CN103502229B - 用于改善环氧乙烷催化剂选择性的方法 - Google Patents

用于改善环氧乙烷催化剂选择性的方法 Download PDF

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CN103502229B
CN103502229B CN201280020804.7A CN201280020804A CN103502229B CN 103502229 B CN103502229 B CN 103502229B CN 201280020804 A CN201280020804 A CN 201280020804A CN 103502229 B CN103502229 B CN 103502229B
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catalyst
ethylene
feed
selectivity
mmol
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CN103502229A (zh
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W·E·埃万斯
J·M·科贝
M·玛图兹
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Shell Internationale Research Maatschappij BV
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/04—Preparation of esters of carbonic or haloformic acids from carbon dioxide or inorganic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201280020804.7A 2011-04-29 2012-04-26 用于改善环氧乙烷催化剂选择性的方法 Active CN103502229B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161480581P 2011-04-29 2011-04-29
US61/480,581 2011-04-29
PCT/US2012/035106 WO2012149098A1 (en) 2011-04-29 2012-04-26 Process for improving the selectivity of an eo catalyst

Publications (2)

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CN103502229A CN103502229A (zh) 2014-01-08
CN103502229B true CN103502229B (zh) 2016-02-03

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Country Link
US (1) US9174928B2 (enExample)
EP (1) EP2714670B2 (enExample)
JP (1) JP6104888B2 (enExample)
KR (1) KR102027597B1 (enExample)
CN (1) CN103502229B (enExample)
BR (1) BR112013027585B1 (enExample)
CA (1) CA2834299C (enExample)
RU (1) RU2606504C2 (enExample)
TW (1) TWI566831B (enExample)
WO (1) WO2012149098A1 (enExample)

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CN104437663B (zh) * 2013-09-16 2016-09-21 中国石油化工股份有限公司 一种制备α-氧化铝载体的方法
CN106311228B (zh) * 2015-07-02 2019-06-28 中国石油化工股份有限公司 银催化剂、其制备方法及应用
CN105233824B (zh) * 2015-11-05 2018-02-06 中国海洋石油总公司 一种高选择性乙烯氧化制环氧乙烷银催化剂及其使用方法
US11059017B2 (en) 2017-09-15 2021-07-13 MultiPhase Solutions, Inc. Halogen selective detection gas chromatography for the on-line analysis and control of selective oxidation chemical production processes
TWI801461B (zh) * 2017-12-08 2023-05-11 荷蘭商蜆殼國際研究所 用於製備碳酸伸乙酯及乙二醇之製程
CN110357837B (zh) * 2018-03-26 2021-07-02 中国石油化工股份有限公司 一种乙烯环氧化方法
CA3214971A1 (en) 2021-04-08 2022-10-13 Shell Internationale Research Maatschappij B.V. Moderator and catalyst performance optimization for epoxidation of ethylene

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US6372925B1 (en) * 2000-06-09 2002-04-16 Shell Oil Company Process for operating the epoxidation of ethylene
US7193094B2 (en) * 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
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Also Published As

Publication number Publication date
EP2714670B1 (en) 2018-08-01
WO2012149098A1 (en) 2012-11-01
CA2834299C (en) 2019-09-03
EP2714670A1 (en) 2014-04-09
KR102027597B1 (ko) 2019-10-01
EP2714670A4 (en) 2015-04-08
JP6104888B2 (ja) 2017-03-29
CN103502229A (zh) 2014-01-08
BR112013027585B1 (pt) 2020-09-29
TWI566831B (zh) 2017-01-21
KR20140034774A (ko) 2014-03-20
US9174928B2 (en) 2015-11-03
RU2013153098A (ru) 2015-06-10
RU2606504C2 (ru) 2017-01-10
US20120277447A1 (en) 2012-11-01
BR112013027585A2 (pt) 2016-07-26
TW201247316A (en) 2012-12-01
CA2834299A1 (en) 2012-11-01
JP2014517827A (ja) 2014-07-24
EP2714670B2 (en) 2022-03-02

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