RU2432222C2 - Применение аминовых смесей для стержней, формованных литьем, и литейных металлов - Google Patents
Применение аминовых смесей для стержней, формованных литьем, и литейных металлов Download PDFInfo
- Publication number
- RU2432222C2 RU2432222C2 RU2009131704/02A RU2009131704A RU2432222C2 RU 2432222 C2 RU2432222 C2 RU 2432222C2 RU 2009131704/02 A RU2009131704/02 A RU 2009131704/02A RU 2009131704 A RU2009131704 A RU 2009131704A RU 2432222 C2 RU2432222 C2 RU 2432222C2
- Authority
- RU
- Russia
- Prior art keywords
- dmea
- tea
- mixture
- dema
- dmipa
- Prior art date
Links
- 150000001412 amines Chemical class 0.000 title claims description 74
- 229910052751 metal Inorganic materials 0.000 title claims description 9
- 239000002184 metal Substances 0.000 title claims description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 38
- 239000003054 catalyst Substances 0.000 claims abstract description 33
- 238000005266 casting Methods 0.000 claims abstract description 7
- 230000009257 reactivity Effects 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 159
- 239000000203 mixture Substances 0.000 claims description 104
- DAZXVJBJRMWXJP-UHFFFAOYSA-N n,n-dimethylethylamine Chemical compound CCN(C)C DAZXVJBJRMWXJP-UHFFFAOYSA-N 0.000 claims description 98
- 150000003512 tertiary amines Chemical class 0.000 claims description 47
- GNVRJGIVDSQCOP-UHFFFAOYSA-N n-ethyl-n-methylethanamine Chemical compound CCN(C)CC GNVRJGIVDSQCOP-UHFFFAOYSA-N 0.000 claims description 35
- 238000007711 solidification Methods 0.000 claims description 33
- 230000008023 solidification Effects 0.000 claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- VMOWKUTXPNPTEN-UHFFFAOYSA-N n,n-dimethylpropan-2-amine Chemical compound CC(C)N(C)C VMOWKUTXPNPTEN-UHFFFAOYSA-N 0.000 claims description 25
- 229920005989 resin Polymers 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 23
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000003110 molding sand Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- AXWLKJWVMMAXBD-UHFFFAOYSA-N 1-butylpiperidine Chemical class CCCCN1CCCCC1 AXWLKJWVMMAXBD-UHFFFAOYSA-N 0.000 claims description 2
- UJGVUACWGCQEAO-UHFFFAOYSA-N 1-ethylaziridine Chemical compound CCN1CC1 UJGVUACWGCQEAO-UHFFFAOYSA-N 0.000 claims description 2
- ONQBOTKLCMXPOF-UHFFFAOYSA-N 1-ethylpyrrolidine Chemical compound CCN1CCCC1 ONQBOTKLCMXPOF-UHFFFAOYSA-N 0.000 claims description 2
- WWYVZTLIFYLZFM-UHFFFAOYSA-N 1-methylazetidine Chemical compound CN1CCC1 WWYVZTLIFYLZFM-UHFFFAOYSA-N 0.000 claims description 2
- XLJQPXVBQNJNLW-UHFFFAOYSA-N 1-methylaziridine Chemical compound CN1CC1 XLJQPXVBQNJNLW-UHFFFAOYSA-N 0.000 claims description 2
- AVFZOVWCLRSYKC-UHFFFAOYSA-N 1-methylpyrrolidine Chemical compound CN1CCCC1 AVFZOVWCLRSYKC-UHFFFAOYSA-N 0.000 claims description 2
- LQWJONARYDIOSE-UHFFFAOYSA-N 1-pentylpiperidine Chemical class CCCCCN1CCCCC1 LQWJONARYDIOSE-UHFFFAOYSA-N 0.000 claims description 2
- NWRUFJHICAREBX-UHFFFAOYSA-N 1-pentylpyrrolidine Chemical class CCCCCN1CCCC1 NWRUFJHICAREBX-UHFFFAOYSA-N 0.000 claims description 2
- HLNRRPIYRBBHSQ-UHFFFAOYSA-N 1-propylpyrrolidine Chemical class CCCN1CCCC1 HLNRRPIYRBBHSQ-UHFFFAOYSA-N 0.000 claims description 2
- AHVYPIQETPWLSZ-UHFFFAOYSA-N N-methyl-pyrrolidine Natural products CN1CC=CC1 AHVYPIQETPWLSZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- PQZTVWVYCLIIJY-UHFFFAOYSA-N diethyl(propyl)amine Chemical class CCCN(CC)CC PQZTVWVYCLIIJY-UHFFFAOYSA-N 0.000 claims description 2
- GDHRQDYGUDOEIZ-UHFFFAOYSA-N n,n,2-trimethylpropan-1-amine Chemical compound CC(C)CN(C)C GDHRQDYGUDOEIZ-UHFFFAOYSA-N 0.000 claims description 2
- OXQMIXBVXHWDPX-UHFFFAOYSA-N n,n,2-trimethylpropan-2-amine Chemical compound CN(C)C(C)(C)C OXQMIXBVXHWDPX-UHFFFAOYSA-N 0.000 claims description 2
- VGIVLIHKENZQHQ-UHFFFAOYSA-N n,n,n',n'-tetramethylmethanediamine Chemical compound CN(C)CN(C)C VGIVLIHKENZQHQ-UHFFFAOYSA-N 0.000 claims description 2
- XHDKYWMKOLURNK-UHFFFAOYSA-N n,n-diethylhexan-1-amine Chemical class CCCCCCN(CC)CC XHDKYWMKOLURNK-UHFFFAOYSA-N 0.000 claims description 2
- YZULHOOBWDXEOT-UHFFFAOYSA-N n,n-diethylpentan-1-amine Chemical class CCCCCN(CC)CC YZULHOOBWDXEOT-UHFFFAOYSA-N 0.000 claims description 2
- LSICDRUYCNGRIF-UHFFFAOYSA-N n,n-dimethylheptan-1-amine Chemical class CCCCCCCN(C)C LSICDRUYCNGRIF-UHFFFAOYSA-N 0.000 claims description 2
- UQKAOOAFEFCDGT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine Chemical class CCCCCCCCN(C)C UQKAOOAFEFCDGT-UHFFFAOYSA-N 0.000 claims description 2
- IDFANOPDMXWIOP-UHFFFAOYSA-N n,n-dimethylpentan-1-amine Chemical class CCCCCN(C)C IDFANOPDMXWIOP-UHFFFAOYSA-N 0.000 claims description 2
- WOLFCKKMHUVEPN-UHFFFAOYSA-N n-ethyl-n-methylbutan-1-amine Chemical class CCCCN(C)CC WOLFCKKMHUVEPN-UHFFFAOYSA-N 0.000 claims description 2
- YBGSFVGRGACOAE-UHFFFAOYSA-N n-ethyl-n-methylheptan-1-amine Chemical class CCCCCCCN(C)CC YBGSFVGRGACOAE-UHFFFAOYSA-N 0.000 claims description 2
- GSVWUPPSQAZZTF-UHFFFAOYSA-N n-ethyl-n-methylhexan-1-amine Chemical class CCCCCCN(C)CC GSVWUPPSQAZZTF-UHFFFAOYSA-N 0.000 claims description 2
- SMBYUOXUISCLCF-UHFFFAOYSA-N n-ethyl-n-methylpropan-1-amine Chemical compound CCCN(C)CC SMBYUOXUISCLCF-UHFFFAOYSA-N 0.000 claims description 2
- UTLDDSNRFHWERZ-UHFFFAOYSA-N n-ethyl-n-methylpropan-2-amine Chemical compound CCN(C)C(C)C UTLDDSNRFHWERZ-UHFFFAOYSA-N 0.000 claims description 2
- ROUGWENZKICCJW-UHFFFAOYSA-N n-ethyl-n-propylpentan-1-amine Chemical class CCCCCN(CC)CCC ROUGWENZKICCJW-UHFFFAOYSA-N 0.000 claims description 2
- UVBMZKBIZUWTLV-UHFFFAOYSA-N n-methyl-n-propylpropan-1-amine Chemical class CCCN(C)CCC UVBMZKBIZUWTLV-UHFFFAOYSA-N 0.000 claims description 2
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical class CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 2
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 claims 10
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 claims 1
- ZEZOIRFVLXEXBC-UHFFFAOYSA-N 1-ethylazetidine Chemical compound CCN1CCC1 ZEZOIRFVLXEXBC-UHFFFAOYSA-N 0.000 claims 1
- MMMPMWQSPXSMAH-UHFFFAOYSA-N 1-propan-2-ylaziridine Chemical compound CC(C)N1CC1 MMMPMWQSPXSMAH-UHFFFAOYSA-N 0.000 claims 1
- APKJRCRGAMSYHH-UHFFFAOYSA-N 1-propylaziridine Chemical compound CCCN1CC1 APKJRCRGAMSYHH-UHFFFAOYSA-N 0.000 claims 1
- OUVIXBXUCNUWFU-UHFFFAOYSA-N N,N-dimethylbutan-1-amine N,N-dimethylbutan-2-amine Chemical compound CN(C)C(C)CC.CN(C)CCCC OUVIXBXUCNUWFU-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 239000012971 dimethylpiperazine Substances 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000004576 sand Substances 0.000 abstract description 25
- 239000000126 substance Substances 0.000 abstract description 6
- 238000005272 metallurgy Methods 0.000 abstract 1
- 238000010327 methods by industry Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 37
- -1 C 5 tertiary amines Chemical class 0.000 description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 28
- 239000005011 phenolic resin Substances 0.000 description 22
- 229920001568 phenolic resin Polymers 0.000 description 22
- 239000002904 solvent Substances 0.000 description 22
- 238000009835 boiling Methods 0.000 description 21
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 239000005056 polyisocyanate Substances 0.000 description 19
- 229920001228 polyisocyanate Polymers 0.000 description 19
- 150000002989 phenols Chemical class 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 150000001299 aldehydes Chemical class 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 239000004814 polyurethane Substances 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000003849 aromatic solvent Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003784 tall oil Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 150000005676 cyclic carbonates Chemical class 0.000 description 3
- 150000003997 cyclic ketones Chemical class 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004071 soot Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 description 2
- XQDNFAMOIPNVES-UHFFFAOYSA-N 3,5-Dimethoxyphenol Chemical compound COC1=CC(O)=CC(OC)=C1 XQDNFAMOIPNVES-UHFFFAOYSA-N 0.000 description 2
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 description 2
- MBGGFXOXUIDRJD-UHFFFAOYSA-N 4-Butoxyphenol Chemical compound CCCCOC1=CC=C(O)C=C1 MBGGFXOXUIDRJD-UHFFFAOYSA-N 0.000 description 2
- ZSBDGXGICLIJGD-UHFFFAOYSA-N 4-phenoxyphenol Chemical compound C1=CC(O)=CC=C1OC1=CC=CC=C1 ZSBDGXGICLIJGD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 125000003282 alkyl amino group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 239000003495 polar organic solvent Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 238000007712 rapid solidification Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- DDPRYTUJYNYJKV-UHFFFAOYSA-N 1,4-diethylpiperazine Chemical compound CCN1CCN(CC)CC1 DDPRYTUJYNYJKV-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- JSHASCFKOSDFHY-UHFFFAOYSA-N 1-butylpyrrolidine Chemical class CCCCN1CCCC1 JSHASCFKOSDFHY-UHFFFAOYSA-N 0.000 description 1
- VTDIWMPYBAVEDY-UHFFFAOYSA-N 1-propylpiperidine Chemical class CCCN1CCCCC1 VTDIWMPYBAVEDY-UHFFFAOYSA-N 0.000 description 1
- OLUNIGWWQYXBJA-UHFFFAOYSA-N 2,3,4-trimethoxyphenol Chemical compound COC1=CC=C(O)C(OC)=C1OC OLUNIGWWQYXBJA-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- MVRPPTGLVPEMPI-UHFFFAOYSA-N 2-cyclohexylphenol Chemical compound OC1=CC=CC=C1C1CCCCC1 MVRPPTGLVPEMPI-UHFFFAOYSA-N 0.000 description 1
- HRUHVKFKXJGKBQ-UHFFFAOYSA-N 3,5-dibutylphenol Chemical compound CCCCC1=CC(O)=CC(CCCC)=C1 HRUHVKFKXJGKBQ-UHFFFAOYSA-N 0.000 description 1
- PEZSSBYAUDZEMO-UHFFFAOYSA-N 3,5-dicyclohexylphenol Chemical compound C=1C(O)=CC(C2CCCCC2)=CC=1C1CCCCC1 PEZSSBYAUDZEMO-UHFFFAOYSA-N 0.000 description 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- LKVFCSWBKOVHAH-UHFFFAOYSA-N 4-Ethoxyphenol Chemical compound CCOC1=CC=C(O)C=C1 LKVFCSWBKOVHAH-UHFFFAOYSA-N 0.000 description 1
- CHQPRDVSUIJJNP-NSCUHMNNSA-N 4-[(e)-but-2-enyl]phenol Chemical compound C\C=C\CC1=CC=C(O)C=C1 CHQPRDVSUIJJNP-NSCUHMNNSA-N 0.000 description 1
- ILASIIGKRFKNQC-UHFFFAOYSA-N 4-methoxy-3-methylphenol Chemical compound COC1=CC=C(O)C=C1C ILASIIGKRFKNQC-UHFFFAOYSA-N 0.000 description 1
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 description 1
- ZNPSUQQXTRRSBM-UHFFFAOYSA-N 4-n-Pentylphenol Chemical compound CCCCCC1=CC=C(O)C=C1 ZNPSUQQXTRRSBM-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- NTDQQZYCCIDJRK-UHFFFAOYSA-N 4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C=C1 NTDQQZYCCIDJRK-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- DJEQZVQFEPKLOY-UHFFFAOYSA-N N,N-dimethylbutylamine Chemical compound CCCCN(C)C DJEQZVQFEPKLOY-UHFFFAOYSA-N 0.000 description 1
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical class [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- ORSUTASIQKBEFU-UHFFFAOYSA-N n,n-diethylbutan-1-amine Chemical class CCCCN(CC)CC ORSUTASIQKBEFU-UHFFFAOYSA-N 0.000 description 1
- USSPHSVODLAWSA-UHFFFAOYSA-N n,n-dimethylbutan-2-amine Chemical compound CCC(C)N(C)C USSPHSVODLAWSA-UHFFFAOYSA-N 0.000 description 1
- QMHNQZGXPNCMCO-UHFFFAOYSA-N n,n-dimethylhexan-1-amine Chemical class CCCCCCN(C)C QMHNQZGXPNCMCO-UHFFFAOYSA-N 0.000 description 1
- VJIRBKSBSKOOLV-UHFFFAOYSA-N n,n-dipropylbutan-1-amine Chemical class CCCCN(CCC)CCC VJIRBKSBSKOOLV-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- WJSIFDOFSKLUHL-UHFFFAOYSA-N n-ethyl-n-methylpentan-1-amine Chemical class CCCCCN(C)CC WJSIFDOFSKLUHL-UHFFFAOYSA-N 0.000 description 1
- XWCCTMBMQUCLSI-UHFFFAOYSA-N n-ethyl-n-propylpropan-1-amine Chemical class CCCN(CC)CCC XWCCTMBMQUCLSI-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 229940116423 propylene glycol diacetate Drugs 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 125000004149 thio group Chemical group *S* 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/12—Treating moulds or cores, e.g. drying, hardening
- B22C9/123—Gas-hardening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/02—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
- B22C1/10—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives for influencing the hardening tendency of the mould material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/162—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents use of a gaseous treating agent for hardening the binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/10—Cores; Manufacture or installation of cores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D15/00—Casting using a mould or core of which a part significant to the process is of high thermal conductivity, e.g. chill casting; Moulds or accessories specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D29/00—Removing castings from moulds, not restricted to casting processes covered by a single main group; Removing cores; Handling ingots
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mold Materials And Core Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07100920.3 | 2007-01-22 | ||
| EP07100920.3A EP1955792B1 (en) | 2007-01-22 | 2007-01-22 | Process for making foundry shaped cores and for casting metals |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2009131704A RU2009131704A (ru) | 2011-02-27 |
| RU2432222C2 true RU2432222C2 (ru) | 2011-10-27 |
Family
ID=37873122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009131704/02A RU2432222C2 (ru) | 2007-01-22 | 2008-01-22 | Применение аминовых смесей для стержней, формованных литьем, и литейных металлов |
Country Status (14)
| Country | Link |
|---|---|
| US (4) | US20100126690A1 (OSRAM) |
| EP (2) | EP1955792B1 (OSRAM) |
| JP (2) | JP5490545B2 (OSRAM) |
| KR (1) | KR101131033B1 (OSRAM) |
| CN (1) | CN101588880B (OSRAM) |
| BR (1) | BRPI0806620B1 (OSRAM) |
| ES (2) | ES2739455T3 (OSRAM) |
| HU (2) | HUE044427T2 (OSRAM) |
| MX (2) | MX385815B (OSRAM) |
| PL (2) | PL1955792T3 (OSRAM) |
| RU (1) | RU2432222C2 (OSRAM) |
| TR (1) | TR201911247T4 (OSRAM) |
| WO (1) | WO2008090161A1 (OSRAM) |
| ZA (1) | ZA200904537B (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010046981A1 (de) * | 2010-09-30 | 2012-04-05 | Ashland-Südchemie-Kernfest GmbH | Bindemittel enthaltend substituierte Benzole und Napthaline zur Herstellung von Kernen und Formen für den Metallguss, Formstoffmischung und Verfahren |
| JP6084610B2 (ja) * | 2011-07-19 | 2017-02-22 | エーエスケー ケミカルズ リミテッド パートナーシップ | 気体触媒を用いた鋳型形状の硬化処理方法 |
| CN102898317B (zh) * | 2012-10-12 | 2015-04-22 | 四川农业大学 | 用作免疫增强剂、代谢促进剂、强壮剂的有机胺类化合物及其制备方法和应用 |
| FR3017130B1 (fr) * | 2014-02-06 | 2019-10-18 | Arkema France | Composition d'amines a odeur masquee |
| KR101579549B1 (ko) | 2015-01-23 | 2015-12-22 | 에이비이씨기업 주식회사 | 콜드 박스 공정용 아민 가스 악취 중화방법 및 이를 적용한 아민 가스 제너레이터 |
| DE102015102952A1 (de) | 2015-03-02 | 2016-09-08 | Ask Chemicals Gmbh | Verfahren zur Aushärtung von Polyurethan-Bindemitteln in Formstoffmischungen durch Einleiten tertiärer Amine und Lösungsmittel und Kit zur Durchführung des Verfahrens |
| CN107282869B (zh) * | 2017-06-28 | 2019-05-14 | 山西科瑞再生资源综合利用有限公司 | 一种覆膜砂及其制备方法 |
| CN107716852B (zh) * | 2017-08-31 | 2024-05-14 | 山东鲁达轿车配件股份有限公司 | 一种abs齿圈冷芯盒及其制芯方法 |
| DE102018100694A1 (de) * | 2018-01-12 | 2019-07-18 | Ask Chemicals Gmbh | Formaldehydreduziertes Phenolharzbindemittel |
| DE102020118148A1 (de) | 2020-07-09 | 2022-01-13 | Bindur Gmbh | Formstoff zur Herstellung von Kernen und Verfahren zu dessen Härtung |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0177871A2 (en) * | 1984-10-12 | 1986-04-16 | Acme Resin Corporation | Polyurethane binder compositions |
| SU1256845A1 (ru) * | 1985-04-02 | 1986-09-15 | Белорусский Ордена Трудового Красного Знамени Политехнический Институт | Суспензи дл керамических форм и стержней по посто нным модел м и способ их изготовлени |
| EP0854159A1 (en) * | 1997-01-21 | 1998-07-22 | Sumitomo Bayer Urethane Co., Ltd. | Method for producing low-fuming rigid polyurethane foam |
| US5981622A (en) * | 1995-10-18 | 1999-11-09 | Borden Chemical, Inc. | Foundry binder of polyurethane, phenolic resin, polyisocyanate and epoxy resin |
| US20040051078A1 (en) * | 2002-09-12 | 2004-03-18 | Gernon Michael David | Reactive amine catalysts for use in PUCB foundry binder |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3225115A (en) * | 1960-12-28 | 1965-12-21 | Union Carbide Corp | Curable compositions containing epoxy alcohol, unsaturated polycarboxylic acid and unsaturated monomer |
| US3485797A (en) * | 1966-03-14 | 1969-12-23 | Ashland Oil Inc | Phenolic resins containing benzylic ether linkages and unsubstituted para positions |
| US3429848A (en) | 1966-08-01 | 1969-02-25 | Ashland Oil Inc | Foundry binder composition comprising benzylic ether resin,polyisocyanate,and tertiary amine |
| US3432457A (en) * | 1967-07-12 | 1969-03-11 | Ashland Oil Inc | Resinous composition comprising benzylic ether resin,polyisocyanate,and tertiary amine |
| US3676392A (en) * | 1971-01-26 | 1972-07-11 | Ashland Oil Inc | Resin compositions |
| US4293480A (en) | 1979-05-11 | 1981-10-06 | Ashland Oil, Inc. | Urethane binder compositions for no-bake and cold box foundry application utilizing isocyanato-urethane polymers |
| US4268425A (en) * | 1979-05-14 | 1981-05-19 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems containing a drying oil and use thereof |
| US4517222A (en) | 1983-03-10 | 1985-05-14 | Ashland Oil, Inc. | Vaporous amine catalyst spray method of applying a film to a substrate |
| DE3327711A1 (de) | 1983-07-29 | 1985-02-07 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur herstellung elektrisch isolierender verbundwerkstoffe |
| US4540724A (en) * | 1984-01-30 | 1985-09-10 | Ashland Oil Inc. | Phenolic resin-polyisocyanate binder systems containing a phosphorus halide and use thereof |
| US4590229A (en) * | 1984-06-04 | 1986-05-20 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems |
| US4634758A (en) * | 1984-10-12 | 1987-01-06 | Acme Resin Corporation | Process for preparing alkoxy-modified phenolic resole resins |
| US4683252A (en) | 1986-02-25 | 1987-07-28 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems containing an organohalophosphate and use thereof |
| DE3736775C1 (de) * | 1987-10-30 | 1988-04-28 | Daimler Benz Ag | Verfahren zum Haerten von Sandformkoerpern |
| US5286765A (en) * | 1989-09-15 | 1994-02-15 | Bayer Aktiengesellschaft | Process for the preparation of foundry cores and molds |
| US5077323A (en) * | 1989-10-10 | 1991-12-31 | Acme Resin Corporation | Method to improve flowability of alkaline phenolic resin coated sand |
| US5135043A (en) * | 1990-06-25 | 1992-08-04 | Omco Usa, Inc. | Apparatus and method for gas curing foundry cores and molds |
| US5447968A (en) * | 1993-07-23 | 1995-09-05 | Ashland Inc. | Polyurethane-forming binder systems containing 2,2'-dipyridyl, 1,10-phenanthroline, and their substituted alkyl derivatives |
| DE4327292C2 (de) | 1993-08-13 | 1996-04-25 | Ashland Suedchemie Kernfest | Bindemittel zur Herstellung von Gießereikernen und -formen und ihre Verwendung |
| US5698613A (en) | 1995-02-21 | 1997-12-16 | Mancuso Chemicals Limited | Chemical binder |
| DK0771599T4 (da) * | 1995-11-01 | 2004-05-17 | Huettenes Albertus | Bindemiddel-system på polyurethan-basis til stöbe-sands-blandinger til fremstilling af stöbeforme og -kerner |
| MX203069B (es) | 1996-08-08 | 2001-07-13 | Petramin Sa De Cv | La nueva aplicacion industrial de n, n-dimetilpropilamina para disminuir el olor de composiciones de aglutinantes de fundicion |
| US6017978A (en) | 1998-02-28 | 2000-01-25 | Ashland Inc. | Polyurethane forming no-bake foundry binders |
| ZA995240B (en) * | 1998-09-02 | 2000-02-21 | Ashland Inc | Amine cured foundry binder systems and their uses. |
| DE19850833C2 (de) | 1998-11-04 | 2001-06-13 | Ashland Suedchemie Kernfest | Bindemittelsystem zur Herstellung von Kernen und Gießformen auf Polyurethanbasis, deren Verwendung und Verfahren zur Herstellung eines Gießformteils auf Polyurethanbasis |
| US7495034B2 (en) * | 2002-02-22 | 2009-02-24 | Henkel Corporation | Deformable soft molding compositions |
| JP3879083B2 (ja) * | 2002-07-24 | 2007-02-07 | 東レ・ファインケミカル株式会社 | 硬化型組成物 |
| JP4369653B2 (ja) * | 2002-11-05 | 2009-11-25 | リグナイト株式会社 | 鋳型用レジンコーテッドサンド及び鋳型の製造方法 |
| JP4445232B2 (ja) * | 2003-09-08 | 2010-04-07 | 旭有機材工業株式会社 | 合成ムライト砂の処理方法 |
| US20050087321A1 (en) * | 2003-10-28 | 2005-04-28 | Thomas Hathaway | Apparatus for cleaning metal parts |
| DE102004014863A1 (de) | 2004-03-26 | 2005-10-13 | Wf-Maschinenbau Und Blechformtechnik Gmbh & Co Kg | Verfahren und Vorrichtung zur Herstellung eines außen profilierten Getriebeteils |
| WO2005092539A1 (en) | 2004-03-29 | 2005-10-06 | Mancuso Chemicals Limited | Novel catalytic composition |
| JP4452538B2 (ja) * | 2004-03-30 | 2010-04-21 | アシュランドジャパン株式会社 | 鋳型用鋳型製造方法 |
| JP4452553B2 (ja) | 2004-04-21 | 2010-04-21 | アシュランドジャパン株式会社 | ガスキュア型コールドボックス法鋳型用鋳型製造方法 |
| US20050250874A1 (en) * | 2004-05-04 | 2005-11-10 | Ha-International, Llc | Phenolic urethane foundry binder |
| JP2006289467A (ja) * | 2005-04-13 | 2006-10-26 | Hodogaya Ashland Kk | 鋳型製造用粘結剤組成物、鋳型製造用組成物、および鋳造用鋳型の製造方法 |
| MX337959B (es) | 2007-01-19 | 2016-03-29 | Huntsman Petrochemical Llc | Aminas terciarias bloqueadas con acidos polimericos. |
-
2007
- 2007-01-22 EP EP07100920.3A patent/EP1955792B1/en not_active Revoked
- 2007-01-22 HU HUE07100920 patent/HUE044427T2/hu unknown
- 2007-01-22 PL PL07100920T patent/PL1955792T3/pl unknown
- 2007-01-22 ES ES07100920T patent/ES2739455T3/es active Active
-
2008
- 2008-01-22 US US12/523,089 patent/US20100126690A1/en not_active Abandoned
- 2008-01-22 KR KR1020097015275A patent/KR101131033B1/ko active Active
- 2008-01-22 MX MX2016016196A patent/MX385815B/es unknown
- 2008-01-22 HU HUE08708087A patent/HUE045595T2/hu unknown
- 2008-01-22 RU RU2009131704/02A patent/RU2432222C2/ru active
- 2008-01-22 MX MX2009007800A patent/MX344137B/es active IP Right Grant
- 2008-01-22 EP EP08708087.5A patent/EP2106310B1/en not_active Revoked
- 2008-01-22 BR BRPI0806620-5A patent/BRPI0806620B1/pt active IP Right Grant
- 2008-01-22 TR TR2019/11247T patent/TR201911247T4/tr unknown
- 2008-01-22 PL PL08708087T patent/PL2106310T3/pl unknown
- 2008-01-22 ES ES08708087T patent/ES2739545T3/es active Active
- 2008-01-22 JP JP2009545952A patent/JP5490545B2/ja active Active
- 2008-01-22 ZA ZA200904537A patent/ZA200904537B/xx unknown
- 2008-01-22 CN CN200880002712XA patent/CN101588880B/zh active Active
- 2008-01-22 WO PCT/EP2008/050722 patent/WO2008090161A1/en not_active Ceased
-
2013
- 2013-04-04 JP JP2013078774A patent/JP2013173937A/ja active Pending
-
2015
- 2015-09-14 US US14/853,156 patent/US20160067768A1/en not_active Abandoned
-
2018
- 2018-05-29 US US15/991,707 patent/US10828696B2/en active Active
-
2020
- 2020-10-22 US US17/077,435 patent/US20210039158A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0177871A2 (en) * | 1984-10-12 | 1986-04-16 | Acme Resin Corporation | Polyurethane binder compositions |
| SU1256845A1 (ru) * | 1985-04-02 | 1986-09-15 | Белорусский Ордена Трудового Красного Знамени Политехнический Институт | Суспензи дл керамических форм и стержней по посто нным модел м и способ их изготовлени |
| US5981622A (en) * | 1995-10-18 | 1999-11-09 | Borden Chemical, Inc. | Foundry binder of polyurethane, phenolic resin, polyisocyanate and epoxy resin |
| EP0854159A1 (en) * | 1997-01-21 | 1998-07-22 | Sumitomo Bayer Urethane Co., Ltd. | Method for producing low-fuming rigid polyurethane foam |
| US20040051078A1 (en) * | 2002-09-12 | 2004-03-18 | Gernon Michael David | Reactive amine catalysts for use in PUCB foundry binder |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101131033B1 (ko) | 2012-04-12 |
| CN101588880A (zh) | 2009-11-25 |
| HUE045595T2 (hu) | 2020-01-28 |
| JP2013173937A (ja) | 2013-09-05 |
| BRPI0806620A2 (pt) | 2011-09-20 |
| JP5490545B2 (ja) | 2014-05-14 |
| US20100126690A1 (en) | 2010-05-27 |
| JP2010516470A (ja) | 2010-05-20 |
| ES2739455T3 (es) | 2020-01-31 |
| ZA200904537B (en) | 2010-09-29 |
| US20210039158A1 (en) | 2021-02-11 |
| US20160067768A1 (en) | 2016-03-10 |
| EP2106310A1 (en) | 2009-10-07 |
| US20180272421A1 (en) | 2018-09-27 |
| KR20090108041A (ko) | 2009-10-14 |
| EP2106310B1 (en) | 2019-05-22 |
| BRPI0806620B1 (pt) | 2019-02-19 |
| TR201911247T4 (tr) | 2019-08-21 |
| EP1955792B1 (en) | 2019-06-05 |
| MX385815B (es) | 2025-03-18 |
| ES2739545T3 (es) | 2020-01-31 |
| HUE044427T2 (hu) | 2019-10-28 |
| WO2008090161A1 (en) | 2008-07-31 |
| RU2009131704A (ru) | 2011-02-27 |
| US10828696B2 (en) | 2020-11-10 |
| CN101588880B (zh) | 2012-03-07 |
| MX344137B (es) | 2016-12-07 |
| MX2009007800A (es) | 2009-07-31 |
| PL2106310T3 (pl) | 2019-11-29 |
| PL1955792T3 (pl) | 2019-11-29 |
| EP1955792A1 (en) | 2008-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2432222C2 (ru) | Применение аминовых смесей для стержней, формованных литьем, и литейных металлов | |
| KR100871534B1 (ko) | 콜드 박스법에 의한 주물 모형의 제조 방법 | |
| RU2578603C2 (ru) | Связующее на основе полиуретана для получения стержней и литейных форм с применением изоцианатов, содержащих уретониминовую и/или карбодиимидную группу, смесь формовочных материалов, содержащая указанное связующее, и способ применения указанного связующего | |
| JP5408805B2 (ja) | 造型材料混合物、鋳造業のための鋳型の製造方法および鋳造業のための鋳型 | |
| CA2805506A1 (en) | Binder system based on polyurethane for producing cores and casting molds using cyclic formals, molding material mixture, and method | |
| RU2743950C9 (ru) | Связующее на основе фенольных смол бензилэфирного типа, содержащее свободный фенол и свободные гидроксибензиловые спирты | |
| JP6023714B2 (ja) | 鋳造用中子及び鋳型製造のための置換ベンゼン及びナフタレンを含有するバインダー、モールド材混合物及び方法 | |
| CA3083304A1 (en) | Phenolic resin binder with reduced formaldehyde content | |
| US6772820B2 (en) | Polyurethane based binder system for the manufacture of foundry cores and molds | |
| WO2008090159A1 (en) | Catalytic system for making foundry shaped cores and casting metals |