RU2014151995A - Способ нанесения на монолитную основу покрытия из компонента катализатора - Google Patents
Способ нанесения на монолитную основу покрытия из компонента катализатора Download PDFInfo
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- RU2014151995A RU2014151995A RU2014151995/04A RU2014151995A RU2014151995A RU 2014151995 A RU2014151995 A RU 2014151995A RU 2014151995/04 A RU2014151995/04 A RU 2014151995/04A RU 2014151995 A RU2014151995 A RU 2014151995A RU 2014151995 A RU2014151995 A RU 2014151995A
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- 239000011248 coating agent Substances 0.000 title claims abstract 15
- 238000000576 coating method Methods 0.000 title claims abstract 15
- 239000003054 catalyst Substances 0.000 title claims abstract 5
- 238000000034 method Methods 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 claims abstract 23
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000000463 material Substances 0.000 claims abstract 4
- 239000010457 zeolite Substances 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims abstract 3
- 239000002184 metal Substances 0.000 claims abstract 3
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 3
- 150000003624 transition metals Chemical group 0.000 claims abstract 3
- 239000012528 membrane Substances 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011148 porous material Substances 0.000 claims abstract 2
- 239000007787 solid Substances 0.000 claims abstract 2
- 238000011144 upstream manufacturing Methods 0.000 claims abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims 2
- 229910052676 chabazite Inorganic materials 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910001657 ferrierite group Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
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Abstract
1. Каталитическая монолитная основа фильтра с протеканием через стенки, на впускные каналы которой производителем монолитной основы фильтра с протеканием через стенки предварительно нанесен поверхностный мембранный слой, содержащий высокодисперсные огнеупорные твердотельные частицы, в которой выпускные каналы содержат пористое оксидное каталитическое покрытие с, по существу, равномерным в осевом направлении профилем, причем загрузка материала пористого оксидного каталитического покрытия в половине каталитической монолитной основы фильтра с протеканием через стенки в верхнем течении в осевом направлении составляет 10% от загрузки материала пористого оксидного каталитического покрытия в половине монолитной основы в нижнем течении в осевом направлении.2. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 1, в которой пористость монолитной основы фильтра с протеканием через стенки перед нанесением покрытия составляет от 40 до 80%.3. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 2, в которой средний объем пор монолитной основы фильтра с протеканием через стенки перед нанесением покрытия составляет от 8 до 45 мкм.4. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 3, в которой пористое оксидное каталитическое покрытие представляет собой ловушку NO, каталитический сажевый фильтр с пористым оксидным покрытием, содержащим поддерживаемый металл платиновой группы, или NH-SCR катализатор.5. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 4, в которой NH-SCR катализатор содержит цеолит с замещением переходным металлом.6.
Claims (6)
1. Каталитическая монолитная основа фильтра с протеканием через стенки, на впускные каналы которой производителем монолитной основы фильтра с протеканием через стенки предварительно нанесен поверхностный мембранный слой, содержащий высокодисперсные огнеупорные твердотельные частицы, в которой выпускные каналы содержат пористое оксидное каталитическое покрытие с, по существу, равномерным в осевом направлении профилем, причем загрузка материала пористого оксидного каталитического покрытия в половине каталитической монолитной основы фильтра с протеканием через стенки в верхнем течении в осевом направлении составляет 10% от загрузки материала пористого оксидного каталитического покрытия в половине монолитной основы в нижнем течении в осевом направлении.
2. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 1, в которой пористость монолитной основы фильтра с протеканием через стенки перед нанесением покрытия составляет от 40 до 80%.
3. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 2, в которой средний объем пор монолитной основы фильтра с протеканием через стенки перед нанесением покрытия составляет от 8 до 45 мкм.
4. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 3, в которой пористое оксидное каталитическое покрытие представляет собой ловушку NOx, каталитический сажевый фильтр с пористым оксидным покрытием, содержащим поддерживаемый металл платиновой группы, или NH3-SCR катализатор.
5. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 4, в которой NH3-SCR катализатор содержит цеолит с замещением переходным металлом.
6. Каталитическая монолитная основа фильтра с протеканием через стенки по п. 5, в которой переходный металл выбран из группы, состоящей из меди, железа, церия и смесей любых двух или более таких металлов, а цеолит выбран из группы, состоящей из феррьерита, шабазита (CHA), цеолита типа BEA и типа MFI (ZSM-5).
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