WO1992018272A1 - Procede de coulage en continu d'une tole mince utilisant deux cylindres jumeles et appareil prevu a cet effet - Google Patents
Procede de coulage en continu d'une tole mince utilisant deux cylindres jumeles et appareil prevu a cet effet Download PDFInfo
- Publication number
- WO1992018272A1 WO1992018272A1 PCT/JP1992/000483 JP9200483W WO9218272A1 WO 1992018272 A1 WO1992018272 A1 WO 1992018272A1 JP 9200483 W JP9200483 W JP 9200483W WO 9218272 A1 WO9218272 A1 WO 9218272A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sheet
- twin
- support sheet
- thin plate
- rolls
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
Definitions
- the present invention relates to a twin-roll continuous sheet manufacturing method and apparatus, and more particularly to a twin-roll continuous sheet manufacturing method and apparatus suitable for manufacturing a thin sheet of a brittle material such as an Fe—Cu alloy.
- the twin-roll type continuous sheet forming machine rotates a pair of cooled forming rolls that are arranged horizontally in parallel with each other in the opposite direction, and continuously supplies molten metal between the pair of rotating forming rolls to form a thin plate.
- This is a device that continuously manufactures a thin plate, extends the manufactured thin plate to a coiler via a pinch roller and a conveying roller group, and continuously winds the thin plate by the coiler.
- a dummy sheet is used at the time of starting the production of a thin plate.
- the dummy sheet is pre-joined to the tip of the prefabricated thin sheet, and the tip is wound around the coiler via a pinch roller and a transport roller group. Is wound up by a coiler, and guides the leading end of the thin sheet to be wound up by a coiler. If the steel sheet breaks, the operation of the equipment will be stopped and the sheet will be rejoined to the tip of the steel sheet as described above. After that, the operation will be resumed.
- a twin-roll type thin sheet continuous steel making device that does not require a dummy sheet is proposed in Japanese Patent Application Laid-Open No. Sho 60-1777935 and Japanese Utility Model Application Laid-Open No. Sho 59-1657554. Have been.
- the former device includes two belt-shaped sheet supply devices disposed below a pair of structural rolls.
- two strip-shaped sheets are placed on a group of transport rolls, and the leading end is wound around a coiler.
- the leading end of the thin plate formed by the forming roll is sandwiched between two band-shaped sheets, and is wound up with a coiler together with the band-shaped sheet. ⁇
- the flooding of the strip is stopped and only the thin sheet is wound up by the coiler.
- this device since the leading end of the laminated sheet is guided to the coiler by two strip-shaped sheets, no dummy sheet is required. However, in the event of a rupture of the sheet, the operation of the device must be stopped in order to set up the strip.o
- the latter device includes, as a transfer device for transferring the thin sheet to the coiler, a water passage through which fluid flows at a flow rate higher than the transfer speed of the thin sheet.
- a transfer device for transferring the thin sheet to the coiler a water passage through which fluid flows at a flow rate higher than the transfer speed of the thin sheet.
- Each of these devices is suitable for continuous production of thin sheets of ductile material such as stainless steel.
- Equipment not suitable for the production of brittle materials such as Fe-Cu alloys It is. The reason is that tension is applied to the manufactured thin plate when winding the manufactured thin plate around a coil. In the case of ductile materials, this tension is unlikely to break the fabricated sheet, but in the case of brittle materials, the sheet will break as soon as tension is applied. .
- this is ⁇ thin plate continuous brittle material And eliminates the need for a dummy sheet required when starting sheet manufacturing, and operates continuously without stopping equipment even if the sheet breaks. It is an object of the present invention to provide a twin-roll type continuous sheet manufacturing method and apparatus capable of performing the above-mentioned operations.
- the twin-roll continuous sheet forming method includes a pair of forming rolls in which a molten metal supplied from a nozzle is horizontally arranged. And continuously put them on a support sheet extending below a pair of steel rolls. The support sheet on which the steel sheets are placed is coiled. And a step of winding.
- a twin-roll type continuous sheet forming apparatus a nozzle for supplying molten metal, and a pair of forming rolls for forming a molten sheet supplied from the nozzle into thin plates, which are arranged in parallel with each other and horizontally. And a pair of structural rolls that are cooled and rotated in opposite directions to each other, a coiler, and a support sheet extending substantially horizontally below the pair of structural rolls and wound up by the coiler. And one.
- the twin-roll type continuous sheet manufacturing apparatus further includes a displacement detecting unit that detects a displacement of the curved portion that occurs when the formed thin plate is placed on the support sheet, and a detection unit that detects the displacement. Based on the result, there is provided control means for performing feedback control of the support sheet take-up speed of the coiler so that the support sheet take-up speed of the coil matches the production speed.
- the support sheet may be curved toward the structure roll below the pair of structure rolls.
- a curved guide member may be provided between the support sheet and the structural roll.
- the support sheet may be a perforated sheet, and a cooling means may be provided in the transport path of the artificial thin plate.
- Winding the support sheet from the coiler Additional reels may be provided.
- the detector of the detecting means is arranged on the concave side of the curved portion of the artificial thin plate, and when the curved guide member is provided. However, when the detector is at the bottom dead center, an interval through which the thin plate can pass is maintained between the detector and the guide surface of the curved guide member.
- a manufacturing thin plate is wound up without adding tension. Therefore, a thin plate of a brittle material can be continuously manufactured.
- the dummy sheet required to start the sheet manufacturing is not required, and even if the sheet breaks, the equipment can be operated continuously without stopping. I can do things. "Brief description of drawings J
- FIG. 1 is a schematic view of a first embodiment of a twin-roll type continuous sheet forming apparatus according to the present invention
- Fig. 2 is an enlarged view of part A of Fig. 1,
- FIG. 3 is a flow chart of a feedback control of a winding speed of a coiler in a twin roll type continuous sheet forming apparatus according to the present invention.
- FIG. 4 is a schematic view of a second embodiment of a twin-roll type continuous sheet forming apparatus according to the present invention.
- FIG. 5 is a schematic view of a third embodiment of a twin-roll type thin plate continuous cymbalizer according to the present invention
- FIG. 6 is a partially enlarged view of the third embodiment in which a contact type displacement detector is used as the displacement detector, and
- FIG. 7 is a schematic diagram of a fourth embodiment of a twin-roll type continuous sheet forming apparatus according to the present invention.
- Fig. 8 is a plan view of the porous support sheet used in the fourth embodiment
- FIG. 9 is a schematic view of a modified example of the fourth embodiment of the twin-roll type continuous sheet forming apparatus according to the present invention.
- FIG. 1 A twin roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
- FIG. 1 A twin roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
- FIG. 1 A twin roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
- FIG. 1 A twin roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
- the twin roll type continuous sheet forming machine is composed of a pair of forming rolls 1
- a pool 13 is formed above the pair of production rolls 11 and 12. Above the pool 13, a tandem dish 29 for holding the molten metal, and a pool for melting the molten metal are provided. A nozzle 14 is provided continuously from the dish 29 to the basin 13, but a nozzle 14 is provided. Below the pair of structural rolls 11, 12, a support sheet supply reel 15 is provided. And the supporting sheets 16 are From the support sheet supply reel 15, it is supported by a support roll group 18, extends almost horizontally below the construction roll, and is wound up by a coiler 17.
- the type of support sheet is not limited, but mild steel or stainless steel sheets are preferred.
- a displacement of the thin plate 19 is detected in the vicinity of the curved portion 22 generated when the thin plate 19 formed by the forming rolls 11 and 12 is placed on the support sheet 16.
- Displacement detector 20 is installed.
- the displacement detector 20 is installed to detect the position of the curved portion 22 of the thin plate 19 and output a voltage value according to the detected value. It is set to output a small voltage value when approaching 20 and a large voltage value when moving away from it.
- a control device 21 is provided for performing feedback control of the support sheet winding speed of the coiler 17 based on the detection result of the displacement detector 20.
- a standard voltage value V M corresponding to the standard transfer speed of the structural thin plate 19 and a lower limit voltage value VL corresponding to the lower limit transfer speed are described.o
- the fabrication rolls 11 and 12 are rotated in opposite directions, as shown, so that the molten metal from the nozzle 14, such as a brittle material such as Fe—Cu alloy, is poured into the pool.
- a solidified shell is formed on the surface of each of the forged rolls 11 and 12, and both solidified shells are formed by the pair of forged rolls 11 and 12. Integrated at the nip Then, it is continuously discharged vertically downward from the lower side of the production roll as a production thin plate 19.
- the discharged structure thin plate 19 is placed on a support sheet 16 extending substantially horizontally below the structure roll. Since the support sheet 16 is wound by the coiler 17 which is started at the same time as the start of the production roll, the structural thin plate 19 placed on the support sheet 16 becomes the support sheet 1. 6 It is transported in the direction of the coiler while it is placed on top. As shown in FIG. 2, the coiler 17 winds the thin sheet 19 inside the support sheet 16 and winds the support sheet 16. At this time, the tension due to winding is applied to the support sheet 16, but no tension is applied to the thin sheet 19 placed on the support sheet 16.
- the feedback control routine shown in FIG. 3 is, for example, an interrupt routine executed every 4 msec.
- the execution of the feedback control routine is started by turning on the power switch of the coil 17.
- Controller 2 1 the displacement detection can take in 2 0 of the output voltage value V, nitrous et beforehand Symbol billion by standard voltage value and a V M to compare against the standardized transporting speed is (Step 4 0 1, 4 0 2).
- Displacement detector 20 When the output voltage value V is equal to the standard voltage value V M , that is, when the transport speed of the thin sheet is substantially equal to the forging speed, the winding speed of the current coil 17 is maintained. Repeat the feedback control routine.
- the output voltage value V is compared with the lower limit voltage value (Step 405). If the output voltage value V is smaller than the lower limit voltage value VL, the winding speed of the coil 17 is accelerated (step 406). When the output voltage value V is greater than the lower limit voltage value VL (this corresponds to the case where the structure thin plate 19 breaks and there is no structure thin plate to be measured before the displacement detector 20). Maintains the winding speed of the coiler 17 at that speed (step 407). This is a measure to prevent the winding speed of the coiler from becoming excessive.
- twin-roll type continuous sheet forming apparatus according to the present invention will be described, but only different portions from the first embodiment will be described.
- the mechanism for the supporting sheet of the first embodiment may be brought close to the production roll as a whole, but this may not be possible due to space constraints.
- the second embodiment is an effective embodiment in such a case.
- the supporting sheet 16 is curved by the turning roll 28 toward the production rolls 11 and 12 below the production roll. With such a configuration, the thin steel plate 9 is quickly placed on the support sheet 16, and the generation of tension due to the weight of the hanging portion can be suppressed.
- a curved guide member 23 for forming the thin sheet 19 on the support sheet 16 from below the nibs of the structural rolls 11 and 12 is provided. ⁇ Under the rolls 1 1 and 1 2 It is provided in one.
- the curved guide member 23 is installed so as to be able to move between an initial position B located at the start of the production and an operation position C away from the production thin plate 19.
- the support sheet 16 is extended substantially horizontally from the vicinity of the exit of the curved guide member 23 to the coiler 17 by the turning ring 24.
- the curved guide member 23 guides the tip of the production thin plate 19 hanging from the nip portion of the production rolls 11 and 12 onto a support sheet 16 extending downward and almost horizontally. I do. ⁇ After the tip of the thin plate 19 is placed on the support sheet 16, the curved guide member 23 moves to the operation position C.
- the position of the thin sheet 19 is set as the position corresponding to the above-mentioned standard transfer speed, and the support sheet take-up speed of the coiler 17 is set as the above-mentioned filer. Control according to the feedback control routine.
- the position where the thin plate 19 is slightly lifted from the guide surface of the curved guide member 23 at the initial position B is set as the position corresponding to the standard transfer speed, and the support sheet take-up speed of the coiler 17 is reduced. If the control is performed in accordance with the above-described feedback control routine, the curved guide member 23 may remain at the initial position B.
- the contact type displacement detector 20 is connected to the curved guide member. Installed on the concave side of 23, and the contact type displacement detection Between the bottom dead center of the output unit 20 (the position where the detector 20 ′ of the contact type displacement detector projects most in the direction of the curved guide member), there is a gap D through which the thin plate 19 can pass. Is important. When the structural thin plate 19 breaks, the detector 20 ′ of the contact displacement detector 20 protrudes to the bottom dead center, and if there is no gap D, the broken part of the thin plate 19 The thin plate 19 cannot reach the support sheet 16 because the tip of the thin plate 19 hits the detector 20 ′.
- FIG. 7 a fourth embodiment of a twin-roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 7 and 8.
- FIG. 7 a fourth embodiment of a twin-roll type continuous sheet forming apparatus according to the present invention will be described with reference to FIGS. 7 and 8.
- a plurality of through holes 27 are formed in the support sheet as shown in FIG.
- the support sheet 16 is fed out from the support sheet supply reel 15 and extends almost horizontally below the production roll.
- the support sheet is taken up via the coil 17. Wound by reel 25.
- a plurality of cooling medium injection nozzles 26 arranged vertically are installed in the transport path of the support sheet 16 and the thin sheet 19.
- the cooling medium injection nozzle sprays the cooling medium onto the artificial thin plate. Since the support sheet 16 is a perforated sheet, the cooling medium injected from the cooling medium injection nozzle 26 installed below the transport path passes through the through hole 27 of the support sheet 16. Direct contact with the structure sheet 16, and cool the structure sheet 19 sufficiently. On the other hand, the support sheet 16 is wound around the coil 17 by the support sheet take-up reel 25 after winding the thin sheet 19 around the coiler 17. I have. ⁇ Because the thin sheet is wound around the coiler by the tension of the support sheet, no tension is applied to the thin sheet and there is no danger of breakage. According to this embodiment, it is possible to sufficiently cool the artificial thin plate in the transport path, and it is possible to wind only the artificial thin plate in a coil shape. It is also a theory that a mesh sheet may be used instead of a porous sheet.
- FIG. 9 shows a modification of the fourth embodiment.
- the transport path for the support sheet 16 and the thin sheet 19 is provided with a detour including only the support sheet 16. ⁇
- the thin sheet 19 is supported by the support roll group 18 and is conveyed in the direction of the coil 17, and the support sheet 16 is routed through the bypass 17 Has been wound up.
- a plurality of cooling medium injection nozzles 26 are installed on the transport path of the structure sheet 19 in which the support sheet is bypassed.
- the support sheet 16 since the support sheet 16 is bypassed, the cooling efficiency from below the thin plate 19 can be improved.
- the support sheet 16 need not be a porous sheet.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/971,922 US5350009A (en) | 1991-04-19 | 1992-04-16 | Twin roll-type sheet continuous casting method and apparatus |
KR1019920703270A KR960004420B1 (ko) | 1991-04-19 | 1992-04-16 | 쌍 로울식 박판 연속 주조 방법 및 장치 |
DE69228411T DE69228411T2 (de) | 1991-04-19 | 1992-04-16 | Doppelroll-stranggiessverfahren und vorrichtung |
EP92908240A EP0535245B1 (en) | 1991-04-19 | 1992-04-16 | Twin roll-type sheet continuous casting method and apparatus therefor |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3/88364 | 1991-04-19 | ||
JP3088364A JP2647753B2 (ja) | 1991-04-19 | 1991-04-19 | 双ロール式薄板鋳造法における金属鋳片の搬送捲取方法 |
JP4/10625 | 1992-01-24 | ||
JP4/11083 | 1992-01-24 | ||
JP4010625A JPH05200493A (ja) | 1992-01-24 | 1992-01-24 | 薄板連続鋳造法における鋳片の搬送冷却方法 |
JP4011083A JP3014198B2 (ja) | 1992-01-24 | 1992-01-24 | 双ロール式薄板連続鋳造装置 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992018272A1 true WO1992018272A1 (fr) | 1992-10-29 |
Family
ID=27279030
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1992/000483 WO1992018272A1 (fr) | 1991-04-19 | 1992-04-16 | Procede de coulage en continu d'une tole mince utilisant deux cylindres jumeles et appareil prevu a cet effet |
Country Status (6)
Country | Link |
---|---|
US (1) | US5350009A (ja) |
EP (1) | EP0535245B1 (ja) |
KR (1) | KR960004420B1 (ja) |
CA (1) | CA2084418C (ja) |
DE (1) | DE69228411T2 (ja) |
WO (1) | WO1992018272A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012025343A1 (en) | 2010-08-24 | 2012-03-01 | Unilever Nv | Water purification device comprising a gravity- fed filter |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6192973B1 (en) * | 1996-06-07 | 2001-02-27 | Mannesmann Ag | Strip casting plant |
AT406026B (de) | 1998-03-25 | 2000-01-25 | Voest Alpine Ind Anlagen | Stranggiessanlage zum kontinuierlichen giessen eines dünnen bandes sowie verfahren hierzu |
DE19838774A1 (de) * | 1998-08-26 | 2000-03-02 | Schloemann Siemag Ag | Strangabzugsverfahren und hiermit korrespondierende Bogenstranggießanlage |
KR20010017302A (ko) * | 1999-08-10 | 2001-03-05 | 이구택 | 쌍롤형 박판 제조장치에서의 적응퍼지제어를 이용한 압하력 제어장치 |
US7888158B1 (en) * | 2009-07-21 | 2011-02-15 | Sears Jr James B | System and method for making a photovoltaic unit |
US20110036530A1 (en) * | 2009-08-11 | 2011-02-17 | Sears Jr James B | System and Method for Integrally Casting Multilayer Metallic Structures |
US20110036531A1 (en) * | 2009-08-11 | 2011-02-17 | Sears Jr James B | System and Method for Integrally Casting Multilayer Metallic Structures |
JP5669006B2 (ja) * | 2010-10-19 | 2015-02-12 | 日本電気硝子株式会社 | 帯状ガラスフィルム製造方法及び帯状ガラスフィルム製造装置 |
Citations (3)
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JPS6330158A (ja) * | 1986-07-23 | 1988-02-08 | Nippon Kokan Kk <Nkk> | ストリツプキヤスタ |
JPH01228650A (ja) * | 1988-03-09 | 1989-09-12 | Nippon Steel Corp | ツインドラム式連続鋳造機用ダミーシート |
JPH02211944A (ja) * | 1989-02-10 | 1990-08-23 | Ishikawajima Harima Heavy Ind Co Ltd | ロール式連続鋳造設備 |
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JPS53123304A (en) * | 1977-04-04 | 1978-10-27 | Furukawa Electric Co Ltd:The | Preparation of noncrystalline metal of tape form |
GB1551755A (en) * | 1977-06-21 | 1979-08-30 | British Steel Corp | Continuous casting of metal strip |
US4316497A (en) * | 1980-05-09 | 1982-02-23 | Atlantic Richfield Company | Method an apparatus for feed on to a take-up reel in high speed silico |
DE3306837A1 (de) * | 1983-02-26 | 1984-10-04 | Braas & Co Gmbh, 6000 Frankfurt | First- oder gratabdeckung fuer mit dacheindeckungsplatten eingedeckte daecher |
JPS6072647A (ja) * | 1983-09-28 | 1985-04-24 | Hitachi Ltd | クラツド材の製造方法 |
JPS60177935A (ja) * | 1984-02-23 | 1985-09-11 | Kawasaki Steel Corp | 急冷薄帯の搬送および巻取り方法 |
JPS61108452A (ja) * | 1984-10-31 | 1986-05-27 | Kawasaki Steel Corp | 急冷薄帯の巻取り方法 |
US4644999A (en) * | 1985-01-25 | 1987-02-24 | Allied Corporation | Inline winder with take-up web |
JPS63104756A (ja) * | 1986-10-23 | 1988-05-10 | Nippon Steel Corp | 薄肉金属鋳片の連続鋳造装置 |
JPS6466047A (en) * | 1987-09-07 | 1989-03-13 | Nippon Steel Corp | Method and apparatus for coiling metal strip |
JPH07121439B2 (ja) * | 1987-11-13 | 1995-12-25 | 株式会社日立製作所 | 薄板連続鋳造設備 |
SU1614892A1 (ru) * | 1988-02-10 | 1990-12-23 | М.Л.Этельзон, А.Я.Усв т и С.А.Стукалов | Способ изготовлени и смотки в рулон быстрозакаленной ленты |
SU1581468A1 (ru) * | 1988-02-17 | 1990-07-30 | Etelzon Mikhail L | Способ непрерывного лить быстрозакаленной ленты |
JPH1166865A (ja) * | 1997-08-26 | 1999-03-09 | Sony Corp | 半導体記憶装置 |
-
1992
- 1992-04-16 US US07/971,922 patent/US5350009A/en not_active Expired - Fee Related
- 1992-04-16 EP EP92908240A patent/EP0535245B1/en not_active Expired - Lifetime
- 1992-04-16 CA CA002084418A patent/CA2084418C/en not_active Expired - Fee Related
- 1992-04-16 KR KR1019920703270A patent/KR960004420B1/ko not_active IP Right Cessation
- 1992-04-16 DE DE69228411T patent/DE69228411T2/de not_active Expired - Fee Related
- 1992-04-16 WO PCT/JP1992/000483 patent/WO1992018272A1/ja active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6330158A (ja) * | 1986-07-23 | 1988-02-08 | Nippon Kokan Kk <Nkk> | ストリツプキヤスタ |
JPH01228650A (ja) * | 1988-03-09 | 1989-09-12 | Nippon Steel Corp | ツインドラム式連続鋳造機用ダミーシート |
JPH02211944A (ja) * | 1989-02-10 | 1990-08-23 | Ishikawajima Harima Heavy Ind Co Ltd | ロール式連続鋳造設備 |
Non-Patent Citations (1)
Title |
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See also references of EP0535245A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012025343A1 (en) | 2010-08-24 | 2012-03-01 | Unilever Nv | Water purification device comprising a gravity- fed filter |
Also Published As
Publication number | Publication date |
---|---|
KR930700232A (ko) | 1993-03-13 |
DE69228411D1 (de) | 1999-03-25 |
EP0535245A1 (en) | 1993-04-07 |
KR960004420B1 (ko) | 1996-04-03 |
EP0535245A4 (en) | 1993-08-04 |
EP0535245B1 (en) | 1999-02-10 |
CA2084418C (en) | 1997-02-25 |
US5350009A (en) | 1994-09-27 |
DE69228411T2 (de) | 1999-09-16 |
CA2084418A1 (en) | 1992-10-20 |
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