TWI815958B - 無機微粒子分散用載體組成物、無機微粒子分散漿料組成物及無機微粒子分散片之製造方法 - Google Patents
無機微粒子分散用載體組成物、無機微粒子分散漿料組成物及無機微粒子分散片之製造方法 Download PDFInfo
- Publication number
- TWI815958B TWI815958B TW108131196A TW108131196A TWI815958B TW I815958 B TWI815958 B TW I815958B TW 108131196 A TW108131196 A TW 108131196A TW 108131196 A TW108131196 A TW 108131196A TW I815958 B TWI815958 B TW I815958B
- Authority
- TW
- Taiwan
- Prior art keywords
- inorganic fine
- boiling point
- meth
- weight
- particle dispersion
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 112
- 239000010419 fine particle Substances 0.000 title claims abstract description 110
- 239000006185 dispersion Substances 0.000 title claims abstract description 73
- 239000002002 slurry Substances 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title abstract description 21
- 238000009835 boiling Methods 0.000 claims abstract description 189
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 47
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 47
- -1 aromatic amine compounds Chemical class 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 38
- 229920005989 resin Polymers 0.000 claims abstract description 38
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 28
- 239000011230 binding agent Substances 0.000 claims abstract description 25
- 239000003960 organic solvent Substances 0.000 claims abstract description 22
- 150000002989 phenols Chemical class 0.000 claims abstract description 7
- 150000002828 nitro derivatives Chemical class 0.000 claims abstract description 6
- 150000004053 quinones Chemical class 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 61
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 39
- 229910052799 carbon Inorganic materials 0.000 claims description 38
- 150000002148 esters Chemical group 0.000 claims description 36
- 239000004014 plasticizer Substances 0.000 claims description 24
- 239000011859 microparticle Substances 0.000 claims description 15
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000011521 glass Substances 0.000 description 22
- 239000003826 tablet Substances 0.000 description 21
- 238000000354 decomposition reaction Methods 0.000 description 16
- 238000005238 degreasing Methods 0.000 description 16
- 239000010408 film Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 15
- 229910004298 SiO 2 Inorganic materials 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 14
- 239000000919 ceramic Substances 0.000 description 14
- 239000011572 manganese Substances 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical class OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000011342 resin composition Substances 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 6
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 230000009477 glass transition Effects 0.000 description 6
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 6
- UODXCYZDMHPIJE-UHFFFAOYSA-N menthanol Chemical compound CC1CCC(C(C)(C)O)CC1 UODXCYZDMHPIJE-UHFFFAOYSA-N 0.000 description 6
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 5
- JECYUBVRTQDVAT-UHFFFAOYSA-N 2-acetylphenol Chemical class CC(=O)C1=CC=CC=C1O JECYUBVRTQDVAT-UHFFFAOYSA-N 0.000 description 5
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- QWBBPBRQALCEIZ-UHFFFAOYSA-N 2,3-dimethylphenol Chemical compound CC1=CC=CC(O)=C1C QWBBPBRQALCEIZ-UHFFFAOYSA-N 0.000 description 4
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 4
- HBNHCGDYYBMKJN-UHFFFAOYSA-N 2-(4-methylcyclohexyl)propan-2-yl acetate Chemical compound CC1CCC(C(C)(C)OC(C)=O)CC1 HBNHCGDYYBMKJN-UHFFFAOYSA-N 0.000 description 4
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 4
- YCOXTKKNXUZSKD-UHFFFAOYSA-N 3,4-xylenol Chemical compound CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 4
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 4
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 4
- 150000004056 anthraquinones Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000003985 ceramic capacitor Substances 0.000 description 4
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 4
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- RBXVOQPAMPBADW-UHFFFAOYSA-N nitrous acid;phenol Chemical class ON=O.OC1=CC=CC=C1 RBXVOQPAMPBADW-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 4
- 229920001515 polyalkylene glycol Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000011118 polyvinyl acetate Substances 0.000 description 4
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000001716 (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl) acetate Substances 0.000 description 3
- LWHDQPLUIFIFFT-UHFFFAOYSA-N 2,3,5,6-tetrabromocyclohexa-2,5-diene-1,4-dione Chemical compound BrC1=C(Br)C(=O)C(Br)=C(Br)C1=O LWHDQPLUIFIFFT-UHFFFAOYSA-N 0.000 description 3
- LNXVNZRYYHFMEY-UHFFFAOYSA-N 2,5-dichlorocyclohexa-2,5-diene-1,4-dione Chemical compound ClC1=CC(=O)C(Cl)=CC1=O LNXVNZRYYHFMEY-UHFFFAOYSA-N 0.000 description 3
- WZUODJNEIXSNEU-UHFFFAOYSA-N 2-Hydroxy-4-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C(O)=C1 WZUODJNEIXSNEU-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 236TMPh Natural products CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 description 3
- IAVREABSGIHHMO-UHFFFAOYSA-N 3-hydroxybenzaldehyde Chemical compound OC1=CC=CC(C=O)=C1 IAVREABSGIHHMO-UHFFFAOYSA-N 0.000 description 3
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 3
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 3
- FZHSPPYCNDYIKD-UHFFFAOYSA-N 5-methoxysalicylaldehyde Chemical compound COC1=CC=C(O)C(C=O)=C1 FZHSPPYCNDYIKD-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910007472 ZnO—B2O3—SiO2 Inorganic materials 0.000 description 3
- 230000001133 acceleration Effects 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 3
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004054 benzoquinones Chemical class 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- JVTZFYYHCGSXJV-UHFFFAOYSA-N isovanillin Chemical compound COC1=CC=C(C=O)C=C1O JVTZFYYHCGSXJV-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical class [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 3
- 229920001748 polybutylene Polymers 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229940116411 terpineol Drugs 0.000 description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- PPTXVXKCQZKFBN-UHFFFAOYSA-N (S)-(-)-1,1'-Bi-2-naphthol Chemical compound C1=CC=C2C(C3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 PPTXVXKCQZKFBN-UHFFFAOYSA-N 0.000 description 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 2
- PWKNBLFSJAVFAB-UHFFFAOYSA-N 1-fluoro-2-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1F PWKNBLFSJAVFAB-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- BRRSNXCXLSVPFC-UHFFFAOYSA-N 2,3,4-Trihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1O BRRSNXCXLSVPFC-UHFFFAOYSA-N 0.000 description 2
- KLAQSPUVCDBEGF-UHFFFAOYSA-N 2,3,5,6-tetramethylphenol Chemical compound CC1=CC(C)=C(C)C(O)=C1C KLAQSPUVCDBEGF-UHFFFAOYSA-N 0.000 description 2
- AUFZRCJENRSRLY-UHFFFAOYSA-N 2,3,5-trimethylhydroquinone Chemical compound CC1=CC(O)=C(C)C(C)=C1O AUFZRCJENRSRLY-UHFFFAOYSA-N 0.000 description 2
- OGRAOKJKVGDSFR-UHFFFAOYSA-N 2,3,5-trimethylphenol Chemical compound CC1=CC(C)=C(C)C(O)=C1 OGRAOKJKVGDSFR-UHFFFAOYSA-N 0.000 description 2
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 2
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 2
- CZZZABOKJQXEBO-UHFFFAOYSA-N 2,4-dimethylaniline Chemical compound CC1=CC=C(N)C(C)=C1 CZZZABOKJQXEBO-UHFFFAOYSA-N 0.000 description 2
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 description 2
- KUFFULVDNCHOFZ-UHFFFAOYSA-N 2,4-xylenol Chemical compound CC1=CC=C(O)C(C)=C1 KUFFULVDNCHOFZ-UHFFFAOYSA-N 0.000 description 2
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- FIGPGTJKHFAYRK-UHFFFAOYSA-N 2,6-dibromo-4-methylphenol Chemical compound CC1=CC(Br)=C(O)C(Br)=C1 FIGPGTJKHFAYRK-UHFFFAOYSA-N 0.000 description 2
- JCARTGJGWCGSSU-UHFFFAOYSA-N 2,6-dichlorobenzoquinone Chemical compound ClC1=CC(=O)C=C(Cl)C1=O JCARTGJGWCGSSU-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- YCCILVSKPBXVIP-UHFFFAOYSA-N 2-(4-hydroxyphenyl)ethanol Chemical compound OCCC1=CC=C(O)C=C1 YCCILVSKPBXVIP-UHFFFAOYSA-N 0.000 description 2
- PETRWTHZSKVLRE-UHFFFAOYSA-N 2-Methoxy-4-methylphenol Chemical compound COC1=CC(C)=CC=C1O PETRWTHZSKVLRE-UHFFFAOYSA-N 0.000 description 2
- YJTIFIMHZHDNQZ-UHFFFAOYSA-N 2-[2-(2-methylpropoxy)ethoxy]ethanol Chemical compound CC(C)COCCOCCO YJTIFIMHZHDNQZ-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- WYXXLXHHWYNKJF-UHFFFAOYSA-N 2-methyl-4-propan-2-ylphenol Chemical compound CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- DOLQYFPDPKPQSS-UHFFFAOYSA-N 3,4-dimethylaniline Chemical compound CC1=CC=C(N)C=C1C DOLQYFPDPKPQSS-UHFFFAOYSA-N 0.000 description 2
- MKARNSWMMBGSHX-UHFFFAOYSA-N 3,5-dimethylaniline Chemical compound CC1=CC(C)=CC(N)=C1 MKARNSWMMBGSHX-UHFFFAOYSA-N 0.000 description 2
- JJYPMNFTHPTTDI-UHFFFAOYSA-N 3-methylaniline Chemical compound CC1=CC=CC(N)=C1 JJYPMNFTHPTTDI-UHFFFAOYSA-N 0.000 description 2
- CHWNEIVBYREQRF-UHFFFAOYSA-N 4-Ethyl-2-methoxyphenol Chemical compound CCC1=CC=C(O)C(OC)=C1 CHWNEIVBYREQRF-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- XQXPVVBIMDBYFF-UHFFFAOYSA-N 4-hydroxyphenylacetic acid Chemical compound OC(=O)CC1=CC=C(O)C=C1 XQXPVVBIMDBYFF-UHFFFAOYSA-N 0.000 description 2
- ZSBDGXGICLIJGD-UHFFFAOYSA-N 4-phenoxyphenol Chemical compound C1=CC(O)=CC=C1OC1=CC=CC=C1 ZSBDGXGICLIJGD-UHFFFAOYSA-N 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- GUOVZPRFHWZQBA-UHFFFAOYSA-N 6-(2-butoxyethoxy)-6-oxohexanoic acid Chemical compound CCCCOCCOC(=O)CCCCC(O)=O GUOVZPRFHWZQBA-UHFFFAOYSA-N 0.000 description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- 229930192627 Naphthoquinone Natural products 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910020617 PbO—B2O3—SiO2 Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910004283 SiO 4 Inorganic materials 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001448 anilines Chemical class 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 2
- 229910002113 barium titanate Inorganic materials 0.000 description 2
- BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229940043232 butyl acetate Drugs 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 229940093499 ethyl acetate Drugs 0.000 description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229960001867 guaiacol Drugs 0.000 description 2
- BJRNKVDFDLYUGJ-RMPHRYRLSA-N hydroquinone O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-RMPHRYRLSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- CSFWPUWCSPOLJW-UHFFFAOYSA-N lawsone Chemical compound C1=CC=C2C(=O)C(O)=CC(=O)C2=C1 CSFWPUWCSPOLJW-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 229940032007 methylethyl ketone Drugs 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 2
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 2
- 229960003742 phenol Drugs 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229940079877 pyrogallol Drugs 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 2
- 229960000984 tocofersolan Drugs 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- DEUGOISHWHDTIR-UHFFFAOYSA-N (1-hydroxy-5,5-dimethylhexyl) 2-methylpropanoate Chemical compound C(C(C)C)(=O)OC(CCCC(C)(C)C)O DEUGOISHWHDTIR-UHFFFAOYSA-N 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 description 1
- OVFWWDRGWIAOIT-UHFFFAOYSA-N 1,2,3,4-tetramethyl-5,6-dinitrobenzene Chemical compound CC1=C(C)C(C)=C([N+]([O-])=O)C([N+]([O-])=O)=C1C OVFWWDRGWIAOIT-UHFFFAOYSA-N 0.000 description 1
- AEPQXGFMAZTUEA-UHFFFAOYSA-N 1,2,4,5-tetramethyl-3,6-dinitrobenzene Chemical compound CC1=C(C)C([N+]([O-])=O)=C(C)C(C)=C1[N+]([O-])=O AEPQXGFMAZTUEA-UHFFFAOYSA-N 0.000 description 1
- OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
- IZUKQUVSCNEFMJ-UHFFFAOYSA-N 1,2-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O IZUKQUVSCNEFMJ-UHFFFAOYSA-N 0.000 description 1
- DWCLEQILYXIKKV-UHFFFAOYSA-N 1,2-dinitrobenzene;nitromethylbenzene Chemical class [O-][N+](=O)CC1=CC=CC=C1.[O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O DWCLEQILYXIKKV-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- 229940005561 1,4-benzoquinone Drugs 0.000 description 1
- REGMWDPZVFOJLY-UHFFFAOYSA-N 1,4-bis(2-hydroperoxypropan-2-yl)benzene Chemical compound OOC(C)(C)C1=CC=C(C(C)(C)OO)C=C1 REGMWDPZVFOJLY-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- SQZCAOHYQSOZCE-UHFFFAOYSA-N 1-(diaminomethylidene)-2-(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N=C(N)N=C(N)N SQZCAOHYQSOZCE-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
- MZQZXSHFWDHNOW-UHFFFAOYSA-N 1-phenylpropane-1,2-diol Chemical compound CC(O)C(O)C1=CC=CC=C1 MZQZXSHFWDHNOW-UHFFFAOYSA-N 0.000 description 1
- OWQCUVRSJUABCB-UHFFFAOYSA-N 16-methylheptadecyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C(C)=C OWQCUVRSJUABCB-UHFFFAOYSA-N 0.000 description 1
- STFXXRRQKFUYEU-UHFFFAOYSA-N 16-methylheptadecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C=C STFXXRRQKFUYEU-UHFFFAOYSA-N 0.000 description 1
- WALBTDFSFTVXII-UHFFFAOYSA-N 2,3,4,5,6-pentamethylphenol Chemical compound CC1=C(C)C(C)=C(O)C(C)=C1C WALBTDFSFTVXII-UHFFFAOYSA-N 0.000 description 1
- HTQNYBBTZSBWKL-UHFFFAOYSA-N 2,3,4-trihydroxbenzophenone Chemical compound OC1=C(O)C(O)=CC=C1C(=O)C1=CC=CC=C1 HTQNYBBTZSBWKL-UHFFFAOYSA-N 0.000 description 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 1
- VVAKEQGKZNKUSU-UHFFFAOYSA-N 2,3-dimethylaniline Chemical compound CC1=CC=CC(N)=C1C VVAKEQGKZNKUSU-UHFFFAOYSA-N 0.000 description 1
- MHKBMNACOMRIAW-UHFFFAOYSA-N 2,3-dinitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O MHKBMNACOMRIAW-UHFFFAOYSA-N 0.000 description 1
- 150000004483 2,3-naphthoquinones Chemical class 0.000 description 1
- GUMCAKKKNKYFEB-UHFFFAOYSA-N 2,4,5-trichloroaniline Chemical compound NC1=CC(Cl)=C(Cl)C=C1Cl GUMCAKKKNKYFEB-UHFFFAOYSA-N 0.000 description 1
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- CEPCPXLLFXPZGW-UHFFFAOYSA-N 2,4-difluoroaniline Chemical compound NC1=CC=C(F)C=C1F CEPCPXLLFXPZGW-UHFFFAOYSA-N 0.000 description 1
- RMBFBMJGBANMMK-UHFFFAOYSA-N 2,4-dinitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O RMBFBMJGBANMMK-UHFFFAOYSA-N 0.000 description 1
- CZNRFEXEPBITDS-UHFFFAOYSA-N 2,5-bis(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=C(C(C)(C)CC)C=C1O CZNRFEXEPBITDS-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- AVYGCQXNNJPXSS-UHFFFAOYSA-N 2,5-dichloroaniline Chemical compound NC1=CC(Cl)=CC=C1Cl AVYGCQXNNJPXSS-UHFFFAOYSA-N 0.000 description 1
- QYXHDJJYVDLECA-UHFFFAOYSA-N 2,5-diphenylcyclohexa-2,5-diene-1,4-dione Chemical compound O=C1C=C(C=2C=CC=CC=2)C(=O)C=C1C1=CC=CC=C1 QYXHDJJYVDLECA-UHFFFAOYSA-N 0.000 description 1
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- FNORUNUDZNWQFF-UHFFFAOYSA-N 2,6-dimethyl-4-nitrophenol Chemical compound CC1=CC([N+]([O-])=O)=CC(C)=C1O FNORUNUDZNWQFF-UHFFFAOYSA-N 0.000 description 1
- SENUUPBBLQWHMF-UHFFFAOYSA-N 2,6-dimethylcyclohexa-2,5-diene-1,4-dione Chemical compound CC1=CC(=O)C=C(C)C1=O SENUUPBBLQWHMF-UHFFFAOYSA-N 0.000 description 1
- VJXIZXJHJXDYGJ-UHFFFAOYSA-N 2,6-dimethylphenol;phenol Chemical compound OC1=CC=CC=C1.CC1=CC=CC(C)=C1O VJXIZXJHJXDYGJ-UHFFFAOYSA-N 0.000 description 1
- HOYRZHJJAHRMLL-UHFFFAOYSA-N 2,6-dinitro-p-cresol Chemical compound CC1=CC([N+]([O-])=O)=C(O)C([N+]([O-])=O)=C1 HOYRZHJJAHRMLL-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- MWSIBOZRUWYJET-UHFFFAOYSA-N 2-(4-hydroxy-3-methoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC(C(=C)C(O)=O)=CC=C1O MWSIBOZRUWYJET-UHFFFAOYSA-N 0.000 description 1
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- IZLVFLOBTPURLP-UHFFFAOYSA-N 2-Methoxy-4-nitrophenol Chemical compound COC1=CC([N+]([O-])=O)=CC=C1O IZLVFLOBTPURLP-UHFFFAOYSA-N 0.000 description 1
- PKZJLOCLABXVMC-UHFFFAOYSA-N 2-Methoxybenzaldehyde Chemical compound COC1=CC=CC=C1C=O PKZJLOCLABXVMC-UHFFFAOYSA-N 0.000 description 1
- WPMUZECMAFLDQO-UHFFFAOYSA-N 2-[2-(2-hexanoyloxyethoxy)ethoxy]ethyl hexanoate Chemical compound CCCCCC(=O)OCCOCCOCCOC(=O)CCCCC WPMUZECMAFLDQO-UHFFFAOYSA-N 0.000 description 1
- PHXLONCQBNATSL-UHFFFAOYSA-N 2-[[2-hydroxy-5-methyl-3-(1-methylcyclohexyl)phenyl]methyl]-4-methyl-6-(1-methylcyclohexyl)phenol Chemical compound OC=1C(C2(C)CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1(C)CCCCC1 PHXLONCQBNATSL-UHFFFAOYSA-N 0.000 description 1
- JYYLQSCZISREGY-UHFFFAOYSA-N 2-amino-4-chlorobenzoic acid Chemical compound NC1=CC(Cl)=CC=C1C(O)=O JYYLQSCZISREGY-UHFFFAOYSA-N 0.000 description 1
- VYZCFAPUHSSYCC-UHFFFAOYSA-N 2-amino-5-chloro-4-methylbenzenesulfonic acid Chemical compound CC1=CC(N)=C(S(O)(=O)=O)C=C1Cl VYZCFAPUHSSYCC-UHFFFAOYSA-N 0.000 description 1
- GWIAAIUASRVOIA-UHFFFAOYSA-N 2-aminonaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(N)=CC=C21 GWIAAIUASRVOIA-UHFFFAOYSA-N 0.000 description 1
- VRVRGVPWCUEOGV-UHFFFAOYSA-N 2-aminothiophenol Chemical compound NC1=CC=CC=C1S VRVRGVPWCUEOGV-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LOCWBQIWHWIRGN-UHFFFAOYSA-N 2-chloro-4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1Cl LOCWBQIWHWIRGN-UHFFFAOYSA-N 0.000 description 1
- AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical compound NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- ODEFERITUOZPHJ-UHFFFAOYSA-N 2-hydroxy-3-methylbenzenesulfonic acid Chemical compound CC1=CC=CC(S(O)(=O)=O)=C1O ODEFERITUOZPHJ-UHFFFAOYSA-N 0.000 description 1
- AXZKCQSGDARVRL-UHFFFAOYSA-N 2-hydroxy-5-methylbenzenesulfonic acid Chemical compound CC1=CC=C(O)C(S(O)(=O)=O)=C1 AXZKCQSGDARVRL-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- JITSLEIKSRKKCZ-UHFFFAOYSA-N 2-iodo-4-methylphenol Chemical compound CC1=CC=C(O)C(I)=C1 JITSLEIKSRKKCZ-UHFFFAOYSA-N 0.000 description 1
- IVJQGBHYRPCKGH-UHFFFAOYSA-N 2-methoxy-4-nitrophenol;sodium Chemical compound [Na].COC1=CC([N+]([O-])=O)=CC=C1O IVJQGBHYRPCKGH-UHFFFAOYSA-N 0.000 description 1
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 description 1
- YEKPNMQQSPHKBP-UHFFFAOYSA-N 2-methyl-6-nitrobenzoic anhydride Chemical compound CC1=CC=CC([N+]([O-])=O)=C1C(=O)OC(=O)C1=C(C)C=CC=C1[N+]([O-])=O YEKPNMQQSPHKBP-UHFFFAOYSA-N 0.000 description 1
- KFETUQFRWIVAMU-UHFFFAOYSA-N 2-methyl-6-propan-2-ylphenol Chemical compound CC(C)C1=CC=CC(C)=C1O KFETUQFRWIVAMU-UHFFFAOYSA-N 0.000 description 1
- TWCXRVFSIAWFMA-UHFFFAOYSA-N 2-morpholin-4-ium-2-ylacetate Chemical compound OC(=O)CC1CNCCO1 TWCXRVFSIAWFMA-UHFFFAOYSA-N 0.000 description 1
- DLURHXYXQYMPLT-UHFFFAOYSA-N 2-nitro-p-toluidine Chemical compound CC1=CC=C(N)C([N+]([O-])=O)=C1 DLURHXYXQYMPLT-UHFFFAOYSA-N 0.000 description 1
- PLAZTCDQAHEYBI-UHFFFAOYSA-N 2-nitrotoluene Chemical compound CC1=CC=CC=C1[N+]([O-])=O PLAZTCDQAHEYBI-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- RLQZIECDMISZHS-UHFFFAOYSA-N 2-phenylcyclohexa-2,5-diene-1,4-dione Chemical class O=C1C=CC(=O)C(C=2C=CC=CC=2)=C1 RLQZIECDMISZHS-UHFFFAOYSA-N 0.000 description 1
- 229940061334 2-phenylphenol Drugs 0.000 description 1
- BVCOHOSEBKQIQD-UHFFFAOYSA-N 2-tert-butyl-6-methoxyphenol Chemical compound COC1=CC=CC(C(C)(C)C)=C1O BVCOHOSEBKQIQD-UHFFFAOYSA-N 0.000 description 1
- 229940044119 2-tert-butylhydroquinone Drugs 0.000 description 1
- AKLOLDQYWQAREW-UHFFFAOYSA-N 3,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C([N+]([O-])=O)=C1 AKLOLDQYWQAREW-UHFFFAOYSA-N 0.000 description 1
- UENRXLSRMCSUSN-UHFFFAOYSA-N 3,5-diaminobenzoic acid Chemical compound NC1=CC(N)=CC(C(O)=O)=C1 UENRXLSRMCSUSN-UHFFFAOYSA-N 0.000 description 1
- UEMBNLWZFIWQFL-UHFFFAOYSA-N 3,5-dinitrophenol Chemical compound OC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UEMBNLWZFIWQFL-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- ZBMISJGHVWNWTE-UHFFFAOYSA-N 3-(4-aminophenoxy)aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC(N)=C1 ZBMISJGHVWNWTE-UHFFFAOYSA-N 0.000 description 1
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- AZXBHGKSTNMAMK-UHFFFAOYSA-N 3-methyl-2-propan-2-ylphenol Chemical compound CC(C)C1=C(C)C=CC=C1O AZXBHGKSTNMAMK-UHFFFAOYSA-N 0.000 description 1
- ZDUIHRJGDMTBEX-UHFFFAOYSA-N 3-methyl-5-propan-2-ylphenol Chemical compound CC(C)C1=CC(C)=CC(O)=C1 ZDUIHRJGDMTBEX-UHFFFAOYSA-N 0.000 description 1
- RTZZCYNQPHTPPL-UHFFFAOYSA-N 3-nitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1 RTZZCYNQPHTPPL-UHFFFAOYSA-N 0.000 description 1
- JKIGHOGKGARVAG-UHFFFAOYSA-N 3-phenyl-1h-benzimidazole-2-thione Chemical compound S=C1NC2=CC=CC=C2N1C1=CC=CC=C1 JKIGHOGKGARVAG-UHFFFAOYSA-N 0.000 description 1
- QMGBIPKOKCSUCL-UHFFFAOYSA-N 3-propan-2-yloxyaniline Chemical compound CC(C)OC1=CC=CC(N)=C1 QMGBIPKOKCSUCL-UHFFFAOYSA-N 0.000 description 1
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 description 1
- WECDUOXQLAIPQW-UHFFFAOYSA-N 4,4'-Methylene bis(2-methylaniline) Chemical compound C1=C(N)C(C)=CC(CC=2C=C(C)C(N)=CC=2)=C1 WECDUOXQLAIPQW-UHFFFAOYSA-N 0.000 description 1
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- FAYGEALAEQKPDI-UHFFFAOYSA-N 4-(2-methoxyethyl)phenol Chemical compound COCCC1=CC=C(O)C=C1 FAYGEALAEQKPDI-UHFFFAOYSA-N 0.000 description 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
- QYIMZXITLDTULQ-UHFFFAOYSA-N 4-(4-amino-2-methylphenyl)-3-methylaniline Chemical compound CC1=CC(N)=CC=C1C1=CC=C(N)C=C1C QYIMZXITLDTULQ-UHFFFAOYSA-N 0.000 description 1
- JTGCXYYDAVPSFD-UHFFFAOYSA-N 4-(4-hydroxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(O)C=C1 JTGCXYYDAVPSFD-UHFFFAOYSA-N 0.000 description 1
- ZRMIETZFPZGBEB-UHFFFAOYSA-N 4-(4-hydroxyphenyl)benzonitrile Chemical group C1=CC(O)=CC=C1C1=CC=C(C#N)C=C1 ZRMIETZFPZGBEB-UHFFFAOYSA-N 0.000 description 1
- CYCBPQPFMHUATH-UHFFFAOYSA-N 4-(oxiran-2-ylmethoxy)butan-1-ol Chemical compound OCCCCOCC1CO1 CYCBPQPFMHUATH-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- BOTGCZBEERTTDQ-UHFFFAOYSA-N 4-Methoxy-1-naphthol Chemical compound C1=CC=C2C(OC)=CC=C(O)C2=C1 BOTGCZBEERTTDQ-UHFFFAOYSA-N 0.000 description 1
- WOCGGVRGNIEDSZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical compound C=1C=C(O)C(CC=C)=CC=1C(C)(C)C1=CC=C(O)C(CC=C)=C1 WOCGGVRGNIEDSZ-UHFFFAOYSA-N 0.000 description 1
- YBAZINRZQSAIAY-UHFFFAOYSA-N 4-aminobenzonitrile Chemical compound NC1=CC=C(C#N)C=C1 YBAZINRZQSAIAY-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073735 4-hydroxy acetophenone Drugs 0.000 description 1
- MTUFXSKAMJWLNG-UHFFFAOYSA-N 4-hydroxybenzenesulfonic acid;hydrate Chemical compound O.OC1=CC=C(S(O)(=O)=O)C=C1 MTUFXSKAMJWLNG-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- VSMDINRNYYEDRN-UHFFFAOYSA-N 4-iodophenol Chemical compound OC1=CC=C(I)C=C1 VSMDINRNYYEDRN-UHFFFAOYSA-N 0.000 description 1
- CYMPUOGZUXAIMY-UHFFFAOYSA-N 4-methoxy-2-methyl-n-phenylaniline Chemical compound CC1=CC(OC)=CC=C1NC1=CC=CC=C1 CYMPUOGZUXAIMY-UHFFFAOYSA-N 0.000 description 1
- MNVMYTVDDOXZLS-UHFFFAOYSA-N 4-methoxyguaiacol Natural products COC1=CC=C(O)C(OC)=C1 MNVMYTVDDOXZLS-UHFFFAOYSA-N 0.000 description 1
- UDQCDDZBBZNIFA-UHFFFAOYSA-N 4-methyl-1,3-dihydrobenzimidazole-2-thione Chemical compound CC1=CC=CC2=C1NC(=S)N2 UDQCDDZBBZNIFA-UHFFFAOYSA-N 0.000 description 1
- HTAMNOAYOHLVPQ-UHFFFAOYSA-N 4-methyl-3,5-dinitrophenol Chemical compound CC1=C([N+]([O-])=O)C=C(O)C=C1[N+]([O-])=O HTAMNOAYOHLVPQ-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- ZPTVNYMJQHSSEA-UHFFFAOYSA-N 4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1 ZPTVNYMJQHSSEA-UHFFFAOYSA-N 0.000 description 1
- NTDQQZYCCIDJRK-UHFFFAOYSA-N 4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C=C1 NTDQQZYCCIDJRK-UHFFFAOYSA-N 0.000 description 1
- PJJGZPJJTHBVMX-UHFFFAOYSA-N 5,7-Dihydroxyisoflavone Chemical compound C=1C(O)=CC(O)=C(C2=O)C=1OC=C2C1=CC=CC=C1 PJJGZPJJTHBVMX-UHFFFAOYSA-N 0.000 description 1
- YPPZCRZRQHFRBH-UHFFFAOYSA-N 5-hydroxy-3,4-dihydro-2h-naphthalen-1-one Chemical compound O=C1CCCC2=C1C=CC=C2O YPPZCRZRQHFRBH-UHFFFAOYSA-N 0.000 description 1
- XZLVODVCKMHHRJ-UHFFFAOYSA-N 5-methyl-1,3,5-trinitrocyclohexa-1,3-diene Chemical compound [O-][N+](=O)C1(C)CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 XZLVODVCKMHHRJ-UHFFFAOYSA-N 0.000 description 1
- ZIFGQZOJBWXBNW-UHFFFAOYSA-N 5-methyl-2,4-dinitrophenol Chemical compound CC1=CC(O)=C([N+]([O-])=O)C=C1[N+]([O-])=O ZIFGQZOJBWXBNW-UHFFFAOYSA-N 0.000 description 1
- NQXUSSVLFOBRSE-UHFFFAOYSA-N 5-methyl-2-nitrophenol Chemical compound CC1=CC=C([N+]([O-])=O)C(O)=C1 NQXUSSVLFOBRSE-UHFFFAOYSA-N 0.000 description 1
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 1
- KEOUIRVJRXECRC-UHFFFAOYSA-N 6-[2-(2-butoxyethoxy)ethoxy]-6-oxohexanoic acid Chemical compound CCCCOCCOCCOC(=O)CCCCC(O)=O KEOUIRVJRXECRC-UHFFFAOYSA-N 0.000 description 1
- HBZVNWNSRNTWPS-UHFFFAOYSA-N 6-amino-4-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C(O)C2=CC(N)=CC=C21 HBZVNWNSRNTWPS-UHFFFAOYSA-N 0.000 description 1
- BOFRXDMCQRTGII-UHFFFAOYSA-N 619-08-9 Chemical compound OC1=CC=C([N+]([O-])=O)C=C1Cl BOFRXDMCQRTGII-UHFFFAOYSA-N 0.000 description 1
- ACNSFTVESQFFAE-UHFFFAOYSA-N 7-amino-4-hydroxynaphthalene-2-sulfonic acid;hydrate Chemical compound O.OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 ACNSFTVESQFFAE-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- 229940076442 9,10-anthraquinone Drugs 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 229910015999 BaAl Inorganic materials 0.000 description 1
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 description 1
- BKSKRMYVSPJTBY-UHFFFAOYSA-N C(CCCC)C1=CC=2C(C3=CC=CC=C3C(C2C=C1)=O)=O.C(CCCC)C1=CC=2C(C3=CC=CC=C3C(C2C=C1)=O)=O Chemical compound C(CCCC)C1=CC=2C(C3=CC=CC=C3C(C2C=C1)=O)=O.C(CCCC)C1=CC=2C(C3=CC=CC=C3C(C2C=C1)=O)=O BKSKRMYVSPJTBY-UHFFFAOYSA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 239000011627 DL-alpha-tocopherol Substances 0.000 description 1
- 235000001815 DL-alpha-tocopherol Nutrition 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- ZTJORNVITHUQJA-UHFFFAOYSA-N Heptyl p-hydroxybenzoate Chemical compound CCCCCCCOC(=O)C1=CC=C(O)C=C1 ZTJORNVITHUQJA-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 241001611138 Isma Species 0.000 description 1
- XPJVKCRENWUEJH-UHFFFAOYSA-N Isobutylparaben Chemical compound CC(C)COC(=O)C1=CC=C(O)C=C1 XPJVKCRENWUEJH-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-ONEGZZNKSA-N Isoeugenol Natural products COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 description 1
- CMHMMKSPYOOVGI-UHFFFAOYSA-N Isopropylparaben Chemical compound CC(C)OC(=O)C1=CC=C(O)C=C1 CMHMMKSPYOOVGI-UHFFFAOYSA-N 0.000 description 1
- MURCDOXDAHPNRQ-ZJKZPDEISA-N L-685,458 Chemical compound C([C@@H]([C@H](O)C[C@H](C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC=1C=CC=CC=1)C(N)=O)CC=1C=CC=CC=1)NC(=O)OC(C)(C)C)C1=CC=CC=C1 MURCDOXDAHPNRQ-ZJKZPDEISA-N 0.000 description 1
- 229910005317 Li14Zn(GeO4)4 Inorganic materials 0.000 description 1
- 229910008906 Li2OV2O5—SiO2 Inorganic materials 0.000 description 1
- 229910011458 Li4/3 Ti5/3O4 Inorganic materials 0.000 description 1
- 229910011783 Li4GeS4—Li3PS4 Inorganic materials 0.000 description 1
- 229910012820 LiCoO Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 1
- 229910012305 LiPON Inorganic materials 0.000 description 1
- 229910012573 LiSiO Inorganic materials 0.000 description 1
- 229910012465 LiTi Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- 240000009023 Myrrhis odorata Species 0.000 description 1
- 235000007265 Myrrhis odorata Nutrition 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- WRUZLCLJULHLEY-UHFFFAOYSA-N N-(p-hydroxyphenyl)glycine Chemical compound OC(=O)CNC1=CC=C(O)C=C1 WRUZLCLJULHLEY-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910003870 O—Li Inorganic materials 0.000 description 1
- QUGWHPCSEHRAFA-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Ge+2].[Li+] Chemical compound P(=O)([O-])([O-])[O-].[Ge+2].[Li+] QUGWHPCSEHRAFA-UHFFFAOYSA-K 0.000 description 1
- YFYTYOSYQUYIJL-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Si+4].[Li+] Chemical compound P(=O)([O-])([O-])[O-].[Si+4].[Li+] YFYTYOSYQUYIJL-UHFFFAOYSA-K 0.000 description 1
- MKGYHFFYERNDHK-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Ti+4].[Li+] Chemical compound P(=O)([O-])([O-])[O-].[Ti+4].[Li+] MKGYHFFYERNDHK-UHFFFAOYSA-K 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- 235000012550 Pimpinella anisum Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- SKZKKFZAGNVIMN-UHFFFAOYSA-N Salicilamide Chemical compound NC(=O)C1=CC=CC=C1O SKZKKFZAGNVIMN-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910020346 SiS 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910003668 SrAl Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 1
- UATJOMSPNYCXIX-UHFFFAOYSA-N Trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UATJOMSPNYCXIX-UHFFFAOYSA-N 0.000 description 1
- JYSSGQITKNFRQE-UHFFFAOYSA-N [3-(4-anilinoanilino)-2-hydroxypropyl] 2-methylprop-2-enoate Chemical compound C1=CC(NCC(O)COC(=O)C(=C)C)=CC=C1NC1=CC=CC=C1 JYSSGQITKNFRQE-UHFFFAOYSA-N 0.000 description 1
- QBYHSJRFOXINMH-UHFFFAOYSA-N [Co].[Sr].[La] Chemical compound [Co].[Sr].[La] QBYHSJRFOXINMH-UHFFFAOYSA-N 0.000 description 1
- DTTKJBBSHUXGLS-UHFFFAOYSA-N [Li+].[O-2].[Zn+2] Chemical class [Li+].[O-2].[Zn+2] DTTKJBBSHUXGLS-UHFFFAOYSA-N 0.000 description 1
- NBGYOHGMMFXVKN-UHFFFAOYSA-N [Li].[Hf] Chemical compound [Li].[Hf] NBGYOHGMMFXVKN-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- LFZYLAXEYRJERI-UHFFFAOYSA-N [Li].[Zr] Chemical compound [Li].[Zr] LFZYLAXEYRJERI-UHFFFAOYSA-N 0.000 description 1
- SXSVTGQIXJXKJR-UHFFFAOYSA-N [Mg].[Ti] Chemical compound [Mg].[Ti] SXSVTGQIXJXKJR-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- ZUSQJEHVTIBRNR-UHFFFAOYSA-N aluminum;lithium;oxygen(2-) Chemical class [Li+].[O-2].[O-2].[Al+3] ZUSQJEHVTIBRNR-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960000271 arbutin Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- FRAODYKUTZKECF-UHFFFAOYSA-N azanium;4-nitrobenzoate;dihydrate Chemical compound [NH4+].O.O.[O-]C(=O)C1=CC=C([N+]([O-])=O)C=C1 FRAODYKUTZKECF-UHFFFAOYSA-N 0.000 description 1
- 229910021523 barium zirconate Inorganic materials 0.000 description 1
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 description 1
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical class C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229950011260 betanaphthol Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000001191 butyl (2R)-2-hydroxypropanoate Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 1
- HNQGTZYKXIXXST-UHFFFAOYSA-N calcium;dioxido(oxo)tin Chemical compound [Ca+2].[O-][Sn]([O-])=O HNQGTZYKXIXXST-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- CKFRRHLHAJZIIN-UHFFFAOYSA-N cobalt lithium Chemical compound [Li].[Co] CKFRRHLHAJZIIN-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000012691 depolymerization reaction Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- AQIXEPGDORPWBJ-UHFFFAOYSA-N diethyl carbinol Natural products CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- KSHJAFFDLKPUMT-UHFFFAOYSA-N dinitro-ortho-cresol Chemical compound CC1=C(O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O KSHJAFFDLKPUMT-UHFFFAOYSA-N 0.000 description 1
- VMMLSJNPNVTYMN-UHFFFAOYSA-N dinitromethylbenzene Chemical class [O-][N+](=O)C([N+]([O-])=O)C1=CC=CC=C1 VMMLSJNPNVTYMN-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000007919 dispersible tablet Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- 239000002003 electrode paste Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 1
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 235000019251 heptyl p-hydroxybenzoate Nutrition 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910002075 lanthanum strontium manganite Inorganic materials 0.000 description 1
- 239000005355 lead glass Substances 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 1
- RSNHXDVSISOZOB-UHFFFAOYSA-N lithium nickel Chemical compound [Li].[Ni] RSNHXDVSISOZOB-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical class [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
- DMEJJWCBIYKVSB-UHFFFAOYSA-N lithium vanadium Chemical compound [Li].[V] DMEJJWCBIYKVSB-UHFFFAOYSA-N 0.000 description 1
- PSVBHJWAIYBPRO-UHFFFAOYSA-N lithium;niobium(5+);oxygen(2-) Chemical class [Li+].[O-2].[O-2].[O-2].[Nb+5] PSVBHJWAIYBPRO-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229960003464 mefenamic acid Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 229960000990 monobenzone Drugs 0.000 description 1
- BMLIZLVNXIYGCK-UHFFFAOYSA-N monuron Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C=C1 BMLIZLVNXIYGCK-UHFFFAOYSA-N 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- ZQUVDXMUKIVNOW-UHFFFAOYSA-N n,n'-diphenylmethanimidamide Chemical compound C=1C=CC=CC=1NC=NC1=CC=CC=C1 ZQUVDXMUKIVNOW-UHFFFAOYSA-N 0.000 description 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 1
- PJFIAKRRJLGWMD-UHFFFAOYSA-N n-(2,5-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC=C(OC)C(NC(=O)CC(C)=O)=C1 PJFIAKRRJLGWMD-UHFFFAOYSA-N 0.000 description 1
- KYYRTDXOHQYZPO-UHFFFAOYSA-N n-(2-methoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC=CC=C1NC(=O)CC(C)=O KYYRTDXOHQYZPO-UHFFFAOYSA-N 0.000 description 1
- NPWGYMSYFSODBM-UHFFFAOYSA-N n-acetyl-n-(2-methoxyphenyl)acetamide Chemical compound COC1=CC=CC=C1N(C(C)=O)C(C)=O NPWGYMSYFSODBM-UHFFFAOYSA-N 0.000 description 1
- DQNSOAZBRJBCHT-UHFFFAOYSA-N n-acetyl-n-(2-methylphenyl)acetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=CC=C1C DQNSOAZBRJBCHT-UHFFFAOYSA-N 0.000 description 1
- UJPCOKISUIXFFR-UHFFFAOYSA-N n-acetyl-n-(4-methylphenyl)acetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=C(C)C=C1 UJPCOKISUIXFFR-UHFFFAOYSA-N 0.000 description 1
- PCILLCXFKWDRMK-UHFFFAOYSA-N naphthalene-1,4-diol Chemical compound C1=CC=C2C(O)=CC=C(O)C2=C1 PCILLCXFKWDRMK-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- VOPSYYWDGDGSQS-UHFFFAOYSA-N neodymium(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Nd+3].[Nd+3] VOPSYYWDGDGSQS-UHFFFAOYSA-N 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- VLZLOWPYUQHHCG-UHFFFAOYSA-N nitromethylbenzene Chemical class [O-][N+](=O)CC1=CC=CC=C1 VLZLOWPYUQHHCG-UHFFFAOYSA-N 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- HCZKYJDFEPMADG-UHFFFAOYSA-N nordihydroguaiaretic acid Chemical compound C=1C=C(O)C(O)=CC=1CC(C)C(C)CC1=CC=C(O)C(O)=C1 HCZKYJDFEPMADG-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- VMPITZXILSNTON-UHFFFAOYSA-N o-anisidine Chemical compound COC1=CC=CC=C1N VMPITZXILSNTON-UHFFFAOYSA-N 0.000 description 1
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical class CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- JJVNINGBHGBWJH-UHFFFAOYSA-N ortho-vanillin Chemical compound COC1=CC=CC(C=O)=C1O JJVNINGBHGBWJH-UHFFFAOYSA-N 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 description 1
- BJRNKVDFDLYUGJ-UHFFFAOYSA-N p-hydroxyphenyl beta-D-alloside Natural products OC1C(O)C(O)C(CO)OC1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-UHFFFAOYSA-N 0.000 description 1
- KGCNHWXDPDPSBV-UHFFFAOYSA-N p-nitrobenzyl chloride Chemical compound [O-][N+](=O)C1=CC=C(CCl)C=C1 KGCNHWXDPDPSBV-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- RVBALJJVDRFLAA-UHFFFAOYSA-N phenol;terephthalic acid Chemical compound OC1=CC=CC=C1.OC(=O)C1=CC=C(C(O)=O)C=C1 RVBALJJVDRFLAA-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical class OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001281 polyalkylene Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical group OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 229960000581 salicylamide Drugs 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N salicylic acid benzyl ester Natural products OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QKHROXOPRBWBDD-UHFFFAOYSA-N tribromometacresol Chemical compound CC1=C(Br)C=C(Br)C(O)=C1Br QKHROXOPRBWBDD-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C08K5/08—Quinones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Catalysts (AREA)
Abstract
本發明之目的在於提供一種於低溫下具有優異之分解性,並且能夠於短時間內脫脂之無機微粒子分散用載體組成物、含有該無機微粒子分散用載體組成物之無機微粒子分散漿料組成物、及使用該無機微粒子分散漿料組成物之無機微粒子分散片之製造方法。
本發明之無機微粒子分散用載體組成物含有黏合劑樹脂、有機溶劑、及於常壓下沸點為200℃以上未達400℃之有機化合物,上述黏合劑樹脂含有(甲基)丙烯酸樹脂,上述有機化合物含有選自酚化合物、芳香族胺化合物、醌化合物及硝基化合物中之至少1種,上述有機化合物之含量相對於上述黏合劑樹脂100重量份為1~100重量份。
Description
本發明係關於一種於低溫下具有優異之分解性,並且能夠於短時間內脫脂之無機微粒子分散用載體組成物、含有該無機微粒子分散用載體組成物之無機微粒子分散漿料組成物、及使用該無機微粒子分散漿料組成物之無機微粒子分散片之製造方法。
近年來,使陶瓷粉末、玻璃粒子等無機微粒子分散於黏合劑樹脂所得之組成物被用於積層陶瓷電容器等積層電子零件之生產。
此種積層陶瓷電容器通常使用如下所述之方法進行製造。首先,向使黏合劑樹脂溶解於有機溶劑所得之溶液中添加塑化劑、分散劑等添加劑,其後,加入陶瓷原料粉末,使用球磨機等均勻地混合,獲得無機微粒子分散組成物。
使用刮刀、逆輥塗佈機等,使所獲得之無機微粒子分散組成物於經脫模處理之聚對苯二甲酸乙二酯膜、SUS平板等支持體表面流延成形,蒸餾去除有機溶劑等揮發成分後,自支持體剝離而獲得陶瓷坯片(ceramic green sheet)。
其次,藉由網版印刷等,於所獲得之陶瓷坯片上塗敷成為內部電極之導電膏,將其堆積複數層,進行加熱及壓接而獲得積層體。進行對所獲得之積層體進行加熱而使黏合劑樹脂等成分熱分解從而去除之處理、即所謂脫脂處理後,對其進行煅燒,藉此獲得具備內部電極之陶瓷煅燒體。進而,藉由在所獲得之陶瓷煅燒體之端面塗佈外部電極,並進行煅燒,而完成積層陶瓷電容器。
煅燒步驟成為煅燒體之鼓出或破裂等問題之原因之情形居多,因此黏合劑樹脂之脫脂較理想為藉由低溫於短時間內進行。因此,研究使用能夠進行低溫煅燒,且煅燒後之殘留碳成分較少之黏合劑樹脂。
例如,於專利文獻1中,為了將脫脂溫度抑制為230℃至350℃之相對低溫,而研究使用石蠟或聚乙二醇。又,於專利文獻2中,研究藉由使用平均分子量為2.0×105
以上、酸值為2.4~7.2、玻璃轉移溫度為50~90℃之丙烯酸樹脂作為黏合劑樹脂,而提高黏合劑樹脂之去除性。
先前技術文獻
專利文獻
專利文獻1:日本專利第6187810號公報
專利文獻2:日本特開2007-073977號公報
發明所欲解決之課題
然而,於專利文獻1中,為了製作薄膜之陶瓷坯片,存在黏合劑樹脂本身之強度不充分之問題。又,於專利文獻2中記載之方法中,雖然低溫脫脂成為可能,但脫脂時間極長,又,於用於大型陶瓷成形品之情形時,內部之脫脂仍有改善之餘地。
本發明鑒於上述課題,其目的在於提供一種於低溫下具有優異之分解性,並且能夠於短時間內脫脂之無機微粒子分散用載體組成物、含有該無機微粒子分散用載體組成物之無機微粒子分散漿料組成物、及使用該無機微粒子分散漿料組成物之無機微粒子分散片之製造方法。
解決課題之技術手段
本發明係一種無機微粒子分散用載體組成物,其含有黏合劑樹脂、有機溶劑及於常壓下沸點為200℃以上未達400℃之有機化合物,上述黏合劑樹脂含有(甲基)丙烯酸樹脂,上述有機化合物含有選自酚化合物、芳香族胺化合物、醌化合物及硝基化合物中之至少1種,上述有機化合物之含量相對於上述黏合劑樹脂100重量份為1~100重量份。
以下,對本發明進行詳述。
本發明人等發現,(甲基)丙烯酸樹脂之脫脂時間變長之原因係因(甲基)丙烯酸樹脂之熱分解按照以下之機制進行所致。即,於(甲基)丙烯酸樹脂之熱分解中,因煅燒環境溫度成為(甲基)丙烯酸樹脂之最高溫度以上而發生解聚反應,但於此種反應中,被分解之單體之一部分進而藉由熱進行氧化燃燒,分解成更小分子量之成分。此時,大部分被分解之單體藉由煅燒熱再聚合成聚合物。於此種機制中,經熱分解之絕大多數聚合物成分再次聚合物化,因此成為用以使(甲基)丙烯酸樹脂分解之表觀分解速度變慢,脫脂需要較長時間之原因。
因此,本發明人等進行了潛心研究,結果發現,藉由向(甲基)丙烯酸樹脂中添加特定之有機化合物,可提高表觀分解速度,能夠於低溫下在短時間內脫脂。又發現,藉由將含有包含此種特定有機化合物之無機微粒子分散用載體組成物之無機微粒子分散漿料組成物用於陶瓷坯片之製造,可有效地防止於去除黏合劑樹脂時產生之片材之鼓出或破損,從而完成了本發明。
作為本發明之一實施態樣之無機微粒子分散用載體組成物含有包含(甲基)丙烯酸樹脂之黏合劑樹脂。
上述(甲基)丙烯酸樹脂並無特別限定,較佳為含有源自酯取代基之碳數為8以下之(甲基)丙烯酸酯之鏈段。
再者,上述酯取代基之碳數為8以下係表示(甲基)丙烯酸酯之除構成(甲基)丙烯醯基之碳以外之碳數之合計為8以下。又,本說明書中,上述酯取代基之碳數為8以下之(甲基)丙烯酸酯係指除下述具有環氧丙基之(甲基)丙烯酸酯以外者。
作為上述酯取代基之碳數為8以下之(甲基)丙烯酸酯,可列舉具有直鏈狀、支鏈狀或環狀之烷基之(甲基)丙烯酸酯。
作為上述具有直鏈狀烷基之(甲基)丙烯酸酯,例如可列舉:(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丙酯、(甲基)丙烯酸正丁酯等。
作為上述具有支鏈狀烷基之(甲基)丙烯酸酯,例如可列舉:(甲基)丙烯酸第三丁酯、(甲基)丙烯酸異丁酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸苄酯等(甲基)丙烯酸烷基酯。
作為上述具有環狀烷基之(甲基)丙烯酸酯,例如可列舉(甲基)丙烯酸環己酯等。
又,作為上述酯取代基之碳數為8以下之(甲基)丙烯酸酯,亦可使用(甲基)丙烯酸2-羥基乙酯、(甲基)丙烯酸羥基丙酯、(甲基)丙烯酸羥基丁酯、(甲基)丙烯酸等具有羥基或羧基之(甲基)丙烯酸酯等。
其中,就於低溫下可迅速脫脂之方面而言,較佳為具有源自具有直鏈狀烷基之(甲基)丙烯酸酯或具有支鏈狀烷基之(甲基)丙烯酸酯之鏈段,更佳為具有源自甲基丙烯酸甲酯、甲基丙烯酸正丁酯、甲基丙烯酸異丁酯或甲基丙烯酸2-乙基己酯之鏈段。又,作為上述酯取代基之碳數為8以下之(甲基)丙烯酸酯,較佳為具有直鏈狀烷基之(甲基)丙烯酸酯及具有支鏈狀烷基之(甲基)丙烯酸酯之組合。
作為上述酯取代基之碳數為8以下之(甲基)丙烯酸酯,可使用酯取代基之碳數為1~4之(甲基)丙烯酸酯,亦可使用酯取代基之碳數為5~8之(甲基)丙烯酸酯。其中,就低溫分解性之觀點而言,較佳為組合使用酯取代基之碳數為1~4之(甲基)丙烯酸酯及酯取代基之碳數為5~8之(甲基)丙烯酸酯。
關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為8以下之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為40重量%,更佳之下限為50重量%,進而較佳之下限為55重量%,進而更佳之下限為60重量%,較佳之上限為100重量%,更佳之上限為95重量%。
若為上述較佳之下限以上且上述較佳之上限以下,則可提高黏合劑樹脂之低溫分解性,並且可對所獲得之陶瓷坯片賦予優異之強韌性。
關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為1~4之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為30重量%,更佳之下限為35重量%,較佳之上限為100重量%,更佳之上限為95重量%,進而較佳之上限為90重量%,進而更佳之上限為84重量%,尤佳之上限為82重量%。
於本發明之較佳之實施態樣中,關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為1~2之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為20重量%,更佳之下限為30重量%,較佳之上限為70重量%,更佳之上限為60重量%。
於本發明之較佳之實施態樣中,關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為3~4之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為0重量%,更佳之下限為15重量%,較佳之上限為80重量%,更佳之上限為70重量%。
關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為5~8之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為0重量%,更佳之下限為5重量%,進而較佳之下限為15重量%,進而更佳之下限為18重量%,較佳之上限為70重量%,更佳之上限為65重量%,進而較佳之上限為60重量%。
關於上述(甲基)丙烯酸樹脂中之源自上述甲基丙烯酸異丁酯之鏈段之含量,就低溫分解性之觀點而言,較佳之下限為30重量%,更佳之下限為40重量%,較佳之上限為60重量%,更佳之上限為50重量%。
上述(甲基)丙烯酸樹脂亦可具有源自酯取代基之碳數為9以上之(甲基)丙烯酸酯之鏈段。
藉由具有上述源自酯取代基之碳數為9以上之(甲基)丙烯酸酯之鏈段,可充分降低(甲基)丙烯酸樹脂之分解結束溫度,並且可使所獲得之無機微粒子分散片變得強韌。
就低溫分解性之觀點而言,上述酯取代基之碳數為9以上之(甲基)丙烯酸酯較佳為上述酯取代基具有支鏈結構。
上述酯取代基之碳數之較佳之上限為30,更佳之上限為20,進而較佳之上限為10。
作為上述酯取代基之碳數為9以上之(甲基)丙烯酸酯,可列舉具有直鏈狀或支鏈狀之碳數為9以上之烷基之(甲基)丙烯酸酯、聚伸烷基二醇(甲基)丙烯酸酯等。
作為上述具有直鏈狀或支鏈狀之烷基之(甲基)丙烯酸酯,例如可列舉:(甲基)丙烯酸正壬酯、(甲基)丙烯酸異壬酯、(甲基)丙烯酸正癸酯、(甲基)丙烯酸異癸酯、(甲基)丙烯酸正月桂酯、(甲基)丙烯酸異月桂酯、(甲基)丙烯酸正硬脂酯、(甲基)丙烯酸異硬脂酯等。
其中,較佳為具有支鏈狀之碳數為9以上之烷基之(甲基)丙烯酸酯,更佳為(甲基)丙烯酸異壬酯、(甲基)丙烯酸異癸酯、(甲基)丙烯酸異硬脂酯。上述甲基丙烯酸異癸酯與其他甲基丙烯酸長鏈烷基酯相比,分解性尤其優異。
作為上述聚伸烷基二醇(甲基)丙烯酸酯,可列舉具有乙二醇單位(氧乙烯單位)、丙二醇單位(氧丙烯單位)、丁二醇單位(氧丁烯單位)等者。
又,上述聚伸烷基二醇(甲基)丙烯酸酯可為末端具有烷氧基者,亦可為末端具有乙基己基者。
作為上述烷氧基,例如可列舉:甲氧基、乙氧基、丁氧基等。上述烷氧基可為直鏈狀,亦可為支鏈狀,較佳為支鏈狀。
又,上述聚伸烷基二醇(甲基)丙烯酸酯較佳為具有支鏈型之伸烷基二醇結構。
其中,較佳為具有乙二醇單位、丙二醇單位及丁二醇單位中之至少1種之聚伸烷基二醇(甲基)丙烯酸酯。又,進而較佳為聚乙二醇甲基丙烯酸酯、乙氧基聚丙二醇甲基丙烯酸酯、甲氧基聚丙二醇甲基丙烯酸酯、聚丁二醇甲基丙烯酸酯、聚丙二醇-聚丁二醇甲基丙烯酸酯。
甲氧基聚丙二醇甲基丙烯酸酯、聚丙二醇甲基丙烯酸酯、聚丁二醇甲基丙烯酸酯、丙二醇-聚丁二醇甲基丙烯酸酯與其他伸烷基二醇(甲基)丙烯酸酯相比,煅燒殘渣較少,低溫分解性尤其優異。
關於上述(甲基)丙烯酸樹脂中之源自上述酯取代基之碳數為9以上之(甲基)丙烯酸酯之鏈段的含量,就低溫分解性之觀點而言,較佳之下限為5重量%,更佳之下限為10重量%,較佳之上限為40重量%,更佳之上限為30重量%。
上述(甲基)丙烯酸樹脂具有源自具有環氧丙基之(甲基)丙烯酸酯之鏈段。
藉由具有上述源自具有環氧丙基之(甲基)丙烯酸酯之鏈段,可充分提高所獲得之積層體之強度。
作為上述具有環氧丙基之(甲基)丙烯酸酯,可列舉:(甲基)丙烯酸環氧丙酯、(甲基)丙烯酸4-羥基丁酯環氧丙基醚、(甲基)丙烯酸3,4-環氧環己基甲酯等。
上述(甲基)丙烯酸樹脂中之上述源自具有環氧丙基之(甲基)丙烯酸酯之鏈段的含量之下限為1重量%,上限為10重量%。
若上述源自具有環氧丙基之(甲基)丙烯酸酯之鏈段之含量為1重量%以上,則可改善所獲得之無機微粒子分散片之耐溶劑性。若上述源自具有環氧丙基之(甲基)丙烯酸酯之鏈段之含量為10重量%以下,則可充分提高(甲基)丙烯酸樹脂之低溫分解性。
上述具有環氧丙基之(甲基)丙烯酸酯之含量之較佳之下限為2重量%,較佳之上限為7重量%。
作為本發明之一實施態樣之無機微粒子分散用載體組成物中之上述(甲基)丙烯酸樹脂之含量並無特別限定,較佳之下限為5重量%,較佳之上限為80重量%。
藉由將上述(甲基)丙烯酸樹脂之含量設為上述範圍內,即便於低溫下進行煅燒,亦可獲得能夠脫脂之無機微粒子分散漿料組成物。
關於上述(甲基)丙烯酸樹脂之含量,更佳之下限為6重量%,更佳之下限為15重量%,進而較佳之下限為30重量%,更佳之上限為78重量%。
上述(甲基)丙烯酸樹脂之藉由聚苯乙烯換算之重量平均分子量之較佳之下限為10萬,較佳之上限為300萬。藉由將上述重量平均分子量設為10萬以上,無機微粒子分散用載體組成物具有充分之黏度,藉由將上述重量平均分子量設為300萬以下,能夠提高印刷性。
上述重量平均分子量之更佳之下限為20萬,更佳之上限為150萬。
尤其若上述(甲基)丙烯酸樹脂之藉由聚苯乙烯換算之重量平均分子量為20萬~150萬,則藉由使用下述有機溶劑,可以少量之樹脂確保充分之黏度,且獲得拉絲較少之無機微粒子分散漿料,故較佳。
又,重量平均分子量(Mw)與數量平均分子量(Mn)之比(Mw/Mn)較佳為2以上8以下。
藉由設為此種範圍內,由於適度地含有低聚合度之成分,因此無機微粒子分散用載體組成物之黏度為較佳之範圍,可提高生產性。又,可使所獲得之無機微粒子分散片之片材強度適度。
又,若上述Mw/Mn未達2,則存在坯片之塗敷時之調平性較差,坯片之平滑性劣化之情形。若Mw/Mn大於8,則高分子量成分變多,因此存在坯片之乾燥性較差,表面平滑性劣化之情形。
上述Mw/Mn更佳為3以上8以下。
再者,藉由聚苯乙烯換算之重量平均分子量、數量平均分子量可藉由例如使用Column LF-804(昭和電工公司製造)作為管柱進行GPC測定而獲得。
上述(甲基)丙烯酸樹脂之玻璃轉移溫度(Tg)更佳為30℃以上未達60℃。
藉由上述玻璃轉移溫度為上述範圍內,可減少塑化劑之添加量,可提高上述(甲基)丙烯酸樹脂所具有之低溫分解性。
再者,上述Tg例如可使用示差掃描熱量計(DSC)等進行測定。
關於上述玻璃轉移溫度,更佳之下限為35℃,進而較佳之下限為40℃,更佳之上限為60℃。
上述(甲基)丙烯酸樹脂之自30℃以5℃/min進行加熱之情形時之達到90重量%分解所需之時間(以下亦稱為「90重量%分解時間」)之較佳之上限為50分鐘。
藉此,能夠實現極高之低溫分解性,且縮短脫脂所需之時間。
再者,上述90重量%分解時間例如可使用TGDTA等進行測定。
製造上述(甲基)丙烯酸樹脂之方法並無特別限定。例如可列舉如下方法:向含有(甲基)丙烯酸酯等之原料單體混合物中加入有機溶劑等而製備單體混合液。進而,向所獲得之單體混合液中添加聚合起始劑,使上述原料單體共聚。
聚合方法並無特別限定,可列舉:乳化聚合、懸浮聚合、塊狀聚合、界面聚合、溶液聚合等。其中,較佳為溶液聚合。
作為上述聚合起始劑,例如可列舉:氫過氧化對薄荷烷、氫過氧化二異丙苯、氫過氧化1,1,3,3-四甲基丁基、氫過氧化異丙苯、氫過氧化第三丁基、過氧化環己酮、過氧化二琥珀酸等。
作為該等之市售品,例如可列舉:PERMENTA H、Percumyl P、PEROCTA H、Percumyl H-80、PERBUTYL H-69、Perhexa H、PEROYL SA(皆為日油公司製造)等。
作為本發明之一實施態樣之無機微粒子分散用載體組成物含有有機溶劑。
上述有機溶劑並無特別限定,較佳為於製作無機微粒子分散片時,塗敷性、乾燥性、無機粉末之分散性等優異者,例如更佳為沸點未達200℃。作為上述有機溶劑,例如可列舉:醇類、酮類、乙酸酯類、羧酸酯類、芳香族烴類、萜烯類等。於本發明之較佳之實施態樣中,作為有機溶劑,更佳為醇類、乙酸酯類、羧酸酯類及萜烯類。
具體而言,例如可列舉:乙醇、甲苯、乙酸乙酯、乙酸丁酯、異丙醇、甲基異丁基酮、甲基乙基酮、乙二醇乙醚、乙二醇單丁醚、乙二醇單乙醚乙酸酯、二乙二醇單乙醚、二乙二醇單甲醚、二乙二醇單異丁醚、三甲基戊二醇單異丁酸酯、丁基卡必醇、丁基卡必醇乙酸酯、萜品醇、萜品醇乙酸酯、二氫萜品醇、二氫萜品醇乙酸酯、2,2,4-三甲基-1,3-戊二醇單異丁酸酯(TEXANOL)、異佛爾酮、乳酸丁酯、鄰苯二甲酸二辛酯、己二酸二辛酯、苄醇、苯基丙二醇等。其中,較佳為乙醇、甲苯、乙酸乙酯、乙酸丁酯、甲基乙基酮、萜品醇、萜品醇乙酸酯、二氫萜品醇、二氫萜品醇乙酸酯、二乙二醇單乙醚、二乙二醇單甲醚、二乙二醇單異丁醚、丁基卡必醇、丁基卡必醇乙酸酯、2,2,4-三甲基-1,3-戊二醇單異丁酸酯(TEXANOL)。又,更佳為乙醇、甲苯、乙酸乙酯、乙酸丁酯、甲基乙基酮、萜品醇、萜品醇乙酸酯、二氫萜品醇、二氫萜品醇乙酸酯、2,2,4-三甲基-1,3-戊二醇單異丁酸酯(TEXANOL)。再者,該等有機溶劑可單獨使用,亦可併用2種以上。
作為本發明之一實施態樣之無機微粒子分散用載體組成物中之上述有機溶劑之含量並無特別限定,較佳之下限為10重量%,較佳之上限為80重量%,更佳之上限為60重量%,進而較佳之上限為50重量%,進而更佳之上限為40重量%。藉由設為上述範圍內,可提高塗敷性、無機微粒子之分散性。
作為本發明之一實施態樣之無機微粒子分散用載體組成物含有於常壓下之沸點為200℃以上、較佳為210℃以上、更佳為220℃以上、進而較佳為230℃以上、進而更佳為240℃以上、尤佳為250℃以上、未達400℃、較佳為380℃以下、更佳為350℃以下、進而較佳為330℃以下、尤佳為300℃以下之有機化合物。
上述有機化合物含有選自由酚化合物、芳香族胺化合物、醌化合物及硝基化合物所組成之群中之至少1種。
藉由含有上述有機化合物,可於黏合劑樹脂脫脂時抑制單體氣體之再聚合,能夠迅速脫脂。再者,有機化合物係不同於有機溶劑之化合物。上述有機化合物較理想為於常溫常壓下為固體。
作為上述酚化合物,例如可列舉:烷酚類、烷氧基酚類、甲醯基酚類、羥基酚類、乙醯基酚類、硝基酚類等。
作為上述烷酚類,例如可列舉:3-甲基苯酚(間甲酚,沸點:203℃)、2-異丙基-6-甲基苯酚(沸點:225℃)、4-異丙基-3-甲基苯酚(沸點:246℃)、4-異丙基-2-甲基苯酚(沸點:236℃)、2-甲氧基-4-甲基苯酚(沸點:221℃)、2-碘-4-甲基苯酚(沸點:241℃)、2,4,6-三溴-3-甲基苯酚(沸點:304℃)、2,3,5,6-四甲基苯酚(沸點:247℃)、五甲基苯酚(沸點:248℃)、4-甲基苯酚(對甲酚,沸點:202℃)、2,6-二第三丁基-4-甲基苯酚(2,6-二第三丁基對甲酚,沸點:265℃)、2,3-二甲基苯酚(2,3-二甲苯酚,沸點:217℃)、2,4-二甲基苯酚(2,4-二甲苯酚,沸點:211℃)、2,5-二甲基苯酚(2,5-二甲苯酚,沸點:212℃)、2,6-二甲基苯酚(2,6-二甲苯酚,沸點:203℃)、3,4-二甲基苯酚(3,4-二甲苯酚,沸點:227℃)、3,5-二甲基苯酚(3,5-二甲苯酚,沸點:222℃)、6-第三丁基-2,4-二甲基苯酚(6-第三丁基-2,4-二甲苯酚,沸點:249℃)等甲基苯酚類;2-辛基苯酚(沸點:305℃)、4-辛基苯酚(沸點:276℃)、2,6-二第三丁基苯酚(沸點:253℃)、6-異丙基-3-甲基苯酚(沸點:232℃)、2-異丙基-3-甲基苯酚(沸點:228℃)、3-異丙基-5-甲基苯酚(沸點:241℃)、2,6-二溴-4-甲基苯酚、2,6-二第三丁基-4-甲氧基苯酚、4-乙基苯酚(沸點:218℃)、2-羥基-3-甲基苯磺酸、4-羥基-3-甲基苯磺酸、十二烷基苯酚(沸點:310℃)、2,3,5-三甲基苯酚(沸點:230℃)、2,3,6-三甲基苯酚(沸點:215℃)、壬基苯酚(沸點:293℃)、4-第三丁基苯酚(沸點:236℃)、3-(3,5-二第三丁基-4-羥基苯基)丙酸硬脂酯、2,4-雙(辛硫基甲基)-6-甲基苯酚、2,2'-亞甲基雙[6-(1-甲基環己基)-對甲酚]、2,6-二第三丁基-4-乙基苯酚(沸點:272℃)、DL-α-生育酚、D-α-生育酚等。
作為上述烷氧基酚類,例如可列舉:2-甲氧基苯酚(癒創木酚,沸點:205℃)、4-甲氧基苯酚(4-羥基大茴香醚,沸點:243℃)、4-(苄氧基)苯酚(對苄氧基苯酚(Monobenzone),沸點:298℃)、2-第三丁基-4-甲氧基苯酚(3-第三丁基-4-羥基大茴香醚,沸點:264℃)、2-甲氧基-4-乙基苯酚(沸點:235℃)、反式-阿魏酸(沸點:250℃)、3-甲氧基-4-羥基苯丙烯酸(沸點:250℃)、第三丁基羥基大茴香醚(沸點:264℃)、異丁香酚(沸點:266℃)、乙香草醛(沸點:285℃)、丁香酚(沸點:254℃)等。
作為上述甲醯基酚類,例如可列舉:4-甲醯基苯酚(4-羥基苯甲醛,沸點:310℃)、3-甲醯基苯酚(3-羥基苯甲醛,沸點:240℃)、2-甲醯基-4-甲氧基苯酚(2-羥基-5-甲氧基苯甲醛,沸點:250℃)、2-甲醯基-5-甲氧基苯酚(2-羥基-4-甲氧基苯甲醛)、4-甲醯基-2-甲氧基苯酚(香草醛,沸點:285℃)、3-甲醯基-6-甲氧基苯酚(異香草醛)、2-甲醯基-6-甲氧基苯酚(鄰香草醛,沸點:265℃)、4-羥基間苯二甲醛(2,4-二甲醯基苯酚)等。
作為上述羥基酚類,例如可列舉:2-羥基苯酚(鄰苯二酚,沸點:245℃)、4-羥基苯酚(對苯二酚,沸點:285℃)、2-第三丁基-4-羥基苯酚(2-第三丁基對苯二酚,沸點:295℃)、4-第三丁基-2-羥基苯酚(4-第三丁基兒茶酚,沸點:285℃)、間苯二酚(沸點:281℃)、4,4'-(2,3-二甲基四亞甲基)雙兒茶酚(沸點:363℃)、1,4-二羥基萘(沸點:246℃)、2,5-二第三戊基對苯二酚(沸點:353℃)、2,5-二第三丁基對苯二酚(沸點:321℃)、三甲基對苯二酚(沸點:295℃)、甲基對苯二酚(沸點:285℃)等苯二酚類;苯-1,2,3-三酚(鄰苯三酚,沸點:309℃)、鄰苯三酚-4-羧酸(2,3,4-三羥基苯甲酸,沸點:259℃)、沒食子酸丙酯(3,4,5-三羥基苯甲酸丙酯,沸點:312℃)、1,3,5-三羥基苯、2,3,4-三羥基二苯甲酮、沒食子酸十二烷基酯(沸點:394℃)、夫洛丙酮(沸點:275℃)等苯三酚類。
作為上述乙醯基酚類,例如可列舉:4-乙醯基苯酚(4-羥基苯乙酮)2-乙醯基苯酚(2-羥基苯乙酮,沸點:218℃)等。
作為上述硝基酚類,例如可列舉:2-硝基苯酚(沸點:216℃)、3-硝基苯酚(沸點:252℃)、4-硝基苯酚(沸點:279℃)、5-氟-2-硝基苯酚(沸點:260℃)、2,6-二甲基-4-硝基苯酚(沸點:285℃)、2-甲氧基-4-硝基苯酚(沸點:298℃)、5-甲基-2-硝基苯酚(沸點:266℃)、2-氯-4-硝基苯酚等硝基酚化合物;2,3-二硝基苯酚(沸點:329℃)、3,5-二硝基苯酚(沸點:318℃)、3,4-二硝基苯酚(沸點:318℃)、5-甲基-2,4-二硝基苯酚(沸點:335℃)、2-甲基-3,5-二硝基苯酚(沸點:335℃)、4-甲基-3,5-二硝基苯酚(沸點:335℃)、2,4-二硝基苯酚(沸點:318℃)、2,4-二硝基-6-甲基苯酚、2,6-二硝基-4-甲基苯酚(沸點:335℃)等二硝基酚化合物;2,4,6-三硝基苯酚(沸點:300℃)等三硝基酚化合物等。
作為除上述烷酚類、烷氧基酚類、甲醯基酚類、羥基酚類、乙醯基酚類、硝基酚類以外之酚化合物,可列舉:2-(4-羥基苯基)乙醇、3-羥基-2-萘甲酸(沸點:283℃)、4-羥基苯甲酸甲酯(沸點:299℃)、4-羥基苯甲酸正庚酯(沸點:338℃)、水楊酸異戊酯(沸點:277℃)、水楊酸甲酯(沸點:222℃)、4-羥基苯甲酸異丁酯、4-羥基苯甲酸異丙酯、4-羥基苯甲酸乙酯(沸點:297℃)、4-羥基苯甲酸丁酯、4-羥基苯甲酸丙酯、4-羥基苯甲酸(沸點:213℃)、6-羥基-2-萘甲酸(沸點:283℃)、4-氯酚(沸點:220℃)、4-羥基苯基乙酸(沸點:234℃)、雙(4-羥基苯基)碸(沸點:363℃)、對苯酚磺酸水合物(沸點:275℃)、1-萘酚(沸點:278℃)、2-萘酚(沸點:285℃)、4-甲氧基-1-萘酚(沸點:265℃)、(R)-(+)-1,1'-聯-2-萘酚(沸點:388℃)、(S)-(-)-1,1'-聯-2-萘酚(沸點:388℃)、2,2-雙(4-羥基苯基)丙烷、4-氰基-4'-羥基聯苯(沸點:332℃)、4-(4-羥基苯基)苯甲酸(沸點:314℃)、4,4'-聯苯酚(沸點:280℃)、2-苯基苯酚(沸點:282℃)、4-苯基苯酚(沸點:321℃)、5-羥基-1-四氫萘酮(沸點:228℃)、4-苯氧基苯酚、4,4'-(二甲基亞甲基)雙[2-(2-丙烯基)苯酚]、4-(2-甲氧基乙基)苯酚、2,2-雙(4-羥基苯基)六氟丙烷(沸點:400℃)、苯乙烯化苯酚(沸點:250℃)、1,1-雙(4-羥基苯基)環己烷(沸點:371℃)、水楊酸苄酯、水楊醯胺(沸點:270℃)、熊果苷(沸點:375℃)、4-碘苯酚等。
作為上述芳香族胺化合物,可列舉苯胺衍生物等。
作為上述苯胺衍生物,例如可列舉:2,3-二甲基苯胺(2,3-茬胺,沸點:221℃)、2,4-二甲基苯胺(2,4-茬胺,沸點:218℃)、2,5-二甲基苯胺(2,5-茬胺,沸點:218℃)、2,6-二甲基苯胺(2,6-茬胺,沸點:216℃)、3,4-二甲基苯胺(3,4-茬胺,沸點:226℃)、3,5-二甲基苯胺(3,5-茬胺,沸點:221℃)、乙醯乙醯鄰甲氧基苯胺(o-Acetoacetanisidide)(沸點:346℃)、乙醯苯胺(沸點:304℃)、乙醯乙醯苯胺、2',4'-二甲基乙醯乙醯苯胺(沸點:344℃)、2'-氯乙醯乙醯苯胺(沸點:303℃)、N-(2,5-二甲氧基苯基)(乙醯基)乙醯胺、4'-氯-2',5'-二甲氧基乙醯乙醯苯胺、N-乙醯乙醯基-鄰甲苯胺(沸點:327℃)、N-乙醯乙醯基-對甲苯胺、鄰甲氧苯胺(沸點:225℃)、對甲氧苯胺(沸點:246℃)、4'-胺基乙醯苯胺(沸點:267℃)、4-胺基苯甲酸(沸點:252℃)、4-胺基苯甲酸乙酯、2-胺基苯硫酚、2-胺基苯酚、3-胺基苯酚、4-胺基苯酚(沸點:284℃)、4-胺基苯甲腈、鄰胺苯甲酸(沸點:252℃)、3-異丙氧基苯胺(沸點:230℃)、N-乙基苯胺(沸點:205℃)、5-胺基-2-氯甲苯-4-磺酸、6-胺基-1-萘酚-3-磺酸水合物、3,5-二胺基苯甲酸(沸點:275℃)、3,4'-二胺基二苯醚(沸點:207℃)、4,4'-二胺基二苯醚、2,2'-二甲基聯苯-4,4'-二胺、N,N-二乙基苯胺(沸點:217℃)、二苯胺(沸點:302℃)、N,N'-二苯基甲脒(沸點:323℃)、4,4'-二胺基-3,3'-二甲基二苯甲烷(沸點:358℃)、N,N-二甲基對甲苯胺(沸點:211℃)、磺胺酸、2-胺基-1-萘磺酸(沸點:220℃)、2,4,5-三氯苯胺(沸點:270℃)、鄰甲苯胺(沸點:200℃)、間甲苯胺(沸點:203℃)、對甲苯胺(沸點:200℃)、2,4-二胺基甲苯(沸點:283℃)、雙(4-胺基苯基)碸、1,4-苯二胺(沸點:267℃)、4-甲氧基-2-甲基二苯胺、N,N-二乙基-3-甲基苯-1,4-二胺、阿米酚、1-苯基-1H-苯并咪唑-2-硫醇、1-苯基-5-巰基-1H-四唑(沸點:342℃)、2-氯苯胺(沸點:208℃)、2,5-二氯苯胺(沸點:251℃)、4-氯鄰胺苯甲酸(沸點:250℃)、2-氯-4-硝基苯胺(沸點:320℃)、5-氯-2-硝基苯胺(沸點:200℃)、3-(4-氯苯基)-1,1-二甲基脲(沸點:301℃)、4,4'-亞甲基雙(2-氯苯胺)、2,4-二氟苯胺、1,3-二鄰甲苯基胍(沸點:371℃)、1-(鄰甲苯基)雙胍(沸點:316℃)、1,3-二苯基-2-硫脲、N-苯基-1-萘胺、苯乙烯化二苯胺、N,N'-二苯基-1,4-苯二胺、N-(1,3-二甲基丁基)-N'-苯基-1,4-苯二胺(沸點:260℃)、甲基丙烯酸2-羥基-3-(4-苯胺基苯胺基)丙酯、N,N'-二-2-萘基-1,4-苯二胺(沸點:232℃)、巰基苯并咪唑、甲基-2-巰基苯并咪唑、鄰胺苯甲酸甲酯(沸點:256℃)、N-甲基鄰胺苯甲酸甲酯(沸點:256℃)、達美磺胺(沸點:265℃)、甲芬那酸(沸點:384℃)、6-胺基-4-羥基-2-萘磺酸、4'-羥基乙醯苯胺(沸點:273℃)、7-苯胺基-4-羥基-2-萘磺酸、4-(甲基胺基)苯酚硫酸鹽、N-(4-羥基苯基)甘胺酸(沸點:295℃)、4-甲基-2-硝基苯胺等。
作為上述醌化合物,例如可列舉:1,4-苯醌(對醌,沸點:293℃)、2,6-二甲基-1,4-苯醌(2,6-二甲基對醌,沸點:201℃)等烷基苯醌類;2,5-二苯基-1,4-苯醌(2,5-二苯基對醌)等苯基苯醌類;2,5-二氯-1,4-苯醌(2,5-二氯對醌,沸點:251℃)、2,6-二氯-1,4-苯醌(2,6-二氯對醌,沸點:251℃)、四溴-1,4-苯醌(四溴對醌,沸點:201℃)、2,3-二氯-5,6-二氰基-1,4-苯醌等鹵化苯醌類等苯醌類;蒽醌(9,10-蒽醌,沸點:380℃)、2-戊基-9,10-蒽二酮(2-戊基蒽醌)等蒽醌類;5,12-萘并萘醌(沸點:361℃)等萘并萘醌類;1,4-萘醌(沸點:243℃)、2-羥基-1,4-萘醌(沸點:265℃)、2,3-二氯-1,4-萘醌等萘醌類等。
作為上述硝基化合物,例如可列舉:4-硝基苯甲酸(沸點:237℃)、對硝基苯甲酸銨二水合物、4-硝基苯甲醯氯、2-氟硝基苯、4-氟硝基苯(沸點:205℃)、硝基苯(沸點:210℃)、5-硝基癒創木酚鈉、2-甲基-6-硝基苯甲酸酐等硝基苯類;1,2-二硝基苯(沸點:319℃)、1,3-二硝基苯(沸點:297℃)、1,4-二硝基苯(對二硝基苯,沸點:299℃)、四甲基對二硝基苯(二硝基均四甲苯,沸點:365℃)等二硝基苯類;1,3,5-三硝基苯(沸點:315℃)等三硝基苯類等硝基苯類;2-硝基甲苯(沸點:225℃)、4-硝基甲苯(沸點:238℃)等硝基甲苯類;2,4-二硝基甲苯(沸點:300℃)等二硝基甲苯類;1,3,5-三硝基甲苯(沸點:240℃)等三硝基甲苯類等硝基甲苯類等。
再者,本說明書中,上述硝基化合物意指除上述酚化合物、芳香族胺化合物、醌化合物以外之化合物。
其中,就提高(甲基)丙烯酸樹脂之分解速度之觀點而言,較佳為酚化合物、醌化合物,更佳為烷酚類、烷氧基酚類、羥基酚類、甲醯基酚類、硝基酚類、苯醌類、蒽醌類,進而較佳為2,6-二第三丁基對甲酚、4-甲氧基苯酚、4-第三丁基兒茶酚、對苯二酚、4-羥基苯甲醛、蒽醌、2-硝基苯酚、2,5-二氯-1,4-苯醌、2-第三丁基-4-羥基苯酚、4-第三丁基苯酚、三甲基對苯二酚。
作為本發明之一實施態樣之無機微粒子分散用載體組成物中之上述有機化合物之含量相對於上述黏合劑樹脂100重量份之下限為1重量份,上限為100重量份。
若上述有機化合物之含量為1重量份以上,則可充分發揮熱分解促進效果。若上述有機化合物之含量為100重量份以下,則陶瓷坯片中未殘留有機化合物,可防止因殘留物所致之鼓出或破損。
關於上述有機化合物之含量,就熱分解促進效果之觀點而言,較佳之下限為2重量份,更佳之下限為5重量份,就防止因殘留物所致之鼓出或破損之觀點而言,較佳之上限為80重量份,更佳之上限為60重量份,進而較佳之上限為40重量份,進而更佳之上限為20重量份,尤佳之上限為10重量份。
製作作為本發明之一實施態樣之無機微粒子分散用載體組成物之方法並無特別限定,可列舉一直以來公知之攪拌方法,具體而言,例如可列舉藉由三輥研磨機等將上述(甲基)丙烯酸樹脂、上述有機溶劑、上述有機化合物及視需要添加之其他成分加以攪拌之方法等。
藉由向作為本發明之一實施態樣之無機微粒子分散用載體組成物中添加無機微粒子、塑化劑及視需要添加之其他成分,可製作無機微粒子分散漿料組成物。
此種無機微粒子分散漿料組成物亦為本發明之一。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物含有無機微粒子。
上述無機微粒子並無特別限定,例如可列舉:玻璃粉末、陶瓷粉末、螢光體微粒子、矽氧化物等、金屬微粒子等。
上述玻璃粉末並無特別限定,例如可列舉:氧化二鉍玻璃、矽酸鹽玻璃、鉛玻璃、鋅玻璃、硼玻璃等之玻璃粉末或CaO-Al2
O3
-SiO2
系、MgO-Al2
O3
-SiO2
系、LiO2
-Al2
O3
-SiO2
系等各種矽氧化物之玻璃粉末等。
又,作為上述玻璃粉末,亦可使用SnO-B2
O3
-P2
O5
-Al2
O3
混合物、PbO-B2
O3
-SiO2
混合物、BaO-ZnO-B2
O3
-SiO2
混合物、ZnO-Bi2
O3
-B2
O3
-SiO2
混合物、Bi2
O3
-B2
O3
-BaO-CuO混合物、Bi2
O3
-ZnO-B2
O3
-Al2
O3
-SrO混合物、ZnO-Bi2
O3
-B2
O3
混合物、Bi2
O3
-SiO2
混合物、P2
O5
-Na2
O-CaO-BaO-Al2
O3
-B2
O3
混合物、P2
O5
-SnO混合物、P2
O5
-SnO-B2
O3
混合物、P2
O5
-SnO-SiO2
混合物、CuO-P2
O5
-RO混合物、SiO2
-B2
O3
-ZnO-Na2
O-Li2
O-NaF-V2
O5
混合物、P2
O5
-ZnO-SnO-R2
O-RO混合物、B2
O3
-SiO2
-ZnO混合物、B2
O3
-SiO2
-Al2
O3
-ZrO2
混合物、SiO2
-B2
O3
-ZnO-R2
O-RO混合物、SiO2
-B2
O3
-Al2
O3
-RO-R2
O混合物、SrO-ZnO-P2
O5
混合物、SrO-ZnO-P2
O5
混合物、BaO-ZnO-B2
O3
-SiO2
混合物等之玻璃粉末。再者,R為選自由Zn、Ba、Ca、Mg、Sr、Sn、Ni、Fe及Mn所組成之群中之元素。
尤佳為PbO-B2
O3
-SiO2
混合物之玻璃粉末或不含有鉛之BaO-ZnO-B2
O3
-SiO2
混合物或ZnO-Bi2
O3
-B2
O3
-SiO2
混合物等之無鉛玻璃粉末。
上述陶瓷粉末並無特別限定,例如可列舉:氧化鋁、鐵氧體、氧化鋯、鋯英石、鋯酸鋇、鋯酸鈣、氧化鈦、鈦酸鋇、鈦酸鍶、鈦酸鈣、鈦酸鎂、鈦酸鋅、鈦酸鑭、鈦酸釹、鋯鈦酸鉛、氮氧化鋁、氮化矽、氮化硼、碳化硼、錫酸鋇、錫酸鈣、矽酸鎂、莫來石、塊滑石、堇青石、矽酸鎂石等。
又,亦可使用:ITO、FTO、氧化鈮、氧化釩、氧化鎢、亞錳酸鑭鍶、鑭鍶鈷鐵氧體、釔穩定氧化鋯、摻釓氧化鈰、氧化鎳、鑭鉻鐵礦等。
上述螢光體微粒子並無特別限定,例如作為螢光體物質,可使用一直以來作為顯示用之螢光體物質而為人所知之藍色螢光體物質、紅色螢光體物質、綠色螢光體物質等。作為藍色螢光體物質,例如可使用:MgAl10
O17
:Eu系、Y2
SiO5
:Ce系、CaWO4
:Pb系、BaMgAl14
O23
:Eu系、BaMgAl16
O27
:Eu系、BaMg2
Al14
O23
:Eu系、BaMg2
Al14
O27
:Eu系、ZnS:(Ag,Cd)系者。作為紅色螢光體物質,例如可使用:Y2
O3
:Eu系、Y2
SiO5
:Eu系、Y3
Al5
O12
:Eu系、Zn3
(PO4
)2
:Mn系、YBO3
:Eu系、(Y,Gd)BO3
:Eu系、GdBO3
:Eu系、ScBO3
:Eu系、LuBO3
:Eu系者。作為綠色螢光體物質,例如可使用:Zn2
SiO4
:Mn系、BaAl12
O19
:Mn系、SrAl13
O19
:Mn系、CaAl12
O19
:Mn系、YBO3
:Tb系、BaMgAl14
O23
:Mn系、LuBO3
:Tb系、GdBO3
:Tb系、ScBO3
:Tb系、Sr6
Si3
O3
Cl4
:Eu系者。此外,亦可使用ZnO:Zn系、ZnS:(Cu,Al)系、ZnS:Ag系、Y2
O2
S:Eu系、ZnS:Zn系、(Y,Cd)BO3
:Eu系、BaMgAl12
O23
:Eu系者。
上述金屬微粒子並無特別限定,例如可列舉由銅、鎳、鈀、鉑、金、銀、鋁、鎢或該等之合金等所構成之粉末等。
又,亦可較佳地使用與羧基、胺基、醯胺基等之吸附特性良好且容易被氧化之銅或鐵等金屬。該等金屬粉末可單獨使用,亦可併用2種以上。
又,除金屬錯合物外,亦可使用各種碳黑、奈米碳管等。
關於上述無機微粒子,由於具有鈣鈦礦系結構之無機化合物之居里點位於300℃附近,故而用於本發明之無機微粒子較佳為含有鋰或鈦。具體而言,例如可列舉:LiO2
-Al2
O3
-SiO2
系無機玻璃等低熔點玻璃、Li2
S-Mx
Sy
(M=B、Si、Ge、P)等鋰硫系玻璃、LiCoO2
等鋰鈷複合氧化物、LiMnO4
等鋰錳複合氧化物、鋰鎳複合氧化物、鋰釩複合氧化物、鋰鋯複合氧化物、鋰鉿複合氧化物、磷酸矽鋰(Li3.5
Si0.5
P0.5
O4
)、磷酸鈦鋰(LiTi2
(PO4
)3
)、鈦酸鋰(Li4
Ti5
O12
)、Li4/3
Ti5/3
O4
、LiCoO2
、磷酸鍺鋰(LiGe2
(PO4
)3
)、Li2
-SiS系玻璃、Li4
GeS4
-Li3
PS4
系玻璃、LiSiO3
、LiMn2
O4
、Li2
S-P2
S5
系玻璃-陶瓷、Li2
O-SiO2
、Li2
O-V2
O5
-SiO2
、LiS-SiS2
-Li4
SiO4
系玻璃、LiPON等離子導電性氧化物、Li2
O-P2
O5
-B2
O3
、Li2
O-GeO2
Ba等氧化鋰化合物、Lix
Aly
Tiz
(PO4
)3
系玻璃、Lax
Liy
TiOz
系玻璃、Lix
Gey
Pz
O4
系玻璃、Li7
La3
Zr2
O12
系玻璃、Liv
Siw
Px
Sy
Clz
系玻璃、LiNbO3
等鋰鈮氧化物、Li-β-氧化鋁等鋰氧化鋁化合物、Li14
Zn(GeO4
)4
等鋰鋅氧化物等。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物中之上述無機微粒子之含量並無特別限定,較佳之下限為10重量%,更佳之下限為20重量%,較佳之上限為90重量%,更佳之上限為60重量%,進而較佳之上限為50重量%,進而更佳之上限為45重量%。藉由設為上述下限以上,可製成具有充分黏度,且具有優異之塗敷性者,藉由設為上述上限以下,可製成無機微粒子之分散性優異者。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物含有塑化劑。
作為上述塑化劑,例如可列舉:己二酸二(丁氧基乙酯)、己二酸二(丁氧基乙氧基乙酯)、三乙二醇雙(2-乙基己酸酯)、三乙二醇二己酸酯、乙醯基檸檬酸三丁酯、癸二酸二丁酯等。
藉由使用該等塑化劑,與使用一般塑化劑之情形相比,能夠降低塑化劑添加量(於相對於黏合劑添加約30重量%時,能夠降低至25重量%以下、進而20重量%以下)。其中,較佳為使用非芳香族之塑化劑,更佳為含有源自己二酸、三乙二醇或檸檬酸之成分。再者,含有芳香環之塑化劑容易燃燒變成煤,故欠佳。
又,作為上述塑化劑,較佳為具有碳數4以上之烷基者。
上述塑化劑藉由含有碳數為4以上之烷基,可抑制塑化劑對水分之吸收,而防止於所獲得之無機微粒子分散片中產生空隙或膨脹等異常。塑化劑之烷基尤佳為位於分子末端。
上述塑化劑較佳為碳:氧比為5:1~3:1。
藉由將碳:氧比設為上述範圍,可提高塑化劑之燃燒性,防止產生殘留碳。又,可提高與(甲基)丙烯酸樹脂之相溶性,即便為少量之塑化劑,亦可發揮塑化效果。又,只要丙二醇骨架或三亞甲基二醇骨架之高沸點有機溶劑亦含有碳數為4以上之烷基,且碳:氧比為5:1~3:1,則可較佳地使用。
上述塑化劑之沸點較佳為240℃以上未達390℃。藉由將上述沸點設為240℃以上,於乾燥步驟中變得容易蒸發,可防止殘留於成形體中。又,藉由設為未達390℃,可防止產生殘留碳。再者,上述沸點係指常壓下之沸點。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物中之上述塑化劑的含量並無特別限定,較佳之下限為0.1重量%,更佳之下限為0.5重量%,進而較佳之下限為1重量%,較佳之上限為3.0重量%,更佳之上限為2.5重量%,進而較佳之上限為2重量%。藉由設為上述範圍內,可減少塑化劑之煅燒殘渣。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物亦可含有界面活性劑等添加劑。
上述界面活性劑並無特別限定,例如可列舉:陽離子系界面活性劑、陰離子系界面活性劑、非離子系界面活性劑。
上述非離子系界面活性劑並無特別限定,較佳為HLB值為10以上20以下之非離子系界面活性劑。此處,HLB值係指,被用作表示界面活性劑之親水性、親油性之指標,且提出有若干計算方法,例如,關於酯系界面活性劑,有將皂化值設為S,將構成界面活性劑之脂肪酸之酸值設為A,而將HLB值設為20(1-S/A)等定義。具體而言,適宜為具有在脂肪鏈上加成伸烷基醚所得之聚環氧乙烷之非離子系界面活性劑,具體而言例如較佳為使用聚氧乙烯月桂醚、聚氧乙烯鯨蠟醚等。再者,上述非離子系界面活性劑之熱分解性較佳,但存在若大量添加,則無機微粒子分散漿料組成物之熱分解性降低之情形,因此含量較佳之上限為5重量%。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物中之上述黏合劑樹脂(尤其係(甲基)丙烯酸樹脂)之含量並無特別限定,較佳之下限為1重量%,更佳之下限為3重量%,進而較佳之下限為5重量%,較佳之上限為30重量%,更佳之上限為20重量%,進而較佳之上限為10重量%。藉由設為上述範圍內,即便於低溫下進行煅燒,亦可獲得能夠脫脂之無機微粒子分散漿料組成物。
關於作為上述無機微粒子分散漿料組成物中之上述有機化合物之含量,較佳之下限為0.01重量%,更佳之下限為0.05重量%,較佳之上限為20重量%,更佳之上限為10重量%。若上述有機化合物之含量為上述下限以上,則可充分發揮熱分解促進效果。若上述有機化合物之含量為上述上限以下,則陶瓷坯片中未殘留有機化合物,可防止因殘留物所致之鼓出或破損。
上述無機微粒子分散漿料組成物中之上述有機溶劑之含量並無特別限定,較佳之下限為40重量%,更佳之下限為45重量%,進而較佳之下限為50重量%,較佳之上限為80重量%,更佳之上限為70重量%,進而較佳之上限為65重量%。藉由設為上述範圍內,可提高塗敷性、無機微粒子之分散性。
作為本發明之另一實施態樣之無機微粒子分散漿料組成物之黏度並無特別限定,於20℃使用B型黏度計並將探針轉速設定為5 rpm進行測定之情形時之黏度較佳之下限為0.1 Pa・s,較佳之上限為100 Pa・s。
藉由將上述黏度設為0.1 Pa・s以上,藉由模嘴塗佈(die coating)印刷法等進行塗敷後,所獲得之無機微粒子分散片能夠維持特定之形狀。又,藉由將上述黏度設為100 Pa・s以下,可防止模嘴之塗出痕無法消失等異常,製成印刷性優異者。
製作作為本發明之另一實施態樣之無機微粒子分散漿料組成物之方法並無特別限定,可列舉一直以來公知之攪拌方法,具體而言,例如可列舉藉由三輥研磨機等將上述(甲基)丙烯酸樹脂、上述塑化劑、上述無機微粒子、上述有機溶劑及視需要添加之其他成分加以攪拌之方法等。
藉由將作為本發明之另一實施態樣之無機微粒子分散漿料組成物塗敷於已實施單面脫模處理之支持膜上,使有機溶劑乾燥去除,成形為片狀,可製造無機微粒子分散片。此種無機微粒子分散片之製造方法亦為本發明之一。
作為本發明之另一實施態樣之無機微粒子分散片之厚度較佳為1~20 μm。
作為上述無機微粒子分散片之製造方法,例如可列舉藉由輥式塗佈機、模嘴塗佈機、擠壓式塗佈機、簾幕式塗佈機等塗敷方式將上述無機微粒子分散漿料組成物於支持膜上均勻地形成塗膜之方法等。
再者,於製造無機微粒子分散片之情形時,較佳為直接將聚合液用作無機微粒子分散漿料組成物,且不使(甲基)丙烯酸樹脂乾燥而加工成無機微粒子分散片。
其原因在於:若使(甲基)丙烯酸樹脂乾燥,則於再次溶液化時產生被稱為顆粒之未乾燥粒子,此種顆粒即便藉由使用濾筒等之過濾亦難以去除,對無機微粒子分散片之強度產生不良影響。
於製造上述無機微粒子分散片時所使用之支持膜較佳為具有耐熱性及耐溶劑性並且具有可撓性之樹脂膜。藉由支持膜具有可撓性,可藉由輥式塗佈機、刮刀塗佈機等於支持膜之表面塗佈無機微粒子分散漿料組成物,可於將所獲得之無機微粒子分散片形成膜捲繞成卷狀之狀態下加以保存並供給。
作為形成上述支持膜之樹脂,例如可列舉:聚對苯二甲酸乙二酯、聚酯、聚乙烯、聚丙烯、聚苯乙烯、聚醯亞胺、聚乙烯醇、聚氯乙烯、聚氟乙烯等含氟樹脂、尼龍、纖維素等。
上述支持膜之厚度例如較佳為20~100 μm。
又,較佳為對支持膜之表面實施脫模處理,藉此,於轉印步驟中,可容易地進行支持膜之剝離操作。
藉由使用上述無機微粒子分散漿料組成物、無機微粒子分散片作為全固體電池之正極、固體電解質、負極之材料,可製造全固體電池。又,藉由將上述無機微粒子分散漿料組成物、無機微粒子分散片用於介電坯片、電極膏,可製造積層陶瓷電容器。
發明之效果
根據本發明,可提供一種於低溫下具有優異之分解性,並且能夠於短時間內脫脂之無機微粒子分散用載體組成物、含有該無機微粒子分散用載體組成物之無機微粒子分散漿料組成物、及使用該無機微粒子分散漿料組成物之無機微粒子分散片之製造方法。
以下揭示實施例進一步詳細地對本發明進行說明,但本發明並不僅限定於該等實施例。
(實施例1)
(1)樹脂組成物之製備
準備具備攪拌機、冷凝器、溫度計、熱水浴及氮氣導入口之2 L可分離式燒瓶。向2 L可分離式燒瓶中投入甲基丙烯酸甲酯(MMA,酯取代基之碳數:1)35重量份、甲基丙烯酸環氧丙酯(GMA)5重量份、甲基丙烯酸2-乙基己酯(2EHMA,酯取代基之碳數:8)60重量份。進而,與作為有機溶劑之乙酸丁酯40重量份混合,獲得單體混合液。
針對所獲得之單體混合液,藉由使用氮氣並通入20分鐘而去除溶氧後,利用氮氣對可分離式燒瓶系內進行置換,一面攪拌一面升溫至熱水浴沸騰。加入0.5重量份作為聚合起始劑之PEROYL SA。進而,於聚合開始3小時後添加0.5重量份之PEROYL SA。
於聚合開始7小時後,冷卻至室溫,結束聚合。藉此,獲得含有(甲基)丙烯酸樹脂之樹脂組成物。
(2)無機微粒子分散用載體組成物之製備
對於所獲得之樹脂組成物,以相對於(甲基)丙烯酸樹脂100重量份之比率成為如表1所示之方式添加表1所示之有機化合物,使用球磨機加以混合,獲得無機微粒子分散用載體組成物。
(3)無機微粒子分散漿料組成物之製備
向所獲得之無機微粒子分散用載體組成物中以成為表1所示之摻合比之方式添加作為無機微粒子之鈦酸鋇(「BT-02」,堺化學工業公司製造,平均粒徑0.2 μm)、作為塑化劑之己二酸二(丁氧基乙酯)、作為有機溶劑之乙酸丁酯,使用球磨機加以混合,獲得無機微粒子分散漿料組成物。
(4)無機微粒子分散片之製作
於經脫模處理之聚酯膜上以乾燥後之厚度成為20 μm之方式塗佈所獲得之無機微粒子分散漿料組成物,於常溫下乾燥1小時後,使用熱風乾燥機於80℃乾燥3小時,其次於120℃乾燥2小時,於支持膜上形成無機微粒子分散片。
(5)燒結體之製作
將所獲得之無機微粒子分散片自基材膜剝離,於氧化鋁基板上在設定為280℃之電爐內保持1小時,其後,於設定為1100℃之電爐內煅燒5小時,獲得燒結體。
(實施例2~15、比較例1~8)
於「(1)樹脂組成物之製備」中,以成為表1所示之摻合之方式混合單體,使用表1所示之有機化合物,設為如表1所示之摻合,除此以外,與實施例1同樣地製作樹脂組成物、無機微粒子分散用載體組成物、無機微粒子分散漿料組成物、無機微粒子分散片及燒結體。
再者,使用以下之化合物作為單體。
EMA:甲基丙烯酸正乙酯,酯取代基之碳數:2
BMA:甲基丙烯酸正丁酯,酯取代基之碳數:4
iBMA:甲基丙烯酸異丁酯,酯取代基之碳數:4
iDMA:甲基丙烯酸異癸酯,酯取代基之碳數:10
SMA:甲基丙烯酸硬脂酯,酯取代基之碳數:18
iSMA:甲基丙烯酸異硬脂酯,酯取代基之碳數:18
(比較例9)
使用聚環氧乙烷樹脂:PEO-1(住友精化股份有限公司製造,數量平均分子量50,000)作為黏合劑樹脂,設為如表1所示之摻合,除此以外,與實施例1同樣地製作樹脂組成物、無機微粒子分散用載體組成物、無機微粒子分散漿料組成物、無機微粒子分散片及燒結體。
(比較例10)
使用聚乙酸乙烯酯樹脂(FUJIFILM Wako Pure Chemical股份有限公司製造,重量平均分子量50,000)作為黏合劑樹脂,使用表1所示之有機化合物,設為如表1所示之摻合,除此以外,與實施例1同樣地製作樹脂組成物、無機微粒子分散用載體組成物、無機微粒子分散漿料組成物、無機微粒子分散片及燒結體。
[表1]
<評價>
對於實施例及比較例中獲得之(甲基)丙烯酸樹脂、聚環氧乙烷樹脂以及聚乙酸乙烯酯樹脂、無機微粒子分散漿料組成物、無機微粒子分散片、燒結體進行以下之評價。將結果示於表2。
(1)平均分子量測定
對於所獲得之(甲基)丙烯酸樹脂、聚環氧乙烷樹脂以及聚乙酸乙烯酯樹脂,使用LF-804(SHOKO公司製造)作為管柱,藉由凝膠滲透層析法測定利用聚苯乙烯換算之重量平均分子量(Mw)。
(2)玻璃轉移溫度測定
對於所獲得之(甲基)丙烯酸樹脂、聚環氧乙烷樹脂以及聚乙酸乙烯酯樹脂,使用示差掃描熱量計(DSC)測定玻璃轉移溫度(Tg)。
(3)TGDTA特性
將所獲得之無機微粒子分散漿料組成物裝滿TG-DTA之氧化鋁鍋,自30℃以5℃/min進行升溫,使溶劑蒸發去除,使樹脂、塑化劑熱分解。其後,測定重量顯示為30.6重量%(90重量%脫脂結束)之時間,作為分解結束時間。關於所獲得之分解結束時間,根據以下之基準進行評價。
○:分解結束時間為50分鐘以下。
×:分解結束時間超過50分鐘。
(4)燒結性
對於所獲得之燒結體,將樣品數設為10而評價外觀,根據以下之基準進行評價。
○:10個均未觀察到鼓出、破裂。
×:有1個以上觀察到鼓出、破裂。
(5)殘留碳
對於所獲得之燒結體,藉由目視確認有無著色,根據以下之基準進行殘留碳之評價。
○:燒結體之顏色為白色或米色,幾乎無著色。
×:燒結體之顏色為茶色或茶褐色,著色較深。
[表2]
於實施例1~15中,於任一評價中均確認到優異特性。另一方面,比較例1~10之組成於280℃下煅燒未充分進行,又,煅燒體產生鼓出或破裂。
產業上之可利用性
根據本發明,可提供一種能夠於低溫下具有優異之分解性,並且能夠於短時間內脫脂之無機微粒子分散用載體組成物、含有該無機微粒子分散用載體組成物之無機微粒子分散漿料組成物、及使用該無機微粒子分散漿料組成物之無機微粒子分散片之製造方法。
無
無
Claims (4)
- 一種無機微粒子分散用載體組成物,其含有:黏合劑樹脂、有機溶劑、及於常壓下沸點為200℃以上未達400℃之有機化合物,上述黏合劑樹脂含有(甲基)丙烯酸樹脂,上述有機化合物含有選自酚化合物、芳香族胺化合物、醌化合物、及硝基化合物中之至少1種,上述有機化合物之含量相對於上述黏合劑樹脂100重量份為1~100重量份,上述(甲基)丙烯酸樹脂含有源自甲基丙烯酸異丁酯之鏈段40重量%以上。
- 如請求項1所述之無機微粒子分散用載體組成物,其中,(甲基)丙烯酸樹脂含有源自酯取代基之碳數為1~2之(甲基)丙烯酸酯之鏈段20重量%以上60重量%以下。
- 一種無機微粒子分散漿料組成物,其含有請求項1或2所述之無機微粒子分散用載體組成物、無機微粒子及塑化劑。
- 一種無機微粒子分散片之製造方法,其使用請求項3所述之無機微粒子分散漿料組成物。
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JPJP2018-161762 | 2018-08-30 | ||
JP2018161762 | 2018-08-30 | ||
JPJP2019-036302 | 2019-02-28 | ||
JP2019036302 | 2019-02-28 | ||
JP2019111069 | 2019-06-14 | ||
JPJP2019-111069 | 2019-06-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW202019857A TW202019857A (zh) | 2020-06-01 |
TWI815958B true TWI815958B (zh) | 2023-09-21 |
Family
ID=69644315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW108131196A TWI815958B (zh) | 2018-08-30 | 2019-08-30 | 無機微粒子分散用載體組成物、無機微粒子分散漿料組成物及無機微粒子分散片之製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20210317296A1 (zh) |
JP (4) | JP6816309B2 (zh) |
KR (2) | KR102466043B1 (zh) |
CN (2) | CN112585212B (zh) |
TW (1) | TWI815958B (zh) |
WO (1) | WO2020045174A1 (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201107389A (en) * | 2009-08-04 | 2011-03-01 | Sekisui Chemical Co Ltd | Inorganic microparticle dispersion paste |
TW201437183A (zh) * | 2013-03-29 | 2014-10-01 | Sekisui Chemical Co Ltd | 無機質燒結體製造用黏合劑 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02306950A (ja) * | 1989-05-19 | 1990-12-20 | Ajinomoto Co Inc | アミノアセタール誘導体 |
JP2001278638A (ja) | 2000-03-30 | 2001-10-10 | Toray Ind Inc | 感光性ガラスペーストおよびそれを用いたプラズマディスプレイ |
DE102004047876A1 (de) * | 2004-10-01 | 2006-04-06 | Degussa Ag | Pulver mit verbesserten Recyclingeigenschaften, Verfahren zu dessen Herstellung und Verwendung des Pulvers in einem Verfahren zur Herstellung dreidimensionaler Objekte |
JP2007197312A (ja) | 2005-12-26 | 2007-08-09 | Toray Ind Inc | 拘束シートおよび焼結体の製造方法 |
JP4037440B2 (ja) | 2006-09-28 | 2008-01-23 | 日本特殊陶業株式会社 | ガラスセラミック多層配線基板の製造方法 |
CN101796087B (zh) * | 2007-09-07 | 2012-10-31 | 积水化学工业株式会社 | 粘合剂树脂、载色剂组合物以及无机微粒分散糊状组合物 |
JP2009263188A (ja) * | 2008-04-28 | 2009-11-12 | Sekisui Chem Co Ltd | 無機微粒子分散ペースト、積層体の製造方法及び積層体 |
JP2010117614A (ja) | 2008-11-14 | 2010-05-27 | Toray Ind Inc | 感光性組成物及びそれを用いた感光性グリーンシートならびにセラミックス多層基板 |
WO2010106980A1 (ja) * | 2009-03-17 | 2010-09-23 | 積水化学工業株式会社 | 無機微粒子分散ペースト組成物 |
CN103189405B (zh) * | 2010-08-31 | 2015-06-24 | 三菱丽阳株式会社 | 丙烯酸系组合物、成型体、手机键盘板以及导光体 |
JP6187810B2 (ja) | 2012-09-27 | 2017-08-30 | 日立金属株式会社 | セラミック焼結体の製造方法 |
JP6108987B2 (ja) * | 2013-06-28 | 2017-04-05 | 古河電気工業株式会社 | 接続構造体 |
JP7068174B2 (ja) * | 2016-09-01 | 2022-05-16 | 日東電工株式会社 | 水分散液型アクリル系粘着剤組成物 |
-
2019
- 2019-08-21 KR KR1020217001993A patent/KR102466043B1/ko active IP Right Grant
- 2019-08-21 KR KR1020227034940A patent/KR20220141912A/ko not_active Application Discontinuation
- 2019-08-21 CN CN201980055375.9A patent/CN112585212B/zh active Active
- 2019-08-21 US US17/270,217 patent/US20210317296A1/en active Pending
- 2019-08-21 JP JP2019555511A patent/JP6816309B2/ja active Active
- 2019-08-21 WO PCT/JP2019/032530 patent/WO2020045174A1/ja active Application Filing
- 2019-08-21 CN CN202210343286.8A patent/CN114605764B/zh active Active
- 2019-08-30 TW TW108131196A patent/TWI815958B/zh active
-
2020
- 2020-10-02 JP JP2020167709A patent/JP6816327B2/ja active Active
- 2020-12-07 JP JP2020202765A patent/JP6894563B2/ja active Active
-
2021
- 2021-05-24 JP JP2021086949A patent/JP2021121679A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201107389A (en) * | 2009-08-04 | 2011-03-01 | Sekisui Chemical Co Ltd | Inorganic microparticle dispersion paste |
TW201437183A (zh) * | 2013-03-29 | 2014-10-01 | Sekisui Chemical Co Ltd | 無機質燒結體製造用黏合劑 |
Also Published As
Publication number | Publication date |
---|---|
US20210317296A1 (en) | 2021-10-14 |
CN112585212B (zh) | 2022-04-19 |
JP2020204048A (ja) | 2020-12-24 |
WO2020045174A1 (ja) | 2020-03-05 |
KR20220141912A (ko) | 2022-10-20 |
CN112585212A (zh) | 2021-03-30 |
KR20210049777A (ko) | 2021-05-06 |
JP6894563B2 (ja) | 2021-06-30 |
KR102466043B1 (ko) | 2022-11-11 |
JP2021042390A (ja) | 2021-03-18 |
CN114605764A (zh) | 2022-06-10 |
JP6816327B2 (ja) | 2021-01-20 |
TW202019857A (zh) | 2020-06-01 |
CN114605764B (zh) | 2024-01-19 |
JP6816309B2 (ja) | 2021-01-20 |
JP2021121679A (ja) | 2021-08-26 |
JPWO2020045174A1 (ja) | 2020-09-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6523546B1 (ja) | 樹脂組成物、無機微粒子分散スラリー組成物、無機微粒子分散シート、全固体電池の製造方法及び積層セラミクスコンデンサの製造方法 | |
EP2204391B1 (en) | Binder resin, vehicle composition, and paste composition having inorganic microparticle dispersed therein | |
KR20070116639A (ko) | 바인더 수지 조성물 및 무기 미립자 분산 페이스트 조성물 | |
TWI815958B (zh) | 無機微粒子分散用載體組成物、無機微粒子分散漿料組成物及無機微粒子分散片之製造方法 | |
TW201035223A (en) | Inorganic microparticle-dispersed paste composition | |
JP2014141394A (ja) | セラミックグリーンシートおよびその製造方法 | |
JP2009263448A (ja) | 無機微粒子含有樹脂組成物及びそれを用いた無機物層 | |
CN102169755B (zh) | 层叠陶瓷电容器内部电极用导电性糊剂 | |
JP2004315719A (ja) | 焼成用樹脂組成物 | |
WO2022270460A1 (ja) | (メタ)アクリル樹脂組成物、無機微粒子分散スラリー組成物及び無機微粒子分散成形物 | |
JP2006151727A (ja) | 焼成体の製造方法 | |
TWI466968B (zh) | 積層陶瓷電容器內部電極用導電性糊 | |
JP2007177035A (ja) | 無機微粒子分散ペースト組成物 | |
CN104672989A (zh) | 触变型调墨油及其制备方法 | |
CN118076696A (zh) | 无机微粒分散用载体组合物、无机微粒分散用载体组合物的制造方法、无机微粒分散浆料组合物和电子部件的制造方法 | |
JP4516871B2 (ja) | アクリル系低温焼成バインダー | |
WO2024048303A1 (ja) | (メタ)アクリル樹脂粒子、ビヒクル組成物、スラリー組成物及び電子部品の製造方法 | |
JP2010138369A (ja) | 焼成ペースト組成物 | |
JP2007106802A (ja) | バインダー樹脂組成物及び無機微粒子分散ペースト組成物 |