RU2700052C2 - Способ получения молекулярного сита - Google Patents

Способ получения молекулярного сита Download PDF

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RU2700052C2
RU2700052C2 RU2017125266A RU2017125266A RU2700052C2 RU 2700052 C2 RU2700052 C2 RU 2700052C2 RU 2017125266 A RU2017125266 A RU 2017125266A RU 2017125266 A RU2017125266 A RU 2017125266A RU 2700052 C2 RU2700052 C2 RU 2700052C2
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mordenite
sio
surface area
zeolite
crystals
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RU2017125266A
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Russian (ru)
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RU2017125266A3 (enExample
RU2017125266A (ru
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Вэньи Ф. ЛАЙ
Николас С. РОЛЛМЕН
Гуан Као
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Эксонмобил Кемикэл Пейтентс Инк.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2836692C1 (ru) * 2020-04-28 2025-03-19 Чайна Петролеум Энд Кемикал Корпорейшн Катализатор гидрирования и способ его получения и применение
US12502654B2 (en) 2020-04-28 2025-12-23 China Petroleum & Chemical Corporation Hydrogenation catalyst and preparation method therefor and use thereof

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104276586B (zh) * 2013-07-03 2016-10-05 中国石油大学(北京) 一种丝光沸石的制备方法
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
SG10202010226SA (en) * 2015-02-04 2020-11-27 Exxonmobil Chemical Patents Inc Process for preparing a molecular sieve
WO2018071184A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and catalyst compositions used
WO2018071185A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and dual bed catalyst systems used
WO2018103089A1 (zh) * 2016-12-09 2018-06-14 中国科学院大连化学物理研究所 合成丝光沸石mor分子筛的方法、及其产品和应用
WO2018134441A1 (en) * 2017-01-23 2018-07-26 Compañ̃Ía Española De Petróleos S.A.U. (Cepsa) Preparation method for core-shell catalysts used in linear alkane hydroisomerisation
WO2018140149A1 (en) 2017-01-25 2018-08-02 Exxonmobil Chemical Patents Inc. Transalkylation process and catalyst composition used therein
WO2018160327A1 (en) 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
CN110337328B (zh) * 2017-02-28 2022-05-06 埃克森美孚化学专利公司 催化剂组合物及其用于芳族化合物烷基化方法的用途
WO2018183009A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
WO2018183012A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
JP7076529B2 (ja) * 2017-07-27 2022-05-27 エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー 小結晶emm-17、その製造及び使用方法
US11866325B2 (en) 2018-05-16 2024-01-09 University Of Houston System Synthesis of mordenite using multiple organics
WO2020022868A1 (ko) * 2018-07-27 2020-01-30 에스케이이노베이션 주식회사 입자 균일도가 우수한 모데나이트 제올라이트 및 그 제조방법
CN112512972A (zh) * 2018-07-27 2021-03-16 Sk新技术株式会社 颗粒均匀度优异的丝光沸石及其制造方法
KR101994765B1 (ko) 2018-09-21 2019-07-01 에스케이이노베이션 주식회사 계층화된 제올라이트 및 이의 제조방법
KR102020445B1 (ko) * 2018-09-21 2019-09-10 에스케이이노베이션 주식회사 입자 크기의 제어가 가능한 모데나이트 제올라이트의 제조방법
US11701645B2 (en) * 2018-10-30 2023-07-18 Exxonmobil Chemical Patents Inc. Calcination of microporous molecular sieve catalysts
WO2020205444A1 (en) 2019-03-29 2020-10-08 Exxonmobil Chemical Patents Inc. Catalysts and processes for converting aromatics
TWI749489B (zh) 2019-03-29 2021-12-11 美商艾克頌美孚化學專利股份有限公司 用於轉化芳族化合物之觸媒及方法
WO2021076259A1 (en) 2019-10-17 2021-04-22 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
CN112850743B (zh) * 2019-11-26 2023-01-13 中国科学院大连化学物理研究所 一种调控丝光沸石分子筛形貌的绿色合成方法
WO2021163021A1 (en) * 2020-02-12 2021-08-19 University Of Houston System Synthesis of finned zeolite crystals
WO2021211240A1 (en) * 2020-04-17 2021-10-21 Exxonmobil Chemical Patents Inc. Processes for converting c8 aromatic hydrocarbons
KR20220091672A (ko) * 2020-12-23 2022-07-01 대주전자재료 주식회사 다공성 규소 구조체, 이를 포함하는 다공성 규소-탄소 복합체 및 음극 활물질
US11590481B2 (en) 2021-06-17 2023-02-28 Exxonmobil Technology & Engineering Company Heteroatom-doped zeolites for bifunctional catalytic applications
CN113751056B (zh) * 2021-10-15 2022-07-26 河南大学 用于催化烃类裂解制取丙烯的分子筛催化剂及其制备方法和用途
CN116588949B (zh) * 2023-04-20 2025-08-22 延长中科(大连)能源科技股份有限公司 一种高硅丝光沸石分子筛的制备方法及其应用
CN116621191A (zh) * 2023-06-02 2023-08-22 深圳鼎诚环境科学有限公司 用于去除VOCs中苯系物的分子筛吸附剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000006492A1 (en) * 1998-07-29 2000-02-10 Exxon Chemical Patents, Inc. Molecular sieves and processes for their manufacture
RU2160228C1 (ru) * 1999-04-30 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Способ получения цеолита типа морденит
RU2515729C2 (ru) * 2008-10-13 2014-05-20 Бп Кемикэлз Лимитед Селективное деалюминирование цеолитов структурного типа морденита
WO2014135662A1 (en) * 2013-03-08 2014-09-12 Bp Chemicals Limited Carbonylation process

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3551353A (en) * 1968-10-04 1970-12-29 Mobil Oil Corp Dealuminzation of mordenite
US4536486A (en) 1983-03-31 1985-08-20 Texaco Inc. Process for dewaxing with mordenite
FR2637200B1 (fr) 1988-10-05 1991-01-04 Inst Francais Du Petrole Catalyseur a base de mordenite renfermant au moins un metal du groupe viii et son utilisation en isomerisation d'une coupe c8 aromatique
US5234872A (en) * 1992-05-11 1993-08-10 Mobil Oil Corp. Method for producing zeolites with reduced surface acidity
US5238677A (en) * 1992-06-15 1993-08-24 Mobil Oil Corp. Process for the dealumination of mordenite
CN1088049C (zh) * 1996-05-29 2002-07-24 埃克森美孚化学专利公司 芳烃转化方法和适用的沸石催化剂
US6060417A (en) 1996-06-28 2000-05-09 Toray Industries, Inc. Catalyst composition for transalkylation of alkylaromatic hydrocarbons and process for production of xylene
FR2761904B1 (fr) 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
FR2772751B1 (fr) 1997-12-22 2000-04-14 Inst Francais Du Petrole Catalyseur a base de mordenite contenant au moins un metal du groupe viii et au moins un metal des groupes iii et iv et son utilisation en isomerisation d'une coupe c8 aromatique
US6867340B2 (en) 1998-12-24 2005-03-15 Sk Corporation Disproportionation/transalkylation of aromatic hydrocarbons
US6984764B1 (en) * 1999-05-04 2006-01-10 Exxonmobil Oil Corporation Alkylaromatics production
JP4506908B2 (ja) * 1999-08-03 2010-07-21 三菱瓦斯化学株式会社 メチルアミン製造触媒
US6936744B1 (en) * 2000-07-19 2005-08-30 Exxonmobil Chemical Patents, Inc. Alkylaromatics production
JP4120172B2 (ja) 2001-02-28 2008-07-16 東レ株式会社 モルデナイト構造を有するゼオライト、モルデナイト構造を有するゼオライトの製造方法、芳香族化合物転化用触媒組成物および転化方法
US6504076B1 (en) 2001-05-18 2003-01-07 Fina Technology, Inc. Method of conversion of heavy aromatics
US6815570B1 (en) 2002-05-07 2004-11-09 Uop Llc Shaped catalysts for transalkylation of aromatics for enhanced xylenes production
US7148391B1 (en) 2002-11-14 2006-12-12 Exxonmobil Chemical Patents Inc. Heavy aromatics processing
JP4882202B2 (ja) * 2004-02-09 2012-02-22 東ソー株式会社 高シリカモルデナイトの合成方法
US6972348B2 (en) 2004-03-24 2005-12-06 Uop Llc Catalytic conversion of polycyclic aromatics into xylenes
ES2327753T3 (es) 2004-04-14 2009-11-03 Institut Francais Du Petrole Catalizador que comprende un zaolita 10mr y una zeolita 12mr y su utilizacion en un procedimiento de transalquilacion de hidrocarburos alquilaromaticos.
US7273828B1 (en) 2004-05-27 2007-09-25 Uop Llc Catalyst treatment useful for aromatics conversion process
US7154014B1 (en) 2004-09-22 2006-12-26 Uop Llc Alumina guard bed for aromatics transalkylation process
CN1666956A (zh) * 2005-02-04 2005-09-14 华东理工大学 一种纳米尺寸丝光沸石合成方法
CN101519217B (zh) * 2008-02-28 2011-01-19 中国石油化工股份有限公司石油化工科学研究院 一种小晶粒丝光沸石的制备方法
US7687423B2 (en) 2008-06-26 2010-03-30 Uop Llc Selective catalyst for aromatics conversion
US7626064B1 (en) 2008-06-26 2009-12-01 Uop Llc Transalkylation process
KR20110121474A (ko) * 2010-04-30 2011-11-07 인하대학교 산학협력단 계층적 메조세공 무기 재료 및 그의 제조 방법
JP5351216B2 (ja) * 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
CN102530984A (zh) * 2010-12-30 2012-07-04 中国石油化工股份有限公司 改性丝光沸石、其制备方法及其应用
JP5657458B2 (ja) 2011-04-04 2015-01-21 日本化学工業株式会社 薄片状の結晶形状を有するモルデナイト型ゼオライトおよびその製造方法
JP6084829B2 (ja) * 2012-11-29 2017-02-22 株式会社Ihi 放射性物質収着剤の製造方法
CN103482645B (zh) * 2013-09-22 2015-07-08 华东师范大学 一种多级孔纳米丝光沸石分子筛的制备方法
SG10202010226SA (en) * 2015-02-04 2020-11-27 Exxonmobil Chemical Patents Inc Process for preparing a molecular sieve
US10118165B2 (en) * 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000006492A1 (en) * 1998-07-29 2000-02-10 Exxon Chemical Patents, Inc. Molecular sieves and processes for their manufacture
RU2160228C1 (ru) * 1999-04-30 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Способ получения цеолита типа морденит
RU2515729C2 (ru) * 2008-10-13 2014-05-20 Бп Кемикэлз Лимитед Селективное деалюминирование цеолитов структурного типа морденита
WO2014135662A1 (en) * 2013-03-08 2014-09-12 Bp Chemicals Limited Carbonylation process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2836692C1 (ru) * 2020-04-28 2025-03-19 Чайна Петролеум Энд Кемикал Корпорейшн Катализатор гидрирования и способ его получения и применение
US12502654B2 (en) 2020-04-28 2025-12-23 China Petroleum & Chemical Corporation Hydrogenation catalyst and preparation method therefor and use thereof

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