RU2352592C2 - Смеси полиолов и полученные из них полиуретаны - Google Patents
Смеси полиолов и полученные из них полиуретаны Download PDFInfo
- Publication number
- RU2352592C2 RU2352592C2 RU2005136653/04A RU2005136653A RU2352592C2 RU 2352592 C2 RU2352592 C2 RU 2352592C2 RU 2005136653/04 A RU2005136653/04 A RU 2005136653/04A RU 2005136653 A RU2005136653 A RU 2005136653A RU 2352592 C2 RU2352592 C2 RU 2352592C2
- Authority
- RU
- Russia
- Prior art keywords
- mixture
- polyols
- catalyst
- initiator
- polyol
- Prior art date
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- 229920005862 polyol Polymers 0.000 title claims abstract description 218
- 150000003077 polyols Chemical class 0.000 title claims abstract description 211
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- 239000004814 polyurethane Substances 0.000 title claims abstract description 17
- 239000003999 initiator Substances 0.000 claims abstract description 93
- 239000000203 mixture Substances 0.000 claims abstract description 85
- 239000003054 catalyst Substances 0.000 claims abstract description 76
- 239000000178 monomer Substances 0.000 claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 43
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 229920000768 polyamine Polymers 0.000 claims abstract description 14
- 230000035484 reaction time Effects 0.000 claims abstract description 13
- 150000001414 amino alcohols Chemical class 0.000 claims abstract description 8
- 230000003993 interaction Effects 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 6
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 77
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 37
- 235000011187 glycerol Nutrition 0.000 claims description 29
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims description 12
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 10
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 10
- 239000012974 tin catalyst Substances 0.000 claims description 10
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 9
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- 239000005720 sucrose Substances 0.000 claims description 9
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical group CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 9
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 8
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 8
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 8
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- 125000003277 amino group Chemical group 0.000 claims description 7
- 235000019421 lipase Nutrition 0.000 claims description 7
- 239000000600 sorbitol Substances 0.000 claims description 7
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 6
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 4
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 claims description 4
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical group OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 3
- SNOJPWLNAMAYSX-UHFFFAOYSA-N 2-methylpropan-1-ol;titanium Chemical compound [Ti].CC(C)CO.CC(C)CO.CC(C)CO.CC(C)CO SNOJPWLNAMAYSX-UHFFFAOYSA-N 0.000 claims description 2
- KIONPQSPGFQNGJ-UHFFFAOYSA-N ethyl heptanoate tin(2+) Chemical compound [Sn++].CCCCCCC(=O)OCC KIONPQSPGFQNGJ-UHFFFAOYSA-N 0.000 claims description 2
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 claims 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 7
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 5
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Images
Classifications
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Cited By (1)
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| RU2658398C2 (ru) * | 2013-08-23 | 2018-06-21 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Текстиль, соединенный с полиуретановыми пенами низкой плотности, полученными с использованием комбинации способов пенообразования и дутья |
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| CA2566626C (en) * | 2004-06-10 | 2013-04-30 | Randall C. Jenkines | Polyurethane carpet backings made using fatty acid amide polyols |
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- 2004-04-21 RU RU2005136653/04A patent/RU2352592C2/ru not_active IP Right Cessation
- 2004-04-21 BR BRPI0410530-3A patent/BRPI0410530B1/pt not_active IP Right Cessation
- 2004-04-21 MX MXPA05011487A patent/MXPA05011487A/es active IP Right Grant
- 2004-04-21 CN CNB2004800111155A patent/CN100439413C/zh not_active Expired - Fee Related
- 2004-04-21 US US10/553,767 patent/US7960444B2/en not_active Expired - Fee Related
- 2004-04-21 KR KR1020057020176A patent/KR101110522B1/ko not_active Expired - Fee Related
- 2004-04-21 CA CA2523507A patent/CA2523507C/en not_active Expired - Fee Related
- 2004-04-21 WO PCT/US2004/012427 patent/WO2004096882A1/en not_active Ceased
- 2004-04-21 DE DE602004012246T patent/DE602004012246T2/de not_active Expired - Lifetime
- 2004-04-21 AT AT04760326T patent/ATE388177T1/de not_active IP Right Cessation
- 2004-04-21 EP EP04760326A patent/EP1620483B1/en not_active Expired - Lifetime
- 2004-04-21 AU AU2004234367A patent/AU2004234367B2/en not_active Ceased
- 2004-04-22 MY MYPI20041473A patent/MY137938A/en unknown
- 2004-04-23 AR ARP040101403A patent/AR044086A1/es not_active Application Discontinuation
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Also Published As
| Publication number | Publication date |
|---|---|
| US20060276609A1 (en) | 2006-12-07 |
| KR101110522B1 (ko) | 2012-01-31 |
| JP2011080093A (ja) | 2011-04-21 |
| JP5662179B2 (ja) | 2015-01-28 |
| CN1780867A (zh) | 2006-05-31 |
| CN100355800C (zh) | 2007-12-19 |
| EP1620483B1 (en) | 2008-03-05 |
| AR044086A1 (es) | 2005-08-24 |
| DE602004012246D1 (de) | 2008-04-17 |
| CN1802396A (zh) | 2006-07-12 |
| CA2523507C (en) | 2014-01-28 |
| BRPI0410530B1 (pt) | 2014-08-26 |
| AU2004234367B2 (en) | 2008-09-11 |
| ATE388177T1 (de) | 2008-03-15 |
| BRPI0410530A (pt) | 2006-06-20 |
| CA2523507A1 (en) | 2004-11-11 |
| JP2006524744A (ja) | 2006-11-02 |
| AU2004234367A1 (en) | 2004-11-11 |
| DE602004012246T2 (de) | 2009-03-26 |
| MY137938A (en) | 2009-04-30 |
| KR20060005394A (ko) | 2006-01-17 |
| EP1620483A1 (en) | 2006-02-01 |
| US7960444B2 (en) | 2011-06-14 |
| MXPA05011487A (es) | 2005-12-15 |
| WO2004096882A1 (en) | 2004-11-11 |
| CN100439413C (zh) | 2008-12-03 |
| RU2005136653A (ru) | 2006-05-27 |
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