WO2008084838A1 - 溶接部耐食性および鋼板の靭性に優れた温水器用フェライト系ステンレス鋼板 - Google Patents
溶接部耐食性および鋼板の靭性に優れた温水器用フェライト系ステンレス鋼板 Download PDFInfo
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- WO2008084838A1 WO2008084838A1 PCT/JP2008/050224 JP2008050224W WO2008084838A1 WO 2008084838 A1 WO2008084838 A1 WO 2008084838A1 JP 2008050224 W JP2008050224 W JP 2008050224W WO 2008084838 A1 WO2008084838 A1 WO 2008084838A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
Definitions
- the present invention relates to a stainless steel sheet, a ferritic stainless steel sheet for water heaters, which is excellent in corrosion resistance, in particular, the corrosion resistance of welds and the toughness of steel sheets. 1 ) Background
- Ferritic stainless steel such as JIS (Japanese Industrial Standards) -SUS44 is more sensitive to stress corrosion cracking (SCC) than austenitic stainless steel. Since it has the characteristic of low temperature, it is used as a material for electric water heaters. '
- corrosion resistance is improved by reducing P and S, C and N using a high purity refining technique.
- a method for improving the above is disclosed.
- JP-A-10-81940 the amount of Ti added is limited and Ti and A1 are combined.
- a technique for improving the corrosion resistance of welds by adding an appropriate amount of Cu is disclosed.
- Japanese Patent Laid-Open No. 7-286239 describes a ferrite containing ll% ⁇ Cr ⁇ 35% with a quality of 3 ⁇ 4% and C ⁇ 0.03%, ⁇ 0 ⁇ 025% and 0 ⁇ 0.02%.
- Stainless steel, the oxygen and nitrogen concentrations of the laser welding portion are 250 ppm or less and 350 ppm or less, respectively, and the precipitated carbides and nitrides have an average particle size.
- Japanese Patent Laid-Open No. 2005-15816 states that quality *%, C ⁇ 0.003%, 0.1 %% Si ⁇ 0.4% Mn ⁇ 0.4%, P ⁇ 0.04%, S ⁇ 0.01%, 16.0% ⁇ Cr ⁇ 25.0%, 0.8% ⁇ o ⁇ 2.5%, N ⁇ 0.03%, 0.1% ⁇ Nb ⁇ 0.6%, 0 05% ⁇ Ti ⁇ 0. 3%, 0. 01% ⁇ A1 ⁇ 0. 5%, and Nb + Ti ⁇ 7 (C + N) +0.15 between Nb, Ti, C and N
- the water heater with excellent corrosion resistance is composed of a ferritic stainless steel plate, the balance of which is substantially made of Fe, and the body and upper and lower end panels (barrelhead) are caulking joints.
- Japanese Patent Laid-Open No. 2006-257544 discloses that in mass%, 0.001% ⁇ C ⁇ 0.02%, 0.001% ⁇ N ⁇ 0 ⁇ 02%, 0.01% ⁇ Si ⁇ 0.3. % 0. 05% ⁇ Mn ⁇ l%, P ⁇ 0. 04% 0. 15% ⁇ Ni ⁇ 3%, ll% ⁇ Cr ⁇ 22%, 0. 01% ⁇ Ti ⁇ 0. 5%, 0. 0002 Including% ⁇ Mg ⁇ 0.002%, 0.5% ⁇ Mo ⁇ 3.0%, 0.02% ⁇ Nb ⁇ 0.6%, 0.l% ⁇ Cu ⁇ 1.5.
- One or more of Mo, Nb and Cu Ferritic stainless steel is disclosed that includes Cr + 3Mo + 6 (Ni + Nb + Cu) ⁇ 23, with the balance being Fe and unavoidable impurities and excellent crevice corrosion resistance. . Disclosure of the invention
- the present invention provides a ferritic stainless steel sheet for water heaters that has sufficient toughness and has sufficient corrosion resistance of welds even when the concentration of chlorine increases.
- Objective. In order to solve the above problems, the present inventors have conducted a thorough investigation on the influence of the chemical composition of steel on the corrosion resistance of the base metal part and the welded part, and the influence of the chemical composition of steel on the manufacturability of the steel sheet. , Study was carried out.
- TIG welding Tungsten Inert Gas welding
- the inert gas on both the front and back of the weld Shield with an inert gas and make sure that the welds do not stick to the temper color (oxide layer).
- this gas shield is not sufficient, oxygen in the air is slightly mixed in, and the tempering force is applied to the bead on the surface of the weld or the bead on the back surface. A called oxide film forms on the weld.
- this oxide film consumes the Cr of the base metal, lowers the Cr concentration of the base metal directly under the oxide film, and becomes the main cause of deterioration in corrosion resistance.
- the maximum heating temperature is less than 800-1000
- the generated oxide film has a low generation speed of Cr oxide, and the base material is moved to the surface of the steel plate. It is relatively unaffected by the rapid diffusion of Cr.
- the oxide film formed at less than 800 ° C has a low Cr oxide generation rate, but the Cr diffusion from the base metal to the copper plate surface is slow. Corrosion resistance deteriorates.
- this temperature range it was found that by selectively forming an oxide of Si and an oxide of A1, it becomes a high density protective coating and the deterioration of corrosion resistance can be reduced.
- the toughness of the hot-rolled sheet is significantly deteriorated with a slight addition of Ti. Even if the Cr concentration is increased, by adding Nb alone as a C and N fixing element, it is possible to manufacture a steel plate without reducing the productivity of the steel plate (steel strip).
- the corrosion resistance of the weld is greatly affected by the oxide film produced during welding and the base material directly under the oxide film.
- Corrosion resistance of welds can be controlled by selective formation of A1 oxide and Si oxide.
- Addition of Ti and Nb improves the corrosion resistance of the base metal part, but excessive addition of Ti deteriorates the toughness of the steel sheet, especially the hot-rolled sheet, and significantly deteriorates the productivity of the steel sheet.
- the present invention has been made based on the above findings, and the gist thereof is as follows.
- Cr, Mo, Si, and A1 contain Cr, Mo, Si, and Al, respectively (mass%)
- V, Nb, C, and N are the contents of V, Nb, N, respectively (mass%)
- the composition further contains at least one of mass%, Cu: 0.2 to; 1.0%, Zr: 0.10 to 0.60%. Corrosion resistance of welds characterized by the characteristics of high-strength stainless steel sheet for hot water heaters with excellent toughness.
- group stainless steel for water heaters excellent in the corrosion resistance of a welding part and the toughness of a steel plate is obtained. Furthermore, since the present invention solves the above-mentioned problems by optimizing the component system, the corrosion resistance of the welded portion can be improved without reducing the productivity of the copper plate.
- the ferritic stainless steel of the present invention has excellent hot rolled sheet toughness and further improved corrosion resistance of the welded portion, when used as a material for a can body for a water heater, residual chlorine in tap water Even if the amount added is increased, damage due to corrosion of the welded portion can be remarkably reduced, resulting in a remarkable industrial effect.
- Fig. 1 A graph showing the results of Charpy impact tests (relationship between test temperature and absorbed energy) of hot-rolled sheets of 4nmt thickness with two compositions.
- Fig. 2 is a graph showing the results of Charpy impact test (relationship between test temperature and brittle fracture surface ratio) of hot-rolled strips of 4 t-thickness with two compositions.
- Charpy impact test correlation between test temperature and brittle fracture surface ratio
- BEST MODE FOR CARRYING OUT THE INVENTION The present invention is described in detail below. First, the chemical component composition of the present invention will be described.
- C is set to 0.020% or less. More preferably, it is 0.001% or less.
- Si is an element effective for the corrosion resistance of the welded part, and is an important element in the present invention.
- a dense film Si oxide
- Si oxide oxidation in the heat-affected zone during welding
- it works to prevent deterioration of the corrosion resistance of the base metal.
- a dense film is formed by adding 0.30% or more, and It minimizes the oxidation of Cr, prevents the oxide film and the underlying iron Cr concentration from decreasing, prevents the deterioration of the corrosion resistance of the base metal, and provides an effect on the oxide film of the weld.
- Si is 0.30% or more, preferably 0.40% or more.
- Si degrades the pickling properties of hot and cold rolled sheets and decreases productivity. If added too much, the material becomes hard and the workability deteriorates. Therefore, the upper limit is 1.00%. More preferably, the upper limit is 0.80%.
- Mn combines with S present in steel to form MnS, a soluble sulfide, which reduces corrosion resistance. Therefore, Mn shall be 1.00% or less. More preferably, it is 0.60% or less.
- P is an element harmful to corrosion resistance. In particular, it becomes remarkable when it exceeds 0.040%. Therefore, P is set to 0.040% or less. More preferably, it is 0.030% or less.
- S is an element harmful to corrosion resistance.
- MnS when it is present together with Mn, it forms MnS, and the effect on corrosion resistance becomes significant when it exceeds 0.010%. So S is 0. Limited to 010% or less. More preferably, it is 0.006% or less.
- the oxide film formed at 1000 or more contains a large amount of Cr; ⁇ , and if the base metal Cr concentration is low, the corrosion resistance in this temperature range is extremely deteriorated even if the Mo content is high.
- the lower limit of Cr is set to 20.0% or more.
- the content exceeds 28.0%, the workability is remarkably lowered.
- Cr is made 20.00% or more and 28.0% or less. Preferably, it is 20.2% to 25.5% or less.
- Ni is an element that advantageously contributes to the improvement of toughness. In order to obtain the effect, 0.1% or more is preferable. However, if the Ni force exceeds 0.6%, the sensitivity to stress corrosion cracking (SCC) increases. Therefore, Ni should be 0.6% or less. More preferably, it is 0.4% or less.
- A1 like Si, is an important element in the present invention regarding the oxide film formed at less than 800 ° C. Corrosion resistance is improved by adding 0.03% A1.
- A1 forms an oxide immediately below the oxide film on the hot-rolled sheet and cold-rolled sheet, strengthening the oxide film, making pickling difficult, and reducing productivity. Therefore, in the present invention, A1 is set to 0.03% to 0.15%. More preferably, it is 0.06 to 0.12%. • N: 0.020% or less
- N is likely to combine with Cr to form Cr nitride.
- Cr nitride When Cr nitride is formed in the heat-affected zone during welding, it causes intergranular attack, so a lower N is desirable. Therefore, in the present invention, N is set to 0.020% or less. More preferably, it is 0.014% or less.
- O oxygen
- O is an element that improves the depth of penetration of the weld. In order to obtain the effect, 0.0020% or more is preferable. On the other hand, if O exceeds 0.0150%, inclusions increase, and the presence of these inclusions causes a significant deterioration in corrosion resistance. Therefore, O is 0.0020% or more and 0.0150% or less. More preferably, it is 0.0030 to 0.0100%.
- Mo is an element that significantly improves the corrosion resistance. Such an effect becomes remarkable when the content is 0.3% or more. On the other hand, if the content exceeds 1.5%, the toughness is remarkably reduced within the Cr concentration range of the present invention, and the workability in the cold-rolled sheet is also deteriorated. Therefore, it is 0.3% or more and 1.5% or less. Preferably, it is 0.7% or more and 1.2% or less.
- Nb preferentially forms carbonitride over Cr. Therefore, formation of Cr carbonitride after hot rolling can be prevented and deterioration of toughness can be suppressed. Therefore, Nb is added at 0.25% or more. On the other hand, if it exceeds 0.60%, the toughness of the hot-rolled sheet deteriorates, and the corrosion resistance at the weld zone decreases. Therefore, Nb is set to 0.25 to 0.60%. Preferably, it is 0.30 to 0.50%.
- V is an element that improves corrosion resistance. By improving the corrosion resistance of the base metal, the corrosion resistance of the weld can be indirectly improved. In addition, it has been clarified that it is an element that improves oxidation resistance by coexisting with Nb. Although its mechanism is not well understood, when an oxidation test is performed at a temperature of 1100 ° C or higher, Nb and V may coexist on the surface of the steel plate immediately below the oxide film to form an oxide. confirmed. It is thought that Nb and V coexist on the surface of the steel sheet to form an oxide, thereby suppressing the diffusion of Fe and Cr from the steel sheet to the outside and reducing the oxidation amount of the steel sheet.
- V In order to improve surface properties, V needs to be 0.50% or less. Therefore, in the present invention, V is set to 0.005 to 0.50%. More preferably, it is 0.01 to 0.20%.
- Ti is an important element in the present invention. Ti, like Nb, forms carbonitride preferentially over Cr and improves corrosion resistance in welds and so on, so it is an element that should be added when considering the corrosion resistance of welds. However, as described above, Ti, in the Cr and Mo balance as in the present invention, remarkably deteriorates the toughness of the hot-rolled sheet even when added in a small amount. In addition, the formation of TiN in steelmaking slabs causes surface defects in cold-rolled steel sheets. Therefore, in the present invention, Ti is set to 0.05% or less. Preferably, Ti is 0.03% or less.
- the lower limit of the above formula (1) is a necessary condition for obtaining the corrosion resistance of the base metal part and the welded part even when the residual chlorine concentration in the hot water is high. Meanwhile, the corrosion resistance of the base metal and welding When the difference in corrosion resistance of welds deteriorated due to the formation of oxide film increases, dissolution occurs preferentially at the part where the oxide film is formed, which in turn promotes crevice corrosion. Therefore, the upper limit is 30 in the above equation (1). More preferably, it is 26-29.
- the above formula (2) is a necessary condition for obtaining the corrosion resistance of the weld.
- Si oxide and A1 oxide form a sufficient protective film, and suppress deterioration of corrosion resistance.
- S i + Al needs to be 0.35 or more.
- elements such as Si and A 1 are concentrated immediately below the oxide film during the formation of the oxide film, thereby preventing deterioration of the corrosion resistance. If the upper limit of the above formula (2) is exceeded, Si and / or A 1 grows too much to form a dense protective film (film without pinholes). Therefore, in the above equation (2), the upper limit is 0.85. More preferably, it is 0.40 to 0.75.
- the lower limit of the above formula (3) is a necessary condition for further improving the corrosion resistance of the weld. If there is no more than a certain amount of V with respect to the solid solution Nb, sufficient oxidation resistance cannot be obtained, and the effect of improving corrosion resistance will not be exhibited.
- the upper limit of the above formula (3) is a condition necessary for further improving the corrosion resistance of the welded portion and for improving the surface properties. If the ratio of V becomes too high, the oxidation resistance becomes too strong, which prevents the formation of a dense protective film with A1 and Si, and also suppresses the formation of an oxide film during hot rolling, thereby preventing metal contact (metal lic contact). ) causes surface defects. Therefore, in the above equation (3), the lower limit is 0.1 and the upper limit is 5.0. More preferably, it is 0.5 to 4.0.
- the balance other than the above components is Fe and inevitable impurities.
- Mg 0.000020% or less
- Ca 0.000020% or less are acceptable.
- the steel sheet of the present invention can achieve the desired properties with the above essential additive elements, but can contain the following elements depending on the desired properties.
- Cu improves the corrosion resistance of the base metal in the case of steel containing 20.0% or more of Cr. This effect is large in a low pH acid solution containing halogen, and dissolution of the iron base can be reduced by adding 0.2% or more of Cu. Although this mechanism is not clear, it is presumed that Cu dissolved in the low pH solution adheres most to the iron and improves the dissolution resistance. On the other hand, if Cu is added in excess of 1.0%, dissolution of Cu is accelerated, and crevice corrosion resistance may be reduced. Therefore, when Cu is added, Cu should be 0.2% or more 1. ( ⁇ or less, preferably 0.3% or more and 0.7% or less.
- Zr like Nb, forms carbonitride preferentially over Cr and improves corrosion resistance in welds and so on, so it is an element that should be added when considering the corrosion resistance of welds. This effect appears with the addition of 0.10%. On the other hand, if added too much, an intermetallic compound is formed, and the toughness of the hot-rolled sheet may deteriorate. Therefore, when Zr is added, it should be 0.10% or more and 0.60 or less. Preferably, it is 0.15% or more and 0.35% or less.
- the manufacturing method is not particularly limited.
- Molten steel having the above composition is melted by a known method such as a steel converter, an electric furnace, a vacuum fusion furnace, etc. cast ing) is made of steel (slab) by the ingot casting method —blooming method.
- the steel material is then heated, or directly hot-rolled without heating to a hot-rolled steel sheet.
- Hot-rolled sheets are usually subjected to hot-rolled sheet annealing, but depending on the application, hot-rolled sheet annealing may be omitted.
- cold-rolled steel is used to make cold-rolled steel sheets, which are then subjected to cold-rolled sheet annealing and pickling.
- 2B of JIS G4305 (Sukin'no ⁇ 0 scan rolled material (skin pass rol led steel sheet) ) is used as a product, no problem no be subjected to polishing or the like after machining.
- a more preferable production method preferably uses a partial condition in the hot rolling process and the cold rolling process as the specific condition.
- steel making it is preferable to melt the molten steel containing the essential components and components added as necessary in a converter or an electric furnace, and perform secondary refining by the VOD method.
- the molten steel can be made into a steel material according to a known production method, but from the viewpoint of productivity and quality, it is preferable to use a continuous forging method.
- the copper material obtained by continuous forging is, for example, heated to 100 ° C to 125 ° C and hot rolled to a desired thickness by hot rolling with a finishing temperature of 700 to 950 ° C. It is said. Of course, it can be processed as other than plate material.
- This hot-rolled sheet is subjected to batch-type annealing at 600 to 800 ° C or continuous annealing at 900 ° C-110 ° C, and then descaled by pickling etc. Become a product. If necessary, the oxide film may be removed by shot blasting before pickling.
- the hot-rolled annealed plate obtained above is made into a cold-rolled plate through a cold rolling process.
- two or more cold rolling processes including intermediate annealing may be performed as necessary for the convenience of production.
- the total rolling reduction in the cold rolling process consisting of one or more cold rollings is 60% or more, preferably 70% or more.
- the cold-rolled sheet is 950- 1 1500, more preferably 980-0-1120 ° C continuous annealing (cold-rolled sheet annealing), then pickled, Is done.
- mild rolling skin pass rolling, etc.
- the welding method for welding these members is not particularly limited, and MIG (Metal Inert Gas), MAG (Metal Active Gas), TIG (Tungsten Inert Gas) and other ordinary arc welding methods, spot welding, seam welding and other resistance welding methods, and electric resistance welding methods such as high frequency resistance welding and high frequency induction welding Applicable.
- finishing temperature 750 to 9503 ⁇ 4
- Coiling temperature Hot rolling was performed under the conditions of 650 to 8503 ⁇ 4 to obtain a hot rolled sheet having a thickness of 4.0 mm.
- the toughness of the obtained hot-rolled sheet was investigated.
- the shape of the test specimen is JIS Z2202, No. 4, and V-notch is processed so that the V-notch direction is perpendicular to the rolling direction (C direction).
- a Charbi impact test was conducted.
- the toughness was evaluated by observing the fracture cross section with a microscope at 0 and a scanning electron microscope (SEM) and evaluating the brittle fracture surface ratio.
- SEM scanning electron microscope
- Electrode 1. 6mm diameter tungsten electrode
- the welded specimens were subjected to an immersion test in order to investigate the corrosion resistance in the environment where the water heater was used.
- the test solution was used 0. l% NaCl + 0. 1% CUC1 2 aqueous solution maintained at 80 ° C.
- the welded specimen was changed to the test solution every 5 days and immersed for 3 cycles (15 days in total), and the maximum pitting depth of pitting corrosion occurred in the weld was measured.
- the corrosion resistance of the weld was evaluated according to the following criteria.
- the maximum pore depth is 20 / z m or more and less than 50 ⁇
- Each item was rated according to the following criteria. -The brittle fracture surface at 0 ° C in the Charpy test was scored at 5 points for 20% or less, 2 points for 20-80%, and 0 points for 80% or more.
- the pitting corrosion potential of the base metal was 5 points for 500 mV or more, 2 points for 450 to 500 mV, and 0 point for 450 mV or less.
- the pitting potential (3.5% NaCl) of the weld was 5 points for lOOmV or more, 2 points for 0 to 100 mV, and 0 point for less than OmV. .
- the pitting corrosion potential (200ppmCr) of the weld was 5 points for lOOmV or more, 2 points for 0 to 100mV, and 0 point for OmV or less.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08703088A EP2100983B1 (en) | 2007-01-12 | 2008-01-07 | Ferritic stainless steel sheet for water heater excellent in corrosion resistance at welded part and steel sheet toughness |
CN2008800021000A CN101578385B (zh) | 2007-01-12 | 2008-01-07 | 焊接部耐腐蚀性以及钢板的韧性优良的热水器用铁素体系不锈钢板 |
ES08703088T ES2396221T3 (es) | 2007-01-12 | 2008-01-07 | Chapa de acero inoxidable ferrítico para calentador de agua de excelente resistencia a la corrosión en una parte soldada y tenacidad de la chapa de acero |
US12/516,212 US8383034B2 (en) | 2007-01-12 | 2008-01-07 | Ferritic stainless steel sheet for water heater excellent in corrosion resistance at welded part and steel sheet toughness |
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US (1) | US8383034B2 (ja) |
EP (1) | EP2100983B1 (ja) |
JP (1) | JP5050863B2 (ja) |
KR (2) | KR20090087072A (ja) |
CN (1) | CN101578385B (ja) |
ES (1) | ES2396221T3 (ja) |
WO (1) | WO2008084838A1 (ja) |
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- 2008-01-07 EP EP08703088A patent/EP2100983B1/en active Active
- 2008-01-07 WO PCT/JP2008/050224 patent/WO2008084838A1/ja active Application Filing
- 2008-01-07 KR KR1020097012588A patent/KR20090087072A/ko active Application Filing
- 2008-01-07 CN CN2008800021000A patent/CN101578385B/zh active Active
- 2008-01-07 KR KR1020127016896A patent/KR20120083939A/ko not_active Application Discontinuation
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- 2008-01-07 US US12/516,212 patent/US8383034B2/en active Active
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Also Published As
Publication number | Publication date |
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KR20120083939A (ko) | 2012-07-26 |
CN101578385B (zh) | 2012-03-21 |
JP2008190035A (ja) | 2008-08-21 |
JP5050863B2 (ja) | 2012-10-17 |
US8383034B2 (en) | 2013-02-26 |
EP2100983A1 (en) | 2009-09-16 |
EP2100983B1 (en) | 2012-10-31 |
US20100061878A1 (en) | 2010-03-11 |
ES2396221T3 (es) | 2013-02-20 |
CN101578385A (zh) | 2009-11-11 |
EP2100983A4 (en) | 2010-03-10 |
KR20090087072A (ko) | 2009-08-14 |
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