US20070249512A1 - Solid particulate laundry detergent composition comprising perfume particle - Google Patents

Solid particulate laundry detergent composition comprising perfume particle Download PDF

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Publication number
US20070249512A1
US20070249512A1 US11/788,080 US78808007A US2007249512A1 US 20070249512 A1 US20070249512 A1 US 20070249512A1 US 78808007 A US78808007 A US 78808007A US 2007249512 A1 US2007249512 A1 US 2007249512A1
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US
United States
Prior art keywords
perfume
micrometers
laundry detergent
particle
solid particulate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/788,080
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English (en)
Inventor
Paul R. Mort
Nigel Patrick Somerville Roberts
Christopher Charles Graham
Julie Ellis
John Peter Eric Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US11/788,080 priority Critical patent/US20070249512A1/en
Assigned to PROCTER & GAMBLE COMPANY, THE reassignment PROCTER & GAMBLE COMPANY, THE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MORT III, PAUL R., ELLIS, JULIE, ROBERTS, NIGEL PATRICK SOMERVILLE, GRAHAM, CHRISTOPHER CHARLES, MULLER, JOHN PETER ERIC
Publication of US20070249512A1 publication Critical patent/US20070249512A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay

Definitions

  • the present invention relates to a solid particulate laundry detergent composition comprising perfume particles.
  • Detergent manufacturers incorporate perfume into laundry powder products to impart olfactory benefits to the laundered garments.
  • detergent manufacturers have also developed separate perfume particles, such as perfume microcapsules, perfume loaded zeolites and perfume starch encapsulates, that can be dry-added with the remainder of the laundry powder.
  • these separate perfume particles are very small and are prone to electrostatic attraction to the walls of containers during their incorporation into the laundry detergent powder, which results in uneven incorporation into the laundry powder.
  • the present invention provides a solid particulate laundry detergent composition as defined in Claim 1 .
  • the present invention relates to a perfume particle as defined in Claim 6 .
  • the Inventors have found that perfume particles can be incorporated into solid particulate laundry detergent compositions in an even manner by carefully controlling the physical properties of the perfume particles in relation to the remainder of the solid particulate laundry detergent composition.
  • the solid particulate laundry detergent composition comprises: (a) from 0.2 wt % to 20 wt %, or preferably from 1 wt % and preferably to 10 wt % or even 5 wt % perfume particle; and (b) to 100 wt % of the remainder of the solid particulate laundry detergent composition.
  • the perfume particle and the remainder of the solid particulate laundry detergent composition are described in more detail below.
  • the perfume particle typically comprises from 1 wt % to 60 wt %, or preferably from 5 wt %, and preferably to 50 wt %, or to 40 wt %, or even to 30 wt % perfume.
  • the perfume may be the reaction product between an amine and an aldehyde or ketone.
  • the perfume particle typically has a weight average particle size of from 400 micrometers to 4,000 micrometers, or from 500 micrometers, or from 600 micrometers, or from 700 micrometers, or even from 800 micrometers, and preferably to 3,000 micrometers, or to 2,000 micrometers, or even to 1,500 micrometers.
  • the perfume particle typically has a bulk density of from 500 g/l to 1,500 g/l, or from 600 g/l, or from 700 g/l, or from 800 g/l, and preferably to 1,200 g/l.
  • the perfume particle preferably has a relative jamming onset (RJO bead ) of less than 10.0, or less than 9.0, or less than 8.0, or less than 7.0, or less than 6.0, and preferably from 0.01, or from 0.1 particle.
  • RJO bead relative jamming onset
  • the perfume particle preferably comprises a core and layer.
  • the core may comprise a perfume and a material selected from sodium carbonate, sodium silicate and/or sodium sulphate.
  • the layer may comprise starch, polymeric carboxylate polymer, and/or a tallow alcohol ethoxylated alcohol having an average degree of ethoxylation of from 50 to 100.
  • the layer may comprise a hydratable material. Suitable hydratable material includes sodium carbonate, preferably in fine particulate form, typically having a weight average particle size of less than 50 micrometers.
  • the core may comprise sodium carbonate and the layer may comprise perfume in the form of a microcapsule.
  • the perfume in microcapsule form is typically encapsulated by any suitable material.
  • the layer may also comprise sodium carbonate.
  • the core may comprise sodium carbonate and the layer may comprise perfume and a material selected from sodium carbonate and/or tallow alcohol ethoxylated alcohol having an average degree of ethoxylation of from 50 to 100.
  • the core may comprise sodium carbonate, polymeric carboxylate polymer and/or zeolite, and the layer may comprise polyethylene glycol and/or sodium carbonate.
  • the layer may also comprise perfume and zeolite; the perfume is typically adsorbed and/or absorbed onto the zeolite.
  • the core may also comprise perfume.
  • the perfume particle preferably has a weight average particle size of from 800 micrometers to 1,500 micrometers.
  • the perfume particle preferably has a bulk density of from 800 g/l to 1,200 g/l.
  • the remainder of the solid particulate laundry detergent composition typically has a weight average particle size of from 200 micrometers to 1,500 micrometers.
  • the remainder of the solid particulate laundry detergent composition typically has a bulk density of from 200 g/l to 1,500 g/l.
  • the remainder of the solid particulate laundry detergent composition preferably has a weight average particle size of from 200 micrometers to 700 micrometers.
  • the remainder of the solid particulate laundry detergent composition preferably has a bulk density of from 500 g/l to 700 g/l.
  • the remainder of the solid particulate laundry detergent composition typically comprises particles that comprise one or more of the following detergent ingredients: detersive surfactants such as anionic detersive surfactants, nonionic detersive surfactants, cationic detersive surfactants, zwitterionic detersive surfactants, amphoteric detersive surfactants; preferred anionic detersive surfactants are linear or branched C 8-24 alkyl benzene sulphonates, preferably linear C 10-13 alkyl benzene sulphonates, other preferred anionic detersive surfactants are alkoxylated anionic detersive surfactants such as linear or branched, substituted or unsubstituted C 12-18 alkyl alkoxylated sulphate having an average degree of alkoxylation of from 1 to 30, preferably from 1 to 10, more preferably a linear or branched, substituted or unsubstituted C 12-18 alkyl ethoxylated sulphate having an average degree of e
  • RJO bead Relative Jamming Onset
  • the relative jamming onset is measured using a FlodexTM instrument supplied by Hanson Research Corporation, Chatsworth, Calif., USA.
  • Hopper refers to the Cylinder Assembly of the FlodexTM instrument
  • orifice refers to the hole in the center of the Flow Disk that is used in a flow test
  • the symbol “B” refers to the diameter of the orifice in the Flow Disk used in the test
  • the FlodexTM instrument is operated in accordance with the instructions contained in the FlodexTM operation manual version 21-101-000 rev. C 2004-03 with the following exceptions:
  • sample preparation A bulk sample of particles is suitably riffled to provide a sub-sample of 150 ml loose-fill volume.
  • the appropriate sample mass can be determined by measuring the loose fill density specified in the test method titled “bulk density test” described below, and then multiplying by the target volume (150 ml). The mass of the sample (sample mass) is recorded before the start of each test measurement. As the test is non destructive, the same sample may be used repeatedly. The entire sample must be discharged, e.g., by inverting the hopper, and then re-loaded before each measurement.
  • RJO Relative Jamming Onset
  • the core material is screened granular sodium carbonate prepared by a classification between 425 micrometer and 710 micrometer screens.
  • the layering powder is also sodium carbonate, milled using a Retsch ZM200 to produce a milled material of ⁇ 30 micrometers.
  • the liquid binder is tallow alcohol ethoxylated alcohol having an average degree of ethoxylation of 80 (TAE 80 ).
  • a mass of 200 grams of the core particles is loaded into a Kenwood FP520 Series mixer with a stainless steel bladed impeller and the mixer turned on to speed setting #1 to induce a centrifugal flow pattern in the mixer.
  • 48.9 grams of perfume oil is then added drop-wise via a syringe, contacting the core particles in the mixer.
  • a series of four sequential layering steps are then performed, alternately adding 6.15 grams of liquid binder drop-wise via a syringe, contacting the core particles in the mixer, followed by 50.5 grams of layering powder, also added through the top of the mixer, adding more binder, more layering powder, etc., until the product composition is built up in layers surrounding the core particles.
  • 202 grams of layering powder is added in total. 24.6 grams of liquid binder is added into the mixer in total.
  • the resulting coated particle is then screened through 1180 micrometers and on 425 micrometers.
  • the particle is free flowing.
  • the core material is screened granular sodium carbonate prepared by a classification between 425 micrometer and 710 micrometer screens.
  • the layering powder is also sodium carbonate, milled using a Retsch ZM200 to produce a milled material of ⁇ 30 micrometers.
  • the liquid binder is an aqueous solution containing perfume microcapsules, with the following composition:
  • Liquid Binder 1 perfume oil—36.0 % w/w, miscellaneous wall material—17.9% w/w, water—46.1% w/w.
  • a mass of 150 grams of the core particles is loaded into a Kenwood FP520 Series mixer with a stainless steel bladed impeller and the mixer turned on to speed setting #1 to induce a centrifugal flow pattern in the mixer.
  • a series of five sequential layering steps are then performed, alternately adding 27 grams of liquid binder drop-wise via a syringe, contacting the core particles in the mixer, followed by 43 grams of layering powder, also added through the top of the mixer, adding more binder, more layering powder, etc., until the product composition is built up in layers surrounding the core particles. 215 grams of layering powder is added in total. 135 grams of liquid binder is added into the mixer in total.
  • the resulting coated particle is then screened through 1180 micrometers and on 425 micrometers.
  • the particle is free flowing.
  • the core material is screened granular sodium carbonate prepared by a classification between 425 micrometer and 710 micrometer screens.
  • the layering powder is also sodium carbonate, milled using a Retsch ZM200 to produce a milled material of ⁇ 30 micrometers.
  • the liquid binder is a hot melt solution containing perfume, with the following composition:
  • Liquid Binder 2 perfume oil—24.0% w/w, polyethyleneimine—16.1% w/w, tallow alcohol ethoxylated alcohol having an average degree of ethoxylation of 80—59.9% w/w.
  • a mass of 200 grams of the core particles is loaded into a Kenwood FP520 Series mixer with a stainless steel bladed impeller and the mixer turned on to speed setting #1 to induce a centrifugal flow pattern in the mixer.
  • a series of five sequential layering steps are then performed, alternately adding 20 grams of liquid binder drop-wise via a syringe, contacting the core particles in the mixer, followed by 32 grams of layering powder, also added through the top of the mixer, adding more binder, more layering powder, etc., until the product composition is built up in layers surrounding the core particles. 160 grams of layering powder is added in total. 100 grams of liquid binder is added into the mixer in total.
  • the resulting coated particle is then screened through 1180 micrometers and on 425 micrometers.
  • the particle is free flowing.
  • the core material agglomerate core material 1
  • the layering powders are a milled version of the same agglomerate core material 1 , milled using a Retsch ZM200 to produce a milled material of ⁇ 30 micrometers and layering powder 1 , a perfume loaded sodium aluminosilicate, zeolite structure material.
  • the liquid binder is a polyethylene glycol having a molecular weight of 4,000 Da (PEG 4000 ) solution at 60° C.
  • Agglomerate core material 1 sodium carbonate—40.4% w/w, sodium aluminosilicate, zeolite structure—36.7% w/w, sodium acrylic-maleic copolymer—16.2% w/w, miscellaneous materials and water—6.7% w/w.
  • Layering powder 1 sodium aluminosilicate, zeolite structure—83% w/w, perfume oil—17% w/w.
  • a mass of 150 grams of the core particles are loaded into a Kenwood FP520 Series mixer with a stainless steel bladed impeller and the mixer turned on to speed setting #1 to induce a centrifugal flow pattern in the mixer.
  • 33.8 grams of Perfume oil is then added drop-wise via a syringe, contacting the core particles in the mixer.
  • a layering step is performed, adding 10 grams of 60° C. PEG 4000 drop-wise via a syringe, contacting the perfume wetted core particles. This is followed by a 29 gram dose of layering powder 1 .
  • a series of three sequential layering steps are then performed, alternately adding 10 grams of 60° C.
  • PEG 4000 drop-wise via a syringe, contacting the core particles in the mixer, followed by 38 grams of the milled agglomerate core material 1 , the product composition is built up in layers surrounding the core particles. 114 grams of milled agglomerate core material 1 is added in total as layering powder. 40 grams of PEG 4000 is added into the mixer in total as liquid binder.
  • the resulting coated particle is then screened through 1180 micrometers and on 425 micrometers.
  • the particle is free flowing.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Medicinal Preparation (AREA)
  • Fats And Perfumes (AREA)
  • Cosmetics (AREA)
  • Glanulating (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Fertilizers (AREA)
  • General Preparation And Processing Of Foods (AREA)
US11/788,080 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising perfume particle Abandoned US20070249512A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/788,080 US20070249512A1 (en) 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising perfume particle

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US79335206P 2006-04-20 2006-04-20
US11/788,080 US20070249512A1 (en) 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising perfume particle

Publications (1)

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US20070249512A1 true US20070249512A1 (en) 2007-10-25

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US11/788,098 Abandoned US20070249513A1 (en) 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising aesthetic particle
US11/788,080 Abandoned US20070249512A1 (en) 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising perfume particle
US13/013,339 Abandoned US20110124545A1 (en) 2006-04-20 2011-01-25 Flowable particulates
US15/618,272 Abandoned US20170275576A1 (en) 2006-04-20 2017-06-09 Flowable particulates

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US11/788,098 Abandoned US20070249513A1 (en) 2006-04-20 2007-04-19 Solid particulate laundry detergent composition comprising aesthetic particle

Family Applications After (2)

Application Number Title Priority Date Filing Date
US13/013,339 Abandoned US20110124545A1 (en) 2006-04-20 2011-01-25 Flowable particulates
US15/618,272 Abandoned US20170275576A1 (en) 2006-04-20 2017-06-09 Flowable particulates

Country Status (10)

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US (4) US20070249513A1 (es)
EP (3) EP2007866A1 (es)
JP (3) JP2009533205A (es)
CN (5) CN101426895A (es)
BR (3) BRPI0710513A2 (es)
CA (3) CA2645501A1 (es)
MX (3) MX2008013356A (es)
RU (1) RU2424283C2 (es)
WO (3) WO2007124371A1 (es)
ZA (3) ZA200808683B (es)

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IT202100019688A1 (it) * 2021-07-23 2023-01-23 Zobele Holding Spa Detersivo/additivo in pastiglie e relativo metodo di fabbricazione

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