WO2000060135A2 - Verfahren zur herstellung dünner, schwer löslicher beschichtungen - Google Patents
Verfahren zur herstellung dünner, schwer löslicher beschichtungen Download PDFInfo
- Publication number
- WO2000060135A2 WO2000060135A2 PCT/DE2000/001173 DE0001173W WO0060135A2 WO 2000060135 A2 WO2000060135 A2 WO 2000060135A2 DE 0001173 W DE0001173 W DE 0001173W WO 0060135 A2 WO0060135 A2 WO 0060135A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- starting substance
- layers
- reactant gas
- production
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S501/00—Compositions: ceramic
- Y10S501/90—Optical glass, e.g. silent on refractive index and/or ABBE number
- Y10S501/906—Thorium oxide containing
Definitions
- the invention relates to a method for producing thin, sparingly soluble coatings on substrates with any morphology. It should preferably be possible to produce ceramic and oxide layers, but also metallic and further chalcogenide layers
- Ceramic materials are inorganic, non-metallic, poorly soluble in water and at least 30% crystalline However, they can be expanded by the group of glasses, glass ceramics and inorganic binders.
- the ceramic materials are divided into the two large groups “functional ceramics” and “structural ceramics”. Structural ceramics consider materials based on oxides and silicates as well as carbides and nitrides , Bonding and silicides (M0S1 2 ) of main group elements
- oxide ceramics can be understood to mean all ceramic materials that essentially (> 90%) consist of single-phase and component metal oxides. In contrast, all materials based on ceramically produced materials from the system boron, carbon, nitrogen, silicon are called and possibly oxygen as "non-oxide ceramics" Oxide ceramic materials are polycrystalline materials made from pure oxides or oxide compounds; they are of high purity and are usually free of glass phase. In addition to the high-melting metal oxides, such as aluminum, zirconium, magnesium, titanium and beryllium oxide, and calcium oxide, one can also use magnetic ceramics Add materials and materials with a high dielectric constant, piezoceramic. However, the limitation to the high-melting oxides is common.
- silicon dioxide Si0 2
- oxide ceramics silicon dioxide (Si0 2 ) is not classified under oxide ceramics.
- oxide ceramic materials a distinction is still made between simple oxides and complex oxides. These include, for example, chromite with a coarse structure and perovskite, ferrites and garnets with a fine structure.
- sputtering For sputtering (cf. for ZnO: "Use of a helicon wave excited plasma of aluminum-doped ZnO thin-film sputtering" by K.Yamaya et al., Appl. Phys. Lett. 72 (2), January 12, 1998, 235-37) atoms are released from a metal cathode by impacting ions of a gas discharge ("cathode sputtering"). The sputtered metal is then deposited on a surface as a uniform layer. Using molecular beam epitaxy using of oxygen-containing plasma in the presence of a microwave field, single-crystal ZnO thin films can be produced on c-planar sapphire (cf.
- ZnO films with good quality can also be produced by direct electrode deposition from aqueous solutions at a low process temperature (see: "Preparation Of ZnO Films By Electro-depositon From Aqueous Solution” by S.Peulon at al., 13th European Photovoltaic Solar Energy Conference, October 23-27, 1995, Nice, France, 1750-52) in the sol-gel technique (see "Micostructure of Ti0 2 and ZnO Films Fabricated by the Sol-Gel Method" by Y.Ohya et al., J.Am.Ceram.Soc. 79 [4] 825-30 (1996)) solidify colloid solutions present as sol under reaction with water and removal of solvent with the solidly adsorbed solvent residues to form a gel which adheres to surfaces and can be dried.
- a solution for the production of thin, sparingly soluble coatings on substrates with any morphology is therefore provided as a solution to the stated main problem, with the following process steps to be carried out cyclically, depending on the desired layer thickness, for the production of ceramic or oxide layers:
- the processes according to the invention can be used to produce films of poorly soluble oxides and generally of those compounds which are formed by reacting a dry solid starting compound with a gaseous reaction component.
- the decisive factor here is the hydrolysis of the starting substance layer, which has been dried to achieve a homogeneous surface, by means of a moist reactant gas to form hydroxides or complexes, for example amine complexes when using moist ammonia gas as the reactant gas.
- the reactant gas can, however, also be another, preferably basic reacting steam or possibly water steam alone.
- steam is always intended to mean moist gases, ie a mixture of gaseous water, basic gas and in most cases an inert carrier gas.
- Moist ammonia gas is produced by simply "bubbling" nitrogen through a wash bottle with an aqueous ammonia solution .
- the generation of metallic layers by Fumigation accordingly requires treatment with reducing gases.
- the desired ceramic or oxidic surface layers or other end layers are then produced by water elimination - and in the case of complexes also by ligand elimination.
- the thermal treatment of the hydroxide or complex layers can be carried out in a separate process step after the gassing with the reactant gas, for example by heating the layers in an oven. However, it can also be brought about during the gassing process by increasing the process temperature. By using a higher temperature, the optional cleaning step may omitted, as this can already remove unwanted substances from the film. In certain cases, an oxide can even form directly even without the use of a specifically brought about temperature increase.
- the thermal treatment can extend to both necessary fumigations.
- the thermal treatment for forming the respective final layer can also be understood as the removal of disruptive components. In the production of metallic layers, this is used to remove unwanted by-products.
- the starting substance is a metal compound, for example metal halides such as ZnCl 2 or AICI 3 , of the metal whose oxide, ceramic (eg ZnO, Al 2 0 3 ) or metal is desired as the end product for the coating.
- the correspondingly dissolved metal salt is then applied to the substrate, dried (if necessary up to a defined residual moisture) and reacted with gaseous reactants.
- Layers produced using the method according to the invention can be used in solar technology in the production of many components of solar cells. In materials technology, all possible smooth, rough and porous substrates can be coated.
- the process allows the use of starting substance mixtures or different starting substances and their alternating use, the production of homogeneously doped layers and mixed layers as well as the generation of multi-layers.
- the thin, poorly soluble coatings can be used wherever an extended surface protection is required This can be purely about mechanical and chemical protection of the surface, but also about influencing its physical and chemical surface properties, such as conductivity, reflection and absorption behavior or catalysis or chemisorption.
- the increased energy requirement during the crystal transformation can of course also be provided directly by an increased process temperature during the chalcogenization step in the sense of the generally known tempering. Illuminating the substrate with a halogen lamp may be sufficient.
- the chalcogenization step can also be carried out within an oven.
- the measures mentioned lead to purer and higher quality thin films with a simultaneous reduction in the quantity of the reactant gas containing chalcogen hydrogen to be used and reduce the deposition time, since it may be possible to dispense with winding steps, which can cost time and reduce the quality of the end product.
- no starting materials are Residues to be expected more, the by-products occurring here are relatively volatile and can be removed in the last process step if the temperature is selected appropriately.
- the temperature may only be increased as low as necessary, so that in such a case the combination of the hydroxide step with a slightly higher process temperature makes sense.
- Nano-kstallites are becoming increasingly important in research and technology because they lead to quantum-size effects in thin films that influence the optical and electrical properties of the material
- FIG. 1 shows the process flow according to the invention in the production of a ceramic coating in a suitable arrangement
- FIG. 2 shows the process flow according to the invention in the production of a chalcogenide coating
- FIG. 1 shows the production of a zinc oxide layer on an amorphous substrate S. which is clamped in a substrate holder SH that can be moved in three-dimensional space. To cover the individual baths, the substrate holder SH has a cover C.
- the substrate S is converted into a suitable one Starting substance P (precursor) immersed In the selected exemplary embodiment, this is a Solution bath LB with the dissolved metal compound zinc chloride ZnCI 2 . After pulling out, there is a starting substance layer PL, here ZnCl 2 , on the substrate surface.
- the ZnCl 2 layer is first dried in a vessel V in a second method step II, for example by introducing a gas stream GS. This can be inert nitrogen.
- a gas stream GS This can be inert nitrogen.
- the dried starting substance layer PLD is again gassed in the vessel V with a moist reactant gas RG, here moist ammonia gas.
- the moist ammonia gas is produced by simply introducing nitrogen N 2 into a wash bottle B in which there are concentrated ammonia solution NH OH and water H 2 0.
- a hydroxide layer HL has formed on the substrate S, in the exemplary embodiment zinc hydroxide Zn (OH) 2 .
- Different vessels V can also be used for drying and gassing.
- a fourth method step IV the substrate S provided with the zinc hydroxide Zn (OH) 2 is introduced into an oven H.
- the Zn (OH) 2 is thermally converted into zinc oxide ZnO by elimination of water by supplying energy.
- This oxidic or ceramic layer OL / CL covers the substrate on its entire accessible surface, including the inner surface, safely and exerts its functionality there.
- a subsequent rinsing and drying process step is optional and not shown here.
- the process steps mentioned can be carried out several times cyclically.
- FIG. 2 schematically shows the process sequence according to the invention for producing other chalcogenide coatings using the example of cadmium sulfide CdS.
- Method steps and reference numerals which are not further explained here can be found in the description of FIG. 1.
- After carrying out process steps I to III with adsorption P (CdCI 2 ), Drying PLD (CdCI 2 ), fumigation (N 2 + NH 3 ) and hydroxide formation HL (Cd (OH) 2 ) is a further process step purple, in which the hydroxide layer HL (Cd (OH) 2 ) formed with a additional, containing chalcogen hydrogen compounds reactant gas CRG (here hydrogen sulfide H 2 S) is brought into contact.
- CRG hydrogen sulfide H 2 S
- This process step purple the chalcogenization step, creates a chalcogenide coating CHL in the form of cadmium sulfide (CdS) on the substrate S.
- the process temperature TP is increased, for example by carrying out the process steps in a muffle furnace H, in order to improve the material conversion.
- the thermal treatment in process step IV therefore extends to both fumigations III, purple.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Photovoltaic Devices (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pyridine Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
Description
Claims
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020017012681A KR20010113877A (ko) | 1999-04-06 | 2000-04-06 | 잘 녹지 않는 얇은 코팅층 제조 방법 |
US09/958,443 US8158204B1 (en) | 1999-04-06 | 2000-04-06 | Method of producing thin, poorly soluble coatings |
AU50600/00A AU757674B2 (en) | 1999-04-06 | 2000-04-06 | Method of producing thin, poorly soluble coatings |
AT00934914T ATE224965T1 (de) | 1999-04-06 | 2000-04-06 | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
SI200030030T SI1169492T1 (en) | 1999-04-06 | 2000-04-06 | Method of producing thin, poorly soluble coatings |
EP00934914A EP1169492B1 (de) | 1999-04-06 | 2000-04-06 | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
CA002367342A CA2367342A1 (en) | 1999-04-06 | 2000-04-06 | Method of producing thin, poorly soluble coatings |
HU0200790A HU222653B1 (hu) | 1999-04-06 | 2000-04-06 | Eljárás vékony, nehezen oldható bevonatok elżállítására |
DE50000568T DE50000568D1 (de) | 1999-04-06 | 2000-04-06 | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
JP2000609623A JP4275319B2 (ja) | 1999-04-06 | 2000-04-06 | 薄い、難溶性の被覆の製造方法 |
DK00934914T DK1169492T3 (da) | 1999-04-06 | 2000-04-06 | Method of producing thin, poorly soluble coatings |
PL350799A PL193049B1 (pl) | 1999-04-06 | 2000-04-06 | Sposób wytwarzania cienkich, trudno rozpuszczalnych warstw powłokowych |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19916403.7 | 1999-04-06 | ||
DE19916403A DE19916403C1 (de) | 1999-04-06 | 1999-04-06 | Verfahren zur Herstellung dünner, schwer löslicher Beschichtungen |
Publications (2)
Publication Number | Publication Date |
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WO2000060135A2 true WO2000060135A2 (de) | 2000-10-12 |
WO2000060135A3 WO2000060135A3 (de) | 2001-04-19 |
Family
ID=7904248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2000/001173 WO2000060135A2 (de) | 1999-04-06 | 2000-04-06 | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
Country Status (16)
Country | Link |
---|---|
US (1) | US8158204B1 (de) |
EP (1) | EP1169492B1 (de) |
JP (2) | JP4275319B2 (de) |
KR (1) | KR20010113877A (de) |
CN (1) | CN1268786C (de) |
AT (1) | ATE224965T1 (de) |
AU (1) | AU757674B2 (de) |
CA (1) | CA2367342A1 (de) |
DE (2) | DE19916403C1 (de) |
DK (1) | DK1169492T3 (de) |
ES (1) | ES2183798T3 (de) |
HU (1) | HU222653B1 (de) |
PL (1) | PL193049B1 (de) |
PT (1) | PT1169492E (de) |
RU (1) | RU2250932C2 (de) |
WO (1) | WO2000060135A2 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003048404A2 (de) * | 2001-11-30 | 2003-06-12 | Hahn-Meitner-Institut Berlin Gmbh | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10142913B4 (de) | 2001-08-27 | 2004-03-18 | Hahn-Meitner-Institut Berlin Gmbh | Vertikale Transistoranordnung mit einem flexiblen, aus Kunststofffolien bestehenden Substrat und Verfahren zu deren Herstellung |
DE10258727A1 (de) * | 2002-12-05 | 2004-06-24 | Schott Glas | Ofen |
DE10339824B4 (de) * | 2003-08-24 | 2005-07-07 | Hahn-Meitner-Institut Berlin Gmbh | Beschichtungsverfahren zur Deposition und Fixierung von Partikeln auf einer Substratoberfläche und Solarzellen mit funkionellem Schichtenaufbau |
KR100863932B1 (ko) * | 2007-07-10 | 2008-11-18 | 주식회사 코미코 | 세라믹 용사 코팅층의 수화 처리 방법과, 이를 이용한정전척 제조 방법 그리고 상기 수화 처리 방법에 형성된세라믹 용사 코팅층을 갖는 기판 구조물 및 정전척 |
DE102008017077B4 (de) | 2008-04-01 | 2011-08-11 | Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 | Verfahren zur Herstellung einer n-halbleitenden Indiumsulfid-Dünnschicht |
DE102009037371B3 (de) * | 2009-08-13 | 2011-03-17 | Helmholtz-Zentrum Berlin Für Materialien Und Energie Gmbh | Beschichtungsvorrichtung mit Ultraschallzerstäuber |
CN103489962B (zh) * | 2013-10-07 | 2017-01-04 | 复旦大学 | 大面积制备半导体量子点的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4242374A (en) * | 1979-04-19 | 1980-12-30 | Exxon Research & Engineering Co. | Process for thin film deposition of metal and mixed metal chalcogenides displaying semi-conductor properties |
EP0580019A1 (de) * | 1992-07-08 | 1994-01-26 | Yeda Research And Development Company, Ltd. | Orientisch polykristalline dünne Filme aus Übergangsmetallchalcogeniden |
WO1999048158A1 (de) * | 1998-03-19 | 1999-09-23 | Hahn-Meitner-Institut Berlin Gmbh | Verfahren und anordnung zur herstellung dünner metallchalkogenid-schichten |
Family Cites Families (6)
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JPS63103886A (ja) * | 1986-10-21 | 1988-05-09 | 日本碍子株式会社 | メタライズペ−ストならびにそれを使用してなるセラミツクスのメタライズ法 |
US5106828A (en) * | 1987-07-20 | 1992-04-21 | North American Philips Corporation | Method for fabricating superconductors by sol-gel process |
JP2535790B2 (ja) * | 1994-09-08 | 1996-09-18 | 工業技術院長 | タングステンブロンズおよびその被覆複合体の製造方法 |
US5686368A (en) * | 1995-12-13 | 1997-11-11 | Quantum Group, Inc. | Fibrous metal oxide textiles for spectral emitters |
JPH10128115A (ja) * | 1996-11-01 | 1998-05-19 | Cosmo Sogo Kenkyusho:Kk | 担持貴金属触媒およびその製造方法 |
DE19831214C2 (de) * | 1998-03-19 | 2003-07-03 | Hahn Meitner Inst Berlin Gmbh | Verfahren und Anordnung zur Herstellung dünner Metallchalkogenid-Schichten |
-
1999
- 1999-04-06 DE DE19916403A patent/DE19916403C1/de not_active Expired - Fee Related
-
2000
- 2000-04-06 US US09/958,443 patent/US8158204B1/en not_active Expired - Fee Related
- 2000-04-06 EP EP00934914A patent/EP1169492B1/de not_active Expired - Lifetime
- 2000-04-06 HU HU0200790A patent/HU222653B1/hu not_active IP Right Cessation
- 2000-04-06 DE DE50000568T patent/DE50000568D1/de not_active Expired - Lifetime
- 2000-04-06 PL PL350799A patent/PL193049B1/pl not_active IP Right Cessation
- 2000-04-06 WO PCT/DE2000/001173 patent/WO2000060135A2/de active IP Right Grant
- 2000-04-06 JP JP2000609623A patent/JP4275319B2/ja not_active Expired - Fee Related
- 2000-04-06 AT AT00934914T patent/ATE224965T1/de not_active IP Right Cessation
- 2000-04-06 CN CNB008059608A patent/CN1268786C/zh not_active Expired - Fee Related
- 2000-04-06 AU AU50600/00A patent/AU757674B2/en not_active Ceased
- 2000-04-06 CA CA002367342A patent/CA2367342A1/en not_active Abandoned
- 2000-04-06 ES ES00934914T patent/ES2183798T3/es not_active Expired - Lifetime
- 2000-04-06 PT PT00934914T patent/PT1169492E/pt unknown
- 2000-04-06 RU RU2001130044/02A patent/RU2250932C2/ru not_active IP Right Cessation
- 2000-04-06 KR KR1020017012681A patent/KR20010113877A/ko active IP Right Grant
- 2000-04-06 DK DK00934914T patent/DK1169492T3/da active
-
2009
- 2009-01-05 JP JP2009000038A patent/JP2009084153A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4242374A (en) * | 1979-04-19 | 1980-12-30 | Exxon Research & Engineering Co. | Process for thin film deposition of metal and mixed metal chalcogenides displaying semi-conductor properties |
EP0580019A1 (de) * | 1992-07-08 | 1994-01-26 | Yeda Research And Development Company, Ltd. | Orientisch polykristalline dünne Filme aus Übergangsmetallchalcogeniden |
WO1999048158A1 (de) * | 1998-03-19 | 1999-09-23 | Hahn-Meitner-Institut Berlin Gmbh | Verfahren und anordnung zur herstellung dünner metallchalkogenid-schichten |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003048404A2 (de) * | 2001-11-30 | 2003-06-12 | Hahn-Meitner-Institut Berlin Gmbh | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
WO2003048404A3 (de) * | 2001-11-30 | 2003-11-27 | Hahn Meitner Inst Berlin Gmbh | Verfahren zur herstellung dünner, schwer löslicher beschichtungen |
Also Published As
Publication number | Publication date |
---|---|
PT1169492E (pt) | 2003-02-28 |
JP2003530284A (ja) | 2003-10-14 |
CN1268786C (zh) | 2006-08-09 |
DE50000568D1 (de) | 2002-10-31 |
HU222653B1 (hu) | 2003-09-29 |
CA2367342A1 (en) | 2000-10-12 |
DK1169492T3 (da) | 2003-02-03 |
RU2250932C2 (ru) | 2005-04-27 |
DE19916403C1 (de) | 2000-10-12 |
PL193049B1 (pl) | 2007-01-31 |
KR20010113877A (ko) | 2001-12-28 |
EP1169492B1 (de) | 2002-09-25 |
WO2000060135A3 (de) | 2001-04-19 |
JP4275319B2 (ja) | 2009-06-10 |
HUP0200790A2 (en) | 2002-07-29 |
ES2183798T3 (es) | 2003-04-01 |
EP1169492A2 (de) | 2002-01-09 |
PL350799A1 (en) | 2003-02-10 |
AU5060000A (en) | 2000-10-23 |
AU757674B2 (en) | 2003-02-27 |
ATE224965T1 (de) | 2002-10-15 |
JP2009084153A (ja) | 2009-04-23 |
CN1346412A (zh) | 2002-04-24 |
US8158204B1 (en) | 2012-04-17 |
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