜、その形成方法、それを用いた表示パネル用透明導電性基材及び有機エレクトロルミネッセンス素子 |
JP2005262951A (ja) | 2004-03-17 | 2005-09-29 | Nissan Motor Co Ltd | 車体前部構造 |
JP2005274741A (ja) | 2004-03-23 | 2005-10-06 | Shinshu Univ | 透明電極基板 |
JP5201566B2 (ja) | 2006-12-11 | 2013-06-05 | 豊田合成株式会社 | 化合物半導体発光素子及びその製造方法 |
-
2010
- 2010-06-23 WO PCT/JP2010/004174 patent/WO2011001631A1/ja active Application Filing
- 2010-06-23 EP EP10793805.2A patent/EP2450466A4/en not_active Withdrawn
- 2010-06-23 KR KR1020117031512A patent/KR20120031185A/ko active Search and Examination
- 2010-06-23 JP JP2011520767A patent/JP5662933B2/ja not_active Expired - Fee Related
- 2010-06-23 US US13/381,403 patent/US8568621B2/en not_active Expired - Fee Related
- 2010-06-23 CN CN201080027935.9A patent/CN102803547B/zh not_active Expired - Fee Related
- 2010-06-29 TW TW099121308A patent/TW201120918A/zh unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000067657A (ja) * | 1998-08-26 | 2000-03-03 | Internatl Business Mach Corp <Ibm> | 赤外線透過に優れた透明導電膜及びその製造方法 |
JP2001155549A (ja) * | 1999-11-26 | 2001-06-08 | Alps Electric Co Ltd | 酸化物透明導電膜と酸化物透明導電膜形成用ターゲットおよび先の酸化物透明導電膜を備えた基板の製造方法と電子機器および液晶表示装置 |
JP2004076094A (ja) * | 2002-08-19 | 2004-03-11 | Okura Ind Co Ltd | 透明導電膜、及びその製造方法 |
WO2007058066A1 (ja) * | 2005-11-21 | 2007-05-24 | Idemitsu Kosan Co., Ltd. | 透明導電膜並びにそれを用いた基板、電子機器及び液晶表示装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2450466A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014024819A1 (ja) * | 2012-08-06 | 2014-02-13 | 積水ナノコートテクノロジー株式会社 | 光透過性導電性フィルム及び光透過性導電性フィルムを含有するタッチパネル |
JP5693749B2 (ja) * | 2012-08-06 | 2015-04-01 | 積水ナノコートテクノロジー株式会社 | 光透過性導電性フィルム及び光透過性導電性フィルムを含有するタッチパネル |
JP2015065169A (ja) * | 2012-08-06 | 2015-04-09 | 積水ナノコートテクノロジー株式会社 | 光透過性導電性フィルム、その製造方法及びその用途 |
JPWO2014024819A1 (ja) * | 2012-08-06 | 2016-07-25 | 積水ナノコートテクノロジー株式会社 | 光透過性導電性フィルム及び光透過性導電性フィルムを含有するタッチパネル |
JP2014067701A (ja) * | 2012-09-05 | 2014-04-17 | Semiconductor Energy Lab Co Ltd | 導電性酸化物膜、表示装置、及び導電性酸化物膜の作製方法 |
JP2022176332A (ja) * | 2017-09-29 | 2022-11-25 | 日東電工株式会社 | エレクトロクロミック調光部材、光透過性導電ガラスフィルムおよびエレクトロクロミック調光素子 |
Also Published As
Publication number | Publication date |
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JP5662933B2 (ja) | 2015-02-04 |
US20120112138A1 (en) | 2012-05-10 |
KR20120031185A (ko) | 2012-03-30 |
US8568621B2 (en) | 2013-10-29 |
EP2450466A1 (en) | 2012-05-09 |
CN102803547B (zh) | 2014-10-08 |
JPWO2011001631A1 (ja) | 2012-12-10 |
TW201120918A (en) | 2011-06-16 |
CN102803547A (zh) | 2012-11-28 |
EP2450466A4 (en) | 2013-12-18 |
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