WO1999016830A1 - Composition de resine de polyarylene sulfure - Google Patents

Composition de resine de polyarylene sulfure Download PDF

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Publication number
WO1999016830A1
WO1999016830A1 PCT/JP1998/004265 JP9804265W WO9916830A1 WO 1999016830 A1 WO1999016830 A1 WO 1999016830A1 JP 9804265 W JP9804265 W JP 9804265W WO 9916830 A1 WO9916830 A1 WO 9916830A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
component
polyarylene sulfide
sulfide resin
parts
Prior art date
Application number
PCT/JP1998/004265
Other languages
English (en)
Japanese (ja)
Inventor
Masaaki Nakamura
Hiroyuki Amano
Original Assignee
Polyplastics Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplastics Co., Ltd. filed Critical Polyplastics Co., Ltd.
Priority to DE19882709T priority Critical patent/DE19882709B4/de
Priority to KR10-2000-7003254A priority patent/KR100527220B1/ko
Publication of WO1999016830A1 publication Critical patent/WO1999016830A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/08—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/016—Additives defined by their aspect ratio

Definitions

  • the present invention relates to an improved polyarylene sulfide resin composition. More specifically, the present invention relates to a polyarylene sulfide resin composition which is excellent in molding processability, in particular, does not corrode or contaminate a metal part such as a mold during molding, and has excellent mechanical properties of a molded product.
  • PAS Polyarylene sulfide
  • PPS polyphenylene sulfide
  • this resin has an iodine atom in its molecular structure, and the raw material for production has an alkyd metal such as iodine and sodium. It has the disadvantage that by-products containing a large amount of, etc. are generated, has the disadvantage of corroding and contaminating metal materials such as molds during molding, There are problems such as corrosion and contamination of the inserted metal, plating or deposited metal, which causes problems.
  • the polymerized PAS resin should be deionized with acid, hot water, organic solvent, etc., washed and reduced to 500 ppm or less, and even 200 ppm or less.
  • PAS resins and their compositions are extremely effective at molding temperatures of at least 280 or higher, these Even after removal and purification of impurities, corrosive gas is generated during molding, and the corrosion resistance to metals is not sufficient.
  • the present invention improves the corrosion and contamination of a metal during the molding of the PAS resin composition and the metal when the PAS resin composition is used, and improves the bow I tensile strength and elongation even when a relatively large amount of a corrosion inhibitor is used.
  • An object of the present invention is to provide a PAS resin composition having excellent metal corrosion resistance and mechanical properties without causing any adverse effects on mechanical properties such as impact strength and toughness.
  • the present inventors have conducted intensive studies to achieve the above object, and as a result, by adding specific zinc oxide to PAS resin, corrosion and contamination of metals have been significantly improved, The present inventors have found that the adverse effect on the mechanical properties due to the strong corrosion inhibitor has been eliminated, the excellent mechanical properties have been maintained, and both properties have been obtained, and the present invention has been completed.
  • the present invention is a polyarylene sulfide resin composition containing (A) 100 parts by weight and (B) 0.05 to 3 parts by weight.
  • the PAS resin as the component (A) in the composition of the present invention is mainly composed of-(Ar-S)-(where AT is an arylene group) as a repeating unit.
  • the arylene group include p-phenylene group, m-phenylene group, 0-phenylene group, substituted phenylene group, ⁇ , ⁇ ′-diphenylene sulfone group, ⁇ , ⁇ ′— Biphenylene group, ⁇ ' ⁇ '-diphenylene ether group, ⁇ , ⁇ '-diphenylenecarponyl group, naphthylene group and the like can be used.
  • a heterogeneous repeating unit is used from the viewpoint of processability of the composition. Included copolymers may be preferred.
  • those having a phenylene sulfide group as a repeating unit using a ⁇ -phenylene group as an arylene group are particularly preferably used.
  • the copolymer two or more different combinations of the arylene sulfide groups consisting of the above-mentioned arylene groups can be used. Combinations are particularly preferred. Among them, those containing a P-phenylene sulfide group in an amount of 70 mol% or more, preferably 80 mol% or more are suitable from the viewpoint of physical properties such as heat resistance, moldability and mechanical properties.
  • a high molecular weight polymer having a substantially linear structure obtained by condensation polymerization from a monomer mainly composed of a bifunctional halogen aromatic compound can be particularly preferably used.
  • a polymer in which a partially branched or crosslinked structure is formed by using a small amount of a monomer such as a polyhaloaromatic compound having three or more halogen substituents during condensation polymerization can also be used, or a polymer with a low molecular weight linear structure polymer heated at high temperature in the presence of oxygen or an oxidizing agent to increase the melt viscosity by oxidative crosslinking or thermal crosslinking and improve moldability. It is possible.
  • component PAS resin the linear PAS (310 ", a viscosity at shear rate 1200sec one 1 10 to 300 Pa 's) as a main component, a part (1 to 30 wt%, preferably Is 2 to 25% by weight), but a mixed system with a branched or cross-linked PAS resin having a relatively high viscosity (300 to 3000 Pa ⁇ s, preferably 500 to 2000 Pa ⁇ s) is also suitable.
  • the PAS resin used in the present invention is subjected to deionization treatment such as acid washing, hot water washing, and organic solvent washing (or a combination thereof) to remove and purify by-product impurities. It is preferable that the content of chlorine and the content of alkali metal are each 500 ppm or less, preferably 300 ppm or less.
  • the zinc oxide whisker used as the component (B) in the present invention has an average fiber diameter (minor diameter) of 0.1 to 5 m and an average fiber length (major diameter) of 2 to 2 at the needle portion measured by microscopy. It is preferable that the average aspect ratio is 5 to 100 urn.
  • zinc oxide having a three-dimensional tetrapot shape is one of the compounds suitable as a whisker having the above-mentioned shape, but is not limited thereto.
  • the amount of the component (B) is 0.05 to 3 parts by weight, preferably 0.1 to 1 part by weight, based on 100 parts by weight of the polyarylene sulfide resin. At 0.05 parts by weight, the effect of preventing corrosion of metals and the effect of suppressing contamination are not sufficient. 3 parts by weight If it exceeds P, the same mechanical properties as in the case where the component (B) is not blended cannot be maintained.
  • Epoxyalkoxysilane is effective as long as it is a silane compound having one or more epoxy groups in one molecule and having two or three alkoxy groups, for example, ⁇ -glycidoxypropyl trimethoxy. Examples thereof include silane and ⁇ -glycidoxypropyltriethoxysilane.
  • the aminoalkoxysilane any silane compound having one or more amino groups in one molecule and having two or three alkoxy groups is effective. For example, aminopropyltrimethoxy can be used. Examples include silane, araminopropyltriethoxysilane, and N-(-aminoethyl) 1-aminopropyltrimethoxysilane.
  • the amount of these alkoxysilanes is preferably 0.05 to 5% by weight based on the zinc oxide wiping power of the component (B).
  • phosphoric acid or hypophosphorous acid or a salt thereof is further blended as the component (C) because long-term wet heat resistance can be improved.
  • the (C) phosphoric acid or hypophosphorous acid or a salt thereof used herein includes, for example, primary phosphoric acid, hypophosphorous acid, calcium phosphate monobasic, sodium phosphate monobasic, calcium hypophosphite, zinc hypophosphite, At least one or two or more selected from salts of zinc, alkali metal, and alkaline earth metal such as magnesium hypophosphite and sodium hypophosphite, and preferably calcium hypophosphite, Magnesium phosphate and zinc hypophosphite.
  • the above components are compounded in the following amounts: (A) polyarylene sulfide resin
  • component (C) By coexisting component (C) with component (B), surprisingly, the interaction between both components is prevented without impairing the effect of preventing the corrosion of metals and the effect of suppressing the contamination of component (B). It was confirmed that the long-term wet heat resistance was improved. In particular, it is effective to mix the component (C) as it is, but it is effective to pre-adhere part or all of it to the inorganic or organic filler, which is the component (D) described later, and mix it with other components Is also effective.
  • the method of adhering the component (C) For example, a solution containing the above compound may be sprayed onto the filler, and the filler may be adhered. Alternatively, the above solution may be applied by applying the solution. It is also possible to treat with a sizing agent based on epoxy resin or urethane resin, which is generally used as a surface treatment agent for glass fiber, or a coupling agent such as aminosilane or epoxysilane.
  • the inorganic or organic filler of the component (D) used in the present invention is not necessarily an essential component, but may have performance such as mechanical strength, heat resistance, dimensional stability (warpage, deformation), and electrical properties.
  • a fibrous, powdery, or plate-like filler or a mixture thereof is used according to the purpose.
  • the fibrous filler include glass fiber, asbestos fiber, carbon fiber, silica fiber, silica 'alumina fiber, zirconia fiber, boron nitride fiber, silicon nitride fiber, boron fiber, potassium titanate fiber, and stainless steel.
  • inorganic fibrous materials such as fibrous materials of metals such as aluminum, titanium, copper, and brass.
  • fibrous fillers are glass fibers, carbon fibers or potassium titanate fibers.
  • a high melting point organic fibrous substance such as an aromatic polyamide, an acrylic resin, or a fluororesin can also be used.
  • the granular fillers include carbon black, graphite, silica, quartz powder, glass beads, glass powder, calcium silicate, aluminum silicate, kaolin, and tar.
  • Silicates such as clay, clay, diatomaceous earth, wollastonite, oxides of metals such as iron oxide, titanium oxide, and alumina; carbonates of metals such as calcium carbonate and magnesium carbonate; metals such as calcium sulfate and barium sulfate And silicon carbide, silicon nitride, and various metal powders.
  • Particularly typical ones are carbon black, silica, glass beads or glass powder, calcium carbonate, talc and the like.
  • examples of the plate-like filler include My force, glass flake, various metal foils, and the like.
  • fillers can be used alone or in combination of two or more.
  • a fibrous filler particularly a glass fiber or a carbon fiber
  • a powdery or plate-like filler is a preferable combination, particularly in terms of having both mechanical strength, dimensional accuracy, electrical properties and the like.
  • the treating agent include functional compounds such as epoxy compounds, isocyanate compounds, silane compounds, and titanate compounds.
  • the amount of the component (D) is from 1 to 75% by weight, preferably from 3 to 70% by weight, based on the total amount of the composition. If it is too large, the molding operation becomes difficult, and there is a problem in the mechanical strength of the molded product.
  • thermoplastic resins that is, stabilizers such as antioxidants and ultraviolet absorbers, flame retardants, coloring agents such as dyes and pigments, A lubricant, a crystallization accelerator, a crystal nucleating agent, and the like can be appropriately added according to required performance.
  • the resin composition of the present invention can be prepared by equipment and methods generally used for preparing a synthetic resin composition. Generally, necessary components can be mixed, melt-kneaded using a single-screw or twin-screw extruder, and extruded to form a pellet for molding. In addition, the resin component is melt-extruded, and an inorganic component such as glass fiber is added during the extrusion. Mixing is one of the preferred methods.
  • the material pellets obtained in this manner can be molded by a generally known thermoplastic resin molding method such as injection molding, extrusion molding, vacuum molding, compression molding, etc., but the most preferred is injection molding. .
  • a generally known thermoplastic resin molding method such as injection molding, extrusion molding, vacuum molding, compression molding, etc., but the most preferred is injection molding. .
  • EXAMPLES Next, the present invention will be described specifically with reference to Examples and Comparative Examples, but the present invention is not limited to these. -Examples 1 to 14 and Comparative Examples 1 to 10
  • a substantially linear polyphenylene sulfide resin (Kureha Chemical Industry Co., Ltd., “Fortron KPS”) having a viscosity of 50 Pa ⁇ s (310, 1200 sec- 1 ) 100 parts by weight
  • the components (B) were added and mixed for 2 minutes with a Henschel mixer as shown in Tables 1 and 2. Further, the components (C) and (D) were added in the amounts shown in Tables 1 and 2 and mixed with a blender for 30 seconds. Was kneaded with an extruder at a cylinder temperature of 310 ° C. to prepare a pellet of a polyphenylene sulfide resin composition.Corrosion properties to metals, mechanical properties and long-term wet heat resistance of this pellet were measured.
  • Example 15 Example 15
  • the evaluation method is as follows.
  • Tensile test pieces were molded using an injection molding machine at a cylinder temperature of 320 ° C and a mold temperature of 150 ° C, and the test pieces were measured for bow I tensile strength and tensile elongation in accordance with ASTM D-638. (Long-term wet heat resistance)
  • Tensile test specimens were molded using an injection molding machine at a cylinder temperature of 320 ° C and a mold temperature of 150 ° C. The test specimens were treated in hot water at 95 ° C for 500 hours, and in accordance with ASTM D-638, The tensile strength was measured.
  • Example 14 A-1 100 Bl 0.05 Glass fiber 40 B 188 1.9 132 m 10 A-1 100 Glass gallery 40 D 188 1.9 132 132 Example 15 100 Bl 0.5 C-1 0.3 Glass complexity 40 A 190 1.9 183

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Cette composition de résine de polyarylène sulfure, des plus apte au moulage et convenant parfaitement à la production de moulages dotés d'excellentes propriétés mécaniques et ce, sans corroder des parties métalliques, des moules par exemple, ni les maculer, lors de l'opération de moulage, comporte, (A), 100 parties par poids d'une résine de polyarylène sulfure et, (B), de 0,05 à 3 parties par poids de fibres whisker d'oxyde de zinc.
PCT/JP1998/004265 1997-09-29 1998-09-22 Composition de resine de polyarylene sulfure WO1999016830A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19882709T DE19882709B4 (de) 1997-09-29 1998-09-22 Polyarylensulfidharz-Zusammensetzung, Verfahren zu ihrer Herstellung sowie ihre Verwendung
KR10-2000-7003254A KR100527220B1 (ko) 1997-09-29 1998-09-22 폴리아릴렌 설파이드 수지 조성물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP9/264576 1997-09-29
JP26457697A JP3624077B2 (ja) 1997-09-29 1997-09-29 ポリアリーレンサルファイド樹脂組成物

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US09509216 A-371-Of-International 2000-03-24
US09/983,679 Continuation US6605660B2 (en) 1997-09-29 2001-10-25 Polyarylene sulfide resin composition

Publications (1)

Publication Number Publication Date
WO1999016830A1 true WO1999016830A1 (fr) 1999-04-08

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Application Number Title Priority Date Filing Date
PCT/JP1998/004265 WO1999016830A1 (fr) 1997-09-29 1998-09-22 Composition de resine de polyarylene sulfure

Country Status (6)

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JP (1) JP3624077B2 (fr)
KR (1) KR100527220B1 (fr)
CN (1) CN1165583C (fr)
DE (1) DE19882709B4 (fr)
TW (1) TW492988B (fr)
WO (1) WO1999016830A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6299942B1 (en) * 1999-02-22 2001-10-09 Idemitsu Petrochemical Co., Ltd. Method of producing the plated molded articles by non-electrode plating, and the resin compositions for that use
US6534124B2 (en) 1999-02-22 2003-03-18 Idemitsu Petrochemical Co., Ltd. Method of producing the plated molded articles by non-electrode plating, and the resin compositions for that use

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* Cited by examiner, † Cited by third party
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JP2005298669A (ja) * 2004-04-12 2005-10-27 Polyplastics Co ポリアリーレンサルファイド樹脂組成物及びその成形品
KR101287305B1 (ko) * 2005-12-16 2013-07-17 오츠카 가가쿠 가부시키가이샤 폴리아릴렌 설파이드 수지 조성물
JP5098386B2 (ja) * 2007-03-16 2012-12-12 東レ株式会社 ポリアリーレンスルフィド樹脂組成物
JP5112387B2 (ja) * 2009-06-12 2013-01-09 株式会社クレファイン 酸化亜鉛ウィスカー含有樹脂組成物、それで成形された歯車成型体及び歯車ブランク成型体並びにそれを用いた歯車、歯車ブランク、減速機及びパワーステアリング装置
JP6317963B2 (ja) * 2013-04-04 2018-04-25 ポリプラスチックス株式会社 ポリアリーレンサルファイド樹脂組成物に対する耐熱老化性の発現方法
JP5831648B2 (ja) * 2013-09-27 2015-12-09 東レ株式会社 ポリアリーレンスルフィド樹脂組成物
CN106832930A (zh) * 2017-01-26 2017-06-13 潮州三环（集团）股份有限公司 Mt插芯原材料及其制备方法
CN109233278A (zh) * 2018-08-16 2019-01-18 金发科技股份有限公司 一种聚苯硫醚复合材料及其制备方法
DE102020105849A1 (de) 2020-03-04 2021-09-09 Christian-Albrechts-Universität Zu Kiel Polymerkomposit sowie Herstellungsverfahren dazu
CN113429786B (zh) * 2021-06-16 2022-05-20 金发科技股份有限公司 一种pps组合物及其制备方法和应用
JP7334873B1 (ja) 2021-11-18 2023-08-29 Dic株式会社 ポリアリーレンスルフィド樹脂混合物、樹脂組成物及び成形品ならびにそれらの製造方法
CN116574375A (zh) * 2023-04-24 2023-08-11 国材(苏州)新材料科技有限公司 具有高cti值的聚苯硫醚树脂及cti值测试方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57205445A (en) * 1981-06-12 1982-12-16 Toray Ind Inc Poly-p-phenylene sulfide resin composition
JPH01217072A (ja) * 1988-02-25 1989-08-30 Matsushita Electric Ind Co Ltd ウイスカー強化プラスチックス
JPH03239756A (ja) * 1990-02-19 1991-10-25 Sutaaraito Kogyo Kk 摺動部材組成物
JPH04164961A (ja) * 1990-10-29 1992-06-10 Dainippon Ink & Chem Inc ポリアリーレンサルファイド樹脂組成物
JPH04225063A (ja) * 1990-12-27 1992-08-14 Tosoh Corp ポリアリ−レンスルフィド樹脂の腐食性低減方法
JPH07258543A (ja) * 1994-03-22 1995-10-09 Polyplastics Co ポリアリーレンサルファイド樹脂組成物及びその製造方法
JPH08151519A (ja) * 1994-11-28 1996-06-11 Idemitsu Petrochem Co Ltd ポリアリーレンスルフィド樹脂組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3214884B2 (ja) * 1992-02-13 2001-10-02 出光石油化学株式会社 ポリアリーレンスルフィド樹脂組成物
JP3494227B2 (ja) * 1993-08-06 2004-02-09 出光石油化学株式会社 ポリアリーレンスルフィド樹脂組成物
DE69528877T2 (de) * 1994-03-17 2003-03-27 Idemitsu Petrochemical Co Polyarylensulfidharzzusammensetzung
WO1995025770A1 (fr) * 1994-03-18 1995-09-28 Mitsubishi Denki Kabushiki Kaisha Composition resineuse destinee au moulage de pieces detachees de precision, manchon et virole fabriques a partir de cette composition
KR20000064264A (ko) * 1996-07-22 2000-11-06 히라이 가쯔히꼬 폴리페닐렌 술피드 수지조성물

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57205445A (en) * 1981-06-12 1982-12-16 Toray Ind Inc Poly-p-phenylene sulfide resin composition
JPH01217072A (ja) * 1988-02-25 1989-08-30 Matsushita Electric Ind Co Ltd ウイスカー強化プラスチックス
JPH03239756A (ja) * 1990-02-19 1991-10-25 Sutaaraito Kogyo Kk 摺動部材組成物
JPH04164961A (ja) * 1990-10-29 1992-06-10 Dainippon Ink & Chem Inc ポリアリーレンサルファイド樹脂組成物
JPH04225063A (ja) * 1990-12-27 1992-08-14 Tosoh Corp ポリアリ−レンスルフィド樹脂の腐食性低減方法
JPH07258543A (ja) * 1994-03-22 1995-10-09 Polyplastics Co ポリアリーレンサルファイド樹脂組成物及びその製造方法
JPH08151519A (ja) * 1994-11-28 1996-06-11 Idemitsu Petrochem Co Ltd ポリアリーレンスルフィド樹脂組成物

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6299942B1 (en) * 1999-02-22 2001-10-09 Idemitsu Petrochemical Co., Ltd. Method of producing the plated molded articles by non-electrode plating, and the resin compositions for that use
US6534124B2 (en) 1999-02-22 2003-03-18 Idemitsu Petrochemical Co., Ltd. Method of producing the plated molded articles by non-electrode plating, and the resin compositions for that use

Also Published As

Publication number Publication date
DE19882709T1 (de) 2000-08-24
TW492988B (en) 2002-07-01
CN1165583C (zh) 2004-09-08
JPH11100505A (ja) 1999-04-13
JP3624077B2 (ja) 2005-02-23
DE19882709B4 (de) 2010-11-25
CN1272124A (zh) 2000-11-01
KR100527220B1 (ko) 2005-11-08
KR20010030731A (ko) 2001-04-16

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