RU2608616C2 - Каталитическая композиция и способ применения в селективном каталитическом восстановлении оксидов азота - Google Patents

Каталитическая композиция и способ применения в селективном каталитическом восстановлении оксидов азота Download PDF

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RU2608616C2
RU2608616C2 RU2014120917A RU2014120917A RU2608616C2 RU 2608616 C2 RU2608616 C2 RU 2608616C2 RU 2014120917 A RU2014120917 A RU 2014120917A RU 2014120917 A RU2014120917 A RU 2014120917A RU 2608616 C2 RU2608616 C2 RU 2608616C2
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component
zeolite
zro
ceo
beta
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RU2014120917A
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RU2014120917A (ru
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Александр Ю. СТАХЕЕВ
Мари ГРИЛЛ
Аркадий КУСТОВ
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Хальдор Топсеэ А/С
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
RU2014120917A 2011-10-24 2012-05-02 Каталитическая композиция и способ применения в селективном каталитическом восстановлении оксидов азота RU2608616C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/EP2011/005344 WO2013060341A1 (fr) 2011-10-24 2011-10-24 Composition de catalyseur s'utilisant dans la réduction catalytique sélective d'oxydes d'azote
EPPCT/EP2011/005344 2011-10-24
PCT/EP2012/058003 WO2013060487A1 (fr) 2011-10-24 2012-05-02 Composition de catalyseur et procédé d'utilisation dans une réduction catalytique sélective d'oxydes d'azote

Publications (2)

Publication Number Publication Date
RU2014120917A RU2014120917A (ru) 2015-12-10
RU2608616C2 true RU2608616C2 (ru) 2017-01-23

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RU2014120917A RU2608616C2 (ru) 2011-10-24 2012-05-02 Каталитическая композиция и способ применения в селективном каталитическом восстановлении оксидов азота

Country Status (11)

Country Link
JP (1) JP6112734B2 (fr)
KR (1) KR101789114B1 (fr)
CN (1) CN103889569B (fr)
AU (1) AU2012327482A1 (fr)
BR (1) BR112014008669B1 (fr)
CA (1) CA2853154C (fr)
CL (1) CL2014000993A1 (fr)
IN (1) IN2014CN02950A (fr)
MX (1) MX2014004494A (fr)
RU (1) RU2608616C2 (fr)
WO (2) WO2013060341A1 (fr)

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CN104014324B (zh) * 2014-05-14 2016-08-17 华东理工大学 氧化铈基负载型烟气脱硝催化剂及其制备方法
CN105435789A (zh) * 2014-09-09 2016-03-30 中国石油化工股份有限公司 一种Cu基甲醇合成催化剂大比表面载体的制备方法
CN104525216B (zh) * 2014-12-11 2017-01-04 清华大学 用于宽温度窗口高硫条件下的脱硝催化剂及其制备方法
CN104437540A (zh) * 2014-12-31 2015-03-25 安徽省元琛环保科技有限公司 一种抗磷低温scr脱硝催化剂及其制备方法
KR102583157B1 (ko) * 2015-08-21 2023-09-27 바스프 코포레이션 배기 가스 처리 촉매
RU2726621C1 (ru) * 2015-09-29 2020-07-15 Джонсон Мэтти Паблик Лимитед Компани Каталитический фильтр, содержащий катализатор окисления сажи и scr-катализатор
CA3182231A1 (fr) 2015-10-30 2017-05-04 Blueshift Materials, Inc. Aerogel non reticule hautement ramifie, procedes de fabrication et utilisations correspondantes
CA3016132A1 (fr) 2016-06-08 2017-12-14 Blueshift Materials, Inc. Aerogel polymere presentant des proprietes mecaniques et thermiques ameliorees
WO2018029329A1 (fr) 2016-08-11 2018-02-15 Umicore Ag & Co. Kg Matériau actif scr présentant une stabilité thermique élevée
EP3281698A1 (fr) 2016-08-11 2018-02-14 Umicore AG & Co. KG Materiau scr actif
TW201838708A (zh) * 2017-03-02 2018-11-01 丹麥商托普索公司 用於移除來自工廠的廢氣所含有的硫氧化物和氮氧化物的方法
WO2019112855A1 (fr) 2017-12-05 2019-06-13 Blueshift Materials, Inc. Aérogel d'amide polyamique traité thermiquement
DE102018100834A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
DE102018100833A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
JP2021514447A (ja) * 2018-02-19 2021-06-10 ビーエーエスエフ コーポレーション 上流ｓｃｒ触媒を有する排気ガス処理システム
CN109126817B (zh) * 2018-11-07 2021-07-16 东北大学 一种铁、钨、锌改良氧化铈/氧化锰scr脱硝催化剂及其制备方法
EP3791955A1 (fr) 2019-09-10 2021-03-17 Umicore Ag & Co. Kg Matériau catalytique scr contenant une zéolite au cuivre et cuivre/alumine, procédé de traitement de gaz d'échappement avec ce matériau et procédé de fabrication de ce matériau
CN110586176B (zh) * 2019-09-27 2020-11-17 中国环境科学研究院 一种电解锰渣基微介孔zsm-5催化剂及制备方法
CN110917829A (zh) * 2019-12-13 2020-03-27 西安润川环保科技有限公司 一种脱硫脱硝的烟气深度处理方法
CN111111429A (zh) * 2019-12-16 2020-05-08 山东金城柯瑞化学有限公司 一种利用单活性中心多相催化剂技术治理乙酰呋喃氧化尾气的方法
CN111389454B (zh) * 2020-04-29 2022-09-20 陕西延长石油（集团）有限责任公司 一种合成气与甲苯制备对甲基苯甲醛的催化剂及方法
US11989661B1 (en) * 2023-07-24 2024-05-21 Morgan Stanley Services Group Inc. Dynamic rules for rules engines

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JPH0557196A (ja) * 1991-08-29 1993-03-09 Toyota Motor Corp 排気ガス浄化用触媒の製造方法
WO2001047634A1 (fr) * 1999-12-28 2001-07-05 Corning Incorporated Compositions supports de catalyseur zeolithe/alumine et procede de preparation associe
US6770251B2 (en) * 2000-06-28 2004-08-03 Ict. Co., Ltd. Exhaust gas purifying catalyst
JP2006136776A (ja) * 2004-11-10 2006-06-01 Toyota Central Res & Dev Lab Inc ＮＯｘ選択還元触媒
WO2008085280A2 (fr) * 2007-01-09 2008-07-17 Catalytic Solutions, Inc. Catalyseur scr à l'ammoniac pour hautes températures et procédé d'utilisation
WO2008132452A2 (fr) * 2007-04-26 2008-11-06 Johnson Matthey Public Limited Company Catalyseurs de scr en métal de transition/zéolite
EP2075063A1 (fr) * 2006-10-18 2009-07-01 Cataler Corporation Catalyseur pour la purification de gaz d'échappement
US20090263297A1 (en) * 2007-09-19 2009-10-22 General Electric Company Catalyst and method of manufacture
US20090304566A1 (en) * 2007-01-09 2009-12-10 Golden Stephen J Ammonia scr catalyst and method of using the catalyst
RU2407584C2 (ru) * 2006-03-21 2010-12-27 Родиа Операсьон Состав на основе оксида циркония и оксида церия с повышенной восстановительной способностью и стабильной удельной поверхностью, способ получения и использование для обработки выхлопных газов

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JP3917541B2 (ja) * 2003-03-20 2007-05-23 日産ディーゼル工業株式会社 ディーゼルエンジンの排気浄化装置
US7527776B2 (en) * 2007-01-09 2009-05-05 Catalytic Solutions, Inc. Ammonia SCR catalyst and method of using the catalyst
JPWO2009141894A1 (ja) * 2008-05-20 2011-09-22 イビデン株式会社 ハニカム構造体
CN101722059B (zh) * 2008-10-31 2011-12-21 中国石油化工股份有限公司 脱除烟气中硫和/或氮氧化物的吸附剂组合物再生方法
EP2335810B1 (fr) * 2009-12-11 2012-08-01 Umicore AG & Co. KG Réduction catalytique sélective d'oxydes d'azote dans du gaz d'échappement de moteurs diesel

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0557196A (ja) * 1991-08-29 1993-03-09 Toyota Motor Corp 排気ガス浄化用触媒の製造方法
WO2001047634A1 (fr) * 1999-12-28 2001-07-05 Corning Incorporated Compositions supports de catalyseur zeolithe/alumine et procede de preparation associe
US6770251B2 (en) * 2000-06-28 2004-08-03 Ict. Co., Ltd. Exhaust gas purifying catalyst
JP2006136776A (ja) * 2004-11-10 2006-06-01 Toyota Central Res & Dev Lab Inc ＮＯｘ選択還元触媒
RU2407584C2 (ru) * 2006-03-21 2010-12-27 Родиа Операсьон Состав на основе оксида циркония и оксида церия с повышенной восстановительной способностью и стабильной удельной поверхностью, способ получения и использование для обработки выхлопных газов
EP2075063A1 (fr) * 2006-10-18 2009-07-01 Cataler Corporation Catalyseur pour la purification de gaz d'échappement
WO2008085280A2 (fr) * 2007-01-09 2008-07-17 Catalytic Solutions, Inc. Catalyseur scr à l'ammoniac pour hautes températures et procédé d'utilisation
US20090304566A1 (en) * 2007-01-09 2009-12-10 Golden Stephen J Ammonia scr catalyst and method of using the catalyst
WO2008132452A2 (fr) * 2007-04-26 2008-11-06 Johnson Matthey Public Limited Company Catalyseurs de scr en métal de transition/zéolite
US20090263297A1 (en) * 2007-09-19 2009-10-22 General Electric Company Catalyst and method of manufacture

Also Published As

Publication number Publication date
RU2014120917A (ru) 2015-12-10
MX2014004494A (es) 2014-07-11
CN103889569B (zh) 2017-02-15
BR112014008669A2 (pt) 2017-04-18
CL2014000993A1 (es) 2014-08-22
JP6112734B2 (ja) 2017-04-12
CA2853154A1 (fr) 2013-05-02
JP2015501210A (ja) 2015-01-15
CN103889569A (zh) 2014-06-25
KR20140095512A (ko) 2014-08-01
AU2012327482A1 (en) 2014-05-15
KR101789114B1 (ko) 2017-10-23
CA2853154C (fr) 2018-04-03
BR112014008669B1 (pt) 2019-07-02
IN2014CN02950A (fr) 2015-07-03
WO2013060487A1 (fr) 2013-05-02
WO2013060341A1 (fr) 2013-05-02

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