TWI232874B - Elastomeric film grade thermoplastic polymer compositions having improved elastic performance - Google Patents
Elastomeric film grade thermoplastic polymer compositions having improved elastic performance Download PDFInfo
- Publication number
- TWI232874B TWI232874B TW089119830A TW89119830A TWI232874B TW I232874 B TWI232874 B TW I232874B TW 089119830 A TW089119830 A TW 089119830A TW 89119830 A TW89119830 A TW 89119830A TW I232874 B TWI232874 B TW I232874B
- Authority
- TW
- Taiwan
- Prior art keywords
- polystyrene
- weight
- molecular weight
- content
- oil
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims abstract description 34
- 229920002223 polystyrene Polymers 0.000 claims abstract description 34
- 229920001400 block copolymer Polymers 0.000 claims abstract description 20
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- 150000001993 dienes Chemical class 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 19
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 229920000428 triblock copolymer Polymers 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000010776 emu oil Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 27
- 239000010408 film Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 9
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- -1 polypropylene Polymers 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 5
- 230000002079 cooperative effect Effects 0.000 description 4
- 239000013013 elastic material Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 229940125904 compound 1 Drugs 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920006132 styrene block copolymer Polymers 0.000 description 2
- 238000011925 1,2-addition Methods 0.000 description 1
- PIMKIZUVIMAVSF-UHFFFAOYSA-N 1-(2-phenylethyl)-9h-fluorene Chemical compound C=1C=CC=2C3=CC=CC=C3CC=2C=1CCC1=CC=CC=C1 PIMKIZUVIMAVSF-UHFFFAOYSA-N 0.000 description 1
- 241001379910 Ephemera danica Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- BAWFJGJZGIEFAR-NNYOXOHSSA-N NAD zwitterion Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP([O-])(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 BAWFJGJZGIEFAR-NNYOXOHSSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- AYBXKPDAFLWWAQ-UHFFFAOYSA-N alumane;rhenium Chemical compound [AlH3].[Re] AYBXKPDAFLWWAQ-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002249 anxiolytic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002745 polystyrene-block- poly(ethylene /butylene) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000003325 tomography Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15411899P | 1999-09-15 | 1999-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI232874B true TWI232874B (en) | 2005-05-21 |
Family
ID=22550077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089119830A TWI232874B (en) | 1999-09-15 | 2000-09-26 | Elastomeric film grade thermoplastic polymer compositions having improved elastic performance |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6630532B1 (enExample) |
| EP (1) | EP1224238A1 (enExample) |
| JP (1) | JP4732650B2 (enExample) |
| CN (1) | CN1175040C (enExample) |
| AU (1) | AU7656900A (enExample) |
| BR (1) | BR0013990B1 (enExample) |
| TW (1) | TWI232874B (enExample) |
| WO (1) | WO2001019919A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002028965A1 (en) * | 2000-10-04 | 2002-04-11 | Kraton Polymers Research, B.V. | An elastomeric film and fiber grade thermoplastic elastomer composition |
| JP2002363376A (ja) * | 2001-06-01 | 2002-12-18 | Kuraray Co Ltd | 伸縮性材料 |
| AU2003239232A1 (en) | 2002-01-31 | 2003-09-02 | Kraton Polymers Research B.V. | Blockcopolymer compositions, having improved mechanical properties and processability |
| US7186779B2 (en) | 2002-01-31 | 2007-03-06 | Kraton Polymers U.S. Llc | Block copolymer compositions, having improved mechanical properties and processability |
| EP1333058A1 (en) * | 2002-01-31 | 2003-08-06 | KRATON Polymers Research B.V. | Modified styrenic block copolymer and compounds thereof having improved mechanical properties and processability |
| JP4069389B2 (ja) * | 2003-03-07 | 2008-04-02 | ジェイエスアール クレイトン エラストマー株式会社 | アスファルト改質用ブロック共重合体組成物、その製造方法、およびアスファルト組成物 |
| US7241540B2 (en) * | 2004-04-27 | 2007-07-10 | Kraton Polymers U.S. Llc | Photocurable compositions and flexographic printing plates comprising the same |
| JP4820542B2 (ja) * | 2004-09-30 | 2011-11-24 | パナソニック株式会社 | 半導体集積回路 |
| CN100369941C (zh) * | 2005-05-17 | 2008-02-20 | 北京化工大学 | 一种氢化苯乙烯类热塑性弹性体及其制备方法 |
| JPWO2007119390A1 (ja) * | 2006-03-28 | 2009-08-27 | 株式会社クラレ | 熱可塑性エラストマー組成物 |
| CN102189630A (zh) * | 2010-03-08 | 2011-09-21 | 波立科技控股公司 | 热塑性材质的无缝套状物制造方法 |
| CN102188062A (zh) * | 2010-03-08 | 2011-09-21 | 波立科技控股公司 | 单一开口的有接缝弹性套状物结构 |
| KR101932166B1 (ko) | 2011-02-14 | 2018-12-24 | 쿠라레이 아메리카 인코포레이티드 | 막 및 시트에 유용한 엘라스토머 제형 |
| CN103347914B (zh) | 2011-02-14 | 2016-08-10 | 可乐丽股份有限公司 | 氢化嵌段共聚物和包含其的组合物 |
| ES2528231T3 (es) * | 2011-12-05 | 2015-02-06 | Mondi Gronau Gmbh | Película elástica para la zona del pañal |
| EP3590983B1 (en) * | 2017-03-31 | 2023-06-21 | LG Chem, Ltd. | Polyolefin-polystyrene multi-block copolymer, organozinc compound for preparing same, and method for preparing polyolefin-polystyrene multi-block copolymer |
| JP6987626B2 (ja) * | 2017-12-08 | 2022-01-05 | 花王株式会社 | 熱可塑性エラストマー樹脂組成物 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3333024A (en) * | 1963-04-25 | 1967-07-25 | Shell Oil Co | Block polymers, compositions containing them and process of their preparation |
| USRE27145E (en) * | 1969-05-20 | 1971-06-22 | Side-chain | |
| US3810957A (en) * | 1970-08-10 | 1974-05-14 | Shell Oil Co | Selectively hydrogenated block copolymer-polystyrene blends |
| US4256232A (en) * | 1978-12-05 | 1981-03-17 | Celanese Corporation | Powder composition and method of preparation |
| JPH0629388B2 (ja) * | 1985-06-14 | 1994-04-20 | 日本石油株式会社 | 熱可塑性ゴム系接着剤組成物 |
| US4772657A (en) * | 1985-07-19 | 1988-09-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Hydrogenated block copolymer compositions |
| JPS638450A (ja) * | 1986-06-27 | 1988-01-14 | Japan Synthetic Rubber Co Ltd | 熱可塑性エラストマ−組成物 |
| JPS6356551A (ja) * | 1986-08-27 | 1988-03-11 | Asahi Chem Ind Co Ltd | シリンジ用熱可塑性ガスケツト |
| US4861819A (en) * | 1987-11-02 | 1989-08-29 | Ford Motor Company | Wiper blade compositions |
| US5216074A (en) * | 1989-07-17 | 1993-06-01 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
| US5068138A (en) | 1989-08-16 | 1991-11-26 | Shell Oil Company | Elastomeric film |
| US4970259A (en) * | 1989-08-16 | 1990-11-13 | Shell Oil Company | Elastomeric film composition |
| US5169706A (en) | 1990-01-10 | 1992-12-08 | Kimberly-Clark Corporation | Low stress relaxation composite elastic material |
| US5093422A (en) | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
| TW209877B (enExample) * | 1991-11-04 | 1993-07-21 | Shell Internat Res Schappej B V | |
| JPH06100755A (ja) * | 1992-09-22 | 1994-04-12 | Sumitomo Bakelite Co Ltd | 水添ブロック共重合体エラストマー組成物 |
| EP0618261B1 (en) * | 1993-04-02 | 1998-06-03 | Shell Internationale Researchmaatschappij B.V. | Conveyor belts derived from hot melt compositions, based on hydrogenated block copolymers derived from a vinyl aromatic and a conjugated diene |
| TR199600222A2 (tr) * | 1995-03-24 | 1996-10-21 | Shell Int Research | Döner kaliplama ve benzeri islemlerde kullanima uygun,monovinil aromatik blok kopolimer iceren bilesimler ve bunlardan türetilen mikrogranüller ve tozlar. |
| JPH1053686A (ja) * | 1996-05-29 | 1998-02-24 | Shell Internatl Res Maatschappij Bv | ブロックコポリマーを主成分とするエラストマー組成物 |
| TR199901056T2 (xx) | 1996-11-14 | 1999-07-21 | Shell Internationale Research Maatschappij B.V. | Geliştirilmiş esneklik performansı olan değiştirilmiş styren blok kopolimer bileşikleri. |
-
2000
- 2000-09-07 US US09/657,015 patent/US6630532B1/en not_active Expired - Fee Related
- 2000-09-14 WO PCT/EP2000/009032 patent/WO2001019919A1/en not_active Ceased
- 2000-09-14 JP JP2001523692A patent/JP4732650B2/ja not_active Expired - Fee Related
- 2000-09-14 EP EP00966024A patent/EP1224238A1/en not_active Withdrawn
- 2000-09-14 BR BRPI0013990-4A patent/BR0013990B1/pt not_active IP Right Cessation
- 2000-09-14 AU AU76569/00A patent/AU7656900A/en not_active Abandoned
- 2000-09-14 CN CNB008129592A patent/CN1175040C/zh not_active Expired - Fee Related
- 2000-09-26 TW TW089119830A patent/TWI232874B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1374985A (zh) | 2002-10-16 |
| EP1224238A1 (en) | 2002-07-24 |
| JP4732650B2 (ja) | 2011-07-27 |
| US6630532B1 (en) | 2003-10-07 |
| WO2001019919A1 (en) | 2001-03-22 |
| AU7656900A (en) | 2001-04-17 |
| JP2003509564A (ja) | 2003-03-11 |
| BR0013990B1 (pt) | 2011-09-06 |
| BR0013990A (pt) | 2002-05-14 |
| CN1175040C (zh) | 2004-11-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |