US20020053663A1 - High density cobalt-manganese coprecipitated nickel hydroxide and process for its production - Google Patents

High density cobalt-manganese coprecipitated nickel hydroxide and process for its production Download PDF

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Publication number
US20020053663A1
US20020053663A1 US10/003,916 US391601A US2002053663A1 US 20020053663 A1 US20020053663 A1 US 20020053663A1 US 391601 A US391601 A US 391601A US 2002053663 A1 US2002053663 A1 US 2002053663A1
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United States
Prior art keywords
cobalt
manganese
nickel hydroxide
high density
salt
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Abandoned
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US10/003,916
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English (en)
Inventor
Hiroyuki Ito
Takeshi Usui
Mamoru Shimakawa
Toyoshi Iida
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Tanaka Chemical Corp
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Tanaka Chemical Corp
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Assigned to TANAKA CHEMICAL CORPORATION reassignment TANAKA CHEMICAL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: IIDA, TOYOSHI, ITO, HIROYUKI, SHIMAKAWA, MAMORU, USUI, TAKESHI
Publication of US20020053663A1 publication Critical patent/US20020053663A1/en
Assigned to TANAKA CHEMICAL CORPORATION reassignment TANAKA CHEMICAL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: IIDA, TOYOSHI, ITO, HIROYUKI, SHIMAKAWA, MAMORU, USUI, TAKESHI
Priority to US10/985,778 priority Critical patent/US7585432B2/en
Priority to US11/243,820 priority patent/US7585435B2/en
Abandoned legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G51/82—Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to high density cobalt-manganese coprecipitated nickel hydroxide with excellent charge/discharge cycle properties and high temperature stability, which is suitable as a positive electrode active material for a lithium ion secondary battery, and to a process for its production.
  • the present inventors have completed the present invention upon finding that it is possible to obtain high density cobalt-manganese coprecipitated nickel hydroxide by continuously supplying a complexing agent and an alkali metal hydroxide to an aqueous solution of a nickel salt containing a cobalt salt and a manganese salt while adequately stirring in an aqueous solution either in an inert gas atmosphere or in the presence of an appropriate reducing agent, and accomplishing continuous crystal growth and continuous removal.
  • the present invention relates to high density cobalt-manganese coprecipitated nickel hydroxide with a tapping density of 1.5 g/cc or greater.
  • the invention further relates to high density cobalt-manganese coprecipitated nickel hydroxide characterized in that, where the cobalt-manganese coprecipitated nickel hydroxide is represented as (Ni (1-x-y) Co x Mn y )(OH) 2 , 1/10 ⁇ x ⁇ 1/3 and 1/20 ⁇ y ⁇ 1/3.
  • the invention still further relates to a process for production of high density cobalt-manganese coprecipitated nickel hydroxide, characterized by continuous supply of an aqueous solution of a nickel salt which contains a cobalt salt and a manganese salt, of a complexing agent and of an alkali metal hydroxide, into a reactor either in an inert gas atmosphere or in the presence of a reducing agent, continuous crystal growth and continuous removal. It particularly relates to this process wherein the reducing agent is hydrazine.
  • the invention also includes Li(Ni (1-x-y) Co x Mn y )O 2 obtained by calcining a cobalt-manganese coprecipitated nickel hydroxide according to the invention with an appropriate lithium salt.
  • FIG. 1 is an electron micrograph of high density cobalt-manganese coprecipitated nickel hydroxide according to the invention.
  • the cobalt-manganese coprecipitated nickel hydroxide of the invention is characterized by having high density, and specifically, a density of 1.5 g/cc or greater.
  • the specific surface area of the cobalt-manganese coprecipitated nickel hydroxide of the invention is in the range of 8-20 m 2 /g, and as shown in FIG. 1 it is spherical with a mean particle size in the range of 5-20 ⁇ m.
  • the content of the cobalt and manganese as additional components is not particularly restricted, if represented by (Ni (1-x-y) Co x Mn y )(OH) 2 the ranges are preferably 1/10 ⁇ x ⁇ 1/3 and 1/20 ⁇ y ⁇ 1/3.
  • the production process for the cobalt-manganese coprecipitated nickel hydroxide of the invention accomplishes production of nickel hydroxide with high density of coprecipitated cobalt and manganese by continuous supply of an aqueous solution of a nickel salt containing a cobalt salt (cobalt (II) ion) and a manganese salt (manganese (II) ion), of a complexing agent and of an alkali metal hydroxide, to a reactor with adequate stirring either in an inert gas atmosphere or in the presence of a reducing agent, continuous crystal growth and continuous removal of the resulting precipitate.
  • a nickel salt containing a cobalt salt (cobalt (II) ion) and a manganese salt (manganese (II) ion) manganese salt
  • the salt concentration, complexing agent concentration, pH and temperature in the reactor are kept within a fixed range to satisfactorily control the powder properties, such as the crystallinity, tapping density, specific surface area, particle size, etc.
  • the salt concentration in the vessel is preferably kept in the range of 50-200 mS/cm ⁇ 5 mS/cm and the ammonium ion concentration is preferably kept in the range of 1-10 g/L ⁇ 0.5 g/L.
  • the reaction pH is preferably kept in the range of 11.0-13.0 ⁇ 0.05, and the reaction temperature is preferably kept in the range of 25-80° C. ⁇ 0.5° C.
  • salt concentration adjustors there may be mentioned sodium chloride, potassium chloride, sodium sulfate, potassium sulfate, ammonium chlorate, ammonium sulfate and the like.
  • calcium salts there may be used nitrate, acetate or oxalate salts.
  • the production process of the invention is based on the high density nickel hydroxide production process described in JP-A 10-97856 but is characterized by further adding an appropriate reducing agent. That is, while adequate stirring is usually necessary, this results in inclusion of air, etc. which causes partial oxidation of the unstable cobalt (II) ion or manganese (II) ion and prevents a product with sufficient density from being obtained.
  • the production process is carried out either in an inert gas atmosphere or in the presence of a reducing agent.
  • the added reducing agent is not particularly restricted, but hydrazine is preferred.
  • the ammonium ion source for the reaction as a complexing agent according to the invention is used as a reaction intermediate, as represented by reaction formulas (1) and (2).
  • the nickel salt, ammonium ion source and alkali metal hydroxide are nickel sulfate, ammonia and sodium hydroxide, respectively.
  • Cobalt and manganese are omitted in order to simplify the formulas, but they likewise progress through ammonium complex salts.
  • 4 equivalents of ammonia are not necessary, as about 0.5 equivalent at most is sufficient.
  • Tapping density (B ⁇ A)/D g/ml
  • the tapping density was 1.71 g/cc.
  • the tapping density was 1.82 g/cc.
  • the tapping density was 1.40 g/cc.
  • the tapping density was 1.33 g/cc.
  • the present invention it is possible to obtain high density cobalt-manganese coprecipitated nickel hydroxide having high density, and particularly a tapping density of 1.5 g/cc or greater, by continuous supply of an aqueous solution of a nickel salt which contains a cobalt salt and a manganese salt, of a complexing agent and of an alkali metal hydroxide, into a reactor either in an inert gas atmosphere or in the presence of a reducing agent, continuous crystal growth and continuous removal.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
US10/003,916 2000-11-06 2001-11-02 High density cobalt-manganese coprecipitated nickel hydroxide and process for its production Abandoned US20020053663A1 (en)

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US10/985,778 US7585432B2 (en) 2000-11-06 2004-11-10 High density cobalt-manganese coprecipitated nickel hydroxide and process for its production
US11/243,820 US7585435B2 (en) 2000-11-06 2005-10-05 High density cobalt-manganese coprecipitated nickel hydroxide and process for its production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000-337873 2000-11-06
JP2000337873 2000-11-06

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US11/243,820 Continuation-In-Part US7585435B2 (en) 2000-11-06 2005-10-05 High density cobalt-manganese coprecipitated nickel hydroxide and process for its production

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Cited By (26)

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Publication number Priority date Publication date Assignee Title
US20030054251A1 (en) * 2001-09-13 2003-03-20 Matsushita Electric Industrial Co., Ltd. Positive electrode active material, production method thereof and non-aqueous electrolyte secondary battery
US20040121234A1 (en) * 2002-12-23 2004-06-24 3M Innovative Properties Company Cathode composition for rechargeable lithium battery
US20060147798A1 (en) * 2001-04-27 2006-07-06 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
US20060159994A1 (en) * 2001-08-07 2006-07-20 Dahn Jeffrey R Cathode compositions for lithium ion batteries
WO2007019986A1 (de) * 2005-08-12 2007-02-22 Toda Kogyo Europe Gmbh Anorganische verbindungen
US7211237B2 (en) 2003-11-26 2007-05-01 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
WO2008043559A1 (en) * 2006-10-13 2008-04-17 Toda Kogyo Europe Gmbh Pulverulent compounds, processes for the preparation thereof and the use thereof in electrochemical applications
US20080121841A1 (en) * 2000-11-16 2008-05-29 Hitachi Maxell, Ltd. Lithium-containing complex oxide, non-aqueous secondary battery using the lithium-containing complex oxide, and method for producing the lithium-containing complex oxide
DE102007039471A1 (de) 2007-08-21 2009-02-26 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien
DE102007049108A1 (de) 2007-10-12 2009-04-16 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien
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CN102983320A (zh) * 2008-04-03 2013-03-20 株式会社Lg化学 锂二次电池
CN103296271A (zh) * 2012-03-01 2013-09-11 日本化学工业株式会社 含镍氢氧化物及其制造方法
US8592085B2 (en) 2009-10-22 2013-11-26 Toda Kogyo Corporation Nickel-cobalt-maganese-based compound particles and process for producing the nickel-cobalt-manganese-based compound particles, lithium composite oxide particles and process for producing the lithium composite oxide particles, and non-aqueous electrolyte secondary battery
CN105340112A (zh) * 2013-06-17 2016-02-17 住友金属矿山株式会社 镍钴锰复合氢氧化物和其制造方法
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CN107732212A (zh) * 2017-10-25 2018-02-23 广东邦普循环科技有限公司 一种多孔镍钴锰复合氢氧化物及其制备方法和在锂离子正极材料中的应用
US10297824B2 (en) 2013-07-10 2019-05-21 Tanaka Chemical Corporation Positive electrode active material for lithium secondary battery, positive electrode, and secondary battery
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US10535875B2 (en) 2014-10-15 2020-01-14 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
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US10923719B2 (en) 2017-11-20 2021-02-16 Sumitomo Chemical Company, Limited Positive-electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
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US11437618B2 (en) 2015-11-05 2022-09-06 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary batteries, method of producing positive electrode active material for lithium secondary batteries, positive electrode for lithium secondary batteries, and lithium secondary battery
US11557754B2 (en) 2014-01-27 2023-01-17 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary batteries, positive electrode for lithium secondary batteries, and lithium secondary battery
US20230124497A1 (en) * 2020-06-15 2023-04-20 L&F Co., Ltd. Device for preparing multi-component metal hydroxide

Families Citing this family (16)

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US20070298512A1 (en) 2005-04-13 2007-12-27 Lg Chem, Ltd. Material for lithium secondary battery of high performance
US20080032196A1 (en) 2005-04-13 2008-02-07 Lg Chem, Ltd. Method of preparing material for lithium secondary battery of high performance
US20070292761A1 (en) * 2005-04-13 2007-12-20 Lg Chem, Ltd. Material for lithium secondary battery of high performance
US7648693B2 (en) * 2005-04-13 2010-01-19 Lg Chem, Ltd. Ni-based lithium transition metal oxide
WO2006136050A1 (en) * 2005-06-20 2006-12-28 Shenzhen Bak Battery Co., Ltd A multicomponent composite lithium oxide containing nickel and cobalt, a method for producing the same, the use thereof as a positive electrode active material for lithium ion secondary battery and lithium ion secondary battery
JP5537929B2 (ja) 2006-05-10 2014-07-02 エルジー・ケム・リミテッド 高性能リチウム２次電池材料
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JP6044463B2 (ja) 2013-06-19 2016-12-14 住友金属鉱山株式会社 ニッケルコバルトマンガン複合水酸化物及びその製造方法
KR101547972B1 (ko) * 2014-01-09 2015-08-27 주식회사 이엔드디 니켈―코발트―망간 복합 전구체 제조 방법
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EP3281915B1 (en) 2016-08-10 2019-02-20 Umicore Precursors for lithium transition metal oxide cathode materials for rechargeable batteries
EP3719885A4 (en) * 2017-11-28 2021-08-18 XTC New Energy Materials(xiamen) Ltd. TERNARY PRECURSOR MATERIAL AND ASSOCIATED PREPARATION PROCESS
JP6650956B2 (ja) * 2018-02-01 2020-02-19 Ｊｘ金属株式会社 リチウムイオン電池用正極活物質、リチウムイオン電池及びリチウムイオン電池用正極活物質の製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700596A (en) * 1991-07-08 1997-12-23 Matsushita Electric Industrial Co., Ltd. Nickel hydroxide active material powder and nickel positive electrode and alkali storage battery using them
US5788943A (en) * 1996-09-05 1998-08-04 The Hall Chemical Company Battery-grade nickel hydroxide and method for its preparation
US6086843A (en) * 1998-09-15 2000-07-11 Ovonic Battery Company, Inc. Structurally modified nickel hydroxide material and method for making same
US6306787B1 (en) * 1998-06-10 2001-10-23 Sakai Chemical Industry Co., Ltd. Nickel hydroxide particles and production and use thereof
US6551744B1 (en) * 2000-07-27 2003-04-22 Matsushita Electric Industrial Co., Ltd. Positive electrode active material and non-aqueous electrolyte secondary battery containing the same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3550783B2 (ja) * 1994-05-16 2004-08-04 東ソー株式会社 リチウム含有遷移金属複合酸化物及びその製造方法並びにその用途
JP3451763B2 (ja) 1994-11-29 2003-09-29 ソニー株式会社 正極活物質の製造方法
JP3232984B2 (ja) 1995-10-31 2001-11-26 松下電器産業株式会社 非水電解液電池および正極活物質の製造法
JP3656353B2 (ja) * 1996-03-13 2005-06-08 松下電器産業株式会社 アルカリ蓄電池用正極活物質の製造法
JP3229544B2 (ja) * 1996-04-01 2001-11-19 松下電器産業株式会社 非水電解液電池活物質用ニッケル−コバルト水酸化物
JPH1025117A (ja) * 1996-07-09 1998-01-27 Japan Metals & Chem Co Ltd 水酸化ニッケルの製造方法
JP3290355B2 (ja) * 1996-07-12 2002-06-10 株式会社田中化学研究所 リチウムイオン二次電池用のリチウム含有複合酸化物及びその製造法
TW363940B (en) * 1996-08-12 1999-07-11 Toda Kogyo Corp A lithium-nickle-cobalt compound oxide, process thereof and anode active substance for storage battery
JP3579545B2 (ja) 1996-09-20 2004-10-20 株式会社田中化学研究所 アルカリ蓄電池用水酸化ニッケル及びその製造法
JP3609231B2 (ja) 1997-03-06 2005-01-12 株式会社田中化学研究所 Ｌｉイオン二次電池用コバルト−ニッケル水酸化物の製造法
JP3644186B2 (ja) 1997-03-24 2005-04-27 松下電器産業株式会社 電池構成用金属水酸化物製造装置
JPH10310433A (ja) * 1997-05-07 1998-11-24 Ise Kagaku Kogyo Kk リチウム二次電池用ニッケル水酸化物、ニッケル酸化物および正極活物質の製造方法
JPH10316431A (ja) 1997-05-14 1998-12-02 Fuji Chem Ind Co Ltd リチウムニッケル複合酸化物及びその製造方法並びにリチウム二次電池用正極活物質
JPH11312519A (ja) 1998-02-25 1999-11-09 Mitsui Mining & Smelting Co Ltd Ｍｎ含有複合水酸化ニッケル活物質およびその製造方法
JP4403594B2 (ja) 1998-03-05 2010-01-27 パナソニック株式会社 アルカリ蓄電池用正極活物質およびその製造方法
EP0940865A3 (en) * 1998-03-05 2004-11-03 Matsushita Electric Industrial Co., Ltd Active materials for the positive electrode in alkaline storage battery and the manufacturing method of them

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700596A (en) * 1991-07-08 1997-12-23 Matsushita Electric Industrial Co., Ltd. Nickel hydroxide active material powder and nickel positive electrode and alkali storage battery using them
US5788943A (en) * 1996-09-05 1998-08-04 The Hall Chemical Company Battery-grade nickel hydroxide and method for its preparation
US6306787B1 (en) * 1998-06-10 2001-10-23 Sakai Chemical Industry Co., Ltd. Nickel hydroxide particles and production and use thereof
US6086843A (en) * 1998-09-15 2000-07-11 Ovonic Battery Company, Inc. Structurally modified nickel hydroxide material and method for making same
US6551744B1 (en) * 2000-07-27 2003-04-22 Matsushita Electric Industrial Co., Ltd. Positive electrode active material and non-aqueous electrolyte secondary battery containing the same

Cited By (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8801960B2 (en) * 2000-11-16 2014-08-12 Hitachi Maxell, Ltd. Lithium-containing complex oxide, non-aqueous secondary battery using the lithium-containing complex oxide, and method for producing the lithium-containing complex oxide
US20080121841A1 (en) * 2000-11-16 2008-05-29 Hitachi Maxell, Ltd. Lithium-containing complex oxide, non-aqueous secondary battery using the lithium-containing complex oxide, and method for producing the lithium-containing complex oxide
US7078128B2 (en) 2001-04-27 2006-07-18 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
US20060147798A1 (en) * 2001-04-27 2006-07-06 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
US8685565B2 (en) 2001-04-27 2014-04-01 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
US8241791B2 (en) 2001-04-27 2012-08-14 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
US20060159994A1 (en) * 2001-08-07 2006-07-20 Dahn Jeffrey R Cathode compositions for lithium ion batteries
US7368071B2 (en) 2001-08-07 2008-05-06 3M Innovative Properties Company Cathode compositions for lithium ion batteries
US7579114B2 (en) * 2001-09-13 2009-08-25 Panasonic Corporation Method of preparing positive electrode active material
US20070009424A1 (en) * 2001-09-13 2007-01-11 Osaka City University Method of Preparing Positive Electrode Active Material
US20030054251A1 (en) * 2001-09-13 2003-03-20 Matsushita Electric Industrial Co., Ltd. Positive electrode active material, production method thereof and non-aqueous electrolyte secondary battery
US7670723B2 (en) * 2001-09-13 2010-03-02 Panasonic Corporation Positive electrode active material, production method thereof and non-aqueous electrolyte secondary battery
US20040121234A1 (en) * 2002-12-23 2004-06-24 3M Innovative Properties Company Cathode composition for rechargeable lithium battery
US20070202407A1 (en) * 2003-11-26 2007-08-30 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
US7488465B2 (en) 2003-11-26 2009-02-10 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
US7211237B2 (en) 2003-11-26 2007-05-01 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
US10326133B2 (en) 2005-08-12 2019-06-18 Toda Kogyo Corp. Methods of making inorganic compounds
WO2007019986A1 (de) * 2005-08-12 2007-02-22 Toda Kogyo Europe Gmbh Anorganische verbindungen
US20090302267A1 (en) * 2005-08-12 2009-12-10 Sven Albrecht Inorganic Compounds
KR101306532B1 (ko) 2005-08-12 2013-09-09 토다 고교 유럽 게엠베하 무기 화합물
WO2008043559A1 (en) * 2006-10-13 2008-04-17 Toda Kogyo Europe Gmbh Pulverulent compounds, processes for the preparation thereof and the use thereof in electrochemical applications
US8663507B2 (en) 2006-10-13 2014-03-04 Toda Kogyo Europe Gmbh Pulverulent compounds, processes for the preparation thereof and the use thereof in electrochemical applications
US20100102282A1 (en) * 2006-10-13 2010-04-29 Stefan Malcus Pulverulent compounds, processes for the preparation thereof and the use thereof in electrochemical applications
KR101397317B1 (ko) * 2006-10-13 2014-05-22 토다 고교 유럽 게엠베하 미세분말 화합물, 그의 제조 방법 및 전기화학적 응용에서의 용도
US20110180748A1 (en) * 2007-08-21 2011-07-28 H.C. Starck Gmbh Powdered niam1 bm2c(o)x(oh)ycompounds, method for the production thereof and use thereof in batteries
US9028710B2 (en) 2007-08-21 2015-05-12 H.C. Starck Gmbh Powdered NiaM1bM2c(O)x(OH)y compounds, method for the production thereof and use thereof in batteries
JP2010536697A (ja) * 2007-08-21 2010-12-02 ハー．ツェー．スタルク ゲゼルシャフト ミット ベシュレンクテル ハフツング 粉末状化合物、その製造方法並びにリチウム二次電池におけるその使用
US9352977B2 (en) 2007-08-21 2016-05-31 H.C. Starck Gmbh Powered compounds, method for the production thereof, and use thereof in lithium secondary batteries
DE102007039471A1 (de) 2007-08-21 2009-02-26 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien
DE102007049108A1 (de) 2007-10-12 2009-04-16 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien
US20100310869A1 (en) * 2007-10-12 2010-12-09 H.C. Starck Gmbh POWDER NiaMbOx(OH)y COMPOUNDS, PROCESSES FOR MAKING THE SAME, AND USES THEREOF IN BATTERIES
US8545794B2 (en) 2007-10-12 2013-10-01 H.C. Starck Gmbh Powder NiaMbOx(OH)γcompounds, processes for making the same, and uses thereof in batteries
CN101903292B (zh) * 2007-10-12 2015-11-25 H.C.施塔克有限公司 粉末状NiaMbOX(OH)Y化合物、其制备方法以及在电池组中的应用
CN102983320A (zh) * 2008-04-03 2013-03-20 株式会社Lg化学 锂二次电池
US8592085B2 (en) 2009-10-22 2013-11-26 Toda Kogyo Corporation Nickel-cobalt-maganese-based compound particles and process for producing the nickel-cobalt-manganese-based compound particles, lithium composite oxide particles and process for producing the lithium composite oxide particles, and non-aqueous electrolyte secondary battery
KR101217453B1 (ko) * 2009-12-24 2013-01-02 제이에이치화학공업(주) 리튬이차전지 양극활물질용 전구체인 니켈계 복합금속수산화물 및 그 제조방법
CN103296271A (zh) * 2012-03-01 2013-09-11 日本化学工业株式会社 含镍氢氧化物及其制造方法
CN105340112A (zh) * 2013-06-17 2016-02-17 住友金属矿山株式会社 镍钴锰复合氢氧化物和其制造方法
US10297824B2 (en) 2013-07-10 2019-05-21 Tanaka Chemical Corporation Positive electrode active material for lithium secondary battery, positive electrode, and secondary battery
US11557754B2 (en) 2014-01-27 2023-01-17 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary batteries, positive electrode for lithium secondary batteries, and lithium secondary battery
US10938019B2 (en) 2014-05-29 2021-03-02 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary batteries, positive electrode for lithium secondary batteries, and lithium secondary battery
US10535875B2 (en) 2014-10-15 2020-01-14 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
US10756343B2 (en) 2015-06-02 2020-08-25 Sumitomo Chemical Company, Limited Positive-electrode active material for lithium secondary cell, positive electrode for lithium secondary cell, and lithium secondary cell
TWI670893B (zh) * 2015-09-30 2019-09-01 比利時商烏明克公司 用於可充電電池組之鋰過渡金屬氧化物陰極材料之前驅物
US10547056B2 (en) 2015-09-30 2020-01-28 Umicore Precursors for lithium transition metal oxide cathode materials for rechargeable batteries
US11437618B2 (en) 2015-11-05 2022-09-06 Sumitomo Chemical Company, Limited Positive electrode active material for lithium secondary batteries, method of producing positive electrode active material for lithium secondary batteries, positive electrode for lithium secondary batteries, and lithium secondary battery
CN107565124A (zh) * 2017-08-22 2018-01-09 山东精工电子科技有限公司 一种镍钴锰酸锂前驱体及其制备方法
CN107732212A (zh) * 2017-10-25 2018-02-23 广东邦普循环科技有限公司 一种多孔镍钴锰复合氢氧化物及其制备方法和在锂离子正极材料中的应用
US10923719B2 (en) 2017-11-20 2021-02-16 Sumitomo Chemical Company, Limited Positive-electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
US20230124497A1 (en) * 2020-06-15 2023-04-20 L&F Co., Ltd. Device for preparing multi-component metal hydroxide

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