JP6104888B2 - Eo触媒の選択率を改善する方法 - Google Patents
Eo触媒の選択率を改善する方法 Download PDFInfo
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- JP6104888B2 JP6104888B2 JP2014508537A JP2014508537A JP6104888B2 JP 6104888 B2 JP6104888 B2 JP 6104888B2 JP 2014508537 A JP2014508537 A JP 2014508537A JP 2014508537 A JP2014508537 A JP 2014508537A JP 6104888 B2 JP6104888 B2 JP 6104888B2
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- catalyst
- concentration
- ethylene
- promoter
- feed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/36—Rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
- C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/04—Preparation of esters of carbonic or haloformic acids from carbon dioxide or inorganic carbonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161480581P | 2011-04-29 | 2011-04-29 | |
| US61/480,581 | 2011-04-29 | ||
| PCT/US2012/035106 WO2012149098A1 (en) | 2011-04-29 | 2012-04-26 | Process for improving the selectivity of an eo catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014517827A JP2014517827A (ja) | 2014-07-24 |
| JP2014517827A5 JP2014517827A5 (enExample) | 2016-09-29 |
| JP6104888B2 true JP6104888B2 (ja) | 2017-03-29 |
Family
ID=47068406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014508537A Active JP6104888B2 (ja) | 2011-04-29 | 2012-04-26 | Eo触媒の選択率を改善する方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9174928B2 (enExample) |
| EP (1) | EP2714670B2 (enExample) |
| JP (1) | JP6104888B2 (enExample) |
| KR (1) | KR102027597B1 (enExample) |
| CN (1) | CN103502229B (enExample) |
| BR (1) | BR112013027585B1 (enExample) |
| CA (1) | CA2834299C (enExample) |
| RU (1) | RU2606504C2 (enExample) |
| TW (1) | TWI566831B (enExample) |
| WO (1) | WO2012149098A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104080778B (zh) | 2011-12-09 | 2016-08-24 | 陶氏技术投资有限责任公司 | 在利用高效催化剂制造环氧烷的工艺中保持环氧烷生产参数值的方法 |
| CN104437663B (zh) * | 2013-09-16 | 2016-09-21 | 中国石油化工股份有限公司 | 一种制备α-氧化铝载体的方法 |
| CN106311228B (zh) * | 2015-07-02 | 2019-06-28 | 中国石油化工股份有限公司 | 银催化剂、其制备方法及应用 |
| CN105233824B (zh) * | 2015-11-05 | 2018-02-06 | 中国海洋石油总公司 | 一种高选择性乙烯氧化制环氧乙烷银催化剂及其使用方法 |
| US11059017B2 (en) | 2017-09-15 | 2021-07-13 | MultiPhase Solutions, Inc. | Halogen selective detection gas chromatography for the on-line analysis and control of selective oxidation chemical production processes |
| US11498911B2 (en) | 2017-12-08 | 2022-11-15 | Shell Usa, Inc. | Process for preparing ethylene carbonate and ethylene glycol |
| CN110357837B (zh) * | 2018-03-26 | 2021-07-02 | 中国石油化工股份有限公司 | 一种乙烯环氧化方法 |
| TWI920276B (zh) * | 2021-04-08 | 2026-04-01 | 荷蘭商蜆殼國際研究所 | 用於乙烯之環氧化的緩和劑及催化劑效能最佳化 |
| WO2026027443A1 (en) | 2024-07-29 | 2026-02-05 | Basf Se | Blended catalyst mix for epoxidation |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US4400559A (en) * | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| US4845296A (en) | 1983-12-13 | 1989-07-04 | Union Carbide Corporation | Process for preparing alkanolamines |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4874879A (en) | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| JP2720124B2 (ja) * | 1990-10-12 | 1998-02-25 | ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション | 向上された活性度及び/又は安定度を有するアルキレンオキシド触媒 |
| US5155242A (en) | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5380697A (en) | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5801259A (en) | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US6040467A (en) | 1997-07-24 | 2000-03-21 | Praxair Technology, Inc. | High purity oxygen for ethylene oxide production |
| JP3781549B2 (ja) * | 1998-03-19 | 2006-05-31 | 三菱化学株式会社 | モノエチレングリコールの製造方法 |
| JP3817947B2 (ja) * | 1999-01-26 | 2006-09-06 | 三菱化学株式会社 | エチレングリコールの製造方法 |
| US6080897A (en) * | 1998-03-19 | 2000-06-27 | Mitsubishi Chemical Corporation | Method for producing monoethylene glycol |
| US6368998B1 (en) | 1998-09-14 | 2002-04-09 | Shell Oil Company | Process for preparing catalyst with improved catalytic properties |
| US6372925B1 (en) | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| DE60207299T2 (de) | 2001-11-20 | 2006-08-10 | Shell Internationale Research Maatschappij B.V. | Verfahren und systeme zur epoxidierung eines olefins |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| BR0312244B1 (pt) | 2002-06-28 | 2013-06-25 | mÉtodo para melhorar a seletividade de um catalisador e um processo para a epoxidaÇço de uma olefina | |
| RU2005102097A (ru) * | 2002-06-28 | 2005-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина |
| CN100376561C (zh) | 2002-06-28 | 2008-03-26 | 国际壳牌研究有限公司 | 环氧化方法的开车方法、烯烃环氧化的催化剂和方法 |
| MY136774A (en) | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
| MY146505A (en) | 2003-02-28 | 2012-08-15 | Shell Int Research | A method of manufacturing ethylene oxide |
| MY153179A (en) | 2003-02-28 | 2015-01-29 | Shell Int Research | A method of manufacturing ethylene oxide |
| US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US7615655B2 (en) | 2003-09-29 | 2009-11-10 | Dow Global Technologies, Inc. | Process for the production of alkylene oxide using a gas-phase promoter system |
| BRPI0512169A (pt) | 2004-06-18 | 2008-02-12 | Shell Int Research | processo para a produção de óxido de olefina, 1,2- diol, 1,2-diol éter,ou alcanolamina |
| JP5421587B2 (ja) | 2005-03-22 | 2014-02-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エチレンオキシドの製造のための反応器システムおよびプロセス |
| RU2008136381A (ru) | 2006-02-10 | 2010-03-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ получения катализатора, катализатор и способ получения олефиноксида, 1,2-диола, простого эфира 1,2,-диола или алканоламина |
| CN101426573B (zh) | 2006-04-18 | 2015-08-05 | 陶氏环球技术公司 | 环氧烷催化剂及其应用 |
| WO2008141030A1 (en) * | 2007-05-09 | 2008-11-20 | Shell Oil Company | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CA2685512C (en) | 2007-05-09 | 2016-12-06 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| US7803957B2 (en) | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| KR101629038B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| WO2009137427A2 (en) * | 2008-05-07 | 2009-11-12 | Shell Oil Company | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| EP2421840B1 (en) | 2009-04-21 | 2015-12-16 | Dow Technology Investments LLC | Simplified method for producing alkylene oxides with a high efficiency catalyst |
| JP5584284B2 (ja) * | 2009-04-21 | 2014-09-03 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法 |
| KR101730667B1 (ko) | 2009-04-21 | 2017-04-26 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 고 효율 촉매에 의한 지정된 알킬렌 옥사이드 생산 파라미터의 달성 및 유지의 개선법 |
| US8513444B2 (en) | 2009-04-21 | 2013-08-20 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
| US8802900B2 (en) * | 2010-11-29 | 2014-08-12 | Shell Oil Company | Process for the preparation of ethylene glycol |
| US8742147B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
-
2012
- 2012-04-26 RU RU2013153098A patent/RU2606504C2/ru active
- 2012-04-26 BR BR112013027585-5A patent/BR112013027585B1/pt active IP Right Grant
- 2012-04-26 JP JP2014508537A patent/JP6104888B2/ja active Active
- 2012-04-26 US US13/456,774 patent/US9174928B2/en active Active
- 2012-04-26 KR KR1020137028065A patent/KR102027597B1/ko active Active
- 2012-04-26 CN CN201280020804.7A patent/CN103502229B/zh active Active
- 2012-04-26 CA CA2834299A patent/CA2834299C/en active Active
- 2012-04-26 EP EP12776466.0A patent/EP2714670B2/en active Active
- 2012-04-26 WO PCT/US2012/035106 patent/WO2012149098A1/en not_active Ceased
- 2012-04-27 TW TW101115254A patent/TWI566831B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| US20120277447A1 (en) | 2012-11-01 |
| CA2834299C (en) | 2019-09-03 |
| EP2714670B2 (en) | 2022-03-02 |
| TW201247316A (en) | 2012-12-01 |
| WO2012149098A1 (en) | 2012-11-01 |
| EP2714670A1 (en) | 2014-04-09 |
| CN103502229A (zh) | 2014-01-08 |
| RU2013153098A (ru) | 2015-06-10 |
| KR102027597B1 (ko) | 2019-10-01 |
| TWI566831B (zh) | 2017-01-21 |
| BR112013027585B1 (pt) | 2020-09-29 |
| JP2014517827A (ja) | 2014-07-24 |
| CA2834299A1 (en) | 2012-11-01 |
| CN103502229B (zh) | 2016-02-03 |
| BR112013027585A2 (pt) | 2016-07-26 |
| KR20140034774A (ko) | 2014-03-20 |
| EP2714670A4 (en) | 2015-04-08 |
| EP2714670B1 (en) | 2018-08-01 |
| US9174928B2 (en) | 2015-11-03 |
| RU2606504C2 (ru) | 2017-01-10 |
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