CN107321302A - 甲基碘吸附剂、其用途以及用于吸附甲基碘的方法 - Google Patents

甲基碘吸附剂、其用途以及用于吸附甲基碘的方法 Download PDF

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Publication number
CN107321302A
CN107321302A CN201710570361.3A CN201710570361A CN107321302A CN 107321302 A CN107321302 A CN 107321302A CN 201710570361 A CN201710570361 A CN 201710570361A CN 107321302 A CN107321302 A CN 107321302A
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China
Prior art keywords
adsorbent
zeolite
weight
iodide
metal
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CN201710570361.3A
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English (en)
Chinese (zh)
Inventor
卡塔琳娜·多纳波尔
阿诺·蒂斯勒
米卡·恩德勒
奥拉夫·比特内尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
Clariant Produkte Deutschland GmbH
Areva GmbH
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Clariant International Ltd
Areva NP GmbH
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Publication of CN107321302A publication Critical patent/CN107321302A/zh
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  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
CN201710570361.3A 2012-04-02 2013-04-02 甲基碘吸附剂、其用途以及用于吸附甲基碘的方法 Pending CN107321302A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102012006542.6 2012-04-02
DE201210006542 DE102012006542A1 (de) 2012-04-02 2012-04-02 Methyliodidadsorber, Verwendung desselben und Verfahren zur Adsorption von Methyliodid
CN201380003133.8A CN103826739A (zh) 2012-04-02 2013-04-02 甲基碘吸附剂、其用途以及用于吸附甲基碘的方法

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117138747A (zh) * 2023-08-15 2023-12-01 中国辐射防护研究院 一种碘吸附材料及其制备方法、应用

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105080478B (zh) * 2014-05-14 2018-01-09 中国石油化工股份有限公司 从混合烷烃中分离低辛烷值组分的方法
US10937555B2 (en) * 2014-12-19 2021-03-02 Caverion Deutschland GmbH Nuclear power plant
GB2547132B (en) * 2015-02-26 2018-08-15 Johnson Matthey Plc Palladium-MAZ zeolite passive NOx adsorber and use thereof
EP3270384B1 (en) * 2015-03-12 2021-08-04 Rasa Industries, Ltd. Filtration material for filtered venting, use thereof and filtered venting device containing the same
JP6366532B2 (ja) * 2015-03-27 2018-08-01 日立Geニュークリア・エナジー株式会社 フィルタベント方法、フィルタベント装置及び原子力プラント
TWI740862B (zh) 2015-12-15 2021-10-01 荷蘭商蜆殼國際研究所 從環氧乙烷製造中的循環氣體流移除碘化物雜質之方法及系統
BR112018011943B1 (pt) 2015-12-15 2021-11-30 Shell Internationale Research Maatschappij B.V. Processo e sistema de reação para produção de óxido de etileno, carbonato de etileno e/ou etilenoglicol a partir de etileno
BR112018012058B1 (pt) 2015-12-15 2021-01-05 Shell Internationale Research Maatschappij B.V. processo para operar um sistema de leito de guarda
TWI723100B (zh) 2015-12-15 2021-04-01 荷蘭商蜆殼國際研究所 從環氧乙烷製造中的循環氣體流移除烷基碘雜質之方法及系統
JP6716247B2 (ja) * 2015-12-24 2020-07-01 株式会社荏原製作所 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法
CN105434462A (zh) * 2015-12-24 2016-03-30 上海复榆医药科技有限公司 碘负载皮肤杀菌剂及负载碘的方法
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
CN110993138A (zh) * 2019-11-06 2020-04-10 中国辐射防护研究院 一种放射性甲基碘法残液的无害化处理方法
DE102020113180B4 (de) * 2020-05-15 2025-11-06 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Vorrichtung zur Probennahme aus einem Abgasmassenstrom
US20230271136A1 (en) * 2020-07-31 2023-08-31 Mitsui Mining & Smelting Co., Ltd. Hydrocarbon adsorption material, exhaust gas cleaning catalyst, and exhaust gas cleaning system
CN112023874A (zh) * 2020-09-18 2020-12-04 上海复旭分子筛有限公司 用于深度脱除气相介质中碘化物的沸石分子筛吸附剂及其制备方法和应用
CN112403032A (zh) * 2020-11-18 2021-02-26 中国核动力研究设计院 一种均匀性水溶液核反应堆燃料溶液中99Mo、131I共提取的方法
KR102517786B1 (ko) 2021-03-23 2023-04-03 인천대학교 산학협력단 소달라이트 구조로 제올라이트간 변환을 통한 방사성 요오드 고정화용 흡착 물질 및 방사성 요오드 고정화 방법
KR102541017B1 (ko) 2021-03-24 2023-06-05 인천대학교 산학협력단 메탄건식개질 반응용 질화 NiN-제올라이트 촉매
JP7538767B2 (ja) 2021-04-16 2024-08-22 日立Geニュークリア・エナジー株式会社 放射性廃液処理方法
US20230083647A1 (en) * 2021-09-10 2023-03-16 Battelle Energy Alliance, Llc Reusable structures containing isotopes for simulating radioactive contamination environments, and methods of formation
CN114832621A (zh) * 2022-04-08 2022-08-02 中国辐射防护研究院 一种放射性甲基碘捕集预处理装置
CN115178230B (zh) * 2022-05-20 2023-05-23 西南科技大学 一种全硅沸石限域铜纳米粒子吸附剂的制备方法和应用
CN115814764A (zh) * 2022-11-18 2023-03-21 西安交通大学 一种基于分子筛的纤维膜及其制备方法和应用
CN117299078B (zh) * 2023-10-26 2025-12-05 浙江大学 一种铋负载无机多孔材料及其制备方法和在吸附碘甲烷和/或气态碘单质中的应用
CN117482904A (zh) * 2023-11-06 2024-02-02 西南科技大学 一种全硅沸石限域咪唑吸附剂的制备及应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4735786A (en) * 1984-04-25 1988-04-05 Toray Industries, Inc. Adsorbent for and method of removing iodine compounds
US5075084A (en) * 1989-01-21 1991-12-24 Bayer Aktiengesellschaft Process for the removal of iodine and iodine compounds from hydrogen-containing gases and vapors
CN1277885A (zh) * 1998-03-06 2000-12-27 环球油品公司 处理被碘化物污染的有机液体的方法
US20120051488A1 (en) * 2010-08-25 2012-03-01 Areva Np Gmbh Method for the Pressure Relief of a Nuclear Power Plant, Pressure-Relief System for a Nuclear Power Plant and Associated Nuclear Power Plant

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2109146C3 (de) * 1971-02-26 1980-03-20 Bayer Ag, 5090 Leverkusen Verfahren zur Entfernung von Jod und Jodverbindungen aus Gasen und Dämpfen und silbernitratimprägnierte Sorptionsmittel zur Durchführung des Verfahrens
US3852407A (en) * 1972-08-08 1974-12-03 Atomic Energy Commission Method for removing alkyl iodides from air by mercuric nitrate solution
JPS5847679B2 (ja) * 1979-04-14 1983-10-24 動力炉・核燃料開発事業団 気体中の放射性ヨウ素の除去方法
JPS56108532A (en) * 1980-02-04 1981-08-28 Hitachi Ltd Iodine adsorbing material and preparation thereof
JPS5891032A (ja) * 1981-11-26 1983-05-30 Toray Ind Inc ペンタシル型ゼオライトの製造法
JPS6168127A (ja) * 1984-09-10 1986-04-08 Hokkaido Electric Power Co Inc:The 金属添着吸着材によるヨウ素除去方法
DE3808742A1 (de) * 1988-03-16 1989-09-28 Kernforschungsz Karlsruhe Verfahren zur entfernung von iod und iodverbindungen aus gasen und daempfen mit silberhaltigem zeolith x
DD296899A5 (de) * 1990-08-02 1991-12-19 Schlicht,Burkhard,De Hydrophobes zeolithisches aluminosilicat mit hydrophiler aluminiumreicher oberflaeche und verfahren zu seiner herstellung
GB9122168D0 (en) * 1991-10-18 1991-11-27 Bp Chem Int Ltd Process
DE4429644A1 (de) * 1994-08-20 1996-02-22 Sued Chemie Ag Iodadsorptionsmittel
US6506935B1 (en) * 1998-03-06 2003-01-14 Uop Llc Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound
KR20000074883A (ko) * 1999-05-27 2000-12-15 토마스 케이. 맥브라이드 요오다이드 화합물로 오염된 유기 액체를 처리하는 방법
EP1134022A1 (de) * 2000-03-15 2001-09-19 Degussa AG Adsorbens
US8529662B2 (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane
JP5588181B2 (ja) * 2010-01-15 2014-09-10 東京瓦斯株式会社 高露点条件下の燃料ガス中の付臭剤除去用吸着剤及び付臭剤除去方法
CN101811023A (zh) * 2010-03-11 2010-08-25 上海复旭分子筛有限公司 醋酸深度脱碘吸附剂的制备方法及其产品和用途
CN101829542B (zh) * 2010-05-13 2012-11-21 复旦大学 一种高载银量沸石分子筛醋酸脱碘吸附剂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4735786A (en) * 1984-04-25 1988-04-05 Toray Industries, Inc. Adsorbent for and method of removing iodine compounds
US5075084A (en) * 1989-01-21 1991-12-24 Bayer Aktiengesellschaft Process for the removal of iodine and iodine compounds from hydrogen-containing gases and vapors
CN1277885A (zh) * 1998-03-06 2000-12-27 环球油品公司 处理被碘化物污染的有机液体的方法
US20120051488A1 (en) * 2010-08-25 2012-03-01 Areva Np Gmbh Method for the Pressure Relief of a Nuclear Power Plant, Pressure-Relief System for a Nuclear Power Plant and Associated Nuclear Power Plant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117138747A (zh) * 2023-08-15 2023-12-01 中国辐射防护研究院 一种碘吸附材料及其制备方法、应用

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