TWI643980B - 利用場區與特徵部之對比的矽通孔電鍍浴的評估 - Google Patents

利用場區與特徵部之對比的矽通孔電鍍浴的評估 Download PDF

Info

Publication number
TWI643980B
TWI643980B TW103120592A TW103120592A TWI643980B TW I643980 B TWI643980 B TW I643980B TW 103120592 A TW103120592 A TW 103120592A TW 103120592 A TW103120592 A TW 103120592A TW I643980 B TWI643980 B TW I643980B
Authority
TW
Taiwan
Prior art keywords
plating
plating bath
interest
electrode
potential
Prior art date
Application number
TW103120592A
Other languages
English (en)
Chinese (zh)
Other versions
TW201510293A (zh
Inventor
柏根 李
史蒂芬T 邁爾
麥修 索倫
喬瑟夫 理察森
大衛W 波特
傅海鷹
Original Assignee
蘭姆研究公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 蘭姆研究公司 filed Critical 蘭姆研究公司
Publication of TW201510293A publication Critical patent/TW201510293A/zh
Application granted granted Critical
Publication of TWI643980B publication Critical patent/TWI643980B/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/18Curved printing formes or printing cylinders
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • C25D21/14Controlled addition of electrolyte components
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/413Concentration cells using liquid electrolytes measuring currents or voltages in voltaic cells
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416Systems
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/24Reinforcing of the conductive pattern
    • H05K3/241Reinforcing of the conductive pattern characterised by the electroplating method; means therefor, e.g. baths or apparatus
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors
    • C25D7/123Semiconductors first coated with a seed layer or a conductive layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Immunology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Automation & Control Theory (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Testing Or Measuring Of Semiconductors Or The Like (AREA)
TW103120592A 2013-06-14 2014-06-13 利用場區與特徵部之對比的矽通孔電鍍浴的評估 TWI643980B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361835418P 2013-06-14 2013-06-14
US61/835,418 2013-06-14
US14/275,750 2014-05-12
US14/275,750 US9689083B2 (en) 2013-06-14 2014-05-12 TSV bath evaluation using field versus feature contrast

Publications (2)

Publication Number Publication Date
TW201510293A TW201510293A (zh) 2015-03-16
TWI643980B true TWI643980B (zh) 2018-12-11

Family

ID=52018295

Family Applications (1)

Application Number Title Priority Date Filing Date
TW103120592A TWI643980B (zh) 2013-06-14 2014-06-13 利用場區與特徵部之對比的矽通孔電鍍浴的評估

Country Status (6)

Country Link
US (2) US9689083B2 (cg-RX-API-DMAC7.html)
JP (1) JP6433161B2 (cg-RX-API-DMAC7.html)
KR (2) KR102297508B1 (cg-RX-API-DMAC7.html)
CN (2) CN104233451B (cg-RX-API-DMAC7.html)
SG (2) SG10201802369YA (cg-RX-API-DMAC7.html)
TW (1) TWI643980B (cg-RX-API-DMAC7.html)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6170938B2 (ja) 2011-12-12 2017-07-26 ノベラス・システムズ・インコーポレーテッドNovellus Systems Incorporated 電気めっき溶液内のレベラー濃度の監視
US9598787B2 (en) * 2013-03-14 2017-03-21 Rohm And Haas Electronic Materials Llc Method of filling through-holes
US9689083B2 (en) 2013-06-14 2017-06-27 Lam Research Corporation TSV bath evaluation using field versus feature contrast
JP6890375B2 (ja) * 2014-10-21 2021-06-18 株式会社半導体エネルギー研究所 装置
US10094038B2 (en) 2015-04-13 2018-10-09 Lam Research Corporation Monitoring electrolytes during electroplating
CN105018977B (zh) * 2015-07-17 2017-09-12 深圳市板明科技有限公司 一种填孔电镀整平剂、制备方法及应用该整平剂的电镀液
US10508357B2 (en) 2016-02-15 2019-12-17 Rohm And Haas Electronic Materials Llc Method of filling through-holes to reduce voids and other defects
US10512174B2 (en) 2016-02-15 2019-12-17 Rohm And Haas Electronic Materials Llc Method of filling through-holes to reduce voids and other defects
WO2017204019A1 (ja) * 2016-05-27 2017-11-30 公立大学法人大阪府立大学 電気銅めっき液評価システム、電気銅めっき液評価方法および電気銅めっき液評価用チップ
US20180202060A1 (en) * 2017-01-18 2018-07-19 Eci Technology, Inc. Measurement of total accelerator in an electrodeposition solution
US10094035B1 (en) * 2017-10-16 2018-10-09 Lam Research Corporation Convection optimization for mixed feature electroplating
KR102785430B1 (ko) * 2017-11-17 2025-03-21 라시크 아이엔씨. 기재로부터의 프로세스 가스의 저장 및 전달을 위한 방법, 시스템, 및 디바이스
JP6971915B2 (ja) * 2018-06-05 2021-11-24 株式会社荏原製作所 めっき方法、めっき装置、及び限界電流密度を推定する方法
US10903050B2 (en) 2018-12-10 2021-01-26 Lam Research Corporation Endpoint sensor based control including adjustment of an edge ring parameter for each substrate processed to maintain etch rate uniformity
CN114514340B (zh) * 2019-07-26 2025-03-21 朗姆研究公司 先进封装应用的差别对比镀覆
US12305307B2 (en) 2020-01-10 2025-05-20 Lam Research Corporation TSV process window and fill performance enhancement by long pulsing and ramping
CN113311032B (zh) * 2020-02-27 2024-05-31 芯恩(青岛)集成电路有限公司 Ecp填充监测设备及监测方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030188977A1 (en) * 2002-04-03 2003-10-09 Eci Technology, Inc. Voltammetric reference electrode calibration
CN1764746A (zh) * 2003-03-25 2006-04-26 凸版印刷株式会社 电镀铜液的分析方法、其分析装置和半导体产品的制造方法
CN101004402A (zh) * 2006-01-18 2007-07-25 伊希特化股份有限公司 监控铜电镀液填孔能力的方法

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA988879A (en) 1972-11-06 1976-05-11 Cominco Ltd. Electrolytic lead refining
US4324621A (en) 1979-12-26 1982-04-13 Cominco Ltd. Method and apparatus for controlling the quality of electrolytes
US4479852A (en) * 1983-01-21 1984-10-30 International Business Machines Corporation Method for determination of concentration of organic additive in plating bath
US5223118A (en) 1991-03-08 1993-06-29 Shipley Company Inc. Method for analyzing organic additives in an electroplating bath
US5196096A (en) 1992-03-24 1993-03-23 International Business Machines Corporation Method for analyzing the addition agents in solutions for electroplating of PbSn alloys
CN1059475C (zh) * 1996-12-29 2000-12-13 中南工业大学 金属电积过程中在线控制有机添加剂的方法和装置
US7531079B1 (en) 1998-10-26 2009-05-12 Novellus Systems, Inc. Method and apparatus for uniform electropolishing of damascene IC structures by selective agitation
US7449098B1 (en) 1999-10-05 2008-11-11 Novellus Systems, Inc. Method for planar electroplating
JP2001152398A (ja) 1999-08-05 2001-06-05 Fujitsu Ltd 電気めっき方法、めっき液評価方法、めっき装置、半導体装置の製造方法
JP3897936B2 (ja) 1999-08-31 2007-03-28 株式会社荏原製作所 硫酸銅めっき液中のレベラー濃度測定方法
EP1136595A4 (en) 1999-08-30 2006-07-19 Ebara Corp METHOD FOR MEASURING THE DIRECT CONCENTRATION OF COATING SOLUTIONS AND METHOD AND DEVICE FOR CONTROLLING COATING SOLUTIONS
JP2001073200A (ja) 1999-08-30 2001-03-21 Ebara Corp めっき液管理方法及び管理装置
US6243615B1 (en) * 1999-09-09 2001-06-05 Aegis Analytical Corporation System for analyzing and improving pharmaceutical and other capital-intensive manufacturing processes
US6280602B1 (en) 1999-10-20 2001-08-28 Advanced Technology Materials, Inc. Method and apparatus for determination of additives in metal plating baths
EP1132500A3 (en) * 2000-03-08 2002-01-23 Applied Materials, Inc. Method for electrochemical deposition of metal using modulated waveforms
US6740220B1 (en) 2000-07-28 2004-05-25 The United States Of America As Represented By The Secretary Of The Navy Electrocatalytic cathode device of palladium and iridium on a high density or porous carbon support and a method for making such a cathode
US6645364B2 (en) 2000-10-20 2003-11-11 Shipley Company, L.L.C. Electroplating bath control
DE60113214T2 (de) 2000-11-02 2006-06-08 Shipley Co., L.L.C., Marlborough Plattierungsbadanalyse
US6458262B1 (en) 2001-03-09 2002-10-01 Novellus Systems, Inc. Electroplating chemistry on-line monitoring and control system
US6740221B2 (en) 2001-03-15 2004-05-25 Applied Materials Inc. Method of forming copper interconnects
US20040046121A1 (en) 2001-07-15 2004-03-11 Golden Josh H. Method and system for analyte determination in metal plating baths
US6936157B2 (en) 2001-08-09 2005-08-30 Advanced Technology Materials, Inc. Interference correction of additives concentration measurements in metal electroplating solutions
GB2379977B (en) 2001-09-25 2005-04-06 Kidde Plc High sensitivity particle detection
US6572753B2 (en) 2001-10-01 2003-06-03 Eci Technology, Inc. Method for analysis of three organic additives in an acid copper plating bath
JP2003129298A (ja) * 2001-10-17 2003-05-08 Matsushita Electric Ind Co Ltd メッキ液評価装置、メッキ液評価方法、電子デバイスの製造装置及び電子デバイスの製造方法
US7144488B2 (en) 2002-06-05 2006-12-05 Shipley Company, L.L.C. Electrode, electrochemical cell, and method for analysis of electroplating baths
EP1540046A4 (en) 2002-07-19 2007-04-04 Technic PROCESS AND DEVICE AT REAL TIME MONITORING OF TECHNICAL ELECTROLYTES
US20040217005A1 (en) 2002-07-24 2004-11-04 Aron Rosenfeld Method for electroplating bath chemistry control
US7799200B1 (en) 2002-07-29 2010-09-21 Novellus Systems, Inc. Selective electrochemical accelerator removal
US7405163B1 (en) 2003-12-17 2008-07-29 Novellus Systems, Inc. Selectively accelerated plating of metal features
US7449099B1 (en) 2004-04-13 2008-11-11 Novellus Systems, Inc. Selectively accelerated plating of metal features
US6749739B2 (en) 2002-10-07 2004-06-15 Eci Technology, Inc. Detection of suppressor breakdown contaminants in a plating bath
JP2004217997A (ja) 2003-01-14 2004-08-05 Fujitsu Ltd 電解めっき成長の添加剤固有特性の評価装置、電解めっき方法、及び半導体装置の製造方法
JP4534983B2 (ja) * 2003-03-25 2010-09-01 凸版印刷株式会社 電気銅めっき液の分析方法、その分析装置
JP2004323971A (ja) 2003-04-25 2004-11-18 Rohm & Haas Electronic Materials Llc 改良された浴分析
JP2005148011A (ja) 2003-11-19 2005-06-09 Ebara Corp 硫酸銅めっき液の有機添加剤濃度の測定方法及び測定装置
JP2005171347A (ja) 2003-12-12 2005-06-30 Shinko Electric Ind Co Ltd 電解銅めっき液の管理方法
US7435320B2 (en) 2004-04-30 2008-10-14 Advanced Technology Materials, Inc. Methods and apparatuses for monitoring organic additives in electrochemical deposition solutions
US7291253B2 (en) * 2004-05-04 2007-11-06 Eci Technology, Inc. Detection of an unstable additive breakdown product in a plating bath
US7186326B2 (en) 2004-05-27 2007-03-06 Eci Technology, Inc. Efficient analysis of organic additives in an acid copper plating bath
US7232513B1 (en) 2004-06-29 2007-06-19 Novellus Systems, Inc. Electroplating bath containing wetting agent for defect reduction
KR20060074593A (ko) 2004-12-27 2006-07-03 동부일렉트로닉스 주식회사 반도체 소자의 농도적정 모니터링 장치 및 그 방법
WO2006110437A1 (en) 2005-04-08 2006-10-19 The Trustees Of Columbia University In The City Of New York Systems and methods for monitoring plating and etching baths
CN2828067Y (zh) 2005-06-09 2006-10-18 福州大学 电镀液中添加剂浓度的实时监测装置
US7662981B2 (en) 2005-07-16 2010-02-16 Rohm And Haas Electronic Materials Llc Leveler compounds
CN100529750C (zh) 2006-01-17 2009-08-19 欧恩吉亚洲股份有限公司 电镀铜加速剂浓度分析方法及其沉积电解液
US20070215490A1 (en) * 2006-03-18 2007-09-20 Rockwood Electrochemicals Asia Ltd. Method of analyzing accelerator for copper electroplating
US8500985B2 (en) 2006-07-21 2013-08-06 Novellus Systems, Inc. Photoresist-free metal deposition
US7879222B2 (en) 2007-08-27 2011-02-01 Eci Technology, Inc. Detection of additive breakdown products in acid copper plating baths
US7776741B2 (en) 2008-08-18 2010-08-17 Novellus Systems, Inc. Process for through silicon via filing
KR101274363B1 (ko) 2009-05-27 2013-06-13 노벨러스 시스템즈, 인코포레이티드 얇은 시드층 상의 도금을 위한 펄스 시퀀스
US8372258B2 (en) * 2009-08-03 2013-02-12 Novellus Systems, Inc. Monitoring of electroplating additives
JP5442400B2 (ja) 2009-11-13 2014-03-12 ルネサスエレクトロニクス株式会社 半導体集積回路装置の製造方法
US8535504B2 (en) * 2010-05-03 2013-09-17 Eci Technology, Inc. Analysis of an auxiliary leveler additive in an acid copper plating bath
CN102286760B (zh) 2010-05-19 2016-10-05 诺发系统有限公司 用金属电化学填充高纵横比的大型凹入特征的方法、水溶液电镀槽溶液、电镀设备以及系统
JP2013077619A (ja) 2011-09-29 2013-04-25 Renesas Electronics Corp 半導体装置の製造方法
JP6170938B2 (ja) 2011-12-12 2017-07-26 ノベラス・システムズ・インコーポレーテッドNovellus Systems Incorporated 電気めっき溶液内のレベラー濃度の監視
CN103014823B (zh) 2013-01-05 2015-05-13 华进半导体封装先导技术研发中心有限公司 改进铜电沉积的添加剂效果快速判定方法
US9689083B2 (en) 2013-06-14 2017-06-27 Lam Research Corporation TSV bath evaluation using field versus feature contrast

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030188977A1 (en) * 2002-04-03 2003-10-09 Eci Technology, Inc. Voltammetric reference electrode calibration
CN1764746A (zh) * 2003-03-25 2006-04-26 凸版印刷株式会社 电镀铜液的分析方法、其分析装置和半导体产品的制造方法
CN101004402A (zh) * 2006-01-18 2007-07-25 伊希特化股份有限公司 监控铜电镀液填孔能力的方法

Also Published As

Publication number Publication date
KR102297508B1 (ko) 2021-09-02
US9689083B2 (en) 2017-06-27
US20140367279A1 (en) 2014-12-18
KR20140146015A (ko) 2014-12-24
SG10201802369YA (en) 2018-04-27
TW201510293A (zh) 2015-03-16
CN104233451A (zh) 2014-12-24
KR20210110787A (ko) 2021-09-09
SG10201402383QA (en) 2015-01-29
US20170241041A1 (en) 2017-08-24
KR102335508B1 (ko) 2021-12-06
US10508359B2 (en) 2019-12-17
JP2015001523A (ja) 2015-01-05
CN107858742B (zh) 2020-06-23
JP6433161B2 (ja) 2018-12-05
CN107858742A (zh) 2018-03-30
CN104233451B (zh) 2017-11-24

Similar Documents

Publication Publication Date Title
TWI643980B (zh) 利用場區與特徵部之對比的矽通孔電鍍浴的評估
KR102147003B1 (ko) 전기도금 용액 내에서의 평탄화제 농도 모니터링
US10774438B2 (en) Monitoring electrolytes during electroplating
US11078591B2 (en) Process for optimizing cobalt electrofill using sacrificial oxidants
TWI692555B (zh) 鑲嵌特徵中之由下而上填充
CN114514340B (zh) 先进封装应用的差别对比镀覆