WO2004055915A2 - Vertical elevated pore phase change memory - Google Patents

Vertical elevated pore phase change memory Download PDF

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Publication number
WO2004055915A2
WO2004055915A2 PCT/US2003/013360 US0313360W WO2004055915A2 WO 2004055915 A2 WO2004055915 A2 WO 2004055915A2 US 0313360 W US0313360 W US 0313360W WO 2004055915 A2 WO2004055915 A2 WO 2004055915A2
Authority
WO
WIPO (PCT)
Prior art keywords
phase change
layer
lower electrode
pore
memory
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/013360
Other languages
English (en)
French (fr)
Other versions
WO2004055915A3 (en
Inventor
Tyler A. Lowrey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ovonyx Inc
Original Assignee
Ovonyx Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ovonyx Inc filed Critical Ovonyx Inc
Priority to AU2003225226A priority Critical patent/AU2003225226A1/en
Priority to JP2004560263A priority patent/JP4446891B2/ja
Priority to CN03825591.XA priority patent/CN1714461B/zh
Publication of WO2004055915A2 publication Critical patent/WO2004055915A2/en
Publication of WO2004055915A3 publication Critical patent/WO2004055915A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/20Multistable switching devices, e.g. memristors
    • H10N70/231Multistable switching devices, e.g. memristors based on solid-state phase change, e.g. between amorphous and crystalline phases, Ovshinsky effect
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • G11C13/0021Auxiliary circuits
    • G11C13/0069Writing or programming circuits or methods
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B63/00Resistance change memory devices, e.g. resistive RAM [ReRAM] devices
    • H10B63/20Resistance change memory devices, e.g. resistive RAM [ReRAM] devices comprising selection components having two electrodes, e.g. diodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/011Manufacture or treatment of multistable switching devices
    • H10N70/061Shaping switching materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/801Constructional details of multistable switching devices
    • H10N70/821Device geometry
    • H10N70/826Device geometry adapted for essentially vertical current flow, e.g. sandwich or pillar type devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/801Constructional details of multistable switching devices
    • H10N70/841Electrodes
    • H10N70/8413Electrodes adapted for resistive heating
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/801Constructional details of multistable switching devices
    • H10N70/881Switching materials
    • H10N70/882Compounds of sulfur, selenium or tellurium, e.g. chalcogenides
    • H10N70/8828Tellurides, e.g. GeSbTe
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • G11C13/0021Auxiliary circuits
    • G11C13/0069Writing or programming circuits or methods
    • G11C2013/008Write by generating heat in the surroundings of the memory material, e.g. thermowrite
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2213/00Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/50Resistive cell structure aspects
    • G11C2213/52Structure characterized by the electrode material, shape, etc.
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]

Definitions

  • This invention relates generally to electronic memories and particularly to electronic memories that use phase change material.
  • Phase change materials may exhibit at least two different states.
  • the states may be called the amorphous and crystalline states. Transitions between these states may be selectively initiated.
  • the states may be distinguished because the amorphous state generally exhibits higher resistivity than the crystalline state.
  • the amorphous state involves a more disordered atomic structure.
  • any phase change material may be utilized. In some embodiments, however, thin- film chalcogenide alloy materials may be particularly suitable.
  • the phase change may be induced reversibly. Therefore, the memory may change from the amorphous to the crystalline state and may revert back to the amorphous state thereafter, or vice versa, in response to temperature changes.
  • each memory cell may be thought of as a programmable resistor, which reversibly changes between higher and lower resistance states.
  • the phase change may be induced by resistive heating.
  • Existing phase change memories may experience inefficient heating of the phase change material. Thus, there is a need for better ways to heat phase change material.
  • Figure 1 is an enlarged cross-sectional view of a portion of a phase change memory in accordance with one embodiment of the present invention
  • Figure 2 is a schematic depiction of a system using a phase change memory in accordance with one embodiment of the present invention.
  • a phase change memory 10 may include a plurality of phase change memory cells 12 including the adjacent cells 12a and 12b on adjacent bitlines 14. Each bitline 14 is positioned over a banier material 16.
  • the barrier material 16 may extend into a pore 46 on top of the phase change material 18 which may be a chalcogenide material in one embodiment of the present invention.
  • phase change memory material include, but are not limited to, chalcogenide element(s) compositions of the class of tellerium-germanium-antimony (TexGeySbz) material or GeSbTe alloys, although the scope of the present invention is not limited to just these.
  • another phase change material may be used whose electrical properties (e.g. resistance, capacitance, etc.) may be changed through the application of energy such as, for example, light, heat, or electrical current.
  • the pore 46 may be defined by a sidewall spacer 22 in one embodiment.
  • the pore 46 and sidewall spacer 22 may be defined by an opening formed in a dielectric or insulating material 20.
  • the material 20 may be an oxide, nitride, or any other insulating material.
  • Below the pore 46 is a pair of lower electrodes including a relatively higher resistivity lower electrode 24 and a relatively lower resistivity lower electrode 26.
  • the higher resistivity electrode 24 may be responsible for heating the adjacent portion of the phase change material 46 and, thus, may have a greater vertical extent.
  • the lower resistivity electrode material 26 functions to distribute electrical current efficiently across the entire width of the higher resistivity electrode material 24.
  • the conductor 30 may be cup- shaped in one embodiment of the present invention and may be filled with an insulator 28 which also surrounds the pedestal liner conductor 30.
  • a nitride layer 32 may be penetrated by the pedestal liner conductor 30. The nitride layer
  • the 32 may be positioned over an isolating layer 35 formed on a semiconductor substrate including a p+ region 38.
  • the p+ region 38 may be adjacent a suicide contact region 34.
  • an n-type silicon layer 40 Below the p+ region 38 is an n-type silicon layer 40.
  • An n+ region 36 may be positioned between adjacent bitlines 14.
  • Underneath the n-type silicon layer 40 is a p-type epitaxial (EPI) silicon layer 42 and a P++ type silicon substrate 44 in one embodiment of the present invention.
  • EPI p-type epitaxial
  • the resistivity of the relatively higher resistivity lower electrode 24 may be in the 1-500 mohm-cm, preferably 3-0.-1-00 mohm-cm range.
  • the lower resistivity lower electrode 26 may have a resistivity in the 0.01-1.0 mohm-cm, preferably 0.05-0.15 mohm-cm range in one embodiment of the present invention.
  • resistive materials that may be used as the electrodes 24 and 26 include silicon nitride and tantalum nitride.
  • a processor-based system may include a processor 50 such as a general purpose or digital signal processor as two examples.
  • the processor 50 may be coupled to the memory 10, for example, by a bus 52.
  • a wireless interface 54 may be provided.
  • the wireless interface 54 may include a transceiver or an antenna, to give two examples.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Semiconductor Memories (AREA)
  • Inert Electrodes (AREA)
  • Battery Electrode And Active Subsutance (AREA)
PCT/US2003/013360 2002-12-13 2003-04-28 Vertical elevated pore phase change memory Ceased WO2004055915A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2003225226A AU2003225226A1 (en) 2002-12-13 2003-04-28 Vertical elevated pore phase change memory
JP2004560263A JP4446891B2 (ja) 2002-12-13 2003-04-28 垂直積層ポア相変化メモリ
CN03825591.XA CN1714461B (zh) 2002-12-13 2003-04-28 垂直上升孔相变存储器

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/319,179 US7049623B2 (en) 2002-12-13 2002-12-13 Vertical elevated pore phase change memory
US10/319,179 2002-12-13

Publications (2)

Publication Number Publication Date
WO2004055915A2 true WO2004055915A2 (en) 2004-07-01
WO2004055915A3 WO2004055915A3 (en) 2004-08-26

Family

ID=32506588

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/013360 Ceased WO2004055915A2 (en) 2002-12-13 2003-04-28 Vertical elevated pore phase change memory

Country Status (8)

Country Link
US (2) US7049623B2 (enExample)
JP (1) JP4446891B2 (enExample)
KR (1) KR100669312B1 (enExample)
CN (1) CN1714461B (enExample)
AU (1) AU2003225226A1 (enExample)
MY (1) MY135245A (enExample)
TW (1) TWI286750B (enExample)
WO (1) WO2004055915A2 (enExample)

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JP2006303294A (ja) * 2005-04-22 2006-11-02 Renesas Technology Corp 相変化型不揮発性メモリ及びその製造方法
KR100687747B1 (ko) * 2005-07-29 2007-02-27 한국전자통신연구원 상변화 메모리소자 및 그 제조방법
JP2007527124A (ja) * 2005-05-02 2007-09-20 キモンダ アクチエンゲゼルシャフト 相変化メモリ装置
JP2009507390A (ja) * 2005-09-07 2009-02-19 韓國電子通信研究院 アンチモン−セレン金属合金を利用した相変化型メモリ素子及びその製造方法

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JP2007527124A (ja) * 2005-05-02 2007-09-20 キモンダ アクチエンゲゼルシャフト 相変化メモリ装置
KR100687747B1 (ko) * 2005-07-29 2007-02-27 한국전자통신연구원 상변화 메모리소자 및 그 제조방법
JP2009507390A (ja) * 2005-09-07 2009-02-19 韓國電子通信研究院 アンチモン−セレン金属合金を利用した相変化型メモリ素子及びその製造方法

Also Published As

Publication number Publication date
MY135245A (en) 2008-03-31
US20060054878A1 (en) 2006-03-16
AU2003225226A1 (en) 2004-07-09
US20040115372A1 (en) 2004-06-17
TW200410245A (en) 2004-06-16
US7364937B2 (en) 2008-04-29
CN1714461A (zh) 2005-12-28
TWI286750B (en) 2007-09-11
JP4446891B2 (ja) 2010-04-07
WO2004055915A3 (en) 2004-08-26
KR100669312B1 (ko) 2007-01-16
JP2006510219A (ja) 2006-03-23
KR20050085526A (ko) 2005-08-29
CN1714461B (zh) 2010-12-08
US7049623B2 (en) 2006-05-23

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