WO2013060487A1 - Composition de catalyseur et procédé d'utilisation dans une réduction catalytique sélective d'oxydes d'azote - Google Patents
Composition de catalyseur et procédé d'utilisation dans une réduction catalytique sélective d'oxydes d'azote Download PDFInfo
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- WO2013060487A1 WO2013060487A1 PCT/EP2012/058003 EP2012058003W WO2013060487A1 WO 2013060487 A1 WO2013060487 A1 WO 2013060487A1 EP 2012058003 W EP2012058003 W EP 2012058003W WO 2013060487 A1 WO2013060487 A1 WO 2013060487A1
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- Prior art keywords
- zeolite
- catalyst composition
- catalyst
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- components
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- 239000003054 catalyst Substances 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000010531 catalytic reduction reaction Methods 0.000 title description 2
- 239000010457 zeolite Substances 0.000 claims abstract description 79
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 73
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000004071 soot Substances 0.000 claims abstract description 22
- 230000002378 acidificating effect Effects 0.000 claims abstract description 16
- 230000003647 oxidation Effects 0.000 claims abstract description 15
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 15
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 43
- 229910052593 corundum Inorganic materials 0.000 claims description 38
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 38
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 239000006069 physical mixture Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 23
- 239000000523 sample Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 20
- 239000000843 powder Substances 0.000 description 20
- 239000010949 copper Substances 0.000 description 18
- 229910052802 copper Inorganic materials 0.000 description 16
- 238000002156 mixing Methods 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 230000003247 decreasing effect Effects 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 238000011068 loading method Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000006722 reduction reaction Methods 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 230000010718 Oxidation Activity Effects 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000013074 reference sample Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910003465 moissanite Inorganic materials 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 230000001256 tonic effect Effects 0.000 description 2
- -1 Μη/Αΐ2θ3 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000286904 Leptothecata Species 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/2073—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/40—Mixed oxides
- B01D2255/407—Zr-Ce mixed oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
- B01D2255/502—Beta zeolites
Definitions
- the present invention relates to catalyst composition for use in selective reduction of nitrogen oxides in off-gases by reaction with ammonia or a precursor thereof.
- Catalysts for NH 3 -SCR i.e. selective reduction of nitrogen oxides (NOx) by use of ammonia as reductant are well known in the art.
- Those catalysts include zeolitic material, op ⁇ tionally promoted with copper or iron
- the catalyst composition and method of this invention shall further include soot and hydrocarbon oxidation activity simultaneously with the DeNOx activity.
- catalyst composition comprising a one or more acidic zeolite or zeotype components physically ad- mixed with one ore more redox active metal compounds shown an improved activity in the selective reduction of nitrogen oxides and oxidation of hydrocarbons, CO and soot contained in off-gas.
- redox active metal compounds as used herein re ⁇ lates to metal compounds which reversibly can be oxidized and reduced in terms of changes in oxidation number, or oxidation state, of the metal atom or compound.
- the present invention pro ⁇ vides a catalyst composition for selective reduction of nitrogen oxides and soot oxidation comprising one or more acidic zeolite or zeotype components selected from the group consisting of BEA, MFI, FAU, FER, CHA, MOR or mixtures thereof physically admixed with one ore more redox active metal compounds selected from the group consisting of Cu/Al 2 0 3 , Mn/Al 2 0 3 , Ce0 2 -Zr0 2 , Ce-Mn/Al 2 0 3 and mixtures thereof.
- Catalyst compositions prepared by mechanical mixing of the above mentioned zeolites or zeotype materials and redox metal components mixing according to the invention exhibit a pronounced synergistic effect. DeNO x activity of such composite catalysts significantly exceeds activity of their individual components.
- the acidic zeolite or zeotype component can be used in pro- tonic form or promoted with Fe .
- the weight ratio between the zeolite components and the redox components is between 1:1 to 1:50
- the redox components are dispersed on a support selected from the group consisting of of AI2O3, T 1 O2 , S 1 O2 , Ce02 , r02 or mixtures thereof.
- the mean molar ratio Si/Al of the zeolite components according to the invention is from 5 to 100.
- the above described catalyst composition according to the invention can be utilised as coating material or as coat on structured bodies of metallic, ceramic, metal oxide, SiC or silica materials or fibres.
- the invention provides furthermore a monolithic structured body being coated with a catalyst composition according to anyone of the above disclosed embodiments of the invention.
- the monolithic structured body is preferably made from me ⁇ tallic, ceramic, metal oxide, SiC or silica fiber materi ⁇ als .
- the monolithic structured body may be in form of a particle filter, e.g. a honeycomb structured filter or a wall flow filter .
- the catalyst composition is coated on the body in of two or several separate catalyst layers in series or as two or several catalyst layers in parallel and wherein the layers have different compositions or layer thicknesses.
- amount of expensive zeolite/zeotype com ⁇ ponent in the composite catalyst can be significantly re ⁇ substituted by its replacement with equivalent volume of redox component.
- overall volume of the catalyst re- mains constant, but the amount of zeolite component can be decreased by 2-5 times, without notable sacrificing DeNO x performance.
- Ce-Mn/Al 2 03 component is used for the catalyst preparation, notable improvement of NOx conversion at Treact ⁇ 250°C is observed despite decreased amount of zeolite component.
- the invention provides additionally a method for the selec ⁇ tive reduction of nitrogen oxides and oxidation of soot contained in an off-gas comprising the step of contacting the off-gas in presence of ammonia with a catalyst composi ⁇ tion comprising one or more acidic zeolite or zeotype com ⁇ ponents selected from the group consisting of BEA, MFI, FAU, FER, CHA, MOR or mixtures thereof physically admixed with one ore more redox active metal compounds selected from the group consisting of CU/AI 2 O 3 , ⁇ / ⁇ 2 ⁇ 3 , Ce0 2 ⁇ Zr0 2 , Ce-Mn/Al 2 03 and mixtures thereof.
- the acidic zeolite or zeotype component can be used in pro- tonic form or promoted with Fe
- the one or more redox active metal compounds are dispersed on a support se ⁇ lected from the group consisting of AI2O3, T1O2, S1O2, Zr02 or mixtures thereof.
- the cata ⁇ lyst composition is contacted with the off-gas at a tem ⁇ perature below 250°C.
- excess of ammonia is selectively oxidized to nitrogen by contact with the catalyst composition.
- Example 1 Synergistic effect in NH 3 -DeNOx over Ce02-Zr02 + H-Beta zeolite catalyst compositions.
- the pow ⁇ ders were thoroughly grinded in agate mortar for 10-15 min, followed by pelletization . The pellets were crushed and sieved collecting 0.2 - 0.4 mm fraction for catalytic test.
- pelletized 74wt%Ce0 2 -26wt%Zr0 2 , H-Beta, and Fe- Beta zeolite were used as reference samples.
- the catalysts were tested in the NH 3 -DeNOx in the tempera- ture range of 150-550 °C.
- the test was performed under fol ⁇ lowing conditions: decreasing reaction temperature with a rate of 2°C/min, feed gas composition: 500 ppm NO, 540 ppm N3 ⁇ 4, 10 vol % O 2 , 6 vol% H 2 O, balanced with 2 to obtain a total flow of 300 mL/min.
- NO x conversion over composite catalyst is similar to NO x conversion over commercial Fe-Beta zeolite (Fe-Beta) at 230-550°C, and exceeds NO x conversion over Fe-Beta zeolite at 150-200°C.
- a first sample was prepared by mixing 74wt%Ce0 2 ⁇ 26wt%Zr0 2 and Fe-Beta zeolite powders at a weight ratio of 3.3. This weight ratio results in a volume ratio of 74wt%Ce02 ⁇
- 26wt%Zr0 2 /Fe-Beta components in composite catalyst 1/1.
- a second sample was prepared by mixing 74wt%Ce0 2 ⁇ 26wt%Zr0 2 and Fe-Beta powders at a weight ratio of 10.
- For the second sample volume ratio of 74wt%Ce0 2 ⁇ 26wt%Zr0 2 /Fe-Beta zeolite equals 3/1.
- the first sample with 1/1 volume component ratio [0.065g 74%Ce0 2 -Zr0 2 + 0.02g Fe-Beta zeolite].
- the second sample with 3/1 volume component ratio [0.197g 74%Ce0 2 -Zr0 2 + 0.02g Fe-Beta zeolite].
- Reference sample 0.02 g Fe-Beta zeolite.
- the catalysts were tested in NH 3 -DeNO x within the tempera ⁇ ture range of 150-550 °C.
- the test was performed under fol ⁇ lowing conditions: decreasing reaction temperature with a rate of 2°C/min, feed gas composition: 500 ppm NO, 540 ppm NH 3 , 10 vol % 0 2 , 6 vol% H 2 0, balanced with N 2 to obtain a total flow of 300 mL/min.
- [Ce0 2 -Zr0 2 + Fe-Beta zeolite] composite catalysts showed enhanced DeNO x activity within low-temperature range (150-300°C), which significantly ex ⁇ ceeded activity of individual Fe-Beta zeolite, as shown in Fig. 2. It is important to note that the activity of [Ce0 2 ⁇ Zr0 2 + Fe-Beta zeolite] is improved when the amount of Ce02 ⁇ Zr02 component was increased.
- a first sample was prepared by mixing 74wt%Ce02 ⁇ 26wt%Zr02 and Fe-Beta powders at a weight ratio of 3.3. In this case volume ratio of 74wt% Ce02 ⁇ 26wt% Zr02 /Fe-Beta zeolite equals 1/1.
- a second sample was prepared by mixing 74wt%Ce0 2 ⁇ 26wt%Zr0 2 and Fe-Beta zeolite powders at a weight ratio of 15.5. For the second sample volume ratio of 74wt%Ce02 ⁇ 26wt%Zr02 and Fe-Beta zeolite components equals 5/1.
- a third sample was prepared by was prepared by mixing
- Second sample [0.109g 74wt%Ce02 ⁇ Zr0 2 + 0.007g Fe-Beta zeolite].
- Reference sample 0.02 g Fe beta-zeolite.
- Feed gas composition 540 ppm NH 3 , 500 ppm NO, 10 % 0 2 , 6 % H 2 0 balance with N 2 .
- the powders were thoroughly grinded in agate mortar for 10-15 min, followed by pelleti- zation. The pellets were crushed and sieved collecting 0.2 - 0.4 mm fraction for catalytic test. Similarly pelletized Fe-Beta was used as reference.
- the catalysts were tested in the NH 3 -DeNOx in the tempera ⁇ ture range of 150-550 °C.
- the test was performed under fol ⁇ lowing conditions: decreasing reaction temperature with a rate of 2°C/min, feed gas composition: 500 ppm NO, 540 ppm NH 3 , 10 vol % O 2 , 6 vol% 3 ⁇ 40, balanced with 2 to obtain a total flow of 300 mL/min.
- Catalyst load 0.04g Fe-Beta and
- the first sample with 1/1 weight component ratio [0.040g 10wt%Cu/Al 2 O 3 + 0.040g H-Beta].
- the second sample with 1/1 weight component ratio [0.040g 10wt%Cu/Al 2 O 3 + 0.040g H-ZSM-5].
- the third sample with 1/1 weight component ratio [0.040g 10wt%Cu/Al 2 O 3 + 0.040g H-ferrierite ] .
- Reference samples 0.040 g H-Beta; 0.040g H-ZSM-5, or H- ferrierite, or 0.040 g 10wt%Cu/Al 2 O 3 .
- the catalysts were tested in NH 3 -DeNO x within the tempera ⁇ ture range of 150-550 °C. The test was performed under fol ⁇ lowing conditions: decreasing reaction temperature with a rate of 2°C/min, feed gas composition: 500 ppm NO, 540 ppm NH 3 , 10 vol % 0 2 , 6 vol% H 2 0, balanced with N 2 to obtain a total flow of 300 mL/min.
- GHSV 270, 000 h "1 .
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- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
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- Crystallography & Structural Chemistry (AREA)
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- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014537523A JP6112734B2 (ja) | 2011-10-24 | 2012-05-02 | 触媒組成物および窒素酸化物の選択的触媒還元における使用方法 |
CA2853154A CA2853154C (fr) | 2011-10-24 | 2012-05-02 | Composition de catalyseur et procede d'utilisation dans une reduction catalytique selective d'oxydes d'azote |
CN201280052240.5A CN103889569B (zh) | 2011-10-24 | 2012-05-02 | 用于选择性催化还原氮的氧化物的催化剂组合物及方法 |
IN2950CHN2014 IN2014CN02950A (fr) | 2011-10-24 | 2012-05-02 | |
RU2014120917A RU2608616C2 (ru) | 2011-10-24 | 2012-05-02 | Каталитическая композиция и способ применения в селективном каталитическом восстановлении оксидов азота |
BR112014008669-9A BR112014008669B1 (pt) | 2011-10-24 | 2012-05-02 | Composição de catalisador e método para utilização em reduções catalíticas de óxidos de nitrogênio |
US14/353,620 US9168517B2 (en) | 2011-10-24 | 2012-05-02 | Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides |
AU2012327482A AU2012327482A1 (en) | 2011-10-24 | 2012-05-02 | Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides |
EP12721442.7A EP2771111A1 (fr) | 2011-10-24 | 2012-05-02 | Composition de catalyseur et procédé d'utilisation dans une réduction catalytique sélective d'oxydes d'azote |
KR1020147013999A KR101789114B1 (ko) | 2011-10-24 | 2012-05-02 | 질소 산화물의 선택적 촉매 환원에서 사용하기 위한 촉매 조성물 및 방법 |
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PCT/EP2011/005344 WO2013060341A1 (fr) | 2011-10-24 | 2011-10-24 | Composition de catalyseur s'utilisant dans la réduction catalytique sélective d'oxydes d'azote |
EPPCT/EP2011/005344 | 2011-10-24 |
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WO2013060487A1 true WO2013060487A1 (fr) | 2013-05-02 |
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PCT/EP2011/005344 WO2013060341A1 (fr) | 2011-10-24 | 2011-10-24 | Composition de catalyseur s'utilisant dans la réduction catalytique sélective d'oxydes d'azote |
PCT/EP2012/058003 WO2013060487A1 (fr) | 2011-10-24 | 2012-05-02 | Composition de catalyseur et procédé d'utilisation dans une réduction catalytique sélective d'oxydes d'azote |
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PCT/EP2011/005344 WO2013060341A1 (fr) | 2011-10-24 | 2011-10-24 | Composition de catalyseur s'utilisant dans la réduction catalytique sélective d'oxydes d'azote |
Country Status (11)
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JP (1) | JP6112734B2 (fr) |
KR (1) | KR101789114B1 (fr) |
CN (1) | CN103889569B (fr) |
AU (1) | AU2012327482A1 (fr) |
BR (1) | BR112014008669B1 (fr) |
CA (1) | CA2853154C (fr) |
CL (1) | CL2014000993A1 (fr) |
IN (1) | IN2014CN02950A (fr) |
MX (1) | MX2014004494A (fr) |
RU (1) | RU2608616C2 (fr) |
WO (2) | WO2013060341A1 (fr) |
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CN104014324B (zh) * | 2014-05-14 | 2016-08-17 | 华东理工大学 | 氧化铈基负载型烟气脱硝催化剂及其制备方法 |
CN105435789A (zh) * | 2014-09-09 | 2016-03-30 | 中国石油化工股份有限公司 | 一种Cu基甲醇合成催化剂大比表面载体的制备方法 |
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RU2014120917A (ru) | 2015-12-10 |
MX2014004494A (es) | 2014-07-11 |
CN103889569B (zh) | 2017-02-15 |
BR112014008669A2 (pt) | 2017-04-18 |
CL2014000993A1 (es) | 2014-08-22 |
JP6112734B2 (ja) | 2017-04-12 |
CA2853154A1 (fr) | 2013-05-02 |
JP2015501210A (ja) | 2015-01-15 |
CN103889569A (zh) | 2014-06-25 |
KR20140095512A (ko) | 2014-08-01 |
AU2012327482A1 (en) | 2014-05-15 |
KR101789114B1 (ko) | 2017-10-23 |
CA2853154C (fr) | 2018-04-03 |
BR112014008669B1 (pt) | 2019-07-02 |
RU2608616C2 (ru) | 2017-01-23 |
IN2014CN02950A (fr) | 2015-07-03 |
WO2013060341A1 (fr) | 2013-05-02 |
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