RU2606504C2 - Способ повышения селективности катализатора эпоксидирования - Google Patents

Способ повышения селективности катализатора эпоксидирования Download PDF

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RU2606504C2
RU2606504C2 RU2013153098A RU2013153098A RU2606504C2 RU 2606504 C2 RU2606504 C2 RU 2606504C2 RU 2013153098 A RU2013153098 A RU 2013153098A RU 2013153098 A RU2013153098 A RU 2013153098A RU 2606504 C2 RU2606504 C2 RU 2606504C2
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catalyst
ethylene
concentration
level
catalysis
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RU2013153098A
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RU2013153098A (ru
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Уэйн Эррол ЭВАНС
Джеффри Майкл КОУБ
Марек МАТУШ
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/04—Preparation of esters of carbonic or haloformic acids from carbon dioxide or inorganic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2013153098A 2011-04-29 2012-04-26 Способ повышения селективности катализатора эпоксидирования RU2606504C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161480581P 2011-04-29 2011-04-29
US61/480,581 2011-04-29
PCT/US2012/035106 WO2012149098A1 (en) 2011-04-29 2012-04-26 Process for improving the selectivity of an eo catalyst

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RU2013153098A RU2013153098A (ru) 2015-06-10
RU2606504C2 true RU2606504C2 (ru) 2017-01-10

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US (1) US9174928B2 (enExample)
EP (1) EP2714670B2 (enExample)
JP (1) JP6104888B2 (enExample)
KR (1) KR102027597B1 (enExample)
CN (1) CN103502229B (enExample)
BR (1) BR112013027585B1 (enExample)
CA (1) CA2834299C (enExample)
RU (1) RU2606504C2 (enExample)
TW (1) TWI566831B (enExample)
WO (1) WO2012149098A1 (enExample)

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SG11201403042SA (en) 2011-12-09 2014-10-30 Dow Technology Investments Llc Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
CN104437663B (zh) * 2013-09-16 2016-09-21 中国石油化工股份有限公司 一种制备α-氧化铝载体的方法
CN106311228B (zh) * 2015-07-02 2019-06-28 中国石油化工股份有限公司 银催化剂、其制备方法及应用
CN105233824B (zh) * 2015-11-05 2018-02-06 中国海洋石油总公司 一种高选择性乙烯氧化制环氧乙烷银催化剂及其使用方法
WO2019055773A1 (en) 2017-09-15 2019-03-21 MultiPhase Solutions, Inc. GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES
KR102723162B1 (ko) * 2017-12-08 2024-10-30 쉘 인터내셔날 리써취 마트샤피지 비.브이. 에틸렌 카르보네이트 및 에틸렌 글리콜을 제조하는 방법
CN110357837B (zh) * 2018-03-26 2021-07-02 中国石油化工股份有限公司 一种乙烯环氧化方法
WO2022214539A1 (en) 2021-04-08 2022-10-13 Shell Internationale Research Maatschappij B.V. Moderator and catalyst performance optimization for epoxidation of ethylene

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US4400559A (en) * 1982-06-14 1983-08-23 The Halcon Sd Group, Inc. Process for preparing ethylene glycol
SU1572414A3 (ru) * 1982-06-14 1990-06-15 Сайентифик Дизайн Компани, Инк (Фирма) Способ получени этиленгликол
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US20040110971A1 (en) * 2002-06-28 2004-06-10 Evans Wayne Errol Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
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Publication number Publication date
EP2714670A1 (en) 2014-04-09
BR112013027585A2 (pt) 2016-07-26
EP2714670B1 (en) 2018-08-01
US9174928B2 (en) 2015-11-03
JP2014517827A (ja) 2014-07-24
US20120277447A1 (en) 2012-11-01
CN103502229A (zh) 2014-01-08
EP2714670B2 (en) 2022-03-02
TWI566831B (zh) 2017-01-21
BR112013027585B1 (pt) 2020-09-29
KR102027597B1 (ko) 2019-10-01
KR20140034774A (ko) 2014-03-20
CA2834299C (en) 2019-09-03
EP2714670A4 (en) 2015-04-08
RU2013153098A (ru) 2015-06-10
CN103502229B (zh) 2016-02-03
JP6104888B2 (ja) 2017-03-29
WO2012149098A1 (en) 2012-11-01
CA2834299A1 (en) 2012-11-01
TW201247316A (en) 2012-12-01

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