RU2006138493A - Способ получения катализатора на основе серебра, катализатор и использование катализатора для окисления олефинов - Google Patents

Способ получения катализатора на основе серебра, катализатор и использование катализатора для окисления олефинов Download PDF

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RU2006138493A
RU2006138493A RU2006138493/04A RU2006138493A RU2006138493A RU 2006138493 A RU2006138493 A RU 2006138493A RU 2006138493/04 A RU2006138493/04 A RU 2006138493/04A RU 2006138493 A RU2006138493 A RU 2006138493A RU 2006138493 A RU2006138493 A RU 2006138493A
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catalyst
silver
carrier
mmol
producing
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RU2006138493/04A
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Цз нь ЛУ (US)
Цзянь ЛУ
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Publication of RU2006138493A publication Critical patent/RU2006138493A/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (13)

1. Способ получения катализатора, содержащего серебро на носителе, при этом способ включает
осаждение серебра на носитель, имеющий содержание экстрагируемых азотной кислотой силикатных компонентов менее чем 1000 частей на миллион, как масса SiO2 относительно массы носителя (млн.ч.в.), и
осаждение на носитель основания, имеющего рКb самое большее 3,5, измеренное в воде при 25°С, в количестве, по меньшей мере, 60 ммоль на кг носителя, одновременно или после осаждения серебра на носитель.
2. Способ по п. 1, в котором содержание экстрагируемых азотной кислотой силикатных компонентов составляет менее 800 млн.ч.в.
3. Способ по п.1 или 2, в котором способ включает пропитку носителя раствором, содержащим соединение серебра и основание, имеющее величину рКb самое большее 3,5, измеренную в воде при 25°С, в количестве, по меньшей мере, 60 ммоль на кг носителя.
4. Способ по п.3, в котором пропиточный раствор имеет величину рН, по меньшей мере, 14, измеренную при температуре 20°С.
5. Способ по любому из пп.1 и 2 или 4, в котором основание имеет величину рКb самое большее 2, в частности самое большее 1, измеренную в воде при 25°С.
6. Способ по любому из пп.1 и 2 или 4, в котором основанием является гидроксид или алкосид, в частности гидроксид лития.
7. Способ по любому из пп.1 и 2 или 4, в котором основание осаждено в количестве, лежащем в интервале от 60 до 100 ммоль/кг, относительно массы носителя.
8. Способ по любому из пп.1 и 2 или 4, в котором серебро осаждено на носитель в количестве, лежащем в интервале от 100 до 400 г/кг, относительно массы катализатора.
9. Способ по любому из пп.1 и 2 или 4, в котором помимо серебра и основания на носитель осаждена одна или несколько высоко селективных присадок, включающих один или несколько таких элементов, как рений, молибден, хром и вольфрам, для получения катализатора, имеющего общее содержание высоко селективной присадки от 0,01 до 500 ммоль/кг, рассчитанное на элемент, то есть, общее количество рения, молибдена, хрома и/или вольфрама на общее количество катализатора.
10. Способ по п.9, в котором помимо серебра и основания на носитель осажден рениевый компонент и рениевый со-промотор, выбранный из компонент, которые включают один или несколько таких элементов, как вольфрам, хром, молибден, сера, фосфор и бор, в количестве, достаточном для получения катализатора, имеющего содержание рениевой компоненты в интервале значений от 0,01 до 50 ммоль/кг, в частности от 0,1 до 10 ммоль/кг, рассчитанное как количество рения относительно массы катализатора, и имеющего общее содержание рениевого со-промотора в интервале значений от 0,01 до 50 ммоль/кг, в частности от 0,1 до 10 ммоль/кг, рассчитанное как элемент, то есть общее количество вольфрама, хрома, молибдена, серы, фосфора и/или бора относительно массы катализатора.
11. Катализатор, который может быть получен способом получения катализатора по любому из пп.1-10.
12. Способ получения оксида олефина взаимодействием олефина с кислородом в присутствии катализатора, который может быть получен способом получения катализатора по любому из пп.1-10.
13. Способ получения 1,2-алкандиола, простого эфира 1,2-алкандиола или 1,2-алканоламина, включающий
получение оксида олефина взаимодействием олефина с кислородом в присутствии катализатора, который может быть получен способом получения катализатора по любому из пп.1-10, и
превращение оксида олефина в 1,2-алкандиол, простой эфир 1,2-алкандиола или 1,2-алканоламин.
RU2006138493/04A 2004-04-01 2005-03-31 Способ получения катализатора на основе серебра, катализатор и использование катализатора для окисления олефинов RU2006138493A (ru)

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US60/558,464 2004-04-01

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US (1) US20050222441A1 (ru)
EP (1) EP1732685A1 (ru)
JP (1) JP2007531621A (ru)
KR (1) KR20070015939A (ru)
CN (1) CN1938084A (ru)
AU (1) AU2005231765A1 (ru)
BR (1) BRPI0509483A (ru)
CA (1) CA2561857A1 (ru)
IN (1) IN2006DE05680A (ru)
MX (1) MXPA06011091A (ru)
RU (1) RU2006138493A (ru)
TW (1) TW200613056A (ru)
WO (1) WO2005097315A1 (ru)
ZA (1) ZA200607830B (ru)

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CN1938084A (zh) 2007-03-28
IN2006DE05680A (ru) 2007-06-15
TW200613056A (en) 2006-05-01
KR20070015939A (ko) 2007-02-06
AU2005231765A1 (en) 2005-10-20
WO2005097315A1 (en) 2005-10-20
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CA2561857A1 (en) 2005-10-20
US20050222441A1 (en) 2005-10-06

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