WO2003038181A1 - Procede de modification du traitement d'une matiere fibreuse fonctionnelle a base de cellulose faisant preuve d'une excellente resistance - Google Patents

Procede de modification du traitement d'une matiere fibreuse fonctionnelle a base de cellulose faisant preuve d'une excellente resistance Download PDF

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Publication number
WO2003038181A1
WO2003038181A1 PCT/JP2002/002527 JP0202527W WO03038181A1 WO 2003038181 A1 WO2003038181 A1 WO 2003038181A1 JP 0202527 W JP0202527 W JP 0202527W WO 03038181 A1 WO03038181 A1 WO 03038181A1
Authority
WO
WIPO (PCT)
Prior art keywords
fiber material
silk
cellulose
amines
water
Prior art date
Application number
PCT/JP2002/002527
Other languages
English (en)
Japanese (ja)
Inventor
Toshio Hagiwara
Eiji Yamada
Original Assignee
Toshio Hagiwara
Eiji Yamada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshio Hagiwara, Eiji Yamada filed Critical Toshio Hagiwara
Publication of WO2003038181A1 publication Critical patent/WO2003038181A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Definitions

  • shape memory fibers, flameproof fibers, UV shielding fibers, insect-proof fibers, antibacterial fibers, antibacterial fibers, deodorant fibers, and high texture Functional fibers such as fibers have been developed and are attracting the attention of the industry.
  • silk fiber mouth or sericin is attached to fiber materials other than silk to give it the characteristics of silk, that is, it has good texture, moisturizing properties, deodorant properties, and antistatic properties. Processing methods that impart functions such as antioxidant properties, ultraviolet shielding properties, and antibacterial properties have been studied.
  • the present invention relates to the above-mentioned known processing methods using sericin or silk fibroin, which have the disadvantages of poor texture, insufficient durability of processing effects, use of dangerous and harmful substances for processing chemicals, and remarkable. Focusing on the fact that strength reduction occurs, we studied strength improvement processing methods that are excellent in economic efficiency, environmental adaptability, and safety. '
  • Our goal is to use sericin aqueous solution obtained by collecting silk smelting waste liquid or dry sericin powder as a raw material for high value-added processing of cellulosic fiber materials, Is to promote a strong cross-linking reaction by using soluble diamines and Z or alkanolamines to develop a new functional cellulose fiber material with excellent strength. It is also an important aim to reduce wastewater loads by achieving resource recycling and to develop environmentally friendly processing methods. In addition, water produced as part of the recycling of silk that is emitted as fiber waste It is also an object of the present invention to contribute to environmental problems by effectively using soluble silk fibroin by a durable and strong processing method. Disclosure of the invention
  • the present inventors have solved the above-mentioned problems and promoted the research and development of functional fibers that are environmentally friendly.As a result, cellulosic fibers and sericin and z or silk fibroin and water-soluble dichlorotriazine compounds were used. It has been found that a functional cellulose fiber material having excellent strength can be produced by covalently bonding or cross-linking a diamine and / or alkanolamine having a property in the presence of an acid binder.
  • processing methods such as a so-called immersion method and a pad-dry-steaming method are applied.
  • One method comprises, as a first step, one of a fiber and a water-soluble dichlorotriazine compound.
  • the chlorine in the eyes is allowed to react as much as possible, and as a second step, the remaining chlorine is reacted with the silk proteins and amines to share the silk proteins and amines with the fiber via the triazine ring.
  • -A method of cross-linking At this time, the amines are assumed to act as agents for promoting cross-linking and improve the strength.
  • a padding bath containing a mixture of drug, silk protein, amines, acid binder, urea, bowel nitrate and wetting agent
  • steaming may be performed for several hours to several seconds at 60 to 150 ° C while keeping it wet.
  • Sericin that can be used in the present invention may be an aqueous solution containing a slightly low molecular weight silk protein obtained by recovering a waste solution of Arikari refining, or a silk protein having a relatively large molecular weight recovered by high temperature method refining. It may be used.
  • Molecular weight distributions generally include those in the thousands to hundreds of thousands.
  • a product concentrated by an ultrafiltration concentration method or the like may be used, or a product obtained by further drying the powder by a spray drying method or the like may be used. It is also possible to use hydrolyzed silk whose molecular weight is adjusted appropriately, and it is also possible to use hydrolyzed silk derivatives.
  • the water-soluble diamines or alkanolamines which can be used in the present invention include aliphatic straight-chain, branched-chain or cyclic alkylenediamines, alkylenetriamines, alkylenetriamines and the like. Specifically, the following compounds can be mentioned, but it is essential that the amines have at least two reactive groups such as amino group, imino group, hydroxyl group and thiol group in total. Is not limited to the specific example. For example, ethylenediamine, triethylenetetrathamine, arginine, ethanolamine, jetanolamine, triethanolamine, isopropanolamine, 1-1 (2 Amines such as monoaminoethyl) piperazine. In some cases, a polyhydric alcohol or urea may be added to the amine to produce a better effect.
  • the fiber material to be processed in the present invention is a cellulosic fiber material such as cotton, hemp, viscose rayon, cupra rayon, lyocell, and cellulose acetate. In essence, it is a natural fiber material having a hydroxyl group that can be covalently bonded to a dichlortriazine compound. These fiber materials may be used alone, or may be blended with other natural fibers or synthetic fibers, or woven fibers. Further, the present invention can be applied to any form of fiber material such as yarn, woven fabric, knitted fabric or non-woven fabric.
  • the fiber material processed and modified by the method of the present invention becomes silk-like and has various characteristics of silk, such as unique luster, warm texture, moisture retention, deodorant, antioxidant, ultraviolet absorption, and antibacterial. Properties, etc., and excellent strength and durability.
  • the method of the present invention in which sericin contained in the waste liquid generated in the silk scouring process can be utilized in a highly practical way, has the effect of reducing wastewater load and recycling waste as one bird and two birds per stone.
  • This is a new technology that responds to environmental problems in the 21st century, and it can be said that it is Eco and Fendri single fiber processing.
  • the dimensional change rate of the cotton broad processed under such conditions was 0.3% in the vertical direction and 0.2% in the horizontal direction, indicating good washability.
  • the tensile strength (N) of the unprocessed product was vertical 683 and horizontal 523, but the processed product had a vertical length of 775 and horizontal 530, and the strength was improved.
  • the tensile strength decreased by about 20%.
  • the moisture retention was measured at 20 ⁇ 2 ° C and 65 ⁇ 5% RH, which was 8.1%, which was superior to the unprocessed product. Both moisture retention and feeling were improved.
  • the dimensional change rate was 0.5% in the vertical direction and 0.3% in the horizontal direction, showing good pushability.
  • the abrasion strength was 100 times by the Mandale method, and the unprocessed product was fibrillated, but the processed product did not produce fibrillation at all.
  • the burst strength of the unprocessed product was 212 KPa, and that of the product processed with sericin alone was 180 KPa, and that of the processed product of this example was 23.5 KPa, indicating improved strength and moisture retention.
  • the texture was better than unprocessed products.
  • silk proteins such as sericin and / or silk fibroin and amines such as diamines and / or alkanolamines can be firmly bound to a cellulosic fiber material by covalent bonds. Therefore, compared to the conventional method of simply coating sericin on the fiber, converting it to resin, or insolubilizing it, physically retaining the sericin in the fiber, it has excellent texture, durability and strength.
  • a silk-like fiber material with good form stability can be obtained.
  • any cellulosic fiber material that has a substituent capable of reacting with a dichlorotriazine-based derivative can be converted into a skin that has good texture, reduced skin damage such as rough skin, rash, and atopy. It can be modified to a cellulose-based functional fiber material with excellent properties.

Abstract

La présente invention concerne une matière fibreuse fonctionnelle à base de cellulose conférant une agréable sensation lors de son utilisation dans des vêtements et faisant preuve d'une excellente résistance grâce à la réaction due à la coexistence de quatre substances p.ex. un composé de dichlorotriazine hydrosoluble, une séricine et/ou une fibrorine de soie et des diamines et/ou des alcanolamines et une matière fibreuse, ou grâce au mélange préalable ou à la mise en réaction préalable d'un composé de dichlorotriazine avec une matière fibreuse à base de cellulose. A cet effet, on modifie une matière fibreuse par réaction de liaison covalente ou par réaction de réticulation entre une matière fibreuse à base de cellulose et des protéines de soie avec des amines par utilisation d'un composé de dichlorotriazine. Par la suite, on ajoute au mélange des protéines de soie et des amines, puis on fait réagir le mélange afin de lier par réticulation/covalence les protéines de soie et les amines avec la matière à base de cellulose au moyen de noyaux de triazine.
PCT/JP2002/002527 2001-11-01 2002-03-15 Procede de modification du traitement d'une matiere fibreuse fonctionnelle a base de cellulose faisant preuve d'une excellente resistance WO2003038181A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001373408A JP2003138482A (ja) 2001-11-01 2001-11-01 強度の優れたセルロース系機能性繊維材料の改質加工法
JP2001-373408 2001-11-01

Publications (1)

Publication Number Publication Date
WO2003038181A1 true WO2003038181A1 (fr) 2003-05-08

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PCT/JP2002/002527 WO2003038181A1 (fr) 2001-11-01 2002-03-15 Procede de modification du traitement d'une matiere fibreuse fonctionnelle a base de cellulose faisant preuve d'une excellente resistance

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JP (1) JP2003138482A (fr)
WO (1) WO2003038181A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011069643A3 (fr) * 2009-12-08 2011-08-11 Amsilk Gmbh Revêtements à base de protéine de soie
CN109563175A (zh) * 2016-06-22 2019-04-02 克洛星有限公司 2,4-二卤代-6-取代-1,3,5-三嗪及其衍生物作为缩合剂、交联剂、鞣剂、接枝剂和固化剂的用途

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4744409B2 (ja) * 2006-10-02 2011-08-10 株式会社オザキプリーツ プリーツ製品の製造方法
CN102965934B (zh) * 2012-12-07 2014-10-08 苏州大学 一种抗菌纤维素纤维或制品及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002030567A (ja) * 2000-07-14 2002-01-31 Nippon Sanmou Senshoku Kk 絹短繊維を用いた加工糸又は布帛及びその製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002030567A (ja) * 2000-07-14 2002-01-31 Nippon Sanmou Senshoku Kk 絹短繊維を用いた加工糸又は布帛及びその製造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011069643A3 (fr) * 2009-12-08 2011-08-11 Amsilk Gmbh Revêtements à base de protéine de soie
CN109563175A (zh) * 2016-06-22 2019-04-02 克洛星有限公司 2,4-二卤代-6-取代-1,3,5-三嗪及其衍生物作为缩合剂、交联剂、鞣剂、接枝剂和固化剂的用途

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