TWI232874B - Elastomeric film grade thermoplastic polymer compositions having improved elastic performance - Google Patents
Elastomeric film grade thermoplastic polymer compositions having improved elastic performance Download PDFInfo
- Publication number
- TWI232874B TWI232874B TW089119830A TW89119830A TWI232874B TW I232874 B TWI232874 B TW I232874B TW 089119830 A TW089119830 A TW 089119830A TW 89119830 A TW89119830 A TW 89119830A TW I232874 B TWI232874 B TW I232874B
- Authority
- TW
- Taiwan
- Prior art keywords
- polystyrene
- weight
- molecular weight
- content
- oil
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims abstract description 34
- 229920002223 polystyrene Polymers 0.000 claims abstract description 34
- 229920001400 block copolymer Polymers 0.000 claims abstract description 20
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- 150000001993 dienes Chemical class 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 19
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 229920000428 triblock copolymer Polymers 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000010776 emu oil Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 27
- 239000010408 film Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 9
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- -1 polypropylene Polymers 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 5
- 230000002079 cooperative effect Effects 0.000 description 4
- 239000013013 elastic material Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 229940125904 compound 1 Drugs 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920006132 styrene block copolymer Polymers 0.000 description 2
- 238000011925 1,2-addition Methods 0.000 description 1
- PIMKIZUVIMAVSF-UHFFFAOYSA-N 1-(2-phenylethyl)-9h-fluorene Chemical compound C=1C=CC=2C3=CC=CC=C3CC=2C=1CCC1=CC=CC=C1 PIMKIZUVIMAVSF-UHFFFAOYSA-N 0.000 description 1
- 241001379910 Ephemera danica Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- BAWFJGJZGIEFAR-NNYOXOHSSA-N NAD zwitterion Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP([O-])(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 BAWFJGJZGIEFAR-NNYOXOHSSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- AYBXKPDAFLWWAQ-UHFFFAOYSA-N alumane;rhenium Chemical compound [AlH3].[Re] AYBXKPDAFLWWAQ-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002249 anxiolytic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002745 polystyrene-block- poly(ethylene /butylene) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000003325 tomography Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15411899P | 1999-09-15 | 1999-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI232874B true TWI232874B (en) | 2005-05-21 |
Family
ID=22550077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089119830A TWI232874B (en) | 1999-09-15 | 2000-09-26 | Elastomeric film grade thermoplastic polymer compositions having improved elastic performance |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6630532B1 (enExample) |
| EP (1) | EP1224238A1 (enExample) |
| JP (1) | JP4732650B2 (enExample) |
| CN (1) | CN1175040C (enExample) |
| AU (1) | AU7656900A (enExample) |
| BR (1) | BR0013990B1 (enExample) |
| TW (1) | TWI232874B (enExample) |
| WO (1) | WO2001019919A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002028965A1 (en) * | 2000-10-04 | 2002-04-11 | Kraton Polymers Research, B.V. | An elastomeric film and fiber grade thermoplastic elastomer composition |
| JP2002363376A (ja) * | 2001-06-01 | 2002-12-18 | Kuraray Co Ltd | 伸縮性材料 |
| CN1286904C (zh) * | 2002-01-31 | 2006-11-29 | 克拉通聚合物研究有限公司 | 具有改善的机械性能和加工性能的嵌段共聚物组合物 |
| EP1333058A1 (en) * | 2002-01-31 | 2003-08-06 | KRATON Polymers Research B.V. | Modified styrenic block copolymer and compounds thereof having improved mechanical properties and processability |
| JP4179990B2 (ja) * | 2002-01-31 | 2008-11-12 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | 機械的特性と加工性が改善されたブロック共重合体組成物およびそれに用いるスチレン系ブロック共重合体 |
| JP4069389B2 (ja) * | 2003-03-07 | 2008-04-02 | ジェイエスアール クレイトン エラストマー株式会社 | アスファルト改質用ブロック共重合体組成物、その製造方法、およびアスファルト組成物 |
| US7241540B2 (en) * | 2004-04-27 | 2007-07-10 | Kraton Polymers U.S. Llc | Photocurable compositions and flexographic printing plates comprising the same |
| JP4820542B2 (ja) * | 2004-09-30 | 2011-11-24 | パナソニック株式会社 | 半導体集積回路 |
| CN100369941C (zh) * | 2005-05-17 | 2008-02-20 | 北京化工大学 | 一种氢化苯乙烯类热塑性弹性体及其制备方法 |
| WO2007119390A1 (ja) * | 2006-03-28 | 2007-10-25 | Kuraray Co., Ltd. | 熱可塑性エラストマー組成物 |
| CN102188062A (zh) * | 2010-03-08 | 2011-09-21 | 波立科技控股公司 | 单一开口的有接缝弹性套状物结构 |
| CN102189630A (zh) * | 2010-03-08 | 2011-09-21 | 波立科技控股公司 | 热塑性材质的无缝套状物制造方法 |
| CN103347914B (zh) | 2011-02-14 | 2016-08-10 | 可乐丽股份有限公司 | 氢化嵌段共聚物和包含其的组合物 |
| CN103534310B (zh) | 2011-02-14 | 2016-09-07 | 可乐丽美国股份有限公司 | 适用于薄膜和片材的弹性体配方 |
| EP2602282B1 (de) * | 2011-12-05 | 2014-10-29 | Mondi Gronau GmbH | Elastische Folie für den Windelbereich |
| CN114380961B (zh) * | 2017-03-31 | 2023-04-25 | Lg化学株式会社 | 聚烯烃-聚苯乙烯多嵌段共聚物，用于制备其的有机锌化合物及其制备方法 |
| JP6987626B2 (ja) * | 2017-12-08 | 2022-01-05 | 花王株式会社 | 熱可塑性エラストマー樹脂組成物 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3333024A (en) * | 1963-04-25 | 1967-07-25 | Shell Oil Co | Block polymers, compositions containing them and process of their preparation |
| USRE27145E (en) * | 1969-05-20 | 1971-06-22 | Side-chain | |
| US3810957A (en) * | 1970-08-10 | 1974-05-14 | Shell Oil Co | Selectively hydrogenated block copolymer-polystyrene blends |
| US4256232A (en) * | 1978-12-05 | 1981-03-17 | Celanese Corporation | Powder composition and method of preparation |
| JPH0629388B2 (ja) * | 1985-06-14 | 1994-04-20 | 日本石油株式会社 | 熱可塑性ゴム系接着剤組成物 |
| EP0209874B2 (en) * | 1985-07-19 | 1995-05-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Hydrogenated block copolymer compositions |
| JPS638450A (ja) * | 1986-06-27 | 1988-01-14 | Japan Synthetic Rubber Co Ltd | 熱可塑性エラストマ−組成物 |
| JPS6356551A (ja) * | 1986-08-27 | 1988-03-11 | Asahi Chem Ind Co Ltd | シリンジ用熱可塑性ガスケツト |
| US4861819A (en) * | 1987-11-02 | 1989-08-29 | Ford Motor Company | Wiper blade compositions |
| US5216074A (en) * | 1989-07-17 | 1993-06-01 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
| US5068138A (en) | 1989-08-16 | 1991-11-26 | Shell Oil Company | Elastomeric film |
| US4970259A (en) * | 1989-08-16 | 1990-11-13 | Shell Oil Company | Elastomeric film composition |
| US5169706A (en) | 1990-01-10 | 1992-12-08 | Kimberly-Clark Corporation | Low stress relaxation composite elastic material |
| US5093422A (en) | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
| TW209877B (enExample) * | 1991-11-04 | 1993-07-21 | Shell Internat Res Schappej B V | |
| JPH06100755A (ja) * | 1992-09-22 | 1994-04-12 | Sumitomo Bakelite Co Ltd | 水添ブロック共重合体エラストマー組成物 |
| EP0618261B1 (en) * | 1993-04-02 | 1998-06-03 | Shell Internationale Researchmaatschappij B.V. | Conveyor belts derived from hot melt compositions, based on hydrogenated block copolymers derived from a vinyl aromatic and a conjugated diene |
| TR199600222A2 (tr) * | 1995-03-24 | 1996-10-21 | Shell Int Research | Döner kaliplama ve benzeri islemlerde kullanima uygun,monovinil aromatik blok kopolimer iceren bilesimler ve bunlardan türetilen mikrogranüller ve tozlar. |
| JPH1053686A (ja) * | 1996-05-29 | 1998-02-24 | Shell Internatl Res Maatschappij Bv | ブロックコポリマーを主成分とするエラストマー組成物 |
| TR199901056T2 (xx) | 1996-11-14 | 1999-07-21 | Shell Internationale Research Maatschappij B.V. | Geliştirilmiş esneklik performansı olan değiştirilmiş styren blok kopolimer bileşikleri. |
-
2000
- 2000-09-07 US US09/657,015 patent/US6630532B1/en not_active Expired - Fee Related
- 2000-09-14 EP EP00966024A patent/EP1224238A1/en not_active Withdrawn
- 2000-09-14 WO PCT/EP2000/009032 patent/WO2001019919A1/en not_active Ceased
- 2000-09-14 JP JP2001523692A patent/JP4732650B2/ja not_active Expired - Fee Related
- 2000-09-14 AU AU76569/00A patent/AU7656900A/en not_active Abandoned
- 2000-09-14 CN CNB008129592A patent/CN1175040C/zh not_active Expired - Fee Related
- 2000-09-14 BR BRPI0013990-4A patent/BR0013990B1/pt not_active IP Right Cessation
- 2000-09-26 TW TW089119830A patent/TWI232874B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1224238A1 (en) | 2002-07-24 |
| JP4732650B2 (ja) | 2011-07-27 |
| BR0013990B1 (pt) | 2011-09-06 |
| CN1175040C (zh) | 2004-11-10 |
| WO2001019919A1 (en) | 2001-03-22 |
| JP2003509564A (ja) | 2003-03-11 |
| AU7656900A (en) | 2001-04-17 |
| BR0013990A (pt) | 2002-05-14 |
| CN1374985A (zh) | 2002-10-16 |
| US6630532B1 (en) | 2003-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |