WO2009098938A1 - 熱硬化性導電ペースト、及びそれを用いて形成した外部電極を有する積層セラミック電子部品 - Google Patents
熱硬化性導電ペースト、及びそれを用いて形成した外部電極を有する積層セラミック電子部品 Download PDFInfo
- Publication number
- WO2009098938A1 WO2009098938A1 PCT/JP2009/050839 JP2009050839W WO2009098938A1 WO 2009098938 A1 WO2009098938 A1 WO 2009098938A1 JP 2009050839 W JP2009050839 W JP 2009050839W WO 2009098938 A1 WO2009098938 A1 WO 2009098938A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- conductive paste
- silver
- component
- thermosetting conductive
- weight
- Prior art date
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- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 63
- 239000000919 ceramic Substances 0.000 title claims abstract description 56
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 34
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- 239000004332 silver Substances 0.000 claims abstract description 31
- QCEUXSAXTBNJGO-UHFFFAOYSA-N [Ag].[Sn] Chemical compound [Ag].[Sn] QCEUXSAXTBNJGO-UHFFFAOYSA-N 0.000 claims abstract description 23
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
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- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/228—Terminals
- H01G4/232—Terminals electrically connecting two or more layers of a stacked or rolled capacitor
- H01G4/2325—Terminals electrically connecting two or more layers of a stacked or rolled capacitor characterised by the material of the terminals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
Definitions
- the present invention relates to a thermosetting conductive paste and a multilayer ceramic electronic component having an external electrode formed using the paste.
- the present invention relates to a thermosetting conductive paste capable of forming an external electrode suitable for plating, and a multilayer ceramic electronic component such as a multilayer ceramic capacitor having the external electrode formed using the paste.
- FIG. 1 shows a multilayer ceramic capacitor 1 which is an example of a multilayer ceramic electronic component.
- the external electrode 4 of the multilayer ceramic capacitor 1 is generally formed by the following method using a fired conductive paste or a thermosetting conductive paste.
- a fired conductive paste in which conductive particles such as silver powder and copper powder and glass frit are mixed in a vehicle is applied to the take-out surface of the internal electrode 3 of the multilayer ceramic composite and dried. Thereafter, the external electrode 4 is formed by firing at a high temperature of 500 to 900 ° C.
- the second method is to apply a thermosetting conductive paste in which conductive particles such as silver powder are mixed with a thermosetting resin to the take-out surface of the internal electrode 3 of the multilayer ceramic composite, and then heat at a low temperature of 150 to 250 ° C.
- This is a method of forming the external electrode 4 by curing (see, for example, Patent Document 1).
- thermosetting conductive paste obtained by mixing a thermosetting resin with a thermally decomposable organometallic material such as silver acetate and conductive particles such as silver powder is applied to the extraction surface of the internal electrode 3 of the multilayer ceramic composite.
- thermosetting is a method of forming the external electrode 4 by thermosetting at 350 ° C. after application (see, for example, Patent Document 2).
- the fourth method is to apply a thermosetting conductive paste containing a high melting point conductive particle and a metal powder having a melting point of 300 ° C. or less to a thermosetting resin on the take-out surface of the internal electrode 3 of the multilayer ceramic composite, and then apply 80-400
- the external electrode 4 is formed by thermosetting at a low temperature of 0 ° C. (see, for example, Patent Document 3).
- plating 5 is applied to the electrode layer surface as necessary in order to increase the adhesive strength when the obtained capacitor element is soldered and mounted on a substrate or the like.
- the surface of the external electrode is subjected to nickel plating by electrolytic plating using a Watt bath or the like, and then further subjected to solder plating or Sn plating by electrolytic plating.
- the glass frit component in the conductive paste diffuses inside the capacitor element at the time of high-temperature firing, which causes cracks when soldering and mounting on the substrate. There is a bug. Furthermore, there is a problem in the reliability of the capacitor performance such that the plating solution permeates into the sintered body during the plating process, so that the capacitance is lower than the design value or the insulation resistance is deteriorated.
- the capacitor having an external electrode obtained by the second method can solve the problems at the time of mounting on the above-mentioned substrate or plating treatment, but since the curing temperature is low, the silver powder in the conductive paste, etc. The solid phase diffusion of the metal between the conductive particles and the internal electrode does not proceed, and the designed electrical characteristics such as capacitance due to poor bonding between the internal and external electrodes cannot be obtained, resulting in poor reliability.
- the capacitor having an external electrode obtained by the third method has problems such as the paste life shortened due to the added silver acetate and amine, and the insulation deterioration in the moisture-resistant life occurs.
- capacitors with external electrodes obtained by the fourth method have a higher solder reflow temperature when mounting electronic components on the board due to the recent lead-free movement due to the lead problem. There is a possibility of solder explosion due to remelting of the metal powder.
- An object of the present invention is to solve the above-described problems of the prior art in the formation of external electrodes and the subsequent plating process. In other words, it solves the problem of the bondability of the inner and outer electrodes of the thermosetting conductive paste, can provide good electrical characteristics (tan ⁇ ) and high reliability (heat cycle resistance, moisture resistance), and can be applied to the plating process.
- An object of the present invention is to provide a thermosetting conductive paste capable of forming a suitable external electrode, and a multilayer ceramic electronic component having an external electrode formed using the same.
- the present invention includes (A) 45 to 85 parts by weight of silver powder having an average particle diameter of 0.2 to 30 ⁇ m, and (B) 5 to 35 parts by weight of tin silver alloy powder having an average particle diameter of 0.2 to 15 ⁇ m. (C) 5 to 25 parts by weight of silver and / or silver tin alloy fine powder having an average particle size of 15 to 150 nm, (D) 6 to 18 parts by weight of a thermosetting resin, and component (A) It is related with the thermosetting electrically conductive paste whose sum total of a component (B) and a component (C) is 100 weight part.
- the present invention also relates to a multilayer ceramic electronic component having an external electrode formed using the thermosetting conductive paste.
- thermosetting conductive paste of the present invention By curing the thermosetting conductive paste of the present invention, it has excellent jointability between internal and external electrodes, has good electrical properties (tan ⁇ ) and high reliability (heat cycle resistance, moisture resistance), and is suitable for plating treatment An external electrode of the laminated ceramic electronic component is provided.
- the present invention 45 to 85 parts by weight of silver powder having an average particle diameter of 0.2 to 30 ⁇ m, 5 to 35 parts by weight of tin silver alloy powder having an average particle diameter of 0.2 to 15 ⁇ m, and an average particle diameter
- the metal powder in the conductive paste and the metal powder and the internal electrode in the conductive paste are formed during the formation of the external electrode. As a result, it is considered that good inner and outer electrode joining properties and electrical characteristics can be obtained.
- a multilayer ceramic electronic component having good electrical characteristics (tan ⁇ ) and high reliability (heat cycle resistance, moisture resistance) on which the external electrode is formed.
- thermosetting conductive paste of the present invention comprises (A) 45 to 85 parts by weight of silver powder having an average particle size of 0.2 to 30 ⁇ m, and (B) a tin-silver alloy having an average particle size of 0.2 to 15 ⁇ m. 5 to 35 parts by weight of powder, (C) 5 to 25 parts by weight of silver and / or silver tin alloy fine powder having an average particle diameter of 15 to 150 nm, and (D) 6 to 18 parts by weight of thermosetting resin
- the total of component (A), component (B) and component (C) is 100 parts by weight.
- the specific resistance of the thermosetting conductive paste after curing can be reduced by blending the component (A).
- the shape of the component (A) may be any shape such as a spherical shape, a flake shape, a flake shape, and a needle shape.
- the average particle size of the component (A) is preferably 0.2 to 30 ⁇ m, preferably 0.2 to 30 ⁇ m, because it gives an excellent surface state after printing or coating and gives excellent conductivity to the formed electrode. Is more preferable. Moreover, it is preferable to use spherical and flaky silver particles in combination from the viewpoints of conductivity and printing or coating.
- the average particle diameter is the particle diameter in the case of a sphere, the diameter of the longest part in the case of flakes, the long diameter of the particle flakes in the case of flakes, and the length in the case of needles, respectively. Mean means. Unless otherwise specified, the average particle diameter of the metal particles is a value obtained by image analysis through observation with a scanning electron microscope (SEM).
- Component (A) is composed of spherical silver powder having an average particle size of 0.2 to 5 ⁇ m and flaky silver powder having an average particle size of 5 to 30 ⁇ m in a weight of 99: 1 to 75:25 from the viewpoint of conductivity. It is particularly preferred to include by ratio.
- thermosetting conductive paste By blending the component (B), the component (A) and / or the component (C) of the thermosetting conductive paste and the internal electrode of the multilayer ceramic electronic component, the component (A) and the component of the thermosetting conductive paste Diffusion between (C) is achieved.
- the shape of the component (B) may be any shape such as a spherical shape, a flake shape, a flake shape, and a needle shape.
- a spherical shape a shape such as a spherical shape, a flake shape, a flake shape, and a needle shape.
- the average particle size of the component (B) is 0.2 to 15 ⁇ m, oxidation prevention and conductivity are achieved.
- the weight ratio of tin and silver as the component (B) is preferably 89:11 to 25.5: 74.5, particularly preferably 89:11 to 50:50, from the viewpoint of connectivity with the internal electrode.
- the tin-silver alloy contains 50% by weight or more of tin.
- the component (B) may be a three or more component system containing 5% by weight or less of Cu, In, Bi, Ni and the like within a range where the melting point does not become 500 ° C. or higher.
- component (C) promotes the formation of an Sn—Ni—Ag intermetallic compound at the interface between the external electrode formed of the thermosetting conductive paste of the present invention and the ceramic composite, and provides good electrical properties. It is considered that characteristics (tan ⁇ ) and high reliability (heat cycle resistance, moisture resistance) can be obtained. In particular, the coexistence of component (A) and component (C) enables low resistance, good electrical properties (tan ⁇ ) and high reliability (heat cycle resistance) of the thermosetting conductive paste after curing. , Moisture resistance) is assumed to be achieved.
- the shape of the component (C) is preferably spherical, flake shaped, needle shaped or the like.
- Component (C) preferably contains silver tin alloy fine powder in which silver is 25.5 wt% or more and less than 100 wt% from the viewpoint of oxidation prevention and diffusibility, and silver is 50 wt% or more and less than 100%. Certain silver tin alloy fine powders are particularly preferred. Thus, it is particularly preferable that the silver tin alloy fine powder contains 50% by weight or more of silver.
- Component (C) may be a system of three or more components containing 5% by weight or less of Cu, In, Bi, Ni and the like.
- the component (C) promotes diffusion between the component (A) and / or the component (B) and the internal electrodes of the multilayer ceramic electronic component, and diffusion between the component (A) and the component (B).
- the average primary particle size is 40 to 150 nm, preferably 50 to 150 nm
- the crystallite size is 15 to 50 nm, preferably 20 to 50 nm
- (c) relative to the crystallite size It is preferable to use silver fine powder having an average particle size ratio of 1 to 10, preferably 1 to 7.5.
- the crystallite size was calculated from the Scherrer equation by obtaining the half-value width of the plane index (1,1,1) plane peak from the measurement by the powder X-ray diffraction method using Cu K ⁇ ray as the radiation source. Say.
- the above-mentioned silver fine powder and silver tin alloy fine powder can be produced by a usual wet reduction method, vapor phase method, or the like, or a commercially available product can be purchased.
- the silver fine powder is prepared by mixing a silver salt of a carboxylic acid and an aliphatic primary amine in the presence or absence of an organic solvent, and then adding a reducing agent at a reaction temperature of 20 to 80 ° C. It is obtained by reacting to deposit silver fine powder.
- the silver salt of carboxylic acid is not particularly limited, but is preferably a silver salt of an aliphatic monocarboxylic acid, and more preferably silver acetate, silver propionate or silver butyrate. These can be used alone or in combination of two or more.
- the aliphatic primary amine is not particularly limited, but may be a chain aliphatic primary amine or a cyclic aliphatic primary amine. 3-methoxypropylamine, 3-aminopropanol or 1,2-diaminocyclohexane is preferred. These can be used alone or in combination of two or more.
- the amount of the aliphatic primary amine used is preferably 1 equivalent or more with respect to 1 equivalent of the silver salt of the carboxylic acid. Considering the influence of excess aliphatic primary amine on the environment, etc., 1 It is preferably 0.0 to 3.0 equivalents, more preferably 1.0 to 2.0 equivalents, still more preferably 1.0 to 1.5 equivalents, and particularly preferably 1.0 to 1.1 equivalents. .
- the silver salt of carboxylic acid and the aliphatic primary amine can be mixed in the absence or presence of an organic solvent.
- the organic solvent include alcohols such as ethanol, propanol, and butanol, and propylene glycol diester.
- examples thereof include ethers such as butyl ether and aromatic hydrocarbons such as toluene. These can be used alone or in combination of two or more.
- the amount of the organic solvent used can be set to an arbitrary amount from the viewpoint of convenience of mixing and productivity of silver fine powder in the subsequent steps.
- the mixing of the silver salt of the carboxylate and the aliphatic primary amine is preferably carried out while maintaining the temperature at 20 to 80 ° C., more preferably 20 to 60 ° C.
- formic acid As the reducing agent, formic acid, formaldehyde, ascorbic acid or hydrazine is preferable from the viewpoint of control of the reaction, and formic acid is more preferable. These may be used alone or in combination of two or more.
- the amount of the reducing agent used is usually not less than the redox equivalent relative to the silver salt of the carboxylic acid, and the redox equivalent is preferably 0.5 to 5 times, more preferably 1 to 3 times.
- the amount of formic acid used in terms of mole is 0.5 to 1 with respect to 1 mol of the silver salt of carboxylic acid.
- the amount is preferably 0.5 mol, more preferably 0.5 to 1.0 mol, still more preferably 0.5 to 0.75 mol.
- the temperature is maintained at 20 ° C. to 80 ° C., preferably 20 to 70 ° C., more preferably 20 to 60 ° C.
- the fine silver powder precipitated by the reaction can be allowed to settle and the supernatant can be removed by decantation or the like, or a solvent such as alcohol such as methanol, ethanol, terpineol can be added and fractionated.
- a solvent such as alcohol such as methanol, ethanol, terpineol can be added and fractionated.
- thermosetting resin of component (D) functions as a binder and has amino resins such as urea resin, melamine resin, and guanamine resin; bisphenol A type, bisphenol F type, phenol novolac type, and benzene ring.
- amino resins such as urea resin, melamine resin, and guanamine resin; bisphenol A type, bisphenol F type, phenol novolac type, and benzene ring.
- phenolic resins such as: silicone epoxy, silicone-modified organic resins such as silicone polyester, bismaleimide, polyimide resins and the like.
- BT resin can also be used.
- an epoxy resin is preferable, and a bifunctional or higher functional epoxy resin is more preferable.
- the 1,1,2,2-tetrakis (hydroxyphenyl) ethane type epoxy resin represented by the formula is particularly preferred. These resins may be used alone or in combination of two or more.
- a resin that is liquid at room temperature because the amount of the organic solvent used as a diluent can be reduced.
- a liquid resin include a liquid epoxy resin and a liquid phenol resin.
- a resin that is compatible with these liquid resins and that exhibits a solid or ultra-high viscosity at room temperature may be further added and mixed within a range in which the mixed system exhibits fluidity.
- Such resins include high molecular weight bisphenol A type epoxy resins, diglycidyl biphenyls, novolac type epoxy resins, tetrabromobisphenol A type epoxy resins; resol type phenol resins, novolac type phenol resins, aralkyl novolac types A phenol resin etc. are illustrated.
- the curing mechanism may be a self-curing resin, a curing agent or a curing catalyst such as amines, imidazoles, acid anhydrides or onium salts, amino resin or phenol
- the resin may function as a curing agent for the epoxy resin. From the viewpoint of storage stability, 2-phenyl-4-methyl-5-hydroxymethylimidazole is particularly preferable.
- the epoxy resin used for the thermosetting conductive paste is preferably cured by a phenol resin.
- the phenol resin may be a phenol resin initial condensate usually used as a curing agent for an epoxy resin, and may be a resol type or a novolac type, but in order to obtain excellent heat cycle resistance, 50% by weight or more thereof. Is preferably an alkyl resol type, alkyl novolak type, aralkyl novolak type phenol resin, xylene resin or allyl phenol resin.
- An aralkyl novolak type phenol resin which is a phenol / p-xylylene glycol dimethyl ether polycondensate represented by the formula (wherein n is 0 to 300) is also preferred.
- the average molecular weight is preferably 2,000 or more in order to obtain excellent printability.
- alkylresole type or alkyl novolac type phenol resins alkyl groups having 1 to 18 carbon atoms can be used, and carbons such as ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl and decyl can be used. Those of formula 2 to 10 are preferred.
- tetrakis (hydroxyphenyl) ethane type epoxy resin and aralkyl novolac type phenol resin since excellent adhesiveness is obtained and heat resistance is excellent, tetrakis (hydroxyphenyl) ethane type epoxy resin and aralkyl novolac type phenol resin, resol type phenol resin, xylene resin or allyl phenol resin
- the combination of 1,1,2,2-tetrakis (hydroxyphenyl) ethane type epoxy resin and aralkyl novolac type phenol resin, resol type phenol resin, xylene resin or allyl phenol resin is particularly preferable.
- the weight ratio of epoxy resin to phenol resin is 4: 1 to 1: The range of 4 is preferable, and 4: 1 to 1: 2 is more preferable.
- polyimide resin is also effective from the viewpoint of heat resistance.
- thermoplastic resin may be used in combination with the thermosetting resin as long as the effects of the present invention are not impaired.
- thermoplastic resin polysulfone, polyethersulfone, maleimide resin and the like are preferable.
- the present invention relates to 45 to 85 parts by weight of component (A), 5 to 35 parts by weight of component (B), 100 parts by weight of component (A), component (B) and component (C). (C) 5 to 25 parts by weight and 6 to 18 parts by weight of component (D), thereby ensuring the printability of the thermosetting paste, the conductivity of the resulting external electrode layer, and the bondability of the internal and external electrodes.
- the total of 100 parts by weight of component (A), component (B) and component (C), Component (B) is particularly preferably 15 to 25 parts by weight.
- the total of 100 parts by weight of component (A), component (B) and component (C), Component (C) is particularly preferably 7 to 15 parts by weight.
- the component (D) is preferably 8 to 8 parts per 100 parts by weight of the total of the component (A), the component (B), and the component (C).
- the amount is preferably 15 parts by weight.
- thermosetting conductive paste is selected from the types and amounts of the components (A), (B), (C) and (D), and if necessary, a diluent is used to make a ceramic composite of the desired electronic component.
- a diluent is used to make a ceramic composite of the desired electronic component.
- the apparent viscosity of the conductive paste at room temperature is preferably 10 to 500 Pa ⁇ s, more preferably 15 to 300 Pa ⁇ s.
- an organic solvent is used, and the organic solvent is selected according to the type of resin, and the amount used is the type of components (A), (B), (C) and (D) used and the amount thereof. It is arbitrarily selected depending on the composition ratio and the method of printing or applying the conductive paste.
- Organic solvents include aromatic hydrocarbons such as toluene, xylene, mesitylene, and tetralin; ethers such as tetrahydrofuran; ketones such as methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, and isophorone; 2-pyrrolidone, 1-methyl Lactones such as -2-pyrrolidone; ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, and the corresponding propylene glycol derivatives Ether alcohols; corresponding esters such as acetates; and dicarboxylic acids such as malonic acid and succinic acid Methyl esters of carboxylic acids, diesters, such as ethyl esters are exemplified. The amount of the
- thermosetting conductive paste In addition to the thermosetting conductive paste, an aluminum chelate compound such as diisopropoxy (ethylacetoacetate) aluminum; a titanate ester such as isopropyltriisostearoyl titanate, if necessary, as a dispersion aid Aliphatic polycarboxylic acid ester; unsaturated fatty acid amine salt; surfactant such as sorbitan monooleate; or polymer compound such as polyesteramine salt and polyamide. Moreover, you may mix
- thermosetting conductive paste can be prepared by uniformly mixing the compounding components by a mixing means such as a reika machine, a propeller stirrer, a kneader, a roll, and a pot mill.
- the preparation temperature is not particularly limited, but for example, it can be prepared at room temperature and 20 to 30 ° C.
- thermosetting conductive paste Using the thermosetting conductive paste thus obtained, a multilayer ceramic electronic component having external electrodes can be formed according to a known method.
- the thermosetting conductive paste is printed or applied to the internal electrode take-out surface of the ceramic composite of the multilayer ceramic capacitor by an arbitrary method such as screen printing, transfer, or dip coating.
- the thickness of the external electrode after curing is preferably printed or applied to a thickness of 1 to 300 ⁇ m, more preferably 20 to 100 ⁇ m.
- an organic solvent it is dried at room temperature or by heating after printing or coating.
- curing can be performed at 80 to 450 ° C., specifically at 200 to 350 ° C.
- thermosetting conductive paste of the present invention is simple because it does not need to be placed in an inert gas atmosphere during curing.
- the curing time can be changed depending on the curing temperature or the like, but is preferably 1 to 60 minutes from the viewpoint of workability. However, in the case of curing at 250 ° C. or lower, it is preferably 10 to 60 minutes from the viewpoint of bondability with the internal electrode.
- the resin in the paste is an epoxy resin using a phenol resin as a curing agent
- the external electrode can be obtained by curing at 200 to 350 ° C. for 10 to 60 minutes.
- rapid heating for example, rapid heating to 300 ° C. or higher.
- the temperature of the ceramic composite is the same as the temperature of the alumina substrate when a K-type thermocouple is fixed with a polyimide tape on an alumina substrate having a width of 20 mm, a length of 20 mm, and a thickness of 1 mm, and placed in a reflow furnace. did.
- the holding time was the time after the temperature of the alumina substrate reached the holding temperature.
- the ceramic composite of the multilayer ceramic electronic component used in the present invention may be produced by any known method.
- the ceramic composite refers to a sintered body in which ceramic layers and internal electrode layers are alternately laminated, or a laminated body in which resin / ceramic hybrid materials and internal electrodes are alternately laminated.
- the ceramic layer or the resin / ceramic hybrid material has properties suitable for the desired electronic component, for example, a capacitor having dielectric properties, and may be obtained by any known method.
- the internal electrode layer is not particularly limited, but a base metal that is inexpensive and easily available, such as nickel or copper, is preferably used as the internal electrode.
- the surface of the internal electrode of the ceramic composite preferably contains nickel, and a ceramic composite in which the internal electrode is nickel is particularly preferable.
- the multilayer ceramic electronic component of the present invention may be, for example, a capacitor, a capacitor array, a thermistor, a varistor, an inductor, and an LC, CR, LR and LCR composite component.
- the obtained multilayer ceramic electronic component is plated on the electrode layer surface as necessary in order to further increase the adhesive strength when soldered and mounted on a substrate or the like.
- the plating process is performed according to a known method, but it is preferable to perform lead-free plating in consideration of the environment.
- the surface of the external electrode is subjected to nickel plating by electrolytic plating such as a Watt bath or electroless plating, and then further subjected to solder plating or tin plating by electrolytic plating or electroless plating.
- the multilayer ceramic electronic component obtained by plating the surface of the external electrode formed of the thermosetting conductive paste of the present invention thus obtained is excellent in electrical characteristics such as bondability of the internal and external electrodes, and can be used for circuit boards and the like. It is useful for the implementation of.
- the manufacturing method of the silver fine powder with an average particle diameter of 130 nm in Table 1 is as follows. In a 10 L glass reaction vessel, 3.0 kg (30.9 mol) of 3-methoxypropylamine was placed. While stirring, the reaction temperature was kept at 45 ° C. or lower, and 5.0 kg (30.0 mol) of silver acetate was added. Immediately after the addition, the solution became a transparent solution and dissolved, but as the addition proceeded, the solution gradually became turbid. To this, 1.0 kg (21.0 mol) of 95% by weight formic acid was slowly added dropwise. Vigorous exotherm was observed immediately after the addition, and during that time, the reaction temperature was maintained at 30-45 ° C.
- the turbid viscous solution changed from brown to black.
- the reaction was terminated after the entire amount was added dropwise.
- the reaction mixture was allowed to stand at 40 ° C. and separated into two layers.
- the upper layer is a yellow transparent liquid, and black silver fine particles settled in the lower layer.
- the upper layer liquid did not contain a silver component.
- the upper layer liquid was removed by decantation, and the layers were separated using methanol to obtain a true spherical fine silver powder having a silver content of 89% by weight.
- the average particle diameter is an average value of Haywood diameters obtained by image analysis by observing with a scanning electron microscope (SEM), and the crystallite diameter is determined by an X-ray diffractometer (M18XHF22) manufactured by Mac Science.
- SEM scanning electron microscope
- M18XHF22 X-ray diffractometer
- the half-value width of the plane index (1, 1, 1) plane peak using Cu K ⁇ ray as a radiation source is obtained by measurement, and is a value calculated from the Scherrer equation.
- the production methods of silver fine powder having an average particle diameter of 30 nm and 80 nm and silver tin fine powder having an average particle diameter of 30 nm in Table 1 are as follows.
- the inside of the plasma reaction chamber was depressurized and replaced with an argon atmosphere, and then the pressure was adjusted to 500 Torr to generate an RF plasma flame.
- argon as carrier gas, a silver foil or silver tin foil with a thickness of 5 ⁇ m and a width of 10 mm is continuously fed into the reaction chamber from the insertion port while cooling the insertion port at a supply rate of 1 to 3 g / min. Supplied.
- Silver or silver tin evaporated in the plasma flame recondensed outside the plasma flame to form fine silver or silver tin powder.
- the resulting silver or silver tin fine powder was sent together with a carrier gas to a collection cylinder and collected by a filter.
- the obtained silver or silver tin fine powder was spherical.
- Silver or silver tin fine powder having an average particle diameter of 30 nm and 80 nm was produced by changing the supply speed of the raw material foil.
- the capacitance of Comparative Example 6 was 9.07 ⁇ F.
- the initial dielectric loss tangent of Examples 1 to 13 was 3.2 to 3.9%.
- the dielectric loss tangents of Comparative Examples 1, 2, 6, and 7 were 4.9, 4.5, 6.1, and 4.3%, respectively.
- the dielectric loss tangent after the moisture resistance test was 3.2 to 4.0%.
- the dielectric loss tangent after the heat cycle test of Comparative Examples 1, 2, 6, and 7 is 5.1, 4.6, 6.2, and 4.5, and the dielectric loss tangent after the moisture resistance test is 5.1. 4.8, 6.4, and 4.7%.
- FIG. 4 shows the cross section of the sample of Comparative Example 1 in the same manner as FIG. In part (a) of FIG.
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Abstract
Description
実施例及び比較例で使用した導電ペーストの組成(表中の数字は、断りのない限り重量部である)は、以下の表1のとおりである。なお、成分(C)は、金属換算の重量部を示す。
得られた銀微粉末は次のとおり。平均粒子径130nm、結晶子径40nm、平均粒子径/結晶子径=3.25。ここで、平均粒子径は、走査型電子顕微鏡(SEM)で観察して画像解析により求めたヘイウッド径の平均値であり、結晶子径は、マックサイエンス社製X線回折測定装置(M18XHF22)による測定によって、CuのKα線を線源とした面指数(1,1,1)面ピークの半値幅を求め、Scherrerの式より計算した値である。
表1に示した組成を有する導電ペーストを、チップ積層コンデンサのセラミック複合体(3216タイプ、B特性、ニッケル内部電極、理論容量10μF)の内部電極取り出し面に、硬化後の厚さが90μm程度になるようにesi社製パロマ印刷機(型番:MODEL2001)で均一に浸漬塗布した後に、塗布面の凹凸を光学顕微鏡にて10倍で観察した。図2に示すように、膜厚A中の中央部の凸部の厚さBが、25μm未満の場合を○、25~30μmの場合を△、30μmより厚い場合を×とした。実施例1~13は、○であった。比較例3は△、比較例4、5は×であった。
表1に示した組成を有する導電ペーストを、チップ積層コンデンサのセラミック複合体(3216タイプ、B特性、ニッケル内部電極、理論容量10μF)の内部電極取り出し面に、硬化後の厚さが90μm程度になるようにesi社製パロマ印刷機(型番:MODEL2001)で均一に浸漬塗布し、150℃で30分間乾燥した後、リフロー炉で大気中、300℃、40分間硬化を行い外部電極を形成した。続いてワット浴でニッケルメッキを行い、次いで電解メッキによりスズメッキを行い、チップ積層コンデンサを得た。
幅20mm、長さ20mm、厚さ1mmのアルミナ基板上に、250メッシュのステンレス製スクリーンを用い、長さ71mm、幅1mm、厚さ20μmのジグザグパターン印刷を行い、150℃で10分乾燥後、大気中で300℃、40分間硬化させ、外部電極を形成した。ジグザグパターンの厚さは、東京精密製表面粗さ形状測定機(製品名:サーフコム1400)にて、パターンと交差するように測定した6点の数値の平均より求めた。硬化後に、LCRメーターを用い、4端子法で比抵抗を測定した。結果を表2に示す。実施例1~13は、0.3~2.7×10-4Ω・cmであった。比較例7は、3.7×10-4Ω・cmであった。
上記で得られたチップ積層コンデンサ素子の初期の静電容量、誘電正接(tanδ)をAgilent製4278Aを用い、室温にて周波数1kHzで測定した。次に、-55℃で30分、耐ヒートサイクル試験(―55℃/125℃(30分/30分);750サイクル)、及び耐湿性試験(プレッシャークッカーテスト:2気圧で121℃(20時間))後の電気特性を初期の特性と同様に測定した。結果を表2に示す。実施例1~13の静電容量は、9.89~10.40μFであった。比較例6の静電容量は、9.07μFであった。また、実施例1~13の初期の誘電正接は、3.2~3.9%であった。比較例1、2、6、7の誘電正接は、それぞれ4.9、4.5、6.1、4.3%であった。実施例1~13の耐ヒートサイクル試験後、耐湿性試験後の誘電正接は、3.2~4.0%であった。比較例1、2、6、7の耐ヒートサイクル試験後の誘電正接は、5.1、4.6、6.2、4.5であり、耐湿性試験後の誘電正接は、5.1、4.8、6.4、4.7%であった。
幅20mm、長さ20mm、厚さ1mmのアルミナ基板上に、250メッシュのステンレス製スクリーンを用い、縦5個×横5個の幅1.5mm、長さ1.5mm、厚さ25μmのパターン印刷を行い、そのパターン上に任意に10個の3216サイズのアルミナチップを載せた。150℃で10分乾燥後、大気中で300℃、40分間硬化させ、外部電極を形成した。硬化後に、外部電極の基板との接合強度(せん断強度)をアイコーエンジニアリング製卓上強度試験機(型番:1605HTP)で、荷重速度12mm/分で測定した。結果を表2に示す。実施例1~13は、2.4~3.7kN/cm2であった。
静電容量の測定で使用した試料の断面を、日本電子株式会社製FE-SEM(型番:JSM-7500F)で反射電子像観察、及びEDS分析を行い、熱硬化性導電ペーストで形成された層とチップ積層コンデンサのセラミック複合体の界面部分を観察した。図3は、実施例2の試料の断面の(a)反射電子像、(b)Agの分布図、(c)Snの分布図、(d)Niの分布図、(e)Tiの分布図、及び(f)Baの分布図を示す。図4は、比較例1の試料の断面を、図3と同様に示したものである。図3のアの部分で、熱硬化性導電ペースト由来の銀、スズとセラミック複合体のNiが拡散し、Sn-Ag-Ni化合物を形成していることを確認した。定量分析の結果、Sn:Ag:Niの重量比は、64.6:6.1:29.3であった。このSn-Ag-Ni化合物により、本発明の熱硬化性導電ペーストで形成された外部電極を有するセラミック複合体の低抵抗、高静電容量、低誘電正接、及び高接合強度が得られていると推測される。これに対して、図4のイの部分ではSn:Ag:Niの重量比は、54.1:0:45.9であり、Sn-Ag-Ni化合物は生成していなかった。
2 セラミック誘電体
3 内部電極層
4 外部電極層
5 メッキ処理層
6 熱硬化性導電ペースト
Claims (14)
- (A)平均粒子径が0.2~30μmである銀粉末45~85重量部と、(B)平均粒子径が0.2~15μmであるスズ銀合金粉末5~35重量部と、(C)平均粒子径が15~150nmである銀及び/又は銀スズ合金微粉末5~25重量部と、(D)熱硬化性樹脂6~18重量部を含み、成分(A)と成分(B)と成分(C)の合計が100重量部である熱硬化性導電ペースト。
- 成分(C)が、銀が25.5重量%以上100重量%未満である銀スズ合金微粉末を含む、請求項1記載の熱硬化性導電ペースト。
- 成分(B)のスズと銀の重量比が、89:11~25.5:74.5である、請求項1又は2記載の熱硬化性導電ペースト。
- 成分(A)が、平均粒子径0.2~5μmの球状の銀粉末と、平均粒子径5~30μmのフレーク状の銀粉末を、99:1~75:25の重量比で含む、請求項1~3のいずれか1項記載の熱硬化性導電ペースト。
- 成分(C)が、
(a)1次粒子の平均粒子径が50~150nmであり、
(b)結晶子径が20~50nmであり、かつ
(c)結晶子径に対する平均粒子径の比が1~7.5である、
請求項1~4のいずれか1項記載の熱硬化性導電ペースト。 - 成分(D)が、エポキシ樹脂を含む、請求項1~5のいずれか1項記載の熱硬化性導電ペースト。
- セラミック複合体と外部電極を含む積層セラミック電子部品の外部電極形成用の、請求項1~7のいずれか1項記載の熱硬化性導電ペースト。
- 請求項1~8のいずれか1項記載の熱硬化性導電ペーストを用いて形成した外部電極を有する積層セラミック電子部品。
- (1)請求項1~8のいずれか1項記載の熱硬化性導電ペーストと、外部電極を設けようとするセラミック複合体を準備し;
(2)セラミック複合体の内部電極取り出し面に、熱硬化性導電ペーストを印刷又は塗布し、場合により乾燥させ;そして
(3)(2)で得られたセラミック複合体を、200~350℃で、10~60分間保持し、外部電極を形成する
ことにより得られる、積層セラミック電子部品。 - 外部電極とセラミック複合体の界面にSn-Ag-Ni化合物を有する、請求項9又は10記載の積層セラミック電子部品。
- セラミック複合体の内部電極がニッケルを主成分とする、請求項9~11のいずれか1項記載の積層セラミック電子部品。
- 外部電極の表面に、更にニッケル層を形成し、次いでスズ層を形成した、請求項9~12のいずれか1項記載の積層セラミック電子部品。
- 積層セラミック電子部品が、コンデンサ、コンデンサアレイ、サーミスタ、バリスター、インダクタ並びにLC、CR、LR及びLCR複合部品のいずれかである、請求項9~13のいずれかに1項記載の積層セラミック電子部品。
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JP2018060941A (ja) * | 2016-10-06 | 2018-04-12 | デュポンエレクトロニクスマテリアル株式会社 | 接合用の導電性ペースト |
US11817251B2 (en) | 2017-03-02 | 2023-11-14 | Samsung Electro-Mechanics Co., Ltd. | Electronic component |
US11183325B2 (en) * | 2017-03-02 | 2021-11-23 | Samsung Electro-Mechanics Co., Ltd. | Electronic component |
US11302480B2 (en) * | 2019-07-22 | 2022-04-12 | Tdk Corporation | Ceramic electronic device with varying roughness terminal electrode |
CN112992539A (zh) * | 2019-12-12 | 2021-06-18 | 三星电机株式会社 | 多层陶瓷电子组件及其制造方法 |
WO2023237344A1 (de) * | 2022-06-09 | 2023-12-14 | Tdk Electronics Ag | Verfahren zur herstellung eines vielschicht-varistors, verwendung einer metallpaste zur bildung von metallschichten, grünkörper zur herstellung eines vielschicht-varistors und vielschicht-varistor |
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KR101559605B1 (ko) | 2015-10-13 |
JPWO2009098938A1 (ja) | 2011-05-26 |
KR20100110891A (ko) | 2010-10-13 |
JP5390408B2 (ja) | 2014-01-15 |
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