RU2010139430A - Бромированные полимеры в качестве пламягасителей и содержащие их полимерные системы - Google Patents
Бромированные полимеры в качестве пламягасителей и содержащие их полимерные системы Download PDFInfo
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- RU2010139430A RU2010139430A RU2010139430/05A RU2010139430A RU2010139430A RU 2010139430 A RU2010139430 A RU 2010139430A RU 2010139430/05 A RU2010139430/05 A RU 2010139430/05A RU 2010139430 A RU2010139430 A RU 2010139430A RU 2010139430 A RU2010139430 A RU 2010139430A
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- styrene
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- 229920000642 polymer Polymers 0.000 title claims abstract 34
- 239000000203 mixture Substances 0.000 claims abstract 16
- 229920001577 copolymer Polymers 0.000 claims abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract 8
- 229920003986 novolac Polymers 0.000 claims abstract 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000004793 Polystyrene Substances 0.000 claims abstract 4
- 239000000178 monomer Substances 0.000 claims abstract 4
- 229920002223 polystyrene Polymers 0.000 claims abstract 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 4
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 claims abstract 2
- FVFJQWWWSSTECI-UHFFFAOYSA-N 1-bromo-3-(3-bromo-2-hydroxypropoxy)propan-2-ol Chemical compound BrCC(O)COCC(O)CBr FVFJQWWWSSTECI-UHFFFAOYSA-N 0.000 claims abstract 2
- OXTQLGARXKFZMR-UHFFFAOYSA-N 3-(2,3-dibromopropyl)pyrrole-2,5-dione Chemical compound BrCC(Br)CC1=CC(=O)NC1=O OXTQLGARXKFZMR-UHFFFAOYSA-N 0.000 claims abstract 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims abstract 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000654 additive Substances 0.000 claims abstract 2
- 230000000996 additive effect Effects 0.000 claims abstract 2
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims abstract 2
- 229920001400 block copolymer Polymers 0.000 claims abstract 2
- 125000001246 bromo group Chemical group Br* 0.000 claims abstract 2
- MAYCNCJAIFGQIH-UHFFFAOYSA-N buta-1,3-diene 5-phenylpenta-2,4-dienenitrile Chemical compound C=CC=C.N#CC=CC=CC1=CC=CC=C1 MAYCNCJAIFGQIH-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- 239000003063 flame retardant Substances 0.000 claims abstract 2
- 229920000578 graft copolymer Polymers 0.000 claims abstract 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims abstract 2
- 229920002857 polybutadiene Polymers 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims abstract 2
- 229920005604 random copolymer Polymers 0.000 claims abstract 2
- 238000007152 ring opening metathesis polymerisation reaction Methods 0.000 claims abstract 2
- 239000006261 foam material Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 1
- 229930003836 cresol Natural products 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08L61/14—Modified phenol-aldehyde condensates
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- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
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- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/02—Homopolymers or copolymers of esters
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- C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
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- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
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- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Reinforced Plastic Materials (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1. Полимерная композиция, включающая горючий полимер, смешанный в ней с бромированной пламягасящей (FR) добавкой, выбранной из числа одного или нескольких приведенных ниже соединений: ! (i) сополимера, содержащего стирольные и 2,3-дибромпропилмалеинимидные повторяющиеся звенья; ! (ii) бромированного сложного полиэфира, содержащего связанные с алифатическими группами атомы брома; ! (iii) простого аллилового эфира бромированной по кольцу новолачной смолы; ! (iv) простого 3-бром-2-гидроксипропилового эфира новолачной смолы; ! (v) простого 2,3-дибромпропилового эфира крезолноволачной смолы, и ! (vi) бромированного полимера или сополимера, полученного методом ROMP. ! 2. Полимерная композиция по п.1, в которой горючий полимер представляет собой полимер или сополимер винилового ароматического мономера. ! 3. Полимерная композиция по п.2, в которой горючий полимер представляет собой полимер или сополимер стирола, альфа-метилстирола, 4-метилстирола, дивинилбензола или смеси любых двух или более из них. ! 4. Полимерная композиция по п.2, в которой горючий полимер представляет собой полистирол, сополимер стирол-акрилонитрил, сополимер стирол-акриловая кислота или стирол-акрилонитрил-бутадиеновые смолы. ! 5. Полимерная композиция по п.2, в которой горючий полимер представляет собой полистирол. ! 6. Полимерная композиция по п.2, в которой горючий полимер представляет собой статистический, блочный или привитой сополимер бутадиена и по меньшей мере одного винилового ароматического мономера. ! 7. Полимерная композиция по любому из пп.1-6, которая представляет собой вспененный материал.
Claims (7)
1. Полимерная композиция, включающая горючий полимер, смешанный в ней с бромированной пламягасящей (FR) добавкой, выбранной из числа одного или нескольких приведенных ниже соединений:
(i) сополимера, содержащего стирольные и 2,3-дибромпропилмалеинимидные повторяющиеся звенья;
(ii) бромированного сложного полиэфира, содержащего связанные с алифатическими группами атомы брома;
(iii) простого аллилового эфира бромированной по кольцу новолачной смолы;
(iv) простого 3-бром-2-гидроксипропилового эфира новолачной смолы;
(v) простого 2,3-дибромпропилового эфира крезолноволачной смолы, и
(vi) бромированного полимера или сополимера, полученного методом ROMP.
2. Полимерная композиция по п.1, в которой горючий полимер представляет собой полимер или сополимер винилового ароматического мономера.
3. Полимерная композиция по п.2, в которой горючий полимер представляет собой полимер или сополимер стирола, альфа-метилстирола, 4-метилстирола, дивинилбензола или смеси любых двух или более из них.
4. Полимерная композиция по п.2, в которой горючий полимер представляет собой полистирол, сополимер стирол-акрилонитрил, сополимер стирол-акриловая кислота или стирол-акрилонитрил-бутадиеновые смолы.
5. Полимерная композиция по п.2, в которой горючий полимер представляет собой полистирол.
6. Полимерная композиция по п.2, в которой горючий полимер представляет собой статистический, блочный или привитой сополимер бутадиена и по меньшей мере одного винилового ароматического мономера.
7. Полимерная композиция по любому из пп.1-6, которая представляет собой вспененный материал.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3147608P | 2008-02-26 | 2008-02-26 | |
| US61/031,476 | 2008-02-26 | ||
| PCT/US2009/032668 WO2009108453A1 (en) | 2008-02-26 | 2009-01-30 | Brominated polymers as flame additives and polymer systems containing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010139430A true RU2010139430A (ru) | 2012-04-20 |
| RU2483088C2 RU2483088C2 (ru) | 2013-05-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010139430/05A RU2483088C2 (ru) | 2008-02-26 | 2009-01-30 | Бромированные полимеры в качестве пламягасителей и содержащие их полимерные системы |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8242183B2 (ru) |
| EP (4) | EP2410016B1 (ru) |
| JP (4) | JP5243559B2 (ru) |
| CN (4) | CN102936382B (ru) |
| CA (2) | CA2903441C (ru) |
| ES (4) | ES2387940T3 (ru) |
| RU (1) | RU2483088C2 (ru) |
| WO (1) | WO2009108453A1 (ru) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| RU2506289C2 (ru) | 2008-10-31 | 2014-02-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Экструдированные полимерные пены, содержащие сложные эфиры сахара и бромированной жирной кислоты, в качествe добавки, ингибирующей воспламенение |
| WO2010080285A2 (en) | 2008-12-18 | 2010-07-15 | Dow Global Technologies Inc. | Stabilizers for polymers containing aliphatically-bound bromine |
| JP5612599B2 (ja) | 2008-12-19 | 2014-10-22 | ダウ グローバル テクノロジーズ エルエルシー | エステル溶媒混合物を使用するブタジエンポリマーの臭素化プロセス |
| US8710155B2 (en) | 2009-03-31 | 2014-04-29 | Dow Global Technologies Llc | Process for brominating unsaturated organic compounds with removal of quaternary ammonium or quaternary phosphonium monochlorides |
| JP2012532206A (ja) | 2009-06-30 | 2012-12-13 | ダウ グローバル テクノロジーズ エルエルシー | 臭素化及びエポキシ化難燃剤 |
| EP2960272B1 (en) * | 2013-02-14 | 2019-04-10 | Kaneka Corporation | Styrenic resin extruded foam and method for recycling same |
| CA2928728C (en) | 2013-10-30 | 2021-02-09 | Dow Global Technologies Llc | Foamed styrenic polymers containing a brominated styrene-butadiene copolymer and having enhanced cell size homogeneity |
| CN105793008B (zh) | 2013-12-19 | 2018-10-19 | 陶氏环球技术有限责任公司 | 硬质热塑性泡沫致密化方法和并有所述致密化硬质热塑性泡沫的复合结构 |
| RU2678442C2 (ru) * | 2014-03-28 | 2019-01-29 | ВЕРСАЛИС С.п.А. | Огнестойкие виниловые полимеры |
| CN109312108A (zh) | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| IT201600071347A1 (it) | 2016-07-08 | 2018-01-08 | Versalis Spa | Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità |
| CN108503810B (zh) * | 2018-05-11 | 2020-07-10 | 黄山嘉恒科技有限公司 | 一种户内粉末涂料用聚酯树脂及制备方法、一种粉末涂料 |
| RU2758427C1 (ru) * | 2021-01-25 | 2021-10-28 | федеральное государственное автономное образовательное учреждение высшего образования «Национальный исследовательский Томский политехнический университет» | Огнестойкая полимерная композиция на основе полидициклопентадиена |
| CN113896832A (zh) * | 2021-11-08 | 2022-01-07 | 复旦大学 | 一种溴系聚合物以及一种阻燃剂 |
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| RU2071424C1 (ru) * | 1993-09-21 | 1997-01-10 | Александр Григорьевич Гроздов | Способ получения самозатухающих слоистых пластиков |
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