SU1050565A3 - Способ получени натриевой соли @ -фосфонометилглицина - Google Patents
Способ получени натриевой соли @ -фосфонометилглицина Download PDFInfo
- Publication number
- SU1050565A3 SU1050565A3 SU802877858A SU2877858A SU1050565A3 SU 1050565 A3 SU1050565 A3 SU 1050565A3 SU 802877858 A SU802877858 A SU 802877858A SU 2877858 A SU2877858 A SU 2877858A SU 1050565 A3 SU1050565 A3 SU 1050565A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- water
- sodium
- salt
- solution
- product
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract description 6
- 159000000000 sodium salts Chemical class 0.000 title description 4
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- NOJNFULGOQGBKB-UHFFFAOYSA-M sodium;3-[3-tert-butylsulfanyl-1-[[4-(6-ethoxypyridin-3-yl)phenyl]methyl]-5-[(5-methylpyridin-2-yl)methoxy]indol-2-yl]-2,2-dimethylpropanoate Chemical compound [Na+].C1=NC(OCC)=CC=C1C(C=C1)=CC=C1CN1C2=CC=C(OCC=3N=CC(C)=CC=3)C=C2C(SC(C)(C)C)=C1CC(C)(C)C([O-])=O NOJNFULGOQGBKB-UHFFFAOYSA-M 0.000 claims 1
- 235000014101 wine Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 230000002363 herbicidal effect Effects 0.000 abstract description 2
- 239000004009 herbicide Substances 0.000 abstract description 2
- 240000000111 Saccharum officinarum Species 0.000 abstract 1
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract 1
- 229930006000 Sucrose Natural products 0.000 abstract 1
- 239000005720 sucrose Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 239000000047 product Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 16
- 239000013078 crystal Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000005562 Glyphosate Substances 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229940097068 glyphosate Drugs 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- UCTWMZQNUQWSLP-UHFFFAOYSA-N adrenaline Chemical compound CNCC(O)C1=CC=C(O)C(O)=C1 UCTWMZQNUQWSLP-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- -1 sodium hydrofluoride nonahydrate Chemical compound 0.000 description 2
- 150000004685 tetrahydrates Chemical group 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 241000252505 Characidae Species 0.000 description 1
- 241000337911 Copium Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 101150057615 Syn gene Proteins 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 230000002951 depilatory effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002332 glycine derivatives Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000037074 physically active Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- DGPIGKCOQYBCJH-UHFFFAOYSA-M sodium;acetic acid;hydroxide Chemical compound O.[Na+].CC([O-])=O DGPIGKCOQYBCJH-UHFFFAOYSA-M 0.000 description 1
- DFIWJEVKLWMZBI-UHFFFAOYSA-M sodium;dihydrogen phosphate;phosphoric acid Chemical compound [Na+].OP(O)(O)=O.OP(O)([O-])=O DFIWJEVKLWMZBI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000007966 viscous suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/866,677 US4140513A (en) | 1978-01-03 | 1978-01-03 | Sodium sesquiglyphosate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1050565A3 true SU1050565A3 (ru) | 1983-10-23 |
Family
ID=25348146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU802877858A SU1050565A3 (ru) | 1978-01-03 | 1980-02-08 | Способ получени натриевой соли @ -фосфонометилглицина |
Country Status (41)
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4481026A (en) * | 1982-11-16 | 1984-11-06 | Stauffer Chemical Company | Aluminum N-phosphonomethylglycine and its use as a herbicide |
| US4472189A (en) * | 1982-12-27 | 1984-09-18 | Stauffer Chemical Co. | Stannic N-phosphonomethyglycine and its use as a herbicide |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| KR860008713A (ko) * | 1985-05-29 | 1986-12-18 | 죤 알. 페넬 | 고체식물 훨성조성물 및 그 제조방법 |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| BR8600460A (pt) * | 1986-02-04 | 1987-09-01 | Monsanto Brasil | Processo para preparacao de um sal de metal alcalino particulado de n-fosfonometilglicina |
| US5047079A (en) * | 1986-08-18 | 1991-09-10 | Ici Americas Inc. | Method of preparation and use of solid, phytoactive compositions |
| NZ231897A (en) | 1988-12-30 | 1992-09-25 | Monsanto Co | Dry water-soluble granular composition comprising glyphosate and a liquid surfactant |
| DK165156C (da) * | 1989-12-20 | 1993-03-01 | Cheminova Agro As | Herbicid formulering indeholdende glyphosatsyre |
| DE4029304A1 (de) * | 1990-09-15 | 1992-03-19 | Hoechst Ag | Synergistische herbizide mittel |
| US6930075B1 (en) | 1990-11-02 | 2005-08-16 | Monsanto Technology, Llc | Fatty acid-based herbicidal composition |
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them |
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| DE19533523A1 (de) * | 1995-09-11 | 1997-03-13 | Bayer Ag | Verwendung von N-Phosphonomethyl-glycinestern in wäßriger Lösung als Herbizide |
| SK772000A3 (en) * | 1997-07-22 | 2000-08-14 | Monsanto Co | High-loaded ammonium glyphosate formulations |
| CA2297749A1 (en) * | 1997-07-30 | 1999-02-11 | Monsanto Company | Process and compositions promoting biological effectiveness of exogenous chemical substances in plants |
| ITTO980048A1 (it) * | 1998-01-20 | 1999-07-20 | Ipici Spa | Composizioni erbicide, procedimenti per la loro preparazione ed impieghi |
| KR20010040972A (ko) * | 1998-02-13 | 2001-05-15 | 죤 에이치. 뷰센 | 외래 화학물질과 실록산 계면활성제를 포함한 저장-안정성조성물 |
| GB9819693D0 (en) | 1998-09-10 | 1998-11-04 | Zeneca Ltd | Glyphosate formulation |
| CN1277474C (zh) | 1998-11-23 | 2006-10-04 | 孟山都公司 | 草甘膦除草剂的浓缩储藏和运输系统 |
| PL348907A1 (en) | 1998-11-23 | 2002-06-17 | Monsanto Co | Highly concentrated aqueous glyphosate compositions |
| ATE285680T1 (de) | 1998-11-30 | 2005-01-15 | Flamel Tech Sa | Förderung der biologischen effektivität exogener chemischer substanzen in pflanzen |
| US6369001B1 (en) | 1999-08-11 | 2002-04-09 | Monsanto Technology, Llc | Microemulsion coformulation of a graminicide and a water-soluble herbicide |
| US6746976B1 (en) | 1999-09-24 | 2004-06-08 | The Procter & Gamble Company | Thin until wet structures for acquiring aqueous fluids |
| JP5433120B2 (ja) | 1999-09-30 | 2014-03-05 | モンサント テクノロジー エルエルシー | 向上した安定性を有するパッケージミックス農薬組成物 |
| MY158895A (en) * | 2000-05-19 | 2016-11-30 | Monsanto Technology Llc | Potassium glyphosate formulations |
| US7135437B2 (en) | 2000-05-19 | 2006-11-14 | Monsanto Technology Llc | Stable liquid pesticide compositions |
| US6992045B2 (en) | 2000-05-19 | 2006-01-31 | Monsanto Technology Llc | Pesticide compositions containing oxalic acid |
| US6300323B1 (en) | 2000-08-08 | 2001-10-09 | Ishihara Sangyo Kaisha, Ltd. | (Poly)ethereal ammonium salts of herbicides bearing acidic moieties and their use as herbicides |
| DE10052489A1 (de) | 2000-10-23 | 2002-05-02 | Hermania Dr Schirm Gmbh | Feste Glyphosat-Formulierung und Verfahren zur Herstellung |
| BR0215676A (pt) * | 2002-04-01 | 2005-02-01 | Valent Biosciences Corp | Composição herbicida, e, métodos para melhorar a atividade herbicida de um inibidor de biossìntese de aminoácidos, e para controlar crescimento de plantas |
| US20050037924A1 (en) * | 2002-08-31 | 2005-02-17 | Monsanto Technology Llc | Sodium glyphosate compositions and process for their preparation |
| AU2003268314A1 (en) * | 2002-08-31 | 2004-03-19 | William Abraham | Process for the preparation of a dry pesticidal composition containing a dicarbodylate component |
| US8470741B2 (en) * | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
| BRPI0515552A (pt) * | 2004-09-17 | 2008-07-29 | Monsanto Technology Llc | formulações de glifosato com sintomas de queimação precoce |
| US7223718B2 (en) * | 2005-03-07 | 2007-05-29 | Falcon Lab Llc | Enhanced glyphosate herbicidal concentrates |
| US20070049498A1 (en) * | 2005-09-01 | 2007-03-01 | Brigance Mickey R | Agricultural compositions which enhance performance of herbicides |
| MY157394A (en) * | 2008-06-18 | 2016-06-15 | Stepan Co | Ultra-high loading glyphosate concentrate |
| PL2939538T3 (pl) | 2008-07-03 | 2019-05-31 | Monsanto Technology Llc | Połączenia derywatyzowanych sacharydowych środków powierzchniowo czynnych i środków powierzchniowo czynnych stanowiących tlenek eteroaminy jako adiuwantów środka chwastobójczego |
| AU2009296340B2 (en) | 2008-09-29 | 2015-02-12 | Monsanto Technology Llc | Glyphosate formulations containing amidoalkylamine surfactants |
| US9233993B2 (en) | 2009-06-30 | 2016-01-12 | Monsanto Technology Llc | N-phosphonomethylglycine guanidine derivative salts |
| US20110071027A1 (en) * | 2009-09-18 | 2011-03-24 | Volker Heide | High strength aqueous glyphosate salt concentrates and methods |
| BR112012011625B1 (pt) | 2009-11-16 | 2018-10-02 | Imtrade Australia Pty Ltd | formulações de glifosato de carga elevada e processo de preparação das mesmas |
| BR112013009948B1 (pt) | 2010-10-25 | 2018-08-14 | Stepan Company | formulação de glifosato |
| BR112016030842B1 (pt) | 2014-07-02 | 2021-06-15 | Stepan Company | Composição agrícola e composição agrícola com reduzida toxicidade aquática |
| PL3454658T3 (pl) | 2016-05-11 | 2025-04-14 | Monsanto Technology Llc | Formulacje glifosatu zawierające amidoalkiloaminowe środki powierzchniowo czynne |
| CA3033440C (en) | 2016-08-09 | 2025-09-09 | Monsanto Technology Llc | HERBICIDAL COMPOSITIONS COMPRISING A GLYPHOSATE AND A MONOCARBOXYLIC ACID SALT |
| EP3628738A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Method for controlling weed beets and other weeds |
| EP3628160A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Use of glyphosate herbicide for controlling unwanted vegetation in beta vulgaris growing areas |
| CN116574129B (zh) * | 2023-04-14 | 2025-04-25 | 湖北泰盛化工有限公司 | 一种消除细晶的草甘膦结晶方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL38138A (en) * | 1970-11-19 | 1974-07-31 | Ciba Geigy Ag | Process and compositions containing thiourea derivatives for the promotion of fruit abscission |
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
-
1978
- 1978-01-03 US US05/866,677 patent/US4140513A/en not_active Expired - Lifetime
- 1978-12-27 RO RO78115568A patent/RO89365A/ro unknown
- 1978-12-27 YU YU03101/78A patent/YU310178A/xx unknown
- 1978-12-27 RO RO96069A patent/RO79038B/ro unknown
- 1978-12-28 ZA ZA00787349A patent/ZA787349B/xx unknown
- 1978-12-28 JP JP16599778A patent/JPS54109921A/ja active Granted
- 1978-12-28 CH CH1325478A patent/CH641187A5/de not_active IP Right Cessation
- 1978-12-29 BE BE192664A patent/BE873199A/xx not_active IP Right Cessation
- 1978-12-29 NL NL7812635A patent/NL7812635A/xx unknown
- 1978-12-29 ES ES476485A patent/ES476485A1/es not_active Expired
-
1979
- 1979-01-02 BG BG043569A patent/BG40656A3/xx unknown
- 1979-01-02 BR BR7900007A patent/BR7900007A/pt unknown
- 1979-01-02 DD DD79210300A patent/DD140968A5/de not_active IP Right Cessation
- 1979-01-02 PH PH22009A patent/PH19009A/en unknown
- 1979-01-02 AT AT0001179A patent/AT363274B/de not_active IP Right Cessation
- 1979-01-02 FI FI790006A patent/FI65437C/fi not_active IP Right Cessation
- 1979-01-02 CA CA000318977A patent/CA1120951A/en not_active Expired
- 1979-01-02 CS CS7957A patent/CS207728B2/cs unknown
- 1979-01-02 DE DE2900025A patent/DE2900025C2/de not_active Expired
- 1979-01-02 IE IE10/79A patent/IE47773B1/en unknown
- 1979-01-02 IL IL56356A patent/IL56356A/xx unknown
- 1979-01-02 GB GB7933A patent/GB2011906B/en not_active Expired
- 1979-01-02 ZM ZM2/79A patent/ZM279A1/xx unknown
- 1979-01-02 BG BG041935A patent/BG29424A3/xx unknown
- 1979-01-02 EG EG6/79A patent/EG13903A/xx active
- 1979-01-02 HU HU79MO1033A patent/HU184659B/hu not_active IP Right Cessation
- 1979-01-02 IN IN3/CAL/79A patent/IN150741B/en unknown
- 1979-01-02 PL PL1979212563A patent/PL114405B1/pl unknown
- 1979-01-02 AU AU43047/79A patent/AU522518B2/en not_active Ceased
- 1979-01-02 MW MW1/79A patent/MW179A1/xx unknown
- 1979-01-02 SE SE7900016A patent/SE444685B/sv not_active IP Right Cessation
- 1979-01-02 NO NO790009A patent/NO150841C/no unknown
- 1979-01-02 FR FR7900052A patent/FR2413398A1/fr active Granted
- 1979-01-02 DK DK000979A patent/DK158356C/da not_active IP Right Cessation
- 1979-01-02 PL PL1979223647A patent/PL119534B1/pl unknown
- 1979-01-02 IT IT19009/79A patent/IT1162701B/it active
- 1979-01-02 PT PT69016A patent/PT69016A/pt unknown
- 1979-01-02 AR AR275038A patent/AR221857A1/es active
- 1979-01-03 MX MX797623U patent/MX5697E/es unknown
-
1980
- 1980-02-08 SU SU802877858A patent/SU1050565A3/ru active
-
1983
- 1983-08-29 SG SG548/83A patent/SG54883G/en unknown
- 1983-10-27 KE KE3342A patent/KE3342A/xx unknown
-
1984
- 1984-01-05 HK HK6/84A patent/HK684A/xx unknown
- 1984-12-30 MY MY322/84A patent/MY8400322A/xx unknown
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