WO2006025221A1 - 画像記録方法 - Google Patents
画像記録方法 Download PDFInfo
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- WO2006025221A1 WO2006025221A1 PCT/JP2005/015090 JP2005015090W WO2006025221A1 WO 2006025221 A1 WO2006025221 A1 WO 2006025221A1 JP 2005015090 W JP2005015090 W JP 2005015090W WO 2006025221 A1 WO2006025221 A1 WO 2006025221A1
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- 230000005484 gravity Effects 0.000 description 1
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- 125000000623 heterocyclic group Chemical group 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
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- 230000000977 initiatory effect Effects 0.000 description 1
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- 229960000310 isoleucine Drugs 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
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- PZYDAVFRVJXFHS-UHFFFAOYSA-N n-cyclohexyl-2-pyrrolidone Chemical compound O=C1CCCN1C1CCCCC1 PZYDAVFRVJXFHS-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- 239000012860 organic pigment Substances 0.000 description 1
- 150000003901 oxalic acid esters Chemical class 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical class COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
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- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
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- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
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- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
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- 229920000642 polymer Polymers 0.000 description 1
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- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
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- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical group C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
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- 235000010215 titanium dioxide Nutrition 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/21—Ink jet for multi-colour printing
- B41J2/2107—Ink jet for multi-colour printing characterised by the ink properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/21—Ink jet for multi-colour printing
- B41J2/2107—Ink jet for multi-colour printing characterised by the ink properties
- B41J2/2114—Ejecting specialized liquids, e.g. transparent or processing liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/14—Multicolour printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
Definitions
- the present invention relates to an image recording method for recording an image by irradiating with ultraviolet rays using an ultraviolet curable ink and an image recording method used therefor.
- the ink jet recording method can easily and inexpensively create an image, and thus has been applied to various printing fields such as photographs, various printing, marking, special printing such as a color filter.
- recording devices that emit and control fine dots, ink with improved color gamut, durability, and emission suitability, and ink absorption, color development, surface gloss, etc.
- improved special paper it is possible to obtain image quality comparable to silver halide photography.
- the improvement in image quality of today's inkjet recording systems can only be achieved when all of the recording devices, ink, and specialty papers are available.
- solvent-free UV curable inks can be cured immediately after landing to suppress bleeding and achieve the durability of finished images and the elimination of volatile organic solvents (VOC).
- VOC volatile organic solvents
- an ultraviolet curable ink that is ejected and ejected from a minute hole by heating is disclosed in JP-A-61-164836, and a solvent-free ink having a similar configuration is disclosed in JP-A-5-214279 and JP-A-5-214280. No., Special Table 2000—504778, W099 / 29787 No., W099Z29788.
- an ink containing a pigment, a water-soluble ultraviolet polymerizable substance, and a water-soluble photopolymerization initiator in an aqueous medium is used, and a large number of ink droplets of one color ink are printed on the printing surface of the printing material.
- the static contact angle with respect to pure water of the printing surface is 60 degrees or less, and the ink volume per unit area and the printing surface to be given when printing one color are inkjet printing method which defines the volume of the ink capable of absorbing the specific conditions has been proposed (e.g., see Patent Document 3.) 0
- the ink after hardening Highly transparent printing is possible if the printing material with high adhesion to the printing material is light transmissive, and printing with high gloss and saturation is possible if the printing material is light reflective. It is said that the inkjet printing method can be realized.
- this method discloses a method in which after curing by ultraviolet irradiation, an operation for removing the remaining solvent is performed, and the non-volatile solvent is washed with water and then dried. Further, since the main purpose is to adjust the wettability of the ink droplets that have landed on the base material to obtain a preferable dot diameter, the surface treatment of the base material is also performed in association therewith.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2000-186243 (Claims)
- Patent Document 2 Japanese Patent Application Laid-Open No. 2002-187918 (Claims)
- Patent Document 3 Japanese Patent Laid-Open No. 2000-117960 (Claims)
- the present invention has been made in view of the above problems, and an object of the present invention is to provide an image recording method excellent in bleeding resistance and adhesion to a substrate, and capable of obtaining an image with high gloss, high density and high saturation, and Provided is an image recording apparatus used for the above.
- a first aqueous ultraviolet curable colored ink is landed on a non-absorbing substrate to form a first colored ink image on the non-absorbing substrate, and the first colored ink image is irradiated with ultraviolet rays.
- To form a first ultraviolet curable colored ink image and then land a second aqueous ultraviolet curable colored ink on the first ultraviolet curable colored ink image to form the first ultraviolet curable colored ink.
- the image recording method after forming a second colored ink image on an ink image, the second colored ink image is irradiated with ultraviolet rays to form a second ultraviolet curable colored ink image.
- An image recording method wherein the static contact angle of the second water-based ultraviolet curable coloring ink to the surface of the curable colored ink image is 10 to 50 degrees.
- the aqueous ultraviolet curable colorless ink is landed on the second ultraviolet curable colored ink image, and the colorless ink is irradiated with ultraviolet rays.
- the first aqueous ultraviolet curable colored ink is landed on a non-absorbing substrate to form a first colored ink image on the non-absorbing substrate, and the first colored ink image is formed on the non-absorbing substrate.
- an aqueous ultraviolet curable colorless ink is landed on the first ultraviolet curable colored ink image, and the colorless ink is irradiated with ultraviolet rays.
- FIG. 1 is a front view showing an example of a configuration of a main part used in a serial printing method in an ink jet recording apparatus that can be used in an image recording method of the present invention.
- FIG. 2 is a schematic view showing an example of an ink jet printing method that can be used in the present invention.
- the present inventors have made an aqueous ultraviolet curable colored ink land on a non-absorbent substrate and then irradiate the ultraviolet curable colored ink with ultraviolet rays.
- the cured ultraviolet curable type is obtained.
- the static contact angle of other UV curable colored ink to the image surface formed with colored ink is 10 to 50 degrees, it has excellent bleeding resistance, adhesion to the substrate, high gloss, and high density.
- the present inventors have found that an image recording method capable of obtaining an image with high saturation can be realized, and have reached the present invention.
- the image recording method of the present invention there are a plurality of steps in which an aqueous ultraviolet curable colored ink is landed on a non-absorbent substrate and then cured by irradiating the ultraviolet curable colored ink with ultraviolet rays. Record the image repeatedly.
- UV irradiation is performed sequentially for each scan, rather than being cured by a single UV irradiation.
- UV curable coloring ink and the UV irradiation conditions are optimally selected to record an image.
- the contact angle of the ink with respect to the cured image surface within the range specified by the present invention, bleeding is suppressed and the gloss in the solid image portion is increased and the density and density are increased. Image formation can be performed with high saturation.
- a method of optimally controlling the environment at the time of ultraviolet irradiation for example, temperature, humidity, or oxygen concentration is also preferable.
- the temperature during UV irradiation is preferably 15 to 50 ° C, and the humidity is preferably in the range of 20 to 70% RH.
- the oxygen concentration is 4. It is preferable that the following 5 X 10- 3 molZL.
- the oxygen concentration is preferably as low as possible, but there is no particular lower limit, but the range of 5 X 10 to 4.5 X 10 3 molZL is preferable from the cost and structural point of view to block oxygen! / ⁇ .
- an upper surface of a substrate that is irradiated with ultraviolet rays after ink ejection is used.
- the space containing the gas and the vicinity of the injection part are roughly sealed, and oxygen in the space is reduced by a known method.
- a method of replacing the sealed space with nitrogen or an inert gas is used.
- gases can be supplied from a compressed gas cylinder, or nitrogen gas produced by removing impurities from the air using activated carbon or a gas filter can be used.
- the desired effect can also be obtained by sending air from which oxygen has been removed with a filter, activated carbon, or the like, into the enclosed space.
- the space cannot be completely sealed due to the conveyance of the recording medium. Therefore, when printing continuously, it is preferable to supply an inert gas continuously or intermittently to avoid an increase in oxygen concentration.
- a surfactant or an appropriate solvent in order to control the surface energy of the cured ink or the surface tension of the ink to be ejected.
- nonionic surfactant examples include polyoxyethylene polyoxypropylene condensate, polyoxyethylene lauryl ether, secondary alcohol ethoxylate, and primary alcohol ethoxylate. , Norphenol ethoxylate
- alcohols such as isopropyl alcohol, n-butyl alcohol, propylene glycol monomethyl ether, propylene glycol monobutyl ether, or glycol ethers are exemplified.
- the nonionic surfactant according to the present invention may be a single type or a mixture of two or more types.
- the nonionic surfactant according to the present invention is preferably used in the ink in the range of 10 to LO, OOOppm, and more preferably 20 to L, OOOppm. Noon according to the present invention When the content of the ionic surfactant is less than 10 ppm, the sufficient effects of the present invention cannot be obtained, and when the content exceeds 10, OOOppm, the weather resistance of the printed portion is slightly higher. It tends to get worse.
- a fluorine-based surfactant having a perfluoroalkyl group in a nonionic surfactant molecule is more preferable. This is thought to be related to the electrical and molecular properties of fluorine atoms and perfluoroalkyl groups.
- the fluorosurfactant having a perfluoroalkyl group in the molecule used in the present invention include a perfluoroalkylethylene oxide-attached product, perfluoroalkylamine oxide, perfluoro Specific examples include, for example, “Surflon (311! « ⁇ 0?
- the fluorosurfactant having a perfluoroalkyl group according to the present invention may be a single type or a mixture of two or more types.
- ink of the present invention water or a mixed solvent of water and an organic solvent is used.
- water-soluble organic solvent preferably used in the ink of the present invention include alcohols (for example, methanol, ethanol, propanol, isopropanol, butanol, isobutanol, secondary butanol, tertiary butanol, pentaanol, and the like).
- alcohols for example, methanol, ethanol, propanol, isopropanol, butanol, isobutanol, secondary butanol, tertiary butanol, pentaanol, and the like).
- polyhydric alcohols for example, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butylene glycol, hexanediol, Pentanediol, glycerin, hexa Ntriol, thioglycol, etc.
- polyhydric alcohol ethers for example, ethylene glycol monomethinoatenoate, ethyleneglycolenomonochinenoatenore, ethyleneglycol mononomonobutinoreatenore, diethyleneglycolenolemono) Methylenoatenore, Diethyleneglycol Monomethinoleatenore, Diethyleneglycol Monobutinoleatenore, Propylene Glycol Monomethyl Ether, Propylene Glyconole Monobutino
- a solid image is formed on the substrate with the first ink. After forming and curing, a new ink droplet is dropped on the solid cured image using a contact angle measuring device, for example, an automatic contact angle measuring device CA-V type manufactured by Kyowa Interface Chemical Co., Ltd. Can be measured.
- a contact angle measuring device for example, an automatic contact angle measuring device CA-V type manufactured by Kyowa Interface Chemical Co., Ltd. Can be measured.
- the amount of ink applied to form a solid image with the ultraviolet curable colored ink was set to 100%.
- the total ink application amount of the ultraviolet curable coloring ink used for image formation is less than 100%.
- the total ink adhesion amount is less than 100%, that is, the ink is applied in an amount that does not completely cover the entire printing surface.
- each color This means that the total amount of ink attached is less than 100%.
- one method is an interleave method, in which the ink is scanned and landed while thinning out the ink, and then sequentially irradiated with ultraviolet rays. is there.
- the image recording method is a line recording method
- a method of irradiating ultraviolet rays for each color printing a method of controlling the amount of ink to be ejected, or a plurality of recordings per color.
- a method of providing a head and irradiating ultraviolet rays for each recording head can be appropriately selected or applied in combination.
- the cured colored ink image has an image area relative to the area of the base material (hereinafter referred to as an image area ratio, also simply referred to as an image line ratio).
- the image area ratio is preferably less than 90%, more preferably 0% or more, preferably less than 100%, that is, it is preferable to irradiate ultraviolet rays without covering the entire area of the substrate with ink. Less than 90%.
- the image is read using a CCD monitor or the like.
- the image area ratio can be obtained from the obtained image data.
- the treatment may be performed in a drying process for removing moisture contained in the ultraviolet curable colored ink. It is preferable from the viewpoint of improving the adhesion of the substrate to the base material and improving the stability of the image formed when stored for a long time.
- the drying process is performed for each scan, or after all the images have been formed, the drying process is performed. May be.
- the drying method that can be used in the present invention includes a method of heating with warm water, a method of heating in contact with a heater or a heating coil, convection heating means for heating by convection such as a dryer, infrared or high-frequency radiation.
- convection heating means for heating by convection such as a dryer, infrared or high-frequency radiation.
- radiant heating means for heating by radiation of electromagnetic waves include radiant heating means for heating by radiation of electromagnetic waves.
- an ultraviolet curable colored ink is ejected to form an image, and then an aqueous ultraviolet curable colorless ink (hereinafter simply referred to as an ultraviolet curable ink) is applied to the image before or after ultraviolet irradiation. It is preferable that a higher density, gloss, and saturation can be obtained.
- colorless ink is applied, followed by curing by irradiating with ultraviolet rays.
- the colorless ink may be applied, followed by curing by irradiation with ultraviolet rays.
- an ink jet recording head used for discharging an ultraviolet curable colored ink may be provided with a colorless ink discharging portion, or an inkjet recording head for an ultraviolet curable colored ink and May be ejected by another ink jet recording head, or may be applied by another coating method or printing method after forming a color image.
- the colorless ink according to the present invention contains a photopolymerizable compound, a photopolymerization initiator, and a polymerization inhibitor, and does not substantially contain a colorant (both color materials!).
- Water-based UV curable ink It is.
- substantially free of a colorant means that the colorant does not contain any colorant or the colorant content power is less than 0.1% by mass relative to the total mass of the colorless ink.
- an ink jet recording apparatus (hereinafter also simply referred to as a recording apparatus) used in the image recording method of the present invention will be described with reference to the drawings as appropriate.
- the recording apparatus of the drawings is merely one aspect of the inkjet recording apparatus of the present invention, and the image recording method of the present invention is not limited to the drawings shown here.
- FIG. 1 is an example of an ink jet recording apparatus that can be used in the image recording method of the present invention, and is a front view showing a configuration of a main part used in a serial printing method.
- the recording apparatus 1 includes a head carriage 2, a recording head 3, an irradiation unit 4, a platen unit 5, and the like.
- the recording material P is guided by the guide member 6 and moves from the front to the back in FIG. 2 by the operation of the conveying means (not shown).
- Head scanning means (not shown) scans the recording head 3 held by the head carriage 2 by reciprocating the head carriage 2 in the Y direction in FIG.
- the head carriage 2 is installed on the upper side of the recording material P, and accommodates a plurality of recording heads 3 according to the number of colors used for image printing on the recording material P, with the discharge ports arranged on the lower side. .
- the head carriage 2 is installed with respect to the main body of the recording apparatus 1 in such a manner that it can reciprocate in the Y direction in FIG. 1, and reciprocates in the Y direction by driving the head scanning means.
- the head carriage 2 is white (W), yellow (Y), magenta (M), cyan (C), black (K), light yellow (Ly), light magenta (Lm), and light cyan. (Lc), light black (Lk), and white (W) should be drawn as containing the recording head 3! /, And the color of the recording head 3 stored in the head carriage 2 when performing 1S.
- the number is appropriately determined, and in addition, for example, the colorless ink according to the present invention may be loaded.
- the recording head 3 records the ultraviolet curable coloring ink supplied from the ink supply means (not shown) from the discharge port by the operation of the discharge means (not shown) provided inside. Discharge toward recording material P.
- the ultraviolet curable ink ejected by the recording head 3 is composed of a coloring material, a polymerizable monomer, an initiator, etc., and is a monomer associated with the initiator acting as a catalyst when irradiated with ultraviolet rays. Curing by crosslinking and polymerization reaction It has the property to do.
- UV curable ink is ejected as ink droplets onto the possible region, and the ink droplets are landed on the landable region.
- the illumination means 4 irradiates the ultraviolet ray to cure.
- the recording material P is appropriately moved from the near side to the back side in FIG. 1 by the conveying means, and scanning with the head scanning means is performed again.
- the UV curable ink is discharged to the next adjacent landable area.
- the irradiation means 4 includes an ultraviolet lamp that emits ultraviolet light in a specific wavelength region with stable exposure energy and a filter that transmits ultraviolet light of a specific wavelength.
- ultraviolet lamp that emits ultraviolet light in a specific wavelength region with stable exposure energy
- a filter that transmits ultraviolet light of a specific wavelength.
- ultraviolet lamps such as strip metal halide lamps, cold cathodes.
- a tube, a mercury lamp, or a black light is preferred.
- the radiation source used in the illumination means 4 according to the present invention is preferably one that can adjust the irradiation intensity (mW) as appropriate.
- serial printing method has been described as an example in FIG. 1, but in addition, an ink jet recording apparatus of each ink jet printing method as shown in FIG. 2 can be used. it can.
- FIG. 2a shows that the recording head 19 is arranged in the width direction of the recording material 20 and that the recording material 20 is conveyed in the direction of the arrow Y and irradiated with actinic rays from the printing and irradiation means 24.
- the recording material 20 is moved in the direction of arrow Y and recording is started.
- FIG. 2 is a method in which printing is performed while moving the head 19 in the sub-scanning direction Y2 (width direction on the recording material) and irradiation with actinic rays from the irradiation means 24 (flat head method).
- Figure 2b As described above, the recording material 20 is moved in the direction of arrow Y, and the recording head 19 is
- the means for controlling the irradiation amount of ultraviolet rays may be a deviation from the means for changing the irradiation range of ultraviolet rays or the means for changing the illuminance of ultraviolet rays. preferable.
- the irradiation intensity of ultraviolet rays can be expressed in mW, which represents the effective ultraviolet energy that the ultraviolet irradiation device can irradiate the recording material in a unit time (1 second).
- the irradiation energy of ultraviolet rays changes the irradiation range, changes the number of irradiation light sources to be lit, or changes the amount of power supplied to the irradiation light sources (changes the exposure time). Desired conditions can be set by appropriately combining the above methods.
- the inkjet recording apparatus of the present invention when there are a plurality of recording speeds, the inkjet recording apparatus of the present invention is! In the inkjet recording method, the energy of ultraviolet rays irradiated per unit area of the recording material regardless of the image recording speed. It is preferable to have a control means for making the amount substantially constant.
- the actinic ray is irradiated between 001 seconds and 2.0 seconds, and more preferably between 0.001 seconds and 1.0 seconds. In order to form a high-definition image, it is particularly important that the irradiation timing is as early as possible.
- the non-absorbing recording material means that the ink composition (ink) is not absorbed!
- the ink transfer amount in the Bristow method as shown below is 0. Less than lmlZmm 2 and substantially OmlZmm 2 is defined as non-absorbent recording material.
- the Bristow method is a method for measuring the liquid absorption behavior of paper and paperboard in a short time.
- liquid Measured according to the absorbency test method (Bristow method) and expressed as the amount of ink transferred (mlZm 2 ) at a contact time of 40 ms.
- the measurement method described above in order to easily determine the force measurement area where pure water (ion-exchanged water) is used for measurement, in the present invention, less than 2% of a water-soluble dye is contained. Moh.
- non-absorbent recording material various non-absorbable plastics and films used for so-called flexible packaging, as well as sized water-resistant coated paper, can be used.
- plastic films include PET (polyethylene terephthalate) film, OPS (stretched polystyrene) film, OPP (stretched polypropylene) film, ONy (stretched nylon) film, PVC (polybule chloride) film, PE (polyethylene).
- TAC triacetyl cellulose
- the surface energy is more preferably preferably the base material is 35 ⁇ 60MjZm 2 instrument is a substrate 40 ⁇ 60MjZm 2
- the ultraviolet curable colored ink used in the image recording method of the present invention contains, in addition to the color material, mainly water, a polymerizable compound that polymerizes by ultraviolet rays, and an aqueous photopolymerization initiator that generates radicals by ultraviolet rays. Speak.
- the polymerizable compound that can be used in the present invention is preferably water-soluble.
- both an acidic group and a (meth) atallyloyl group or a vinyl group have a vinyl group in the molecule.
- a polymerizable compound imparted with hydrophilicity by a polyethylene oxide chain is used.
- examples of such compounds include (meth) atalyses of polyhydric alcohols such as diethylene glycol di (meth) acrylate and tetraethylene glycol di (meth) acrylate. Examples thereof include oxalic acid esters.
- a polyfunctional water-soluble polymerizable compound described in JP-A-8-165441, a (meth) acrylic acid ester of a hydrophilic polyepoxide in which glycerin force is also induced disclosed in JP-A-2000-117960, US Pat.
- the polyfunctional cationic acrylic monomer of US Pat. No. 612,388 is also a preferred water-soluble polymerizable compound.
- More preferable water-soluble polymerizable compounds used in the present invention include hydrophilic polyfunctional polymerizable compounds as exemplified below. These compounds are highly hydrophilic and water-soluble, have polymerizability, have a high polymerization rate, have a low viscosity per se, and have a conventional viscosity as an aqueous solution. Viscosity is much lower than that of other compounds.
- Examples of the polymerizable compound that undergoes radical polymerization by light include a compound represented by the following general formula A1-A11 and a water-soluble polymerizable compound in which the compound power represented by the following general formula B1-B4 is also selected. .
- A, Rp, Rx, Ry, and Rz represent the following atomic groups.
- n5 integer from 2 to 6
- n6 integer from 0 to 5
- n7 integer from 0 to 5
- n10 integer from 1 to 4
- X2 halogen atom, alkoxyl group, ⁇ S)
- a and Rp in the general formula B1— ⁇ 4 represent the following atomic groups
- the exemplified polymerizable compounds A10-1, A10-2 and the like can be produced by adding an amine having a carboxyl group, that is, a broadly defined amine acid, to the butyl group of acrylic acid.
- an amine having a carboxyl group that is, a broadly defined amine acid
- examples of the amine having a carboxyl group used in this method include paraaminobenzoic acid, glycine, parin, leucine, isoleucine, serine, threonine, methionine, and phenylalanine.
- substances having equivalent performance can be derived from amino acids having two carboxyl groups such as glutamic acid and aspartic acid.
- the polymerization rate, the hardness of the cured product, and the water friction resistance are particularly excellent because it has three polymerizable functional groups in the molecule. It is a compound. It is speculated that the main reason for this tendency is that when a compound having three or more reactive groups is polymerized, it has the effect of greatly reducing hydrophilicity by polymerizing with a high crosslinking density. Yes.
- the aqueous photopolymerization initiator that can be used in the present invention is not particularly limited, and examples thereof include a catalyst that operates in a wavelength region of around 400 nm.
- a catalyst for example, photopolymerization initiation represented by the following general formulas TX1, ⁇ 2, and ⁇ 3, which is a substance having functionality in the long wavelength region, that is, a susceptibility to generate radicals upon receiving ultraviolet rays
- TX1, ⁇ 2, and ⁇ 3 which is a substance having functionality in the long wavelength region, that is, a susceptibility to generate radicals upon receiving ultraviolet rays
- a hydrogen group at least one force of a hydrogen atom in the benzene ring, for example, a carboxyl group or a salt thereof, a sulfonic acid or a salt thereof, a linear or branched chain having 1 to 4 carbon atoms Alkyl group, halogen atom (fluorine, chlorine, bromine, etc.), C 1-4 alkoxyl group, aryloxy group such as phenoxy group, etc. selected by one or more groups or atoms selected Also good.
- M represents a hydrogen atom or an alkali metal (for example, Li, Na, K etc.).
- R and R are each independently a hydrogen atom, or a substituted or unsubstituted
- alkyl group Represents an alkyl group.
- the alkyl group include, for example, a linear or branched alkyl group having about 1 to about carbon atoms, especially about 1 to 3 carbon atoms.
- substituents for these alkyl groups include halogen atoms (fluorine atoms, chlorine atoms, sulfur atoms, etc.), hydroxyl groups, alkoxyl groups (about 1 to 3 carbon atoms), and the like.
- the M represents an integer of 1 to 10.
- Thioxanthone substituted with these hydrophilic atomic groups has a water-soluble and co-soluble property with a cation-based aqueous pigment dispersion, and is less affected by absorption of the organic pigment itself. Acts as a catalyst!
- aqueous photopolymerization initiator constituting the aqueous photocurable resin composition according to the present invention
- a photopolymerization initiator Irgacure2959 manufactured by Ciba Specialty Chemicals
- Water-soluble derivatives can also be used.
- IC-1 to IC-3 having the following formulas can be used.
- IC-l to IC-3 are non-ionic power wavelengths that can be perceived by ultraviolet rays.
- the region is in a shorter wavelength region than the photoinitiators shown as TX-1 to TX-3 mentioned above.
- IC-1 to IC-3 are water-soluble like the above-described TX-1 to TX-3, they are useful as components of the ultraviolet curable colored ink according to the present invention.
- a coloring material is added to color the ink composition.
- the color material various color materials that can be dissolved or dispersed in the main component of the polymerizable compound can be used, but pigments are preferred from the viewpoint of weather resistance.
- Pigments that can be preferably used in the present invention are listed below.
- a ball mill, a sand mill, an attritor, a roll mill, an agitator, a Henschel mixer, a colloid mill, an ultrasonic homogenizer, a pearl mill, a wet jet mill, a paint shaker, or the like can be used.
- a dispersing agent can be added when dispersing the pigment.
- the dispersant it is preferable to use a polymer dispersant.
- a synergist according to various pigments can be used as a dispersion aid.
- the dispersants and dispersion aids are preferably added in an amount of 1 to 50 parts by mass with respect to 100 parts by mass of the pigment.
- the dispersion medium is a solvent or a polymerizable compound.
- the actinic ray curable aqueous ink used in the present invention is preferably solvent-free because it is reacted and cured immediately after ink landing. If the solvent remains in the cured image, the solvent resistance deteriorates and the VOC problem of the remaining solvent occurs. Therefore, it is preferable in view of dispersibility that the dispersion medium is not a solvent but a polymerizable compound, and among them, a monomer having the lowest viscosity is selected.
- the dispersion of the pigment is preferably such that the average particle diameter of the pigment particles is 0.08 ⁇ m to 0.5 ⁇ m, and the maximum particle diameter is 0.3 111 to 10 111, preferably 0.3 /
- the pigment, dispersant, dispersion medium, dispersion conditions, and filtration conditions are appropriately set so that ⁇ -3 / ⁇ .
- the color material concentration is preferably 1% by mass to 10% by mass of the whole ink! /.
- a polymerization inhibitor can be added in an amount of 200 ppm to 20000 ppm. Since the ultraviolet curable ink is preferably ejected by heating and reducing the viscosity, it is preferable to add a polymerization inhibitor to prevent clogging of the head due to thermal polymerization.
- Various compounds are known as polymerization inhibitors, and those widely blended in general polymerizable compositions can be used as they are.
- Polymerization inhibitors include phenolic acid antioxidants, amine compounds, phosphorus antioxidants, hydroquinone monomethyl ethers widely used in (meth) attalimers, hydoxy quinone, t-butyl catechol. Pyrogallol, water, etc. can be used. These are described in detail in “Development Technology of High Molecular Additives” (issued by CMC).
- leveling additives matting agents, polyester-based resins, polyurethane-based resins, vinyl-based resins, acrylic-based resins, acrylic resins, rubbers for adjusting film properties as necessary Family Fats and waxes can also be added. It is also effective to add a very small amount of an organic solvent in order to improve the adhesion to the substrate. In this case, it is effective to add water in a range where solvent resistance and VOC problems do not occur, and the amount used is in the range of 0.1% to 5%, preferably 0.1% to 3%. %.
- a pigment dispersion was prepared.
- CI pigment red 122 is dispersed in an aqueous medium using an appropriate amount of water-soluble polyurethane resin (number average molecular weight 3000) as a dispersant, and magenta containing 14% by mass of a pigment having an average particle diameter of 90 nm. A pigment dispersion was prepared.
- CI pigment blue 15: 3 was dispersed in an aqueous medium using an appropriate amount of water-soluble polyurethane resin (number average molecular weight 3000) as a dispersant, and 15% by mass of pigment having an average particle diameter of 75 nm A cyan pigment dispersion containing was prepared.
- Magenta pigment dispersion (pigment concentration 14 mass%) 17.8 wt% water-soluble polymerizable compound 1 4.2 0 wt% water-soluble polymerizable compound 13.0 mass 0/0 aqueous photopolymerization initiator 1 0.5 Mass% water 64.7 mass%
- Black pigment dispersion (pigment concentration 20 mass%) 25.0 wt% water-soluble polymerizable compound 1 4.2 0 wt% water-soluble polymerizable compound 13.0 mass 0/0 aqueous photopolymerization initiator 1 0.5 Mass% Water 57.5 mass%
- Water-soluble polymerizable compound 1 4.0% by mass
- Water-soluble polymerizable compound 2 13. 0% by mass
- Surfactant Fluorine-based nonionic surfactant, Megafax F-470, manufactured by Dainippon Ink & Chemicals, Inc. 0.1% by mass
- the above-prepared ultraviolet curable type of each color was added to the ink jet recording apparatus shown in FIG.
- Each image was recorded on a salty vinyl sheet, which is a non-absorbing base material that was charged with a colored ink and an ultraviolet curable transparent ink and was plasma-treated on both sides.
- the ink supply system consists of an ink tank, supply pipe, all-chamber tank just before the print head, a pipe with a filter, and a piezo-type print head with a droplet size of 14 pl and a nozzle pitch of 360 dpi, and image printing is 720 x 720 dpi
- a solid image was formed by applying a maximum of one dot of ink droplet per color per pixel. As shown in Fig. 1. In this inkjet recording device, the number of printing passes can be changed to 2, 4, and 6, and the scanning speed of the carriage can be changed to change the energy of ultraviolet rays applied to the ink droplets. .
- a four-color solid image was formed by combining the carriage scanning speed and the output of the ultraviolet light source as shown in Table 1. Curing by UV irradiation is performed every time one scan is completed. After all printing and UV irradiation have been completed, a drying process is performed to remove moisture with warm air (80 ° C), and images 1 to 6 was formed.
- images 2 and 5 image recording was performed without performing UV irradiation for each scan, and images 7 and 8 were formed by batch exposure immediately after the sixth scan when all image recording was completed. .
- images 13 and 14 were formed in the same manner except that all the images were formed and UV-cured, and then water was not removed by the drying process.
- Each UV curable colored ink was applied to a polyethylene terephthalate film with a wire bar at a thickness of 10 m, and then mounted on the ink jet recording apparatus as a base material. It was cured by irradiation with ultraviolet rays. Next, 201 ink droplets of each ink droplet were dropped on each solid color image using Kyowa Interface Chemical Co., Ltd., CA-V type, and each contact angle was measured. The range of the contact angle was obtained.
- the image output is stopped immediately after the first scanning on the substrate is cured by printing and ultraviolet irradiation, and the total of four-color ink on the substrate is printed.
- the line ratio was calculated by measuring the line ratio by reading the obtained image with a CCD monitor and calculating the image area ratio of the obtained image data.
- the reflection density was measured for the four color solid images created above with a blank sheet on the back.
- Solid image density of all colors is 1.0 or more and less than 1.2
- Each of the created images was visually evaluated by 20 subjects, and gloss was evaluated according to the following evaluation criteria, and the average rank was determined.
- Table 1 shows the results obtained as described above.
- the density, the image area ratio (image ratio) in the first scan is less than 100%, or the ink application amount per scan is less than 100%. It can be seen that while maintaining good levels of gloss and saturation, bleeding resistance and image adhesion are further improved.
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- Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
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- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Wood Science & Technology (AREA)
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- Ink Jet Recording Methods And Recording Media Thereof (AREA)
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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JP2006531861A JPWO2006025221A1 (ja) | 2004-08-30 | 2005-08-18 | 画像記録方法 |
DE602005010597T DE602005010597D1 (de) | 2004-08-30 | 2005-08-18 | Bildaufzeichnungsverfahren |
US11/661,298 US7661808B2 (en) | 2004-08-30 | 2005-08-18 | Image recording method and image recording apparatus employing the same |
EP05772527A EP1792744B1 (en) | 2004-08-30 | 2005-08-18 | Image recording method |
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JP2004-249935 | 2004-08-30 | ||
JP2004249935 | 2004-08-30 |
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WO2006025221A1 true WO2006025221A1 (ja) | 2006-03-09 |
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PCT/JP2005/015090 WO2006025221A1 (ja) | 2004-08-30 | 2005-08-18 | 画像記録方法 |
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US (1) | US7661808B2 (ja) |
EP (1) | EP1792744B1 (ja) |
JP (1) | JPWO2006025221A1 (ja) |
DE (1) | DE602005010597D1 (ja) |
WO (1) | WO2006025221A1 (ja) |
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US8297729B2 (en) | 2009-07-24 | 2012-10-30 | Seiko Epson Corporation | Printing device and printing method |
JP2011218794A (ja) * | 2010-03-23 | 2011-11-04 | Seiko Epson Corp | 記録方法、記録装置、インクセット |
JP2014046483A (ja) * | 2012-08-29 | 2014-03-17 | Fujifilm Corp | 画像形成装置及び画像形成方法 |
JP2014101479A (ja) * | 2012-11-22 | 2014-06-05 | Seiren Co Ltd | インクジェット印刷用インクおよび印刷方法 |
US10414159B2 (en) | 2016-09-29 | 2019-09-17 | Seiko Epson Corporation | Ink jet recording method and method of controlling ink jet recording apparatus |
JP2019089300A (ja) * | 2017-11-17 | 2019-06-13 | 株式会社ミマキエンジニアリング | 印刷装置及び印刷方法 |
JP7020875B2 (ja) | 2017-11-17 | 2022-02-16 | 株式会社ミマキエンジニアリング | 印刷装置及び印刷方法 |
Also Published As
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EP1792744B1 (en) | 2008-10-22 |
EP1792744A4 (en) | 2007-10-17 |
JPWO2006025221A1 (ja) | 2008-05-08 |
DE602005010597D1 (de) | 2008-12-04 |
EP1792744A1 (en) | 2007-06-06 |
US20080192100A1 (en) | 2008-08-14 |
US7661808B2 (en) | 2010-02-16 |
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