SG43676A1 - Process for the production of acetic acid - Google Patents

Process for the production of acetic acid

Info

Publication number
SG43676A1
SG43676A1 SG1995001784A SG1995001784A SG43676A1 SG 43676 A1 SG43676 A1 SG 43676A1 SG 1995001784 A SG1995001784 A SG 1995001784A SG 1995001784 A SG1995001784 A SG 1995001784A SG 43676 A1 SG43676 A1 SG 43676A1
Authority
SG
Singapore
Prior art keywords
production
acetic acid
acetic
acid
Prior art date
Application number
SG1995001784A
Other languages
English (en)
Inventor
Carl Sherman Garland
Martin Francis Giles
John Glenn Sunley
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26303500&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=SG43676(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GB939318809A external-priority patent/GB9318809D0/en
Priority claimed from GB9408966A external-priority patent/GB9408966D0/en
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of SG43676A1 publication Critical patent/SG43676A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231Halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08Acetic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/825Osmium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20Carbonyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/28Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
SG1995001784A 1993-09-10 1994-09-01 Process for the production of acetic acid SG43676A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB939318809A GB9318809D0 (en) 1993-09-10 1993-09-10 Process
GB9408966A GB9408966D0 (en) 1994-05-05 1994-05-05 Process

Publications (1)

Publication Number Publication Date
SG43676A1 true SG43676A1 (en) 1997-11-14

Family

ID=26303500

Family Applications (1)

Application Number Title Priority Date Filing Date
SG1995001784A SG43676A1 (en) 1993-09-10 1994-09-01 Process for the production of acetic acid

Country Status (19)

Country Link
US (2) US5672743A (sh)
EP (1) EP0643034B1 (sh)
JP (2) JP4195103B2 (sh)
KR (1) KR100337066B1 (sh)
CN (2) CN1041915C (sh)
BR (1) BR9403499A (sh)
CA (1) CA2117569C (sh)
DE (1) DE69410557T2 (sh)
ES (1) ES2116539T3 (sh)
FI (1) FI944164A (sh)
IN (1) IN187227B (sh)
MY (1) MY121194A (sh)
NO (1) NO301708B1 (sh)
NZ (1) NZ264419A (sh)
RU (1) RU2132840C1 (sh)
SG (1) SG43676A1 (sh)
TW (1) TW252105B (sh)
UA (1) UA26345C2 (sh)
YU (1) YU49260B (sh)

Families Citing this family (110)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
GB9503385D0 (en) 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
GB9503382D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
GB9504708D0 (en) * 1995-03-08 1995-04-26 Bp Chem Int Ltd Process
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9521501D0 (en) * 1995-10-20 1995-12-20 Bp Chem Int Ltd Process
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US5831120A (en) * 1996-11-19 1998-11-03 Watson; Derrick John Process for the production of acetic acid
GB9625335D0 (en) * 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626324D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9825424D0 (en) * 1998-11-19 1999-01-13 Bp Chem Int Ltd Process
US6274096B1 (en) 1999-11-01 2001-08-14 Acetex (Cyprus) Limited Methanol plant retrofit
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
GB9926854D0 (en) * 1999-11-12 2000-01-12 Bp Chem Int Ltd Process
GB9926855D0 (en) * 1999-11-12 2000-01-12 Bp Chem Int Ltd Process
US6458995B1 (en) 2000-03-31 2002-10-01 Celanese International Corporation Catalytic composition for carbonylation including iridium and pyridine polymers
US6235673B1 (en) * 2000-04-05 2001-05-22 Eastman Chemical Company Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer
US6627770B1 (en) 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6531630B2 (en) 2000-12-29 2003-03-11 Kenneth Ebenes Vidalin Bimodal acetic acid manufacture
US6599348B2 (en) 2001-06-01 2003-07-29 Celanese International Corporation Methods for reducing entrainment of solids and liquids
GB0211560D0 (en) * 2002-05-20 2002-06-26 Bp Chem Int Ltd Process
GB0212974D0 (en) * 2002-06-06 2002-07-17 Bp Chem Int Ltd Process
GB0221800D0 (en) 2002-09-19 2002-10-30 Bp Chem Int Ltd Process
GB0316756D0 (en) * 2003-07-17 2003-08-20 Bp Chem Int Ltd Process
US6846951B1 (en) 2003-10-09 2005-01-25 Acetex (Cyprus) Limited Integrated process for acetic acid and methanol
MY146697A (en) 2004-07-09 2012-09-14 Acetex Cyprus Ltd Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock
US7053241B1 (en) 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
CN1978055B (zh) * 2005-12-08 2010-05-05 中国科学院化学研究所 一种羰基合成催化体系及应用
GB0601861D0 (en) * 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
TWI465424B (zh) 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
US7902398B2 (en) 2007-04-25 2011-03-08 Celanese International Corporation Method and apparatus for carbonylation with reduced catalyst loss
US7989659B2 (en) 2007-05-17 2011-08-02 Celanese International Corporation Method and apparatus for making acetic acid with improved light ends column productivity
US7902397B2 (en) * 2007-10-11 2011-03-08 Celanese International Corporation Method and apparatus for making acetic acid with improved productivity
US8062482B2 (en) * 2007-10-30 2011-11-22 Celanese International Corporation Acetaldehyde removal from methyl acetate by distillation at elevated pressure
EP2093209A1 (en) 2008-02-19 2009-08-26 BP Chemicals Limited Process for the production of acetic acid
US7820855B2 (en) 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
MY175851A (en) * 2008-04-29 2020-07-13 Celanese Int Corp Methanol carbonylation system having absorber with multiple solvent options
US7790920B2 (en) * 2008-09-11 2010-09-07 Lyondell Chemical Technology, L.P. Preparation of acetic acid
US7884237B2 (en) * 2008-11-07 2011-02-08 Celanese International Corp. Methanol carbonylation with improved aldehyde removal
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
US8076508B2 (en) * 2008-12-08 2011-12-13 Lyondell Chemical Technology Preparation of acetic acid
US8455685B2 (en) * 2009-07-07 2013-06-04 Celanese International Corporation Acetic anhydride production by way of carbonylation with enhanced reaction and flashing
US8168822B2 (en) 2009-07-07 2012-05-01 Celanese International Corporation Acetic acid production by way of carbonylation with enhanced reaction and flashing
CN101722047B (zh) * 2009-11-27 2013-07-10 中国科学院化学研究所 甲醇羰基合成醋酸的均相铱配合物催化剂及其制备方法和应用
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
WO2012039841A1 (en) 2010-02-02 2012-03-29 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8378141B2 (en) 2010-08-16 2013-02-19 Celanese International Corporation Process and system for supplying vapor from drying column to light ends column
US8530696B2 (en) 2010-09-24 2013-09-10 Celanese International Corporation Pump around reactor for production of acetic acid
US8877963B2 (en) 2010-09-28 2014-11-04 Celanese International Corporation Production of acetic acid with high conversion rate
US8394988B2 (en) 2010-09-28 2013-03-12 Celanese International Corporation Production of acetic acid with high conversion rate
US8461379B2 (en) 2010-10-12 2013-06-11 Celanese International Corporation Production of acetic acid comprising feeding at least one reactant to a recycle stream
TWI527793B (zh) 2010-10-13 2016-04-01 瑟蘭斯國際股份有限公司 回收鹵素促進劑和移除過錳酸鹽還原化合物的製程
US8637698B2 (en) 2010-11-19 2014-01-28 Celanese International Corporation Production of acetic acid with an increased production rate
US8563773B2 (en) 2010-12-16 2013-10-22 Celanese International Corporation Eductor-based reactor and pump around loops for production of acetic acid
SG191374A1 (en) 2010-12-30 2013-08-30 Celanese Int Corp Purification of acetic acid product streams
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
WO2012149137A1 (en) 2011-04-26 2012-11-01 Celanese International Corporation Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
CN103080053B (zh) 2011-04-26 2015-08-12 国际人造丝公司 使用叠置床反应器生产乙醇的方法
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US8697908B2 (en) 2011-05-05 2014-04-15 Celanese International Corporation Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants
US8952196B2 (en) 2011-05-05 2015-02-10 Celanese International Corporation Removal of aromatics from carbonylation process
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US9663437B2 (en) 2011-09-13 2017-05-30 Celanese International Corporation Production of acetic acid with high conversion rate
CN103086868B (zh) * 2011-11-02 2015-06-17 中国石油化工股份有限公司 一种羰基化反应制备乙酸的方法
CN103084214B (zh) * 2011-11-02 2014-11-05 中国石油化工股份有限公司 一种铱催化剂体系
WO2013070210A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol having flashing to recover acid production catalyst
US8686201B2 (en) 2011-11-09 2014-04-01 Celanese International Corporation Integrated acid and alcohol production process having flashing to recover acid production catalyst
WO2013070209A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol
US8614359B2 (en) 2011-11-09 2013-12-24 Celanese International Corporation Integrated acid and alcohol production process
US8748673B2 (en) 2011-11-18 2014-06-10 Celanese International Corporation Process of recovery of ethanol from hydrogenolysis process
US20130131400A1 (en) 2011-11-22 2013-05-23 Celanese International Corporation Hydrogenating Acetic Acid to Produce Ethyl Acetate and Reducing Ethyl Acetate to Ethanol
EP2782890A1 (en) 2011-11-22 2014-10-01 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
US9029614B2 (en) 2011-12-14 2015-05-12 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
US9421522B2 (en) 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation
WO2013101304A1 (en) 2011-12-29 2013-07-04 Celanese International Corporation Process for producing ethanol from impure methanol
WO2013119275A1 (en) 2012-02-08 2013-08-15 Celanese International Corporation Production of acetic acid from methanol
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof
US8802903B2 (en) 2012-03-13 2014-08-12 Celanese International Corporation Stacked bed reactor with diluents for producing ethanol
US8859810B2 (en) 2012-08-21 2014-10-14 Celanese International Corporation Process for recovering permanganate reducing compounds from an acetic acid production process
CN103721751B (zh) * 2012-10-11 2016-08-10 中国石油化工股份有限公司 一种羰基化制乙酸用催化剂
WO2014143840A2 (en) 2013-03-15 2014-09-18 Celanese International Corporation Process for separating product gas using carbonylation processes
US9505691B2 (en) 2014-10-02 2016-11-29 Celanese International Corporation Process for producing acetic acid
US9260369B1 (en) 2014-11-14 2016-02-16 Celanese International Corporation Processes for producing acetic acid product having low butyl acetate content
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US9302975B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for flashing a reaction medium
KR101667223B1 (ko) 2014-12-29 2016-10-18 한국화학연구원 카보닐화 반응에 의한 초산 제조용 Rh/WxC 불균일 촉매
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US9487464B2 (en) 2015-01-30 2016-11-08 Celanese International Corporation Processes for producing acetic acid
US9561994B2 (en) 2015-01-30 2017-02-07 Celanese International Corporation Processes for producing acetic acid
US9505696B2 (en) 2015-02-04 2016-11-29 Celanese International Corporation Process to control HI concentration in residuum stream
US9382183B1 (en) 2015-07-01 2016-07-05 Celanese International Corporation Process for flashing a reaction medium
US9302974B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for producing acetic acid
WO2017058264A1 (en) 2015-10-02 2017-04-06 Celanese International Corporation Process to produce acetic acid with recycle of water
US9908835B2 (en) 2015-11-13 2018-03-06 Celanese International Corporation Processes for purifying acetic and hydrating anhydride
US9957216B2 (en) 2015-11-13 2018-05-01 Celanese International Corporation Processes for producing acetic acid
JP2023528451A (ja) 2020-06-03 2023-07-04 セラニーズ・インターナショナル・コーポレーション 酢酸の製造及び精製

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA837644A (en) * 1970-03-24 E. Paulik Frank Production of carboxylic acids and esters
CA837646A (en) * 1970-03-24 E. Paulik Frank Production of carboxylic acids and esters
US3285948A (en) * 1965-01-22 1966-11-15 Commercial Solvents Corp Halides of ruthenium and osmium in conjunction with cobalt and iodine in the production of ethanol from methanol
SE364254B (sh) * 1967-04-05 1974-02-18 Monsanto Co
DE1941449C3 (de) * 1968-08-15 1979-07-26 Monsanto Co., St. Louis, Mo. (V.St.A.) Verfahren zur Herstellung von Monocarbonsäuren
US3813428A (en) * 1968-08-15 1974-05-28 Monsanto Co Production of monocarboxylic acids
DE1941448A1 (de) * 1968-08-15 1970-04-23 Monsanto Co Verfahren zur Herstellung von Dicarbonsaeuren
US3772380A (en) * 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US3852346A (en) * 1972-12-26 1974-12-03 Monsanto Co Production of carboxylic acid anhydrides
DE2303271C3 (de) * 1973-01-24 1975-06-26 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Essigsäure oder deren Gemischen mit Methylacetat
US4029748A (en) * 1974-07-29 1977-06-14 Monsanto Company Iridium carbonyl complexes
DE2450965C2 (de) * 1974-10-26 1983-06-09 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Essigsäureanhydrid
US4102921A (en) * 1977-04-26 1978-07-25 Air Products & Chemicals, Inc. Production of carboxylic acids and esters
US4101450A (en) * 1977-05-09 1978-07-18 Celanese Corporation Catalyst for production of acetic acid
DE2836084A1 (de) * 1978-08-17 1980-03-06 Hoechst Ag Verfahren zur herstellung von essigsaeureanhydrid
JPS5538369A (en) * 1978-09-01 1980-03-17 Texaco Development Corp Manufacture of carboxylic acids and their esters
DE2939839A1 (de) * 1979-10-02 1981-04-23 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von essigsaeureanhydrid
JPS5683439A (en) * 1979-12-13 1981-07-08 Mitsubishi Gas Chem Co Inc Preparation of acetic acid
FR2471965A1 (fr) * 1979-12-21 1981-06-26 Rhone Poulenc Ind Procede de preparation de carboxylates d'alkyles a partir de leurs homologues inferieurs
EP0031606B1 (en) * 1979-12-21 1983-08-24 Shell Internationale Researchmaatschappij B.V. Process for the co-production of carboxylic acids and carboxylic acid esters
DE3164293D1 (en) * 1980-06-19 1984-07-26 Shell Int Research Process for the carbonylation of alkanols and/or ethers
US4476237A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
FR2507597B1 (fr) * 1981-06-12 1985-12-13 Rhone Poulenc Chim Base Procede de carbonylation de l'acetate de methyle
EP0072055B1 (en) * 1981-08-06 1985-05-02 Shell Internationale Researchmaatschappij B.V. Process for the co-production of carboxylic acids and carboxylic acid esters
EP0075335B1 (en) * 1981-09-22 1985-10-23 Shell Internationale Researchmaatschappij B.V. Process for the co-production of carboxylic acids and carboxylic acid esters
JPS5865238A (ja) * 1981-09-22 1983-04-18 シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ カルボン酸とカルボン酸エステルの同時製造法
EP0075337B1 (en) * 1981-09-22 1985-10-23 Shell Internationale Researchmaatschappij B.V. Process for the co-production of carboxylic acids and carboxylic acid esters
JPS6017773B2 (ja) * 1982-04-02 1985-05-07 工業技術院長 含酸素化合物の製造方法
US4640802A (en) * 1981-12-10 1987-02-03 Shell Oil Company Process for the co-production of carboxylic acids and carboxylic acid esters
CA1194033A (en) * 1981-12-10 1985-09-24 Eit Drent Process for the co-production of carboxylic acids and carboxylic acid esters
US4664851A (en) * 1981-12-30 1987-05-12 Shell Oil Company Process for the co-production of carboxylic acids and carboxylic acid esters
US4484002A (en) * 1982-01-13 1984-11-20 Texaco Inc. Process for producing methyl acetate from methanol and carbon monoxide using a novel catalyst system
JPS58152727A (ja) * 1982-03-08 1983-09-10 Fuji Xerox Co Ltd カセツト式給紙装置
JPS5950653B2 (ja) * 1982-03-30 1984-12-10 工業技術院長 エチレングリコ−ルの製造方法
DE3377125D1 (en) * 1982-03-30 1988-07-28 Shell Int Research A process for carbonylating methanol to acetic acid and/or methyl acetate
US4514336A (en) * 1982-05-28 1985-04-30 Shell Oil Company Homologous carboxylic acids production
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
US4661623A (en) * 1983-02-16 1987-04-28 Ashland Oil, Inc. Method of producing methyl formate from methanol and carbon monoxide using anionic group VIII metal cataysts
EP0120631B1 (en) * 1983-03-25 1987-04-22 Texaco Development Corporation A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst
CA1234147A (en) * 1983-07-06 1988-03-15 Eit Drent Process for the preparation of ethanol and/or ethyl acetate
US4629809A (en) * 1983-07-21 1986-12-16 Texaco Inc. Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system
US4519956A (en) * 1983-07-21 1985-05-28 Texaco Inc. Process for selectively preparing acetic anhydride by carbonylation of methyl acetate in the presence of an iodide-free catalyst system
JPS6032724A (ja) * 1983-08-03 1985-02-19 Agency Of Ind Science & Technol 含酸素化合物の製造方法
JPS6032726A (ja) * 1983-08-03 1985-02-19 Agency Of Ind Science & Technol 含酸素化合物を製造する方法
GB8406126D0 (en) * 1984-03-08 1984-04-11 Bp Chem Int Ltd Esters
JPS60199841A (ja) * 1984-03-22 1985-10-09 Agency Of Ind Science & Technol C↓2含酸素化合物の製造方法
JPS60255741A (ja) * 1984-05-31 1985-12-17 Agency Of Ind Science & Technol 含酸素化合物を製造する方法
DE3429179A1 (de) * 1984-08-08 1986-02-20 Hoechst Ag, 6230 Frankfurt Verfahren zur gemeinsamen herstellung von carbonsaeuren und carbonsaeureanhydriden sowie ggf. carbonsaeureestern
DE3429180A1 (de) * 1984-08-08 1986-02-20 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von essigsaeureanhydrid und ggf. essigsaeure
US4588834A (en) * 1984-10-04 1986-05-13 Texaco Inc. Process for carbonylation of olefins to carboxylic acids and esters
DE3511050A1 (de) * 1985-03-27 1986-10-02 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von monocarbonsaeureanhydriden
JPS62135445A (ja) * 1985-12-09 1987-06-18 Idemitsu Kosan Co Ltd カルボン酸無水物の製造方法
GB8618710D0 (en) * 1986-07-31 1986-09-10 Bp Chem Int Ltd Recovering metals
DE3823645C1 (sh) * 1988-07-13 1989-11-30 Hoechst Ag
GB8904125D0 (en) * 1989-02-23 1989-04-05 British Petroleum Co Plc Process for preparing carboxylic acids
JPH03197441A (ja) * 1989-12-26 1991-08-28 Sagami Chem Res Center カルボン酸類の製造方法
JPH0446139A (ja) * 1990-05-15 1992-02-17 Sagami Chem Res Center カルボン酸類を製造する方法
FR2670779A1 (fr) * 1990-12-20 1992-06-26 Rhone Poulenc Chimie Procede de preparation de l'acide adipique par hydrocarboxylation d'acides penteniques.
GB9218346D0 (en) * 1992-08-28 1992-10-14 Bp Chem Int Ltd Process
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
FR2703351A1 (fr) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium.

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JP4195103B2 (ja) 2008-12-10
TW252105B (sh) 1995-07-21
FI944164A0 (fi) 1994-09-09
JPH07165664A (ja) 1995-06-27
BR9403499A (pt) 1995-05-16
CA2117569C (en) 2003-12-30
RU2132840C1 (ru) 1999-07-10
YU53394A (sh) 1996-10-18
ES2116539T3 (es) 1998-07-16
CN1107460A (zh) 1995-08-30
DE69410557D1 (de) 1998-07-02
KR950008463A (ko) 1995-04-17
NO943318D0 (no) 1994-09-08
US5942460A (en) 1999-08-24
NO943318L (no) 1995-03-13
YU49260B (sh) 2004-12-31
EP0643034B1 (en) 1998-05-27
US5672743A (en) 1997-09-30
FI944164A (fi) 1995-03-11
KR100337066B1 (ko) 2002-11-30
CN1092541C (zh) 2002-10-16
CN1210760A (zh) 1999-03-17
RU94033107A (ru) 1996-07-20
NO301708B1 (no) 1997-12-01
JP2008110990A (ja) 2008-05-15
MY121194A (en) 2006-01-28
NZ264419A (en) 1995-03-28
IN187227B (sh) 2002-03-02
EP0643034A1 (en) 1995-03-15
UA26345C2 (uk) 1999-08-30
CA2117569A1 (en) 1995-03-11
DE69410557T2 (de) 1998-09-17
CN1041915C (zh) 1999-02-03

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