CN101903292B - 粉末状NiaMbOX(OH)Y化合物、其制备方法以及在电池组中的应用 - Google Patents
粉末状NiaMbOX(OH)Y化合物、其制备方法以及在电池组中的应用 Download PDFInfo
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- CN101903292B CN101903292B CN200880111354.6A CN200880111354A CN101903292B CN 101903292 B CN101903292 B CN 101903292B CN 200880111354 A CN200880111354 A CN 200880111354A CN 101903292 B CN101903292 B CN 101903292B
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
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- C01G53/00—Compounds of nickel
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
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- C01P2002/00—Crystal-structural characteristics
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- C01P2002/54—Solid solutions containing elements as dopants one element only
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
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- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- C01P2006/40—Electric properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/34—Gastight accumulators
- H01M10/345—Gastight metal hydride accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
附图 标记 | 实施例 1 | 实施例 2 | 实施例 3 | 比较例 1 | 比较例 2 | 实施例 4 | |
1 | 反应器[升]: | 190 | 190 | 190 | 190 | 190 | 190 |
2 | 混合器[RPM]: [千瓦]: P/VR[瓦/升]: P/流速悬浮液[瓦小时/升]: | 1000 0.48 2.54 51 | 1000 0.52 2.76 55 | 1000 0.52 2.75 55 | 1000 0.18 0.93 19 | 1000 0.46 2.44 49 | 1000 0.52 2.76 55 |
3 | T[℃]: | 50 | 50 | 50 | 50 | 50 | 50 |
4 | 循环泵[立方米/小时]: | 10 | 10 | 10 | 10 | 10 | 10 |
5 | 金属盐溶液[克/小时]: Ni[克/升]: Co[克/升]: Zn[克/升]: | 11223 79.9 20.1 0.00 | 22446 79.9 20.1 0.00 | 22446 79.9 20.1 0.00 | 6328 79.9 20.1 0.00 | 6328 79.9 20.1 0.00 | 21298 98.4 1.69 6.75 |
6 | 碱液[克/小时]: NaOH[克/升]: | 7746 200 | 16148 200 | 16572 200 | 4367 200 | 4367 200 | 16033 200 |
7 | 铵盐[克/小时]: NH3[克/升]: | 731 225 | 1492 225 | 1512 225 | 412 225 | 412 225 | 1434 225 |
8 | VE水[克/小时]: | 0 | 0 | 0 | 0 | 0 | 0 |
12 | 母液[克/小时]: NaOH[克/升]: NH3[克/升]: | 8154 4.8 11 | 27556 8 11 | 28012 10 11 | 0 4.8 11 | 0 4.8 11 | 26202 8 11 |
9 | 悬浮液[克/小时]: 固体[克/升]: 停留时间[小时]: | 11545 150 20 | 12529 300 20 | 12518 300 20 | 11107 85 20 | 11107 85 20 | 12563 300 20 |
产物量[千克]: 残留水分[%]: Ni[%]: Co[%]: Zn[%]: d10[微米]: d50[微米]: d90[微米]: d90/d50: 振实密度KD[克/立方厘米]: KD/d50[克/立方厘米*微米]: BET[平方米/克] | 34.4 0.44 50.5 12.8 1.4 4.9 9.7 1.98 2.22 0.45 7.3 | 68.5 0.20 50.7 12.4 0.8 4.2 8.6 2.02 2.18 0.51 6.4 | 68.7 0.46 50.3 12.9 0.7 2.6 5.4 2.08 2.17 0.83 12.8 | 19.3 0.19 50.8 12.7 5.8 14.8 26.2 1.77 2.28 0.15 14.9 | 19.3 0.16 50.6 12.7 4.6 11.1 19.9 1.79 2.24 0.20 9.2 | 68.5 0.21 58.3 1.0 4.1 0.5 2.2 4.8 2.18 2.11 0.97 13.8 |
Claims (19)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007049108A DE102007049108A1 (de) | 2007-10-12 | 2007-10-12 | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien |
DE102007049108.7 | 2007-10-12 | ||
PCT/EP2008/061530 WO2009049955A1 (de) | 2007-10-12 | 2008-09-02 | Pulverförmige niambox(oh)y verbindungen, verfahren zu deren herstellung sowie deren verwendung in batterien |
Publications (2)
Publication Number | Publication Date |
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CN101903292A CN101903292A (zh) | 2010-12-01 |
CN101903292B true CN101903292B (zh) | 2015-11-25 |
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CN200880111354.6A Active CN101903292B (zh) | 2007-10-12 | 2008-09-02 | 粉末状NiaMbOX(OH)Y化合物、其制备方法以及在电池组中的应用 |
Country Status (10)
Country | Link |
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US (1) | US8545794B2 (zh) |
EP (1) | EP2209741B1 (zh) |
JP (1) | JP5553761B2 (zh) |
KR (1) | KR101526628B1 (zh) |
CN (1) | CN101903292B (zh) |
CA (1) | CA2695763A1 (zh) |
DE (1) | DE102007049108A1 (zh) |
RU (1) | RU2010118409A (zh) |
TW (1) | TWI419839B (zh) |
WO (1) | WO2009049955A1 (zh) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
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HUE060257T2 (hu) * | 2008-04-03 | 2023-02-28 | Lg Energy Solution Ltd | Új prekurzor lítium kompozit átmenetifém-oxid elõállítására |
JP2012099470A (ja) * | 2010-10-08 | 2012-05-24 | Sumitomo Chemical Co Ltd | リチウム二次電池用正極材料前駆体の製造方法およびリチウム二次電池用正極材料の製造方法 |
US20120177921A1 (en) * | 2011-01-10 | 2012-07-12 | Basf Se | Process for preparing transition metal carbonates |
KR101575024B1 (ko) * | 2013-02-13 | 2015-12-07 | 주식회사 엘지화학 | 낮은 탭 밀도를 갖는 전이금속 전구체 및 높은 입자 강도를 가진 리튬 전이금속 산화물 |
CN103553152B (zh) * | 2013-10-22 | 2015-09-23 | 金天能源材料有限公司 | 高密度球形镍钴铝前驱体材料及其制备方法 |
TWI633062B (zh) * | 2014-06-12 | 2018-08-21 | 烏明克公司 | 用於可充電電池的鋰過渡金屬氧化物陰極材料之先質 |
CN105983383A (zh) * | 2015-02-15 | 2016-10-05 | 江苏海四达电源股份有限公司 | 一种制备锂离子电池正极材料镍钴锰酸锂前躯体的装置 |
CN106450287B (zh) * | 2016-10-31 | 2019-05-28 | 湘潭大学 | 一种氟氧化铋/氢氧化镍二次碱性电池及其制备方法 |
KR102123541B1 (ko) * | 2017-06-29 | 2020-06-16 | 주식회사 엘지화학 | 리튬 이차전지용 양극 활물질 전구체의 제조 방법 |
CN110739447A (zh) * | 2018-07-20 | 2020-01-31 | 河南科隆新能源股份有限公司 | 一种锂离子电池前躯体粒径分布可控的制备方法 |
JP7262230B2 (ja) * | 2019-01-22 | 2023-04-21 | 株式会社田中化学研究所 | 非水電解質二次電池用複合水酸化物小粒子 |
Citations (3)
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CN1685541A (zh) * | 2002-09-28 | 2005-10-19 | 瓦尔塔汽车系统有限责任公司 | 用于碱性蓄电池的活性混合氢氧化镍阴极材料及其制备方法 |
CN1774400A (zh) * | 2003-04-17 | 2006-05-17 | 清美化学股份有限公司 | 含锂-镍-钴-锰复合氧化物及锂二次电池用正极活性物质用原料和它们的制造方法 |
WO2007113102A2 (de) * | 2006-03-31 | 2007-10-11 | H.C. Starck Gmbh | Vorrichtung und verfahren zur herstellung von verbindungen durch fällung |
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EP0572788B1 (de) | 1992-05-04 | 1998-07-15 | H.C. Starck GmbH & Co. KG | Submicrone Carbonitrid-Pulver, Verfahren zu ihrer Herstellung sowie deren Verwendung |
JP3290355B2 (ja) | 1996-07-12 | 2002-06-10 | 株式会社田中化学研究所 | リチウムイオン二次電池用のリチウム含有複合酸化物及びその製造法 |
JP3579545B2 (ja) | 1996-09-20 | 2004-10-20 | 株式会社田中化学研究所 | アルカリ蓄電池用水酸化ニッケル及びその製造法 |
DE19939025A1 (de) * | 1998-12-24 | 2000-06-29 | Starck H C Gmbh Co Kg | Nickel-Mischydroxid, Verfahren zu dessen Herstellung und dessen Verwendung als Kathodenmaterial in alkalischen Batterien |
US6569567B1 (en) * | 1999-09-13 | 2003-05-27 | Ovonic Battery Company, Inc. | Method of activating metal hydride material and electrode |
FR2803104B1 (fr) * | 1999-12-23 | 2002-03-15 | Cit Alcatel | Electrode au nickel non frittee pour generateur electrochimique secondaire a electrolyte alcalin |
US20020053663A1 (en) | 2000-11-06 | 2002-05-09 | Tanaka Chemical Corporation | High density cobalt-manganese coprecipitated nickel hydroxide and process for its production |
DE10132895A1 (de) | 2001-07-06 | 2003-01-16 | Starck H C Gmbh | Nickelhydroxid und Verfahren zu dessen Herstellung |
JP3827545B2 (ja) | 2001-09-13 | 2006-09-27 | 松下電器産業株式会社 | 正極活物質、その製造方法および非水電解質二次電池 |
JP2003323890A (ja) * | 2002-04-30 | 2003-11-14 | Sumitomo Metal Mining Co Ltd | アルカリ蓄電池用水酸化ニッケル及びその製造方法 |
US20050221179A1 (en) | 2002-09-28 | 2005-10-06 | Varta Automotive Systems Gmbh | Active mixed nickel hydroxide cathode material for alkaline storage batteries and process for its production |
JPWO2006001210A1 (ja) * | 2004-06-24 | 2008-04-17 | 松下電器産業株式会社 | アルカリ電池 |
DE102004044557B3 (de) * | 2004-09-15 | 2006-06-14 | Bayer Inc., Sarnia | Mischmetallhydroxide, deren Herstellung und Verwendung |
US7985503B2 (en) * | 2005-06-27 | 2011-07-26 | Shenzhen Bak Battery Co., Ltd | Method for preparing spherical nickelous hydroxide which is dopped and multiple metal oxides, and lithium ion secondary battery |
CA2618780C (en) * | 2005-08-12 | 2015-10-20 | Toda Kogyo Europe Gmbh | Partly oxidized mixed metal hydroxides |
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2007
- 2007-10-12 DE DE102007049108A patent/DE102007049108A1/de not_active Ceased
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2008
- 2008-09-02 WO PCT/EP2008/061530 patent/WO2009049955A1/de active Application Filing
- 2008-09-02 EP EP08803505A patent/EP2209741B1/de active Active
- 2008-09-02 RU RU2010118409/05A patent/RU2010118409A/ru not_active Application Discontinuation
- 2008-09-02 US US12/682,707 patent/US8545794B2/en active Active
- 2008-09-02 CA CA2695763A patent/CA2695763A1/en not_active Abandoned
- 2008-09-02 CN CN200880111354.6A patent/CN101903292B/zh active Active
- 2008-09-02 KR KR1020107006338A patent/KR101526628B1/ko active IP Right Grant
- 2008-09-29 JP JP2010528335A patent/JP5553761B2/ja active Active
- 2008-10-09 TW TW097138805A patent/TWI419839B/zh active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1685541A (zh) * | 2002-09-28 | 2005-10-19 | 瓦尔塔汽车系统有限责任公司 | 用于碱性蓄电池的活性混合氢氧化镍阴极材料及其制备方法 |
CN1774400A (zh) * | 2003-04-17 | 2006-05-17 | 清美化学股份有限公司 | 含锂-镍-钴-锰复合氧化物及锂二次电池用正极活性物质用原料和它们的制造方法 |
WO2007113102A2 (de) * | 2006-03-31 | 2007-10-11 | H.C. Starck Gmbh | Vorrichtung und verfahren zur herstellung von verbindungen durch fällung |
Also Published As
Publication number | Publication date |
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RU2010118409A (ru) | 2011-11-27 |
CN101903292A (zh) | 2010-12-01 |
US20100310869A1 (en) | 2010-12-09 |
JP5553761B2 (ja) | 2014-07-16 |
WO2009049955A1 (de) | 2009-04-23 |
KR20100067086A (ko) | 2010-06-18 |
EP2209741A1 (de) | 2010-07-28 |
US8545794B2 (en) | 2013-10-01 |
TWI419839B (zh) | 2013-12-21 |
DE102007049108A1 (de) | 2009-04-16 |
TW200936507A (en) | 2009-09-01 |
EP2209741B1 (de) | 2013-01-16 |
CA2695763A1 (en) | 2009-04-23 |
KR101526628B1 (ko) | 2015-06-05 |
JP2011501727A (ja) | 2011-01-13 |
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