RU2599660C2 - Адсорбент метилйодида, его применение и способ адсорбции метилйодида - Google Patents

Адсорбент метилйодида, его применение и способ адсорбции метилйодида Download PDF

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RU2599660C2
RU2599660C2 RU2014140439/05A RU2014140439A RU2599660C2 RU 2599660 C2 RU2599660 C2 RU 2599660C2 RU 2014140439/05 A RU2014140439/05 A RU 2014140439/05A RU 2014140439 A RU2014140439 A RU 2014140439A RU 2599660 C2 RU2599660 C2 RU 2599660C2
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adsorbent
zeolite
iodide
methyl iodide
mass
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RU2014140439/05A
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English (en)
Russian (ru)
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RU2014140439A (ru
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Катарина ДОНАБАУЭР
Арно ТИССЛЕР
Мика Эндлер
Олаф БЮТТНЕР
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Клариант Интернэшнл Лтд.
Арева Гмбх
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Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105080478B (zh) * 2014-05-14 2018-01-09 中国石油化工股份有限公司 从混合烷烃中分离低辛烷值组分的方法
US10937555B2 (en) * 2014-12-19 2021-03-02 Caverion Deutschland GmbH Nuclear power plant
GB2539745B (en) * 2015-02-26 2017-05-24 Johnson Matthey Plc Palladium-MAZ zeolite passive NOx adsorber and use thereof
US10434494B2 (en) 2015-03-12 2019-10-08 Rasa Industries, Ltd. Filtration material for filtered venting, and filtered venting device
JP6366532B2 (ja) * 2015-03-27 2018-08-01 日立Geニュークリア・エナジー株式会社 フィルタベント方法、フィルタベント装置及び原子力プラント
CN108368080B (zh) 2015-12-15 2022-04-15 国际壳牌研究有限公司 从环氧乙烷制造中的循环气体流去除乙烯基碘杂质的方法和系统
KR102667368B1 (ko) 2015-12-15 2024-05-21 쉘 인터내셔날 리써취 마트샤피지 비.브이. 에틸렌 옥사이드의 제조 시 재순환 가스 스트림으로부터 알킬 요오드화물 불순물을 제거하기 위한 방법 및 시스템
BR112018012058B1 (pt) 2015-12-15 2021-01-05 Shell Internationale Research Maatschappij B.V. processo para operar um sistema de leito de guarda
EP3390356B1 (en) * 2015-12-15 2019-11-13 Shell International Research Maatschappij B.V. Processes and systems for removing iodide impurities from a recycle gas stream in the production of ethylene oxide
JP6716247B2 (ja) * 2015-12-24 2020-07-01 株式会社荏原製作所 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法
CN105434462A (zh) * 2015-12-24 2016-03-30 上海复榆医药科技有限公司 碘负载皮肤杀菌剂及负载碘的方法
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
CN110993138A (zh) * 2019-11-06 2020-04-10 中国辐射防护研究院 一种放射性甲基碘法残液的无害化处理方法
DE102020113180B4 (de) * 2020-05-15 2025-11-06 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Vorrichtung zur Probennahme aus einem Abgasmassenstrom
CN116157191B (zh) * 2020-07-31 2025-03-14 三井金属矿业株式会社 烃吸附材、废气净化催化剂及废气净化系统
CN112023874A (zh) * 2020-09-18 2020-12-04 上海复旭分子筛有限公司 用于深度脱除气相介质中碘化物的沸石分子筛吸附剂及其制备方法和应用
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US20230083647A1 (en) * 2021-09-10 2023-03-16 Battelle Energy Alliance, Llc Reusable structures containing isotopes for simulating radioactive contamination environments, and methods of formation
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CN117482904B (zh) * 2023-11-06 2026-01-27 西南科技大学 一种全硅沸石限域咪唑吸附剂的制备及应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0175435A1 (en) * 1984-04-25 1986-03-26 Toray Industries, Inc. Adsorbent for and method of removing iodine compounds
US5075084A (en) * 1989-01-21 1991-12-24 Bayer Aktiengesellschaft Process for the removal of iodine and iodine compounds from hydrogen-containing gases and vapors
RU2091365C1 (ru) * 1991-10-18 1997-09-27 БП Кемикэлс Лтд Способ удаления примесей с*001-с*001*000-алкилйодидов из жидких карбоновых кислот с*002-с*006 и/или соответствующих ангидридов кислот, содержащих также примеси ионов металлов
US6380428B1 (en) * 1998-03-06 2002-04-30 Uop Llc Method for treating a liquid stream contaminated with an iodine-containing compound using a cation-exchanged zeolite
US6506935B1 (en) * 1998-03-06 2003-01-14 Uop Llc Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2109146C3 (de) * 1971-02-26 1980-03-20 Bayer Ag, 5090 Leverkusen Verfahren zur Entfernung von Jod und Jodverbindungen aus Gasen und Dämpfen und silbernitratimprägnierte Sorptionsmittel zur Durchführung des Verfahrens
US3852407A (en) * 1972-08-08 1974-12-03 Atomic Energy Commission Method for removing alkyl iodides from air by mercuric nitrate solution
JPS5847679B2 (ja) * 1979-04-14 1983-10-24 動力炉・核燃料開発事業団 気体中の放射性ヨウ素の除去方法
JPS56108532A (en) * 1980-02-04 1981-08-28 Hitachi Ltd Iodine adsorbing material and preparation thereof
JPS5891032A (ja) 1981-11-26 1983-05-30 Toray Ind Inc ペンタシル型ゼオライトの製造法
JPS6168127A (ja) 1984-09-10 1986-04-08 Hokkaido Electric Power Co Inc:The 金属添着吸着材によるヨウ素除去方法
DE3808742A1 (de) * 1988-03-16 1989-09-28 Kernforschungsz Karlsruhe Verfahren zur entfernung von iod und iodverbindungen aus gasen und daempfen mit silberhaltigem zeolith x
DD296899A5 (de) * 1990-08-02 1991-12-19 Schlicht,Burkhard,De Hydrophobes zeolithisches aluminosilicat mit hydrophiler aluminiumreicher oberflaeche und verfahren zu seiner herstellung
DE4429644A1 (de) * 1994-08-20 1996-02-22 Sued Chemie Ag Iodadsorptionsmittel
KR20000074883A (ko) * 1999-05-27 2000-12-15 토마스 케이. 맥브라이드 요오다이드 화합물로 오염된 유기 액체를 처리하는 방법
EP1134022A1 (de) * 2000-03-15 2001-09-19 Degussa AG Adsorbens
US8529662B2 (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane
JP5588181B2 (ja) * 2010-01-15 2014-09-10 東京瓦斯株式会社 高露点条件下の燃料ガス中の付臭剤除去用吸着剤及び付臭剤除去方法
CN101811023A (zh) * 2010-03-11 2010-08-25 上海复旭分子筛有限公司 醋酸深度脱碘吸附剂的制备方法及其产品和用途
CN101829542B (zh) * 2010-05-13 2012-11-21 复旦大学 一种高载银量沸石分子筛醋酸脱碘吸附剂及其制备方法
DE102010035510A1 (de) * 2010-08-25 2012-03-01 Areva Np Gmbh Verfahren zur Druckentlastung eines Kernkraftwerks, Druckentlastungssystem für ein Kernkraftwerk sowie zugehöriges Kernkraftwerk

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0175435A1 (en) * 1984-04-25 1986-03-26 Toray Industries, Inc. Adsorbent for and method of removing iodine compounds
US5075084A (en) * 1989-01-21 1991-12-24 Bayer Aktiengesellschaft Process for the removal of iodine and iodine compounds from hydrogen-containing gases and vapors
RU2091365C1 (ru) * 1991-10-18 1997-09-27 БП Кемикэлс Лтд Способ удаления примесей с*001-с*001*000-алкилйодидов из жидких карбоновых кислот с*002-с*006 и/или соответствующих ангидридов кислот, содержащих также примеси ионов металлов
US6380428B1 (en) * 1998-03-06 2002-04-30 Uop Llc Method for treating a liquid stream contaminated with an iodine-containing compound using a cation-exchanged zeolite
US6506935B1 (en) * 1998-03-06 2003-01-14 Uop Llc Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J. Stelzer et. All, "Hydrohobic properties of all-silica zeolite beta", Microporous and Mesoporous Materials, 22, 1998, 1-8. R.T. Jubin, "A Literature Survey jf Methods Remove Iodin from Off-Gas Streams Using Solide Sorbents", date issued 10.04.1979, стр. 28-41. *

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EP2731706A1 (de) 2014-05-21
BR112014024676B1 (pt) 2021-11-30
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DE202012012866U1 (de) 2014-02-06
BR112014024676A2 (pt) 2017-06-20
US20150110697A1 (en) 2015-04-23
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