WO2008066319A1 - Composition de pigments minéraux à très haute dureté - Google Patents

Composition de pigments minéraux à très haute dureté Download PDF

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Publication number
WO2008066319A1
WO2008066319A1 PCT/KR2007/006049 KR2007006049W WO2008066319A1 WO 2008066319 A1 WO2008066319 A1 WO 2008066319A1 KR 2007006049 W KR2007006049 W KR 2007006049W WO 2008066319 A1 WO2008066319 A1 WO 2008066319A1
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Prior art keywords
oxide
weight
composition according
silica
silicate
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PCT/KR2007/006049
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English (en)
Inventor
Woo-Jae Lee
Jeong Hoon Lee
Woo-Chang Song
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Woo-Jae Lee
Jeong Hoon Lee
Woo-Chang Song
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Priority claimed from KR1020070118619A external-priority patent/KR100838126B1/ko
Application filed by Woo-Jae Lee, Jeong Hoon Lee, Woo-Chang Song filed Critical Woo-Jae Lee
Priority to CN200780044057XA priority Critical patent/CN101547978B/zh
Publication of WO2008066319A1 publication Critical patent/WO2008066319A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

Definitions

  • the present invention relates to a high-hardness inorganic coating composition.
  • the present invention relates to a high-hardness inorganic coating composition which is capable of forming a coating film having high hardness, antibacterial activity, water resistance, chemical resistance and non-flammability, and exhibiting superior adhesion to a substrate, on a metal or non-metal surface.
  • Such coating agents have an extremely broad spectrum of applications, ranging from various industrial fields (including railways, vehicles, shipping, road facilities, a nd electric and electronic products) to conventional domestic fields such as in the household environment (including as kitchens, sitting rooms and the like).
  • the conventional coating agents employ organic solvents such as alcohols, solvents and the like, and therefore suffer from the risk of environmental contamination.
  • an inorganic coating composition containing water-soluble silicate as a main component which is prepared from water-soluble silicate and aluminum or an aluminum metal oxide.
  • a coating composition has a problem associated with whitening of the coating surfaces due to the release of a trace amount of alkaline components to the coating film surface after formation of the coating film, because the water-soluble modified silicate used as a binder is a strong alkaline material.
  • the present invention has been made in view of the above problems, and it is an object of the present invention to provide a high-hardness inorganic coating composition which is capable of forming a coating film having high hardness on a metal or non-metal surface.
  • a high-hardness inorganic coating composition comprising a frit of at least one material selected from silicate and modified silicate, a microparticulate silica-containing material, and an inorganic filler.
  • the high-hardness inorganic coating composition may comprise 20 to 80% by weight of the frit, 10 to 70% by weight of the inorganic filler, and 10 to 35% by weight of the particulate silica-containing material, based on the total weight of the composition.
  • the frit may be at least one selected from silicon dioxide, aluminum oxide, sodium oxide, magnesium oxide, potassium oxide, lithium oxide, and zinc oxide.
  • the frit may be a molten vitreous product of a raw material.
  • the inorganic filler may be at least one selected from carbide, sodium silicate, potassium silicate, sodium and potassium colloidal silica, aluminum hydroxide, barium sulfate, clay, calcium carbonate, titanium oxide, kaolin, bentonite, zeolite, alumina, silica, titania, zirconia, and lithium oxide.
  • the carbide may be at least one selected from a carbide group consisting of titanium carbide and silica carbide.
  • the coating composition may further comprise at least one material selected from chlorates, oxides, hydroxides and phosphates of alkali metals.
  • the phosphate may be at least one selected from aluminum phosphate, calcium phosphate, and magnesium phosphate.
  • the chlorate of the alkali metal may be at least one selected from lithium perchlorate, sodium chlorate, and potassium chlorate.
  • the oxide may be at least one selected from aluminum oxide, calcium oxide, sodium oxide, potassium oxide, lithium oxide, zinc oxide, yttrium oxide, strontium oxide, magnesium oxide, barium oxide, manganese oxide, vanadium oxide, zirconium oxide, titania oxide, and silicon oxide.
  • the hydroxide may be at least one selected from magnesium hydroxide, aluminum hydroxide, lithium hydroxide, potassium hydroxide, sodium hydroxide, and calcium hydroxide.
  • a content of the oxide may be in a range of 5 to 40% by weight, based on the total weight of the high-hardness inorganic coating composition.
  • the coating composition may further comprise at least one compound selected from aluminum oxide, sodium oxide, iron oxide, potassium oxide, zirconia, titania, silica, aluminum phosphate, and lithium oxide. These materials may be used alone or in any combination thereof. [25] A content of the above compound may be in a range of 5 to 15% by weight, based on the total weight of the high-hardness inorganic coating composition. [26] The coating composition may further comprise a non-ionic surfactant.
  • a content of the non-ionic surfactant may be in a range of 0.1 to 3% by weight, based on the total weight of the high-hardness inorganic coating composition.
  • the non-ionic surfactant may be at least one selected from amine oxides, alkyl esters, and polysorbates.
  • the coating composition may further comprise a dispersant.
  • a content of the dispersant may be in a range of 0.1 to 6% by weight, based on the total weight of the high-hardness inorganic coating composition.
  • the coating composition may further comprise at least one additive selected from ethylene glycol, diethylene glycol, aluminum stearate, silica, zirconium silicate, calcium silicate, metal alkylsulfonates, modified polysiloxane, and silane.
  • a content of the additive may be in a range of 0.1 to 2% by weight, based on the total weight of the high-hardness inorganic coating composition.
  • An inorganic coating film which is formed using the high-hardness inorganic coating composition in accordance with the present invention, has a surface that exhibits low bonding strength to organic materials, but shows high bonding strength to metal or non-metal surface. Therefore, organic materials scarcely adhere to the coating film of the present invention, and can be easily removed even when the film is contaminated with such organic materials. Further, due to excellent bonding strength to metal or non-metals to be coated, it is possible to produce high-quality coating products.
  • the coating film of the present invention has desired features such as high weatherability, durability, chemical resistance, abrasion resistance, surface hardness, far- infrared radiation, non- flammability, chemical resistance, and contamination resistance.
  • a life span of the film is advantageously semi-permanent.
  • the present invention exhibits no occurrence of whitening due to release of the alkali components into the coating film surface, and superior water resistance.
  • the high-hardness inorganic coating composition in accordance with the present invention may be used in admixture with water, so it is an environmentally- friendly coating material because it does not produce contaminants during a coating process.
  • the present invention provides a high-hardness inorganic coating composition
  • a high-hardness inorganic coating composition comprising a silicate or modified- silicate frit, a microparticulate silica-containing material, and an inorganic filler.
  • the silicate or modified- silicate frit may be at least one selected from silicon dioxide, aluminum oxide, sodium oxide, magnesium oxide, potassium oxide, lithium oxide, and zinc oxide, such that a water-soluble material can easily be used.
  • the frit may be a molten vitreous product which is prepared by previously melting and vitrifying a raw material.
  • Use of the molten vitreous type of a frit material leads to improvements in adhesion of the coating composition and also provides superior surface hardness, as compared to use of a ground frit material.
  • a content of the frit may be in a range of 20 to 80% by weight, based on the total weight of the high-hardness inorganic coating composition. If the content of the frit is lower than 20% by weight, it is impossible to form a high-hardness inorganic coating composition due to a low viscosity. On the other hand, if the content of the frit is higher than 80% by weight, dispersibility of particles is lowered due to high bonding strength of particles which results from an excessive viscosity increase. Therefore, this may result in inconvenience of use, interference of melting due to becoming fire- resistant, and the occurrence of cracking and swelling of the coating film during a drying process.
  • the modified silicate frit that can be used in the present invention may be a material in which silicate represented by Formula of M OxAl O -nSiO -xH O is modified with
  • 2 2 3 2 2 aluminum, or an oxide or hydroxide of a metal selected from metals or transition metals belonging to Group HA elements of the Periodic Table of the Elements, or may be a material in which colloidal silicate is modified with a basic catalyst such that other metals are introduced into an aqueous silicate solution and polymerization of colloidal silicate occurs via cross-linking.
  • a modifying agent used in preparation of the modified silicate may include oxides and hydroxides of metals.
  • the basic catalyst may include aluminum oxide, aluminum hydroxide, magnesium oxide, sodium hexametaphosphate, calcium oxide, amorphous silica, ethyl silicate, and cellulose.
  • the modified silicate can be prepared by a conventional method for preparing the modified silicate, for example by mixing the modifying agent or basic catalyst with the aqueous solution of silicate, and heating or hydrolyzing the resulting mixture.
  • the inorganic filler that can be used in the present invention may be selected from carbide, sodium silicate, potassium silicate, sodium and potassium colloidal silica, aluminum hydroxide, barium sulfate, clay, calcium carbonate, titanium oxide, kaolin, bentonite, zeolite, alumina, silica, titania, zirconia, and lithium oxide. These materials may be used alone or in any combination thereof.
  • Examples of the carbide which is used as the inorganic filler may include titanium carbides and silica carbides. These materials may be used alone or in any combination thereof.
  • a content of the inorganic filler in the coating composition may be in a range of 10 to 70% by weight. If the content of the filler is lower than 10% by weight, it is impossible to form a high-hardness inorganic coating composition due to a low surface density of the coating film. On the other hand, if the content of the filler is higher than 70% by weight, this may result in cracking of the coating film due to high bonding strength of particles which results from an excessive viscosity increase.
  • microparticulate silica-containing material in the present invention there may employed particulate silica or amorphous silica, silica slip, colloidal silica, silicon carbide or the like.
  • Silica serves to accelerate curing of the high-hardness inorganic coating film formed on the substrate surface. Further, such a silica component is completely dispersed at room temperature in the silicate or modified-silicate frit to thereby neutralize the high-hardness inorganic coating composition. In addition, when the coating film is formed through the drying process, silica particles migrate and fix to the coating film surface during the heating and dehydrating processes, which consequently leads to fixation of alkali metal components within a regular tetrahedral structure of the silica to thereby prevent release of the alkali metal components to the coating film surface.
  • a high-hardness inorganic coating film is formed which has a coating film surface with no occurrence of coat whitening due to the alkali metal release, in conjunction with a superior water-resistance.
  • the amorphous silica used in the present invention may be one which is prepared by mixing SiO and Al O in a weight ratio of 1:1, followed by heat-melting and calcining, quenching with cold water, and grinding with a ball mill to have a particle size of 5 to 20 D, or may be one which is prepared by hydrolyzing ethyl silicate (SiCOC 2H 5 ) 4 , followed by drying at 100 0 C for 1 hour.
  • a content of the particulate silica-containing material may be in a range of 10 to 35% by weight.
  • the coating film-forming silica of the high-hardness coating film formed by the present invention can be represented by Formula of M 0-xAl O -nSiO -mH O wherein M represents an alkali metal, and x, n and m are independently a natural number.
  • silicate used in the present invention can be represented by Formula of M
  • metal M may include lithium, potassium, sodium and the like.
  • kinds of silicate are selected taking into consideration characteristics of the composition and physical properties of the coating film. For example, when it is desired to form a water-resistant coating film, a potassium salt is preferably used. When it is desired to enhance adhesion, a sodium salt is preferably used. In the case of silicate which is conventionally used, it is preferred to use one having a molecular weight of 300 to 500.
  • the silicate or modified-silicate frit and silica are preferably used after they are completely dispersed or dissolved.
  • compositions may be mixed and heat-stirred to thereby increase dispersibility of particles.
  • such materials are reacted and dispersed at a temperature of 8O 0 C or higher for more than 24 hours, and rotation speed of a stirrer is preferably set to about 80 to 800 rpm, even though the temperature and time and the stirring rate are not limited thereto.
  • the coating composition may further comprise at least one material selected from the group consisting of chlorates, oxides, hydroxides and phosphates of alkali metals.
  • the chlorate of the alkali metal may be at least one selected from lithium perchlorate, sodium chlorate and potassium chlorate.
  • Examples of the oxide may include aluminum oxide, calcium oxide, sodium oxide, potassium oxide, lithium oxide, zinc oxide, yttrium oxide, strontium oxide, magnesium oxide, barium oxide, manganese oxide, vanadium oxide, zirconium oxide, titania oxide, silicon oxide, and the like.
  • Examples of the hydroxide may include magnesium hydroxide, aluminum hydroxide, lithium hydroxide, potassium hydroxide, sodium hydroxide, and calcium hydroxide
  • examples of the phosphate may include aluminum phosphate, zinc phosphate, sodium phosphate, ammonium phosphate, magnesium phosphate, potassium phosphate, and phosphoric silicate.
  • a content of the oxide may be in a range of 5 to 40% by weight, based on the total weight of the high-hardness inorganic coating agent. If the content of the oxide is lower than 5% by weight, this may result in a low conductivity. On the other hand, if the content of the oxide is higher than 40% by weight, this may result in self- aggregation and no further increased conductivity.
  • the coating composition may further comprise at least one compound selected from aluminum oxide, sodium oxide, iron oxide, potassium oxide, zirconia, titania, silica, aluminum phosphate, and lithium oxide. Further incorporation of these compounds also improves water resistance and hardness of the coating film.
  • a content of the above compound may be preferably in a range of 5 to 15% by weight based on the total weight of the composition. If the content of the compound is lower than 5% by weight, adverse effects on the composition and coating properties, and failure to form a thick coat on the substrate due to poor mechanical properties may result in. On the other hand, if the content of the compound is higher than 15% by weight, this leads to increases in mechanical properties such as impact strength, hardness, and durability, which are then responsible for cracking of the coating film and bring about changes in the mechanical properties.
  • non-ionic surfactant may include amine oxides such as lauryl dimethyl amine oxide and cocamido propyl dimethyl amine oxide; alkyl esters such as ethylene glycol stearate, cetyl octanoate and isooctyl stearate; and polysorbates such as polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monostearate, poly- oxyethylene sorbitan trioleate, and polyoxyethylene sorbitan monooleate. These materials may be used alone or in any combination thereof.
  • amine oxides such as lauryl dimethyl amine oxide and cocamido propyl dimethyl amine oxide
  • alkyl esters such as ethylene glycol stearate, cetyl octanoate and isooctyl stearate
  • polysorbates such as polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monostearate, poly- oxyethylene sorbitan trio
  • a content of the non-ionic surfactant may be in a range of 0.1 to 3% by weight, based on the total weight of the high-hardness inorganic coating composition. If the content of the non-ionic surfactant is lower than 0.1% by weight, it is difficult to achieve an effective emulsion state on an inorganic particle surface. On the other hand, if the content of the non-ionic surfactant is higher than 3% by weight, it is difficult to control a particle size, in conjunction with problems associated with recovery of a residual emulsifier and excessively increased production costs.
  • a dispersant may be further added to stabilize dispersion of the coating composition and lower a viscosity thereof.
  • the dispersant may be at least one selected from sodium alkyl naphthalene sulfonate, sodium alkyl benzene sulfonate, alkyl allyl ether, diethanol amine, a polyacrylate ammonium salt solution, and an alkylol ammonium salt solution of a low-molecular weight polycarboxylic acid polymer.
  • a content of the dispersant may be preferably in a range of 0.1 to 6% by weight, based on the total weight of the coating composition. If the content of the dispersant is lower than 0.1% by weight, this leads to an excessively low viscosity which consequently results in poor effects due to decreased fluidity. On the other hand, if the content of the dispersant is higher than 6% by weight, an increasing viscosity excessively increases the fluidity to thereby result in poor effects.
  • an additive may be optionally added to secure flexibility, adhesiveness, impact resistance, and smoothness of the coating film.
  • the additive may include ethylene glycol, diethylene glycol, aluminum stearate, silica, zirconium silicate, calcium silicate, metal alkyl- sulfonate, modified polysiloxane, and silane. These materials may be used alone or in any combination thereof.
  • a content of the additive may be preferably in a range of 0.1 to 2% by weight, based on the total weight of the high-hardness inorganic coating composition. If the content of the additive is lower than 0.1% by weight, it is impossible to improve the flexibility and adhesion of the coating film. On the other hand, if the content of the additive is higher than 2% by weight, the flexibility is increased to probably cause cracking of the coating film surface.
  • compositions may be mixed in a liquid or powdered state.
  • the dispersant and additive are preferably mixed in a liquid state.
  • a hydrophilic solvent such as water may be used.
  • [87] 50 g of potassium phosphate, 15 g of magnesium phosphate, 5 g of ammonium phosphate, 17 g of aluminum hydroxide, 2.5 g of lithium hydroxide, 3 g of iron oxide, 4 g of potassium chlorate, 2 g of aluminum polyphosphate, 1.5 g of sodium fluo- rosilicate, 3 g of calcium silicate, and 100 g of distilled water were ground using a ball mill for 2 to 4 hours to thereby obtain a finely divided oxide-containing material.
  • lithium oxide 1.5 g of lithium oxide, 4 g of titania, 17 g of silica, 3 g of aluminum phosphate, and 100 g of distilled water were mixed, and the mixture was ground using a ball mill for 2 to 4 hours to thereby obtain finely divided alumina.
  • Example 2 17% by weight of a silica-containing material of Example 3, 13% by weight of an oxide of Example 4, 8% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below.
  • Example 7 Coating of high-hardness inorganic coating composition
  • Example 2 15% by weight of a silica-containing material of Example 3, 18% by weight of an oxide of Example 4, 10% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below.
  • Example 8 Coating of high-hardness inorganic coating composition
  • Example 2 10% by weight of a silica-containing material of Example 3, 20% by weight of an oxide of Example 4, 13% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below. [101] Example 9: Coating of high-hardness inorganic coating composition
  • Example 2 5% by weight of a silica-containing material of Example 3, 5% by weight of an oxide of Example 4, 3% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below. [103]
  • Example 10 Coating of high-hardness inorganic coating composition
  • Example 2 5% by weight of a silica-containing material of Example 3, 5% by weight of an oxide of Example 4, 3% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below. [106]
  • Example 11 Coating of high-hardness inorganic coating composition
  • Example 2 5% by weight of a silica-containing material of Example 3, 5% by weight of an oxide of Example 4, 3% by weight of alumina of Example 5, 0.5% by weight of polyoxyethylene sorbitan monostearate as a non-ionic surfactant, 1.0% by weight of protesol 711 as a dispersant, and 0.5% by weight of metal alkyl sulfonate as an additional additive were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below. [109]
  • Example 12 Coating of high-hardness inorganic coating composition
  • Comparative Example 5 Coating of high-hardness inorganic coating composition
  • 50% by weight of a main material of Comparative Example 1 and 50% by weight of a curing agent of Comparative Example 2 were mixed, and the resulting mixture was stirred and defoamed for 30 min, spray-coated on a metal or non-ferrous metal surface, and dried in a drying oven at a temperature of 270+20 0 C for 20 min to thereby form a high-hardness inorganic coating film. Physical properties of the thus-formed coating film were tested. The results obtained are given in Table 1 below.
  • Adhesion test A cross-cut square of 2 mmx2 mm was made on the high- hardness inorganic coating film surface according to KS D6711-92, and a cellophane adhesive tape was applied thereto and detached to confirm a peeling state.
  • Abrasion resistance A water-soaked 3M scrubbing brush was placed on the high- hardness inorganic coating film surface, and subjected to forward and backward moving under loading of 3 kg weight (movement distance: more than 30 cm, 10 times rubbing test). Thereafter, confirmation of surface scratches was made.
  • Salt water resistance The high-hardness inorganic coating film surface was subjected to a salt spray test. After 720 hours, the coating surface was examined.
  • Waste water test A substrate having the high-hardness inorganic coating film formed thereon was soaked in final effluent from a waste water treatment plant, and changes of the coating film surface were examined after 1000 hours.
  • the frit used in the present invention is superior in adhesion, hardness, antibacterial activity and water resistance, whereas the composition using no frit, as can be seen in Comparative Examples hereinbefore, exhibits low hardness, adhesion and abrasion resistance, poor impact resistance, i.e. brittleness of the coating film, and poor contamination resistance, i.e. difficulty to remove contaminants while still retaining distinct stain. Other tests showed that the composition with no use of the frit has poor physical properties, so the high-hardness coating film was not obtained.
  • a coating film which is formed using a composition in accordance with the present invention, has a surface that exhibits low bonding strength to organic materials, but shows high bonding strength to metal or non-metal surface. Therefore, organic materials scarcely adhere to the coating film of the present invention, and can be easily removed even when the film is contaminated with such organic materials. Further, due to excellent bonding strength with metal or non-ferrous metals to be coated, it is possible to produce high-quality coating products.
  • the coating film of the present invention has desired features such as high weatherability, durability, chemical resistance, abrasion resistance, surface hardness, far-infrared radiation, non-flammability, chemical resistance, and contamination resistance.
  • the coating composition in accordance with the present invention can be applied to various products which require environmentally friendliness and high- quality coating.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
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  • Paints Or Removers (AREA)

Abstract

La présente invention concerne une composition de revêtement minéral à très haute dureté capable de former un film de revêtement à haute dureté, à activité antibactérienne, résistant à l'eau, à résistance chimique et ininflammabilité, et démontrant une adhésion supérieure à un substrat, sur une surface métallique ou non-métallique. La présente invention fournit une composition de revêtement minéral à haute dureté préparée en mélangeant un liant et un agent de remplissage minéral dans de l'eau.
PCT/KR2007/006049 2006-11-28 2007-11-28 Composition de pigments minéraux à très haute dureté WO2008066319A1 (fr)

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CN200780044057XA CN101547978B (zh) 2006-11-28 2007-11-28 具有高硬度的无机涂料组合物

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KR20060118127 2006-11-28
KR10-2006-0118127 2006-11-28
KR10-2007-0118619 2007-11-20
KR1020070118619A KR100838126B1 (ko) 2006-11-28 2007-11-20 무기계 고경도 코팅제 조성물

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ITMO20080317A1 (it) * 2008-12-09 2010-06-10 Giorgio Romano Sarcinella Composto chimico verniciabile per produzione di tegole, coppi e intonaci elettrici e similari.
WO2010112605A1 (fr) * 2009-04-03 2010-10-07 Akzo Nobel Coatings International B.V. Composition de revêtement anticorrosion
CN103053617A (zh) * 2012-09-14 2013-04-24 方孝贤 抗菌液体的制备方法及其应用
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