CA2983038C - Process for preparing a molecular sieve - Google Patents

Process for preparing a molecular sieve Download PDF

Info

Publication number
CA2983038C
CA2983038C CA2983038A CA2983038A CA2983038C CA 2983038 C CA2983038 C CA 2983038C CA 2983038 A CA2983038 A CA 2983038A CA 2983038 A CA2983038 A CA 2983038A CA 2983038 C CA2983038 C CA 2983038C
Authority
CA
Canada
Prior art keywords
mordenite
mordenite zeolite
sio2
zeolite
surface area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2983038A
Other languages
English (en)
French (fr)
Other versions
CA2983038A1 (en
Inventor
Wenyih F. Lai
Nicholas S. Rollman
Guang Cao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CA2983038A1 publication Critical patent/CA2983038A1/en
Application granted granted Critical
Publication of CA2983038C publication Critical patent/CA2983038C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26—Mordenite type
    • C01B39/265—Mordenite type using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26—Mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/22—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/01—Crystal-structural characteristics depicted by a TEM-image
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C07C2529/22—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CA2983038A 2015-02-04 2016-01-21 Process for preparing a molecular sieve Active CA2983038C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562111730P 2015-02-04 2015-02-04
US62/111,730 2015-02-04
EP15160258.8 2015-03-23
EP15160258 2015-03-23
PCT/US2016/014264 WO2016126431A1 (en) 2015-02-04 2016-01-21 Process for preparing a molecular sieve

Publications (2)

Publication Number Publication Date
CA2983038A1 CA2983038A1 (en) 2016-08-11
CA2983038C true CA2983038C (en) 2023-01-31

Family

ID=55524427

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2983038A Active CA2983038C (en) 2015-02-04 2016-01-21 Process for preparing a molecular sieve

Country Status (11)

Country Link
US (2) US10017394B2 (enExample)
EP (1) EP3253713B1 (enExample)
JP (1) JP6724020B2 (enExample)
KR (1) KR102527695B1 (enExample)
CN (1) CN107207269B (enExample)
CA (1) CA2983038C (enExample)
ES (1) ES2750826T3 (enExample)
RU (1) RU2700052C2 (enExample)
SG (2) SG10202010226SA (enExample)
WO (1) WO2016126431A1 (enExample)
ZA (1) ZA201704548B (enExample)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104276586B (zh) * 2013-07-03 2016-10-05 中国石油大学(北京) 一种丝光沸石的制备方法
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
SG10202010226SA (en) * 2015-02-04 2020-11-27 Exxonmobil Chemical Patents Inc Process for preparing a molecular sieve
WO2018071184A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and catalyst compositions used
WO2018071185A1 (en) 2016-10-10 2018-04-19 Exxonmobil Chemical Patents Inc. Heavy aromatics to btx conversion process and dual bed catalyst systems used
WO2018103089A1 (zh) * 2016-12-09 2018-06-14 中国科学院大连化学物理研究所 合成丝光沸石mor分子筛的方法、及其产品和应用
WO2018134441A1 (en) * 2017-01-23 2018-07-26 Compañ̃Ía Española De Petróleos S.A.U. (Cepsa) Preparation method for core-shell catalysts used in linear alkane hydroisomerisation
WO2018140149A1 (en) 2017-01-25 2018-08-02 Exxonmobil Chemical Patents Inc. Transalkylation process and catalyst composition used therein
WO2018160327A1 (en) 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
CN110337328B (zh) * 2017-02-28 2022-05-06 埃克森美孚化学专利公司 催化剂组合物及其用于芳族化合物烷基化方法的用途
WO2018183009A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
WO2018183012A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes
JP7076529B2 (ja) * 2017-07-27 2022-05-27 エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー 小結晶ｅｍｍ－１７、その製造及び使用方法
US11866325B2 (en) 2018-05-16 2024-01-09 University Of Houston System Synthesis of mordenite using multiple organics
WO2020022868A1 (ko) * 2018-07-27 2020-01-30 에스케이이노베이션 주식회사 입자 균일도가 우수한 모데나이트 제올라이트 및 그 제조방법
CN112512972A (zh) * 2018-07-27 2021-03-16 Sk新技术株式会社 颗粒均匀度优异的丝光沸石及其制造方法
KR101994765B1 (ko) 2018-09-21 2019-07-01 에스케이이노베이션 주식회사 계층화된 제올라이트 및 이의 제조방법
KR102020445B1 (ko) * 2018-09-21 2019-09-10 에스케이이노베이션 주식회사 입자 크기의 제어가 가능한 모데나이트 제올라이트의 제조방법
US11701645B2 (en) * 2018-10-30 2023-07-18 Exxonmobil Chemical Patents Inc. Calcination of microporous molecular sieve catalysts
WO2020205444A1 (en) 2019-03-29 2020-10-08 Exxonmobil Chemical Patents Inc. Catalysts and processes for converting aromatics
TWI749489B (zh) 2019-03-29 2021-12-11 美商艾克頌美孚化學專利股份有限公司 用於轉化芳族化合物之觸媒及方法
WO2021076259A1 (en) 2019-10-17 2021-04-22 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
CN112850743B (zh) * 2019-11-26 2023-01-13 中国科学院大连化学物理研究所 一种调控丝光沸石分子筛形貌的绿色合成方法
WO2021163021A1 (en) * 2020-02-12 2021-08-19 University Of Houston System Synthesis of finned zeolite crystals
WO2021211240A1 (en) * 2020-04-17 2021-10-21 Exxonmobil Chemical Patents Inc. Processes for converting c8 aromatic hydrocarbons
US12502654B2 (en) 2020-04-28 2025-12-23 China Petroleum & Chemical Corporation Hydrogenation catalyst and preparation method therefor and use thereof
KR20220091672A (ko) * 2020-12-23 2022-07-01 대주전자재료 주식회사 다공성 규소 구조체, 이를 포함하는 다공성 규소-탄소 복합체 및 음극 활물질
US11590481B2 (en) 2021-06-17 2023-02-28 Exxonmobil Technology & Engineering Company Heteroatom-doped zeolites for bifunctional catalytic applications
CN113751056B (zh) * 2021-10-15 2022-07-26 河南大学 用于催化烃类裂解制取丙烯的分子筛催化剂及其制备方法和用途
CN116588949B (zh) * 2023-04-20 2025-08-22 延长中科（大连）能源科技股份有限公司 一种高硅丝光沸石分子筛的制备方法及其应用
CN116621191A (zh) * 2023-06-02 2023-08-22 深圳鼎诚环境科学有限公司 用于去除VOCs中苯系物的分子筛吸附剂及其制备方法

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3551353A (en) * 1968-10-04 1970-12-29 Mobil Oil Corp Dealuminzation of mordenite
US4536486A (en) 1983-03-31 1985-08-20 Texaco Inc. Process for dewaxing with mordenite
FR2637200B1 (fr) 1988-10-05 1991-01-04 Inst Francais Du Petrole Catalyseur a base de mordenite renfermant au moins un metal du groupe viii et son utilisation en isomerisation d'une coupe c8 aromatique
US5234872A (en) * 1992-05-11 1993-08-10 Mobil Oil Corp. Method for producing zeolites with reduced surface acidity
US5238677A (en) * 1992-06-15 1993-08-24 Mobil Oil Corp. Process for the dealumination of mordenite
CN1088049C (zh) * 1996-05-29 2002-07-24 埃克森美孚化学专利公司 芳烃转化方法和适用的沸石催化剂
US6060417A (en) 1996-06-28 2000-05-09 Toray Industries, Inc. Catalyst composition for transalkylation of alkylaromatic hydrocarbons and process for production of xylene
FR2761904B1 (fr) 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
FR2772751B1 (fr) 1997-12-22 2000-04-14 Inst Francais Du Petrole Catalyseur a base de mordenite contenant au moins un metal du groupe viii et au moins un metal des groupes iii et iv et son utilisation en isomerisation d'une coupe c8 aromatique
GB9816508D0 (en) * 1998-07-29 1998-09-23 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture
US6867340B2 (en) 1998-12-24 2005-03-15 Sk Corporation Disproportionation/transalkylation of aromatic hydrocarbons
RU2160228C1 (ru) * 1999-04-30 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Способ получения цеолита типа морденит
US6984764B1 (en) * 1999-05-04 2006-01-10 Exxonmobil Oil Corporation Alkylaromatics production
JP4506908B2 (ja) * 1999-08-03 2010-07-21 三菱瓦斯化学株式会社 メチルアミン製造触媒
US6936744B1 (en) * 2000-07-19 2005-08-30 Exxonmobil Chemical Patents, Inc. Alkylaromatics production
JP4120172B2 (ja) 2001-02-28 2008-07-16 東レ株式会社 モルデナイト構造を有するゼオライト、モルデナイト構造を有するゼオライトの製造方法、芳香族化合物転化用触媒組成物および転化方法
US6504076B1 (en) 2001-05-18 2003-01-07 Fina Technology, Inc. Method of conversion of heavy aromatics
US6815570B1 (en) 2002-05-07 2004-11-09 Uop Llc Shaped catalysts for transalkylation of aromatics for enhanced xylenes production
US7148391B1 (en) 2002-11-14 2006-12-12 Exxonmobil Chemical Patents Inc. Heavy aromatics processing
JP4882202B2 (ja) * 2004-02-09 2012-02-22 東ソー株式会社 高シリカモルデナイトの合成方法
US6972348B2 (en) 2004-03-24 2005-12-06 Uop Llc Catalytic conversion of polycyclic aromatics into xylenes
ES2327753T3 (es) 2004-04-14 2009-11-03 Institut Francais Du Petrole Catalizador que comprende un zaolita 10mr y una zeolita 12mr y su utilizacion en un procedimiento de transalquilacion de hidrocarburos alquilaromaticos.
US7273828B1 (en) 2004-05-27 2007-09-25 Uop Llc Catalyst treatment useful for aromatics conversion process
US7154014B1 (en) 2004-09-22 2006-12-26 Uop Llc Alumina guard bed for aromatics transalkylation process
CN1666956A (zh) * 2005-02-04 2005-09-14 华东理工大学 一种纳米尺寸丝光沸石合成方法
CN101519217B (zh) * 2008-02-28 2011-01-19 中国石油化工股份有限公司石油化工科学研究院 一种小晶粒丝光沸石的制备方法
US7687423B2 (en) 2008-06-26 2010-03-30 Uop Llc Selective catalyst for aromatics conversion
US7626064B1 (en) 2008-06-26 2009-12-01 Uop Llc Transalkylation process
EP2174713A1 (en) * 2008-10-13 2010-04-14 BP Chemicals Limited Dealumination process
KR20110121474A (ko) * 2010-04-30 2011-11-07 인하대학교 산학협력단 계층적 메조세공 무기 재료 및 그의 제조 방법
JP5351216B2 (ja) * 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
CN102530984A (zh) * 2010-12-30 2012-07-04 中国石油化工股份有限公司 改性丝光沸石、其制备方法及其应用
JP5657458B2 (ja) 2011-04-04 2015-01-21 日本化学工業株式会社 薄片状の結晶形状を有するモルデナイト型ゼオライトおよびその製造方法
JP6084829B2 (ja) * 2012-11-29 2017-02-22 株式会社Ihi 放射性物質収着剤の製造方法
TW201441188A (zh) * 2013-03-08 2014-11-01 Bp Chem Int Ltd 羰基化方法（一）
CN103482645B (zh) * 2013-09-22 2015-07-08 华东师范大学 一种多级孔纳米丝光沸石分子筛的制备方法
SG10202010226SA (en) * 2015-02-04 2020-11-27 Exxonmobil Chemical Patents Inc Process for preparing a molecular sieve
US10118165B2 (en) * 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes

Also Published As

Publication number Publication date
US10017394B2 (en) 2018-07-10
ZA201704548B (en) 2018-08-29
JP2018504357A (ja) 2018-02-15
ES2750826T3 (es) 2020-03-27
RU2700052C2 (ru) 2019-09-12
KR102527695B1 (ko) 2023-04-28
EP3253713B1 (en) 2019-07-31
RU2017125266A3 (enExample) 2019-04-11
US10745285B2 (en) 2020-08-18
RU2017125266A (ru) 2019-01-17
US20180265369A1 (en) 2018-09-20
SG11201705830RA (en) 2017-08-30
JP6724020B2 (ja) 2020-07-15
SG10202010226SA (en) 2020-11-27
EP3253713A1 (en) 2017-12-13
CN107207269A (zh) 2017-09-26
CN107207269B (zh) 2019-12-06
US20160221832A1 (en) 2016-08-04
WO2016126431A1 (en) 2016-08-11
KR20170113573A (ko) 2017-10-12
CA2983038A1 (en) 2016-08-11

Similar Documents

Publication Publication Date Title
US10745285B2 (en) Process for preparing a molecular sieve
TWI644863B (zh) 製造分子篩的方法
JP6776363B2 (ja) 小結晶で高表面積のｅｍｍ−３０ゼオライト、それらの合成および使用
JP7085375B2 (ja) テンプレートである１，６－ビス（メチルピペリジニウム）ヘキサンジヒドロキシドの存在下でのｉｚｍ－２ゼオライトの合成方法
CN104379257B (zh) 具有euo骨架类型的结晶分子筛的合成
CN108622915B (zh) 在模板1,6-双(甲基哌啶鎓)己烷二溴化物的存在下合成izm-2沸石的方法
EP2461907B1 (en) Synthesis and use of zsm-12
US20250001404A1 (en) Method of Synthesizing Aluminum-Rich Molecular Sieve of *MRE Framework Type
JP5730390B2 (ja) モレキュラーシーブｓｓｚ−８１を調製する方法
CN110300729B (zh) 分子筛ssz-111、其合成和用途
JP4345910B2 (ja) 人工多孔性結晶質ｍｃｍ−７１，その合成及び用途
CN110248894B (zh) 分子筛ssz-109、其合成和用途
CN101514015B (zh) ZSM-5/β沸石/MCM-23三相共生分子筛及其合成方法
Kovo et al. Composite Zeolitic Material Synthesis And Its Functionality Synergism: A Review

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20201026

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 9TH ANNIV.) - STANDARD

Year of fee payment: 9

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250114

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT

Effective date: 20250114

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250114

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 10TH ANNIV.) - STANDARD

Year of fee payment: 10

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20260113

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20260113