WO2008035786A1 - Dispositif semi-conducteur et procédé de fabrication d'un dispositif semi-conducteur - Google Patents
Dispositif semi-conducteur et procédé de fabrication d'un dispositif semi-conducteur Download PDFInfo
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- WO2008035786A1 WO2008035786A1 PCT/JP2007/068458 JP2007068458W WO2008035786A1 WO 2008035786 A1 WO2008035786 A1 WO 2008035786A1 JP 2007068458 W JP2007068458 W JP 2007068458W WO 2008035786 A1 WO2008035786 A1 WO 2008035786A1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/423—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
- H01L29/42312—Gate electrodes for field effect devices
- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
- H01L29/42384—Gate electrodes for field effect devices for field-effect transistors with insulated gate for thin film field effect transistors, e.g. characterised by the thickness or the shape of the insulator or the dimensions, the shape or the lay-out of the conductor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4908—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET for thin film semiconductor, e.g. gate of TFT
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66742—Thin film unipolar transistors
- H01L29/6675—Amorphous silicon or polysilicon transistors
- H01L29/66765—Lateral single gate single channel transistors with inverted structure, i.e. the channel layer is formed after the gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78603—Thin film transistors, i.e. transistors with a channel being at least partly a thin film characterised by the insulating substrate or support
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78606—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
- H01L29/78636—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device with supplementary region or layer for improving the flatness of the device
Definitions
- the present invention relates to a semiconductor device, in particular, a thin film transistor (TFT), and a manufacturing method thereof.
- TFT thin film transistor
- a display device such as a liquid crystal display device, an organic EL device, and an inorganic EL device sequentially forms and turns a conductive pattern such as a wiring pattern and an electrode pattern on a substrate having a flat main surface. It is formed by.
- a display device is manufactured by sequentially forming and patterning various films necessary for an electrode film and elements constituting the display device.
- Patent Document 1 in order to form flat display wiring such as a liquid crystal display, wiring is formed on a transparent substrate surface, and a transparent insulating material having the same height is formed so as to be in contact with the wiring pattern. Is disclosed. Further, Patent Document 3 further discloses a method of flattening the wiring by heating press or CMP (Chemical Mechanical Polishing)!
- Patent Document l WO2004 / 110117
- Patent Document 2 Japanese Patent Application No. 2005-173050
- Patent Document 3 Japanese Patent Laid-Open No. 2005-210081
- Patent Document 4 Japanese Patent Laid-Open No. 2002-296780
- Patent Document 5 Japanese Patent Laid-Open No. 2001-188343
- Patent Document 1 discloses that the characteristics of a display device can be improved by embedding wiring in a groove formed by a resin pattern to form a thick film wiring.
- methods such as an ink jet method and a screen printing method are disclosed as wiring forming methods.
- Patent Document 1 when the wiring is formed by conductive ink, screen printing, or the like, the flatness of the insulating layer or the like formed on the wiring with a rough surface of the wiring is deteriorated. That was a component.
- a conductive ink or a wiring formed by screen printing is used as a gate electrode, a phenomenon that the propagation rate of carriers through the channel deteriorates due to the roughness of the wiring surface, impeding high-speed operation has been observed. It was. Furthermore, it has been found that it is difficult to obtain a desired shape when the wiring becomes fine in conductive ink screen printing or the like.
- Patent Document 2 in order to solve these problems, a step of modifying the surface of the insulating substrate so as to improve adhesion to the substrate, a step of forming a resin film on the insulating substrate, By patterning the resin film, a step of forming a recess in which an electrode or wiring is accommodated, a step of applying a catalyst to the recess, a step of heat-curing the resin film, and a method of attaching to the recess And a manufacturing method including at least a step of forming a conductive material.
- a Ni layer is formed by electroplating and used as a gate electrode!
- the adhesion of the gate electrode to the substrate is improved, and further, the width is 20 m and the length is long. Even a 50 m long gate electrode can form a desired pattern regardless of its size.
- the gate insulating layer formed on the gate electrode with a rough gate electrode surface has a poor flatness.
- the flatness of the surface of the Cu layer formed by the electroless plating method reaches 17 ⁇ 74nm for Ra and 193 ⁇ 92nm for the peak 'toe' valley value, and the flatness of the Ni layer formed on it is also flat. Is 8.58nm for Ra and 6 ⁇ 7nm for peak-to-valley value.
- the surface of silicon nitride formed by the CVD method as a gate insulating film that is, the interface with the channel region of the semiconductor layer becomes rough, resulting in poor carrier mobility.
- the flatness of the surface of the gate electrode should be 1 nm or less for Ra and 20 nm or less for the peak 'toe' valley value to maintain the flatness at the interface between the gate insulating film and the channel region and to prevent interfacial scattering of carriers. It is.
- Patent Document 3 as a method for solving the problem of the roughness of the wiring surface, a heat pressing process in which the insulating film and the embedded wiring are pressed by a pressing member, or a process of performing a CMP process is proposed.
- the method of flattening these wirings has become impractical, especially in the fifth generation glass substrates with a size of lOOmm x 1300 mm or larger.
- the heat-pressing process slight glass distortion leads to breakage, and uniform polishing of the entire surface of a large glass substrate by CMP is extremely difficult, leading to increased costs.
- An object of the present invention is to provide a thin film transistor (TFT) having excellent flatness of a gate insulating film and a method for manufacturing the same.
- Another object of the present invention is to provide a semiconductor device and a method for manufacturing the same, in which the problems of the roughness of the gate electrode surface and the gap with the surrounding insulating layer are solved.
- Still another object of the present invention is to provide a display device including a thin film transistor having excellent interface flatness and a method for manufacturing the same. Means for solving the problem
- the substrate, the insulating layer provided on the substrate and having a groove, and the surface of the insulating layer provided in the groove are substantially flat with the surface of the insulating layer.
- a semiconductor device comprising: a conductive layer formed on the conductive layer; an insulating film provided on the conductive layer; and a semiconductor layer provided on the insulating film above at least a part of the conductive layer.
- a semiconductor device is obtained in which the film includes an insulator coating film.
- the insulating film is composed only of the insulator coating film.
- the insulating film may further include another insulator film.
- the other insulator film is preferably an insulator CVD film.
- the other insulator film is provided between the insulator coating film and the semiconductor layer.
- the other insulator film may be provided between the insulator coating film and the conductor layer.
- a part of the conductor layer is a gate electrode, the insulating film on the gate electrode is a gate insulating film, and the semiconductor layer is on the gate insulating film.
- At least one of a source electrode and a drain electrode is electrically connected to the semiconductor layer.
- a groove is provided in the insulator layer on the substrate, and the gate electrode is formed in the groove so that the surface thereof is substantially flat with the surface of the insulator layer.
- the gate insulating film is provided on the gate electrode.
- the insulator coating film has a surface flatness of Ra of 1 nm or less and a peak “toe” valley value of 20 nm or less.
- the gate electrode has a surface flatness of Ra of 3 nm or more and a peak “toe” valley value of 30 nm or more.
- the substrate is a substantially transparent insulator substrate, and the insulator layer is a substantially transparent resin layer.
- the resin layer is formed of a photosensitive resin composition containing an alkali-soluble alicyclic polyolefin resin and a radiation-sensitive component.
- the resin layer is made of an acrylic resin, a silicone resin, a fluorine resin, a polyimide resin, a polyolefin resin, an alicyclic polyolefin resin, and an epoxy resin. Contains one or more resins selected from
- the gate electrode includes at least a base adhesion layer, a conductive metal layer, and a conductive metal diffusion suppression layer.
- the insulator coating film fills a gap between the conductor layer and the insulator layer and extends on a surface of the insulator layer. Yes.
- the insulator coating film is substantially transparent, fills a gap between the gate electrode and the insulator layer, and on the surface of the insulator layer. It extends to les.
- the insulator CVD film is substantially transparent, and extends on the surface of the insulator layer. It is extended to.
- the insulator coating film is a film obtained by drying and baking a liquid coating film containing at least one of a metal organic compound and a metal inorganic compound and a solvent. is there.
- the insulator layer is a substantially transparent resin layer
- the insulator coating film includes at least one of a metal organic compound and a metal inorganic compound and a solvent. This is a film obtained by drying and baking the liquid coating film containing it at 300 ° C or lower.
- the dielectric coating film has a dielectric constant of 2.6 or more.
- the dielectric of the insulator CVD film! The rate should be 4 or more!
- the thickness of the gate insulating film is 95 nm to 200 nm in terms of E OT (silicon dioxide equivalent).
- the thickness of the insulator CVD film is preferably 80 nm to 185 nm in terms of EOT (silicon dioxide equivalent).
- the thickness of the insulator coating film is 15 nm to 120 nm in terms of EOT (silicon dioxide equivalent)! /.
- the conductive metal layer includes at least one of Cu and Ag, and the conductive metal diffusion suppression layer is selected from Ni, W, Ta, Nb, and Ti. Comprising metal to be made.
- a display device manufactured using the semiconductor device according to the first or ninth aspect can be obtained.
- the display device is a liquid crystal display device or an organic EL display device.
- the step of providing an insulator layer having a groove on the substrate, and forming the conductor layer in the groove so that the surface thereof is substantially flat with the surface of the insulator layer A step of forming an insulator coating film on the conductor layer; and a step of forming a semiconductor layer on at least a part of the insulator coating film.
- a manufacturing method is obtained.
- the step of forming the insulator coating film A step of forming another insulator film may be included before or after.
- the other insulator film is formed by CVD.
- a part of the conductor layer is used as a gate electrode
- the insulator coating film on the gate electrode is used as at least a part of the gate insulating film
- the semiconductor layer is used as the gate. It may be provided on the insulating film.
- the manufacturing method according to the twenty-ninth aspect further includes a step of forming at least one of a source electrode and a drain electrode on the semiconductor layer.
- a liquid material containing at least one of a metal organic compound and a metal inorganic compound and a solvent is used as the gate electrode. It includes a step of applying on top, a step of drying the applied film, and a step of firing the dried film.
- the step of forming the gate electrode includes a step of forming the conductive metal layer by a plating method, a printing method, an inkjet method, or a sputtering method.
- a method for manufacturing a semiconductor device characterized by the above is obtained.
- the step of forming the insulator coating film fills a gap between the gate electrode and the insulator layer with the liquid material, and the insulator Applying to extend over the surface of the layer.
- the step of providing an insulating layer having a groove on the substrate includes the step of forming a resin film on the substrate, and the step of turning the resin film Forming a trench for accommodating the gate electrode.
- the manufacturing method according to the thirty-fifth aspect of the present invention there is obtained a method for manufacturing a semiconductor device, characterized in that the baking is performed in an inert gas atmosphere or an air atmosphere.
- a method for manufacturing a liquid crystal display device or an organic EL display device comprising the step of forming a semiconductor device using the manufacturing method according to the 29th or 34th aspect of the present invention. can get.
- the flatness of the surface can be reduced to 1 nm or less in Ra and 20 nm or less in peak 'toe' valley value. .
- the surface of the gate insulating film is flattened, and the interface with the channel region is flattened to prevent carrier interface scattering, thereby achieving high carrier mobility.
- the gap between the gate electrode and the surrounding insulating layer is filled to provide a flat surface from the gate electrode to the insulating layer surface, thereby preventing the gate insulating film from being broken.
- FIG. 1 is a cross-sectional view showing an example of the structure of a thin film transistor according to a first embodiment of the present invention.
- FIG. 2 is an enlarged sectional view showing an example of a structure of a gate electrode portion of the thin film transistor shown in FIG.
- FIG. 3 is a sectional view for explaining an example of a manufacturing method of the thin film transistor shown in FIG. FIG.
- FIG. 5 A sectional view for explaining an example of a method of manufacturing the thin film transistor shown in FIG. 1 in order of steps.
- FIG. 6 is a sectional view for explaining an example of a manufacturing method of the thin film transistor shown in FIG. 1 in order of steps.
- FIG. 7 A sectional view for explaining an example of a method of manufacturing the thin film transistor shown in FIG. 1 in order of steps.
- FIG. 8 A photograph simulating the FIB cross section of the overcoat film in the thin film transistor according to the first embodiment of the present invention.
- FIG. 9 A cross-sectional view showing an example of the structure of the thin film transistor according to the second embodiment of the present invention.
- FIG. 10 is an enlarged sectional view showing an example of the structure of the gate electrode portion of the thin film transistor shown in FIG. .
- FIG. 10 is a sectional view for explaining an example of a manufacturing method of the thin film transistor shown in FIG. 9 in order of steps.
- FIG. 12 A sectional view for explaining an example of a method of manufacturing the thin film transistor shown in FIG. 9 in order of steps.
- FIG. 10 is a cross-sectional view for explaining an example of a manufacturing method of the thin film transistor shown in FIG. 9 in order of steps.
- FIG. 14 A sectional view for explaining an example of a method of manufacturing the thin film transistor shown in FIG. 9 in order of steps.
- FIG. 15 A sectional view for explaining an example of a method of manufacturing the thin film transistor shown in FIG. 9 in order of steps.
- FIG. 16 A sectional view showing an example of the structure of a thin film transistor according to a third embodiment of the present invention.
- FIG. 1 is a cross-sectional view showing an example of the structure of a thin film transistor (TFT) according to the present invention applied to a liquid crystal display device.
- the thin-film transistor is formed of a transparent resin film (insulator layer) 11 made of a transparent photosensitive resin formed on a glass substrate (insulating substrate) 10, a transparent resin film 11 and a glass substrate 10.
- the gate electrode (conductor layer) 12 is formed to reach the same height as the transparent resin film 11.
- the thin film transistor also has a gate insulating film 13 composed of an insulating coating film (overcoat film) 131 formed over the transparent resin film 11 and the gate electrode 12, and a CVD dielectric film (insulator CVD film) 132 thereon.
- FIG. 2 is an enlarged cross-sectional view showing the structure of the gate electrode portion of the thin film transistor according to the first embodiment.
- the illustrated gate electrode 12 is embedded in a groove formed in the flat transparent resin film 11, from the glass substrate 10 side toward the semiconductor layer side (that is, in order from the bottom of the figure), the base adhesion layer 121, the catalyst The layer 122, the conductive metal layer 123, and the conductive metal diffusion suppression layer 124 are configured.
- the surface of the gate electrode 12 and the transparent resin film 11 are embedded in the groove of the transparent resin film 11 so as to form substantially the same plane. For this reason, the flatness of the upper structure of the gate electrode 12 is a sufficient force S, and there is a problem with the flatness when viewed microscopically.
- the flatness of the surface of the conductive metal layer 123 (Cu layer) by electroless plating so far has reached 17.74 nm for Ra and 193 ⁇ 92 nm for the peak “toe” valley (P—V) value.
- the surface of the conductive metal diffusion suppression layer 124 (electroless plating Ni layer) formed in Fig. 5 also has a flatness of Ra of 8.58 nm and a peak “toe” valley value of 68.7 nm.
- an insulator coating film 131 having a thickness of 40 nm is formed on the gate electrode 12 and the transparent resin film 11.
- This insulator coating film 131 fills the gap 112 between the gate electrode 12 and the transparent resin film 11 and does not reflect the irregularities on the surface of the gate electrode 12. It provides a flat surface of 2 ⁇ 16nm with one toe valley value. These values are as follows: Even if the flatness of the gate electrode surface is 3 nm or more at Ra and the peak 'toe' valley value is 30 nm or more, the required Ra for the insulator coating film is 1 nm or less at Ra and the peak 'toe' valley The value is 20nm or less!
- FIG. 8 is an electron micrograph showing a state in which a cross section of a configuration in which an insulator coating film (overcoat film) is formed on a gate electrode by plating wiring is observed by FIB processing. As shown in Fig. 8, it can be seen that a flat surface is formed regardless of the underlying roughness.
- the surface of the silicon nitride dielectric film (CVD dielectric film) 132 having a thickness of 150 to 160 nm formed on the insulator coating film (overcoat film) 131 by the CVD method is Ra 0
- a flatness of 7.54 nm was obtained with a peak value of 70 nm and peak 'toe' ( Figure 2).
- TFT thin film transistor
- SOG spin-on glass
- the SOG film is prepared from the siloxane component that forms the film and the alcohol component as the solvent.
- the solvent is evaporated by heat treatment, and the film is cured to form an SOG insulating film.
- SOG is a general term for films formed with these solutions.
- SOG is classified into silica glass, alkylsiloxane polymer, alkylsilsesquioxane polymer (MSQ), hydrogenated silsesquioxane polymer (HSQ), and hydrogenated alkylsilsesquioxane polymer (HOSQ) according to the structure of siloxane.
- silica glass is first-generation inorganic SOG
- alkylsiloxane polymer is first-generation organic SOG
- HSQ is second-generation inorganic SOG
- MS Q and HOSQ are second-generation organic SOG.
- coating films they are often baked at 500 ° C or higher, but in any case, when using a transparent resin layer, the temperature cannot be increased, so the baking temperature is 300 ° C or lower. Is used. Also, instead of the Si organic compound and Si inorganic compound as described above, use a solution in which at least one of another organic metal compound or metal inorganic compound is dissolved in an organic solvent (especially one having a firing temperature of 300 ° C or lower). That power S. Examples of other metals include Ti, Ta, Al, Sn, and Zr.
- the thickness of the gate insulating film 13 formed of the insulating coating film 131 and the CVD dielectric film 132 thereon is too thick, the driving capability of the transistor deteriorates and the gate capacitance increases. Therefore, in the case of a silicon nitride dielectric film, a thickness of about 350 to 360 nm or less and an EOT of 200 nm or less are preferable.
- EOT is the silicon dioxide equivalent film thickness obtained by multiplying the quotient by dividing the dielectric constant of silicon dioxide by the average dielectric constant of the film.
- the EOT is 95 nm or more.
- the thickness of the insulator coating film 131 does not depend on the roughness of the underlayer, and in order to obtain a flat surface (if the surface roughness of the underlayer is about 30 nm with a peak 'toe' valley), the physical film A minimum thickness of 40 nm is required.
- the dielectric constant of this film can vary. Considering that the maximum dielectric constant is about 10, the EOT is preferably 15 nm or more. The maximum film thickness is preferably about 120nm or less!
- the thickness of the CVD dielectric film 132 is preferably 80 nm or more in EOT considering that the breakdown voltage is mainly assumed by this film.
- the dielectric constant of the insulating coating film 131 is 2.6 or more, and the dielectric constant of the CVD dielectric film 132 is 4
- FIGS. 3 to 7 are schematic views showing the method of manufacturing the thin film transistor according to the first embodiment in the order of steps.
- a glass substrate 10 is prepared as a substrate.
- the glass substrate may be a large substrate capable of forming a large screen of 30 inches or more.
- This glass substrate is treated with a 0.5 volume% hydrofluoric acid aqueous solution for 10 seconds and washed with pure water to remove the surface contamination by lift-off.
- the glass substrate 10 is added with sodium hydroxide to pure water.
- silane coupling agent solution in which aminopropylethoxysilane, which is a silane coupling agent, is dissolved in an aqueous solution whose pH is controlled to 10 at a concentration of 0.1% by volume, that is, the silane coupling agent solution is heated to room temperature. Soaked for 30 minutes to adsorb the silane coupling agent on the surface of the glass substrate. Thereafter, the substrate was treated on a hot plate at 110 ° C. for 60 minutes, and a silane coupling agent was chemically bonded to the surface of the glass substrate to form a base adhesion layer (thickness 10 nm) 121.
- the base adhesion layer 121 it is possible to make a structure in which amino groups are substantially arranged on the surface of the glass substrate 10 and the metal complex is easily coordinated. Since the silane coupling agent is usually transparent, even if it is formed over the entire surface of the glass substrate 10, the effects of the present invention can be obtained. Further, the transparent photosensitive resin used in the glass substrate 10 and subsequent steps can be obtained. Preferable from the viewpoint of obtaining adhesion!
- a positive photoresist solution is applied to the surface of the base adhesive layer 121 using a spinner, and preheated at 100 ° C for 120 seconds on a hot plate.
- a photosensitive transparent resin film 11 having a thickness of 2 ⁇ was formed.
- a photoresist containing alkali-soluble alicyclic olefin-based resin described in Patent Document 4 Japanese Patent Laid-Open No. 2002-296780 was used.
- the organic material forming the transparent film was selected from the group consisting of acrylic resin, silicone resin, fluorine resin, polyimide resin, polyolefin resin, alicyclic olefin resin, and epoxy resin.
- Transparent resin can be used.
- a photosensitive transparent resin film containing an alkali-soluble alicyclic olefin-based resin and a radiation-sensitive component is advantageous as the transparent film, and in particular, Patent Document 4 or Patent It is preferable to use a photosensitive transparent resin composition as described in detail in Reference 5 (Japanese Patent Laid-Open No. 2001-188343).
- the mixed light of g, h, and i rays is selectively applied to the photosensitive transparent resin film 11 through the mask pattern by the mask aligner. Irradiated. Then, after development for 90 seconds at 0.3 weight 0/0 tetramethylammonium Niu arm hydroxide aqueous solution for 60 seconds rinsed with deionized water, to form a groove having a predetermined pattern on the glass substrate 10. Thereafter, heat treatment was performed at 230 ° C. for 60 minutes in a nitrogen atmosphere to cure the photosensitive transparent resin film 11.
- palladium chloride-hydrochloric acid aqueous solution palladium chloride 0 ⁇ 005 (Volume%, hydrochloric acid 0.01% by volume) for 3 minutes at room temperature, treated with reducing agent (Reeduuser MAB-2 manufactured by Uemura Kogyo Co., Ltd.) and washed with water, selectively in the groove formed was added with a palladium catalyst (catalyst layer: thickness 10 to 50 nm) 122.
- the substrate provided with the palladium catalyst 122 is immersed in a copper electroless plating solution (PGT manufactured by Uemura Kogyo Co., Ltd.), and the copper layer 123 (conductive layer) is selectively placed in the groove.
- Metal layer: thickness 1.9 ⁇ 111) was formed.
- the copper layer 123 is preferably finished at a position lower than the surface height of the photosensitive transparent resin film 11 by the thickness of the subsequent diffusion suppression film (conductive metal diffusion suppression layer) 124.
- the conductive metal layer 123 includes at least one of Cu and Ag
- the diffusion suppression film (conductive metal diffusion suppression layer) 124 is a metal selected from any of Ni, W, Ta, Nb, and Ti. It is desirable to comprise.
- the conductive metal layer may be formed by a printing method, an ink jet method, or a sputtering method in addition to the plating method.
- A1 is appropriate as the metal in addition to Cu and Ag, and when A1 is used, the diffusion suppression film (conductive metal diffusion suppression layer) can be omitted.
- an insulator coating film 131 was formed so as to extend from the surface of the gate electrode 12 to the surface of the photosensitive transparent resin film 11.
- the insulating coating film 131 is formed by applying organosiloxane, which is an organic compound of Si, to an organic solvent (propylene glycol monomethyl ether) with a liquid having a solvent power, keeping it at 120 ° C in the atmosphere for 90 seconds, and then drying. It was obtained by firing for 1 hour at 180 ° C in the atmosphere (even in nitrogen gas).
- the Si N film (silicon nitride dielectric film) 132 was applied to the CV using the microwave excitation RLSA plasma processing equipment.
- an amorphous silicon film 141 and an n + amorphous silicon film 142 are continuously deposited by a known PECVD (Plasma Enhanced Chemical Vapor Deposition) method, and then gated by a photolithography method and a known RIE (Reactive Ion Etching) method. A portion of the amorphous silicon film was removed except on and around the electrode 12.
- PECVD Pullasma Enhanced Chemical Vapor Deposition
- the source electrode and the drain electrode are sequentially formed in the order of Ti, Al, and Ti by a known sputtering method or the like, and patterning is performed by one photolithography method.
- the source electrode 15 and the drain electrode 16 were formed.
- the n + -type amorphous silicon film 142 was etched by a known method to separate the source region and the drain region.
- a silicon nitride film (not shown) was formed as a protective film by a known PECVD method to complete the thin film transistor of the first example.
- FIG. 9 is a cross-sectional view showing the structure of a thin film transistor (TFT) according to a second embodiment of the present invention, which is applied to a liquid crystal display device.
- the thin film transistor is formed on a glass substrate (insulating substrate) 10 and made of a transparent photosensitive resin.
- the thin film transistor is formed on the transparent resin film 11 so as to reach the glass substrate 10, and is substantially the same as the transparent resin film 11.
- the gate electrode 12 is formed up to the height of the gate electrode 12, the transparent resin film 11 and the gate insulating film 133 made of an insulating coating film formed on the gate electrode 12, and the gate insulating film 133 is formed on the gate electrode 12.
- a source electrode 15 and a drain electrode 16 connected to the semiconductor layer 14.
- FIG. 10 is an enlarged cross-sectional view showing the structure of the gate electrode portion of the thin film transistor according to the second embodiment.
- the illustrated gate electrode 12 is formed from the glass substrate 10 side to the semiconductor layer side (that is, in order from the bottom of the figure) by the base adhesion layer 121, the catalyst layer 122, the conductive metal layer 123, and the conductive metal diffusion suppression layer 124. It is configured.
- the gate electrode 12 is embedded in a groove formed in the flat transparent resin film 11. As shown in the figure, the surface of the gate electrode 12 and the transparent resin film 11 are embedded in the groove of the transparent resin film 11 so as to form substantially the same plane.
- the flatness of the upper structure of the gate electrode 12 has a problem with the force S to be secured and the flatness when viewed microscopically.
- the flatness of the surface of the conductive metal layer 123 (Cu layer) by the conventional electroless plating reached 17 ⁇ 74nm in Ra and reached 193 ⁇ 92 ⁇ m in peak 'toe' valley value, and was formed on it
- the surface of the conductive metal diffusion suppression layer 124 (Ni layer with electroless plating) has a flatness of 8 ⁇ 58nm for Ra and 6 ⁇ 7nm for the peak tow valley value.
- an insulating coating film (gate insulating film) 133 having a thickness of 250 nm is formed on the conductive metal diffusion suppression layer 124.
- the insulator coating film 133 fills the gap 112 between the gate electrode 12 and the transparent resin film 11, and does not reflect the irregularities on the surface of the gate electrode 12. It was possible to provide a gate insulating film having a flat surface of 0.30 nm at a and a peak “toe” value of 3.55 nm at a.
- FIG. 17 is an electron micrograph showing a state of observing a cross section of a configuration in which a gate insulating film made of an insulating coating film is formed on such a gate electrode. As shown in Fig. 17, it can be seen that a flat surface is formed without depending on the roughness of the substrate.
- a thin film transistor can be formed without causing unevenness due to the gate electrode 12 in the semiconductor layer formed on the gate insulating film.
- the mobility of carriers can be greatly improved, and the CVD process for forming the CVD dielectric film in the film formation process of the gate insulating film can be omitted, and the film can be formed by a simple coating process. The process was simplified.
- FIGS. 11 to 15 are schematic views showing the method of manufacturing the thin film transistor according to the second embodiment in the order of steps.
- a glass substrate 10 is prepared as a substrate.
- the glass substrate may be a large substrate capable of forming a large screen of 30 inches or more.
- This glass substrate is treated with 0.5% by volume hydrofluoric acid aqueous solution for 10 seconds and washed with pure water to remove the surface contamination.
- the glass substrate 10 is a silane in which aminopropylethoxysilane, which is a silane power coupling agent, is dissolved in an aqueous solution whose pH is controlled to 10 by adding sodium hydroxide to pure water at a concentration of 0.1% by volume.
- the silane coupling agent is usually transparent, the effect of the present invention can be obtained even if it is formed over the entire surface of the glass substrate 10, and the transparent photosensitive resin used in the glass substrate 10 and the subsequent steps. It is preferable from the viewpoint of obtaining close contact.
- a positive photoresist solution is applied to the surface of the base adhesive layer 121.
- a photosensitive transparent resin film 11 having a thickness of 2 ⁇ was formed by coating using an inner layer and subjecting it to a prebeta treatment at 100 ° C. for 120 seconds on a hot plate.
- the positive photoresist described above contained an alkali-soluble alicyclic polyolefin resin described in Patent Document 4.
- the organic material forming the transparent film is a transparent resin selected from the group consisting of acrylic resins, silicone resins, fluorine resins, polyimide resins, polyolefin resins, alicyclic olefin resins, and epoxy resins. It can be used.
- a photosensitive transparent resin film is advantageous as the transparent film, and in particular, a photosensitive transparent resin composition as detailed in Patent Document 4 or Patent Document 5 is used. It is preferred to use.
- the mixed light of g, h, and i rays is selectively applied to the photosensitive transparent resin film 11 through the mask pattern by the mask aligner. Irradiated. Then, after development for 90 seconds at 0.3 weight 0/0 tetramethylammonium Niu arm hydroxide aqueous solution for 60 seconds rinsed with deionized water, to form a groove having a predetermined pattern on the glass substrate 10. Thereafter, heat treatment was performed at 230 ° C. for 60 minutes in a nitrogen atmosphere to cure the photosensitive transparent resin film 11.
- the glass substrate 10 provided with the noradium catalyst 122 is immersed in a copper electroless plating solution (PGT manufactured by Uemura Kogyo Co., Ltd.), and the copper substrate is selectively placed in the groove.
- Layer 123 (thickness 1 ⁇ 9 m) was formed as a conductive metal layer.
- the copper layer 123 is preferably finished at a position lower than the surface height of the photosensitive transparent resin film 11 by the film thickness of the subsequent diffusion suppression film (conductive metal diffusion suppression layer) 124.
- a nickel electroless plating solution to form a diffusion suppression film 124 (thickness 0.1 ⁇ m) by nickel on the copper layer 123.
- an insulating film was applied so as to extend from the surface of the gate electrode 12 to the surface of the photosensitive transparent resin film 11, thereby forming a gate insulating film 133.
- the gate insulating film 133 is formed by applying a solution of organosiloxane, which is an Si organic compound, to an organic solvent (propylene glycol monomethyl ether) at 120 ° C in the atmosphere for 90 seconds. It was obtained by baking for 1 hour at 180 ° C in the air (or even nitrogen gas).
- an amorphous silicon film 141 and an n + type amorphous silicon film 142 are continuously deposited by a known PECVD method, and an amorphous silicon film is formed on the gate electrode 12 and its peripheral portion by a photolithography method and a known RIE method. Some removed.
- the source electrode and the drain electrode are sequentially formed in the order of Ti, Al, and Ti by a known sputtering method or the like, and patterning is performed by one photolithography method.
- the source electrode 15 and the drain electrode 16 were formed.
- the n + type amorphous silicon film 142 was etched by a known method to separate the source region and the drain region.
- a silicon nitride film (not shown) was formed as a protective film by a known PECVD method to complete the thin film transistor of the second example.
- a method of forming a thin film transistor according to the third embodiment applied to a liquid crystal display device will be described with reference to FIG.
- a diffusion suppression film 124 (thickness 0 .; m) made of nickel is formed on the copper layer 123, and the gate electrode 12 is formed.
- a Si N film (silicon nitride dielectric film) 132 is grown by CVD using the microwave-excited RLSA plasma processing equipment from the surface of the electrode 12 to the entire surface of the transparent resin film 11.
- This insulator coating film 131 is coated with a liquid obtained by dissolving organosiloxane, which is an Si organic compound, in an organic solvent (propylene glycol monomethyl ether), kept at 120 ° C. in the atmosphere for 90 seconds, and then dried in the atmosphere. (It may be nitrogen gas) It was obtained by baking at 180 ° C for 1 hour.
- organosiloxane which is an Si organic compound
- organic solvent propylene glycol monomethyl ether
- FIG. 16 is a cross-sectional view of the thin film transistor at this time.
- a conductive film such as a metal oxide such as indium tin oxide (ITO) may be formed by using only copper and silver.
- ITO indium tin oxide
- the present invention can be applied to display devices such as liquid crystal display devices, organic EL devices, inorganic EL devices, etc., and these display devices can be enlarged, and can also be applied to wiring other than display devices.
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Description
Claims
Priority Applications (2)
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US12/442,330 US20090278134A1 (en) | 2006-09-22 | 2007-09-21 | Semiconductor device and method of manufacturing the semiconductor device |
EP07807788A EP2088629A1 (en) | 2006-09-22 | 2007-09-21 | Semiconductor device and semiconductor device manufacturing method |
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JP2006257848 | 2006-09-22 | ||
JP2006-257848 | 2006-09-22 | ||
JP2006-313492 | 2006-11-20 | ||
JP2006313492A JP2008103653A (ja) | 2006-09-22 | 2006-11-20 | 半導体装置及び半導体装置の製造方法 |
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PCT/JP2007/068458 WO2008035786A1 (fr) | 2006-09-22 | 2007-09-21 | Dispositif semi-conducteur et procédé de fabrication d'un dispositif semi-conducteur |
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US (1) | US20090278134A1 (ja) |
EP (1) | EP2088629A1 (ja) |
JP (1) | JP2008103653A (ja) |
KR (1) | KR20090071538A (ja) |
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CN101807004A (zh) * | 2010-03-08 | 2010-08-18 | 彩虹集团电子股份有限公司 | 一种用于彩色显像管网版生产的工作版的制做方法 |
US11282964B2 (en) | 2017-12-07 | 2022-03-22 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device |
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WO2012090432A1 (ja) * | 2010-12-27 | 2012-07-05 | シャープ株式会社 | アクティブマトリクス基板及びその製造方法、並びに表示パネル |
US8987071B2 (en) * | 2011-12-21 | 2015-03-24 | National Applied Research Laboratories | Thin film transistor and fabricating method |
WO2013179922A1 (en) | 2012-05-31 | 2013-12-05 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method for manufacturing the same |
CN103681870B (zh) * | 2012-09-13 | 2016-12-21 | 北京京东方光电科技有限公司 | 阵列基板及其制造方法 |
TWI692546B (zh) * | 2013-11-21 | 2020-05-01 | 日商尼康股份有限公司 | 佈線圖案之製造方法及電晶體之製造方法 |
JP6926939B2 (ja) * | 2017-10-23 | 2021-08-25 | 東京エレクトロン株式会社 | 半導体装置の製造方法 |
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JP2005210081A (ja) | 2003-12-02 | 2005-08-04 | Semiconductor Energy Lab Co Ltd | 電子機器、半導体装置およびその作製方法 |
JP2005173050A (ja) | 2003-12-09 | 2005-06-30 | Ricoh Co Ltd | 画像形成用トナー、現像剤及び画像形成装置 |
US20060209222A1 (en) * | 2005-03-15 | 2006-09-21 | Nec Lcd Technologies, Ltd. | Liquid crystal display device and manufacturing method of the same |
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CN101807004A (zh) * | 2010-03-08 | 2010-08-18 | 彩虹集团电子股份有限公司 | 一种用于彩色显像管网版生产的工作版的制做方法 |
CN101807004B (zh) * | 2010-03-08 | 2012-07-11 | 彩虹集团电子股份有限公司 | 一种用于彩色显像管网版生产的工作版的制做方法 |
US11282964B2 (en) | 2017-12-07 | 2022-03-22 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device |
US11784259B2 (en) | 2017-12-07 | 2023-10-10 | Semiconductor Energy Laboratory Co., Ltd. | Oxide semiconductor device |
Also Published As
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US20090278134A1 (en) | 2009-11-12 |
TW200832718A (en) | 2008-08-01 |
JP2008103653A (ja) | 2008-05-01 |
EP2088629A1 (en) | 2009-08-12 |
KR20090071538A (ko) | 2009-07-01 |
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