RU2005123338A - Эмульсионная полимеризация фторированных мономеров - Google Patents

Эмульсионная полимеризация фторированных мономеров Download PDF

Info

Publication number
RU2005123338A
RU2005123338A RU2005123338/04A RU2005123338A RU2005123338A RU 2005123338 A RU2005123338 A RU 2005123338A RU 2005123338/04 A RU2005123338/04 A RU 2005123338/04A RU 2005123338 A RU2005123338 A RU 2005123338A RU 2005123338 A RU2005123338 A RU 2005123338A
Authority
RU
Russia
Prior art keywords
groups
formula
cation
fluorine
carbon atoms
Prior art date
Application number
RU2005123338/04A
Other languages
English (en)
Inventor
Лиан С. ТАН (US)
Лиан С. ТАН
Ричард С. БУКАНИН (US)
Ричард С. БУКАНИН
Original Assignee
ЗМ Инновейтив Пропертиз Компани (US)
Зм Инновейтив Пропертиз Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЗМ Инновейтив Пропертиз Компани (US), Зм Инновейтив Пропертиз Компани filed Critical ЗМ Инновейтив Пропертиз Компани (US)
Publication of RU2005123338A publication Critical patent/RU2005123338A/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D06M15/353—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/568—Reaction products of isocyanates with polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

Claims (11)

1. Способ, состоящий в добавлении фторированного поверхностно-активного вещества с молекулярным весом по меньшей мере примерно 1000 г/моль в процессе эмульсионной полимеризации.
2. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество является перфторполиэфиром, содержащим одну или несколько гидрофильных групп.
3. Способ по п.2, отличающийся тем, что указанные гидрофильные группы включают группы карбоксильных кислот и их солей.
4. Способ по п.2, отличающийся тем, что указанный перфторполиэфир включает вещества, соответствующие формуле
Rf a-O-(CF2O)k(CF2CF2O)p(CF(CF3)CF2O)q-Ql-COOM, или
MOOC-Ql-O-(CF2O)k(CF2CF2O)p(CF(CF3)CF2O)q-Q2-COOZ
где каждая из величин k, р и q представляет собой число от 0 до 15, Rf a представляет собой перфторалкильную группу длиной от 2 до 4 атомов углерода, М и Z - независимо друг от друга представляют собой водород или катион, а Q1 и Q2 независимо друг от друга представляют собой -CF2- или -CF(CF3)-.
5. Способ по п.4, отличающийся тем, что указанный катион является одновалентным катионом.
6. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество имеет формулу
Rf a-O-(CFXCF2O)r-CFX-COOM,
где Rfa представляет собой перфторалкильную группу длиной от 2 до 4 атомов углерода, М представляет собой водород или катион, Х - атом водорода или атом фтора, а r имеет величину от 2 до 15.
7. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество включает перфторполимеры, которые содержат повторяющиеся фрагменты, получаемые из мономера с формулой
Figure 00000001
где s - это 0, 1 или 2, и t - целое число от 2 до 4, a G - остаток, содержащий одну или несколько гидрофильных групп.
8. Способ по п.7, отличающийся тем, что указанные гидрофильные группы являются неионогенными группами, анионными группами или катионными группами.
9. Способ по п.8, отличающийся тем, что указанные неионогенные группы включают -SO2F, гидроксиалкилен, гидроксиарилен или сложный эфир с формулой -COOR, где R - алкильная группа длиной от 1 до 3 атомов углерода.
10. Способ по п.1, отличающийся тем, что указанные анионные группы включают карбоксильные группы или сульфонатные группы.
11. Способ по п.1, отличающийся тем, что указанные катионные группы включают алкиламонийные группы.
RU2005123338/04A 2003-01-24 2003-12-05 Эмульсионная полимеризация фторированных мономеров RU2005123338A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/350,457 US7045571B2 (en) 2001-05-21 2003-01-24 Emulsion polymerization of fluorinated monomers
US10/350,457 2003-01-24

Publications (1)

Publication Number Publication Date
RU2005123338A true RU2005123338A (ru) 2006-02-10

Family

ID=32823704

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2005123338/04A RU2005123338A (ru) 2003-01-24 2003-12-05 Эмульсионная полимеризация фторированных мономеров

Country Status (8)

Country Link
US (2) US7045571B2 (ru)
EP (1) EP1622949A1 (ru)
JP (1) JP2006513303A (ru)
CN (1) CN1742027A (ru)
AU (1) AU2003300980A1 (ru)
RU (1) RU2005123338A (ru)
WO (1) WO2004067588A1 (ru)
ZA (1) ZA200506758B (ru)

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
WO2005007707A1 (ja) 2003-07-16 2005-01-27 Daikin Industries, Ltd. 含フッ素重合体の製造方法、含フッ素重合体水性分散液、２−アシルオキシカルボン酸誘導体及び界面活性剤
JP4687677B2 (ja) * 2003-07-16 2011-05-25 ダイキン工業株式会社 含フッ素重合体の製造方法、含フッ素重合体水性分散液、２−アシルオキシカルボン酸誘導体及び界面活性剤
US7652115B2 (en) * 2003-09-08 2010-01-26 3M Innovative Properties Company Fluorinated polyether isocyanate derived silane compositions
WO2005037880A1 (ja) * 2003-10-22 2005-04-28 Daikin Industries, Ltd. テトラフルオロエチレン重合体水性分散液、その製造方法、テトラフルオロエチレン重合体粉末及びテトラフルオロエチレン重合体成形体
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7141537B2 (en) * 2003-10-30 2006-11-28 3M Innovative Properties Company Mixture of fluorinated polyethers and use thereof as surfactant
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7259208B2 (en) 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7803894B2 (en) * 2003-12-05 2010-09-28 3M Innovatie Properties Company Coating compositions with perfluoropolyetherisocyanate derived silane and alkoxysilanes
US7112614B2 (en) 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
DE602004021467D1 (de) * 2004-03-01 2009-07-23 3M Innovative Properties Co Verfahren zum Beschichten eines Gegenstands mit einer fluorhaltigen Kunststoffsdispersion
ITMI20050188A1 (it) * 2005-02-10 2006-08-11 Solvay Solexis Spa Composizioni acquose contenenti sali di-carbossilici perfluoropolieterei per il trattamento oleorepellente della carta
WO2006102670A1 (en) * 2005-03-24 2006-09-28 E. I. Du Pont De Nemours And Company Process to prepare stable trifluorostyrene containing compounds grafted to base polymers
US8814861B2 (en) 2005-05-12 2014-08-26 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US7147634B2 (en) 2005-05-12 2006-12-12 Orion Industries, Ltd. Electrosurgical electrode and method of manufacturing same
GB0511779D0 (en) * 2005-06-10 2005-07-20 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
US8338518B2 (en) * 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
GB2427170A (en) * 2005-06-17 2006-12-20 3M Innovative Properties Co Fluoropolymer film having glass microspheres
DE602005005317T2 (de) * 2005-07-07 2009-03-12 Solvay Solexis S.P.A. Polymerisationsverfahren
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0525978D0 (en) * 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
US7795332B2 (en) 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
US8124699B2 (en) * 2005-08-08 2012-02-28 Arkema Inc. Polymerization of fluoropolymers using alkyl phosphonate surfactants
GB2430437A (en) * 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
EP1939222B2 (en) * 2005-10-17 2019-09-04 AGC Inc. Process for producing an AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION, AND POLYTETRAFLUOROETHYLENE FINE POWDER AND POROUS MATERIAL PRODUCED FROM THE SAME
JP5391550B2 (ja) * 2005-10-20 2014-01-15 旭硝子株式会社 溶融成形可能なフッ素樹脂の製造方法
US7728087B2 (en) * 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754795B2 (en) * 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US7629397B2 (en) * 2006-06-23 2009-12-08 Exxonmobil Chemical Patents Inc. Phase separation process utilizing a hydrofluorocarbon
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
BRPI0807109A2 (pt) * 2007-02-16 2014-05-06 3M Innovative Properties Co Sistema e processo para a remoção de fluoroquiímicos da água
US20080264864A1 (en) * 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
WO2008147796A1 (en) * 2007-05-23 2008-12-04 3M Innovative Properties Company Aqueous compositions of fluorinated surfactants and methods of using the same
JP5453250B2 (ja) * 2007-06-06 2014-03-26 スリーエム イノベイティブ プロパティズ カンパニー フッ素化エーテル組成物及びフッ素化エーテル組成物の使用方法
US7399887B1 (en) 2007-08-06 2008-07-15 E. I. Du Pont De Nemours And Company Fluorinated sulfonate surfactants
US9893337B2 (en) 2008-02-13 2018-02-13 Seeo, Inc. Multi-phase electrolyte lithium batteries
WO2010009191A2 (en) * 2008-07-18 2010-01-21 3M Innovative Properties Company Fluorinated ether compounds and methods of using the same
US20100113691A1 (en) * 2008-11-06 2010-05-06 E. I. Du Pont De Nemours And Company Fluoro olefin polymerization
EP2358779A4 (en) * 2008-11-25 2012-05-09 3M Innovative Properties Co Fluorinated ethurethenes and methods for their use
US8629089B2 (en) 2008-12-18 2014-01-14 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
US8058376B2 (en) 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
US8436054B2 (en) * 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
US8436053B2 (en) 2008-12-23 2013-05-07 E.I. Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8153738B2 (en) * 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US9000069B1 (en) 2010-07-02 2015-04-07 The Sherwin-Williams Company Self-stratifying coatings
KR101449356B1 (ko) 2010-09-22 2014-10-08 다이킨 고교 가부시키가이샤 필름 콘덴서용 필름 및 필름 콘덴서
JP6377525B2 (ja) 2011-08-04 2018-08-22 ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． イオン化フルオロポリマーの組成物
EP2788318A2 (en) * 2011-12-06 2014-10-15 3M Innovative Properties Company Fluorinated oligomers having pendant functional groups
EP2935370A1 (en) * 2012-12-18 2015-10-28 E. I. du Pont de Nemours and Company Process for producing fluoroelastomers
JPWO2016072397A1 (ja) * 2014-11-07 2017-10-12 旭硝子株式会社 含フッ素エラストマー、含フッ素エラストマー組成物、含フッ素エラストマー架橋物品
US9923245B2 (en) 2015-04-03 2018-03-20 Seeo, Inc. Fluorinated alkali ion electrolytes with urethane groups
WO2016164505A1 (en) 2015-04-07 2016-10-13 Seeo, Inc. Fluorinated alkali ion electrolytes with cyclic carbonate groups
EP3295502B1 (en) 2015-05-12 2021-06-23 Seeo, Inc Copolymers of peo and fluorinated polymers as electrolytes for lithium batteries
WO2016200559A1 (en) 2015-06-09 2016-12-15 Seeo, Inc. Peo-based graft copolymers with pendant fluorinated groups for use as electrolytes
WO2017019163A1 (en) * 2015-07-28 2017-02-02 Seeo, Inc. Multi-phase electrolyte lithium batteries
EP3455896A4 (en) 2016-05-10 2020-01-01 Seeo, Inc FLUORED ELECTROLYTE WITH NITRILE GROUPS
CN108017746B (zh) * 2016-10-28 2020-03-20 中昊晨光化工研究院有限公司 一种低压缩永久变形的过氧化物硫化氟橡胶及其制备方法
JP6974784B2 (ja) 2018-03-01 2021-12-01 ダイキン工業株式会社 フルオロポリマーの製造方法
CN113039241B (zh) 2018-11-19 2023-11-07 大金工业株式会社 组合物和拉伸体
JP7174272B2 (ja) 2018-11-19 2022-11-17 ダイキン工業株式会社 変性ポリテトラフルオロエチレンの製造方法及び組成物
EP3960713A4 (en) 2019-04-26 2023-01-18 Daikin Industries, Ltd. WATER TREATMENT METHOD AND COMPOSITION
EP3960773A4 (en) 2019-04-26 2023-01-04 Daikin Industries, Ltd. METHOD FOR PRODUCING AQUEOUS FLUOROPOLYMER DISPERSION, METHOD FOR DRAINAGE TREATMENT AND AQUEOUS FLUOROPOLYMER DISPERSION
JP7231868B2 (ja) 2019-09-05 2023-03-02 ダイキン工業株式会社 組成物およびその製造方法
JP7368759B2 (ja) 2019-09-05 2023-10-25 ダイキン工業株式会社 パーフルオロエラストマーの製造方法および組成物
CN114651018A (zh) 2019-11-19 2022-06-21 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯的制造方法、全氟弹性体的制造方法和组合物
WO2021194588A1 (en) * 2020-03-23 2021-09-30 Energao, Inc. Ion-conductive polymeric materials as electrolytes for fuel cells
JP7303993B2 (ja) * 2020-10-09 2023-07-06 星光Pmc株式会社 エマルション組成物の製造方法
EP4249516A1 (en) 2020-11-19 2023-09-27 Daikin Industries, Ltd. Method for producing polytetrafluoroethylene, and composition containing polytetrafluoroethylene
WO2022107890A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 パーフルオロエラストマー水性分散液の製造方法、組成物、架橋性組成物および架橋物
WO2022107891A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法および組成物
WO2022181849A1 (ja) * 2021-02-26 2022-09-01 ダイキン工業株式会社 含フッ素共重合体
EP4306553A1 (en) 2021-03-10 2024-01-17 Daikin Industries, Ltd. Coating composition, coating film, layered product, and coated article
EP4342921A1 (en) 2021-05-19 2024-03-27 Daikin Industries, Ltd. Method for producing fluoropolymer, method for producing polytetrafluoroethylene, and composition
WO2022260139A1 (ja) 2021-06-11 2022-12-15 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液
JPWO2023277139A1 (ru) 2021-06-30 2023-01-05
JPWO2023277140A1 (ru) 2021-06-30 2023-01-05

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US531935A (en) * 1895-01-01 Apparatus for demonstrating laws of gravity and mechanics
US2567011A (en) 1949-01-10 1951-09-04 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2732398A (en) 1953-01-29 1956-01-24 cafiicfzsojk
US2809990A (en) 1955-12-29 1957-10-15 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3136745A (en) 1961-06-23 1964-06-09 Du Pont Elastomeric copolymers of vinylidene fluoride and perfluoroalkyl perfluorovinyl ethers
US3450684A (en) 1963-07-24 1969-06-17 Du Pont Fluorocarbon polyethers
US3450562A (en) 1965-06-18 1969-06-17 Du Pont Cellulosic materials coated with an organic polycarbodiimide
DE1720799A1 (de) 1968-03-09 1970-05-14 Hoechst Ag Verfahren zur Herstellung von polymeren Fluoralkyl-vinyl-aethern
US3642742A (en) 1969-04-22 1972-02-15 Du Pont Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers
US3635926A (en) 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US4029867A (en) 1971-02-22 1977-06-14 The United States Of America As Represented By The Secretary Of Agriculture Terpolymers of fluoroalkyl ethers and maleic anhydride
JPS512560B2 (ru) 1972-03-06 1976-01-27
US4024178A (en) 1972-03-06 1977-05-17 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical containing carbodiimides
US3755242A (en) 1972-04-10 1973-08-28 Minnesota Mining & Mfg Polycarbodiimide prepolymers
US3855191A (en) 1973-04-04 1974-12-17 Du Pont Polytetrafluoroethylene molding powders of tetrafluoroethylene and perfluoro (alkyl vinyl ether) copolymer
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
DE2639109A1 (de) 1976-08-31 1978-03-09 Hoechst Ag Copolymerisate des tetrafluoraethylens und verfahren zu deren herstellung
US4215205A (en) 1977-01-12 1980-07-29 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical and carbodiimide containing compositions for fabric treatment
JPS598459B2 (ja) 1979-05-04 1984-02-24 三菱自動車工業株式会社 複動型式のプレス型材
JPS5718710A (en) 1980-07-08 1982-01-30 Asahi Glass Co Ltd Copolymer capable of giving elastomer containing fluorine having improved cold and oil resistance
JPS5770112A (en) 1980-10-21 1982-04-30 Nok Corp Polymerization of fluorine-containing monomer
JPS57109810A (en) 1980-12-26 1982-07-08 Asahi Glass Co Ltd Copolymer giving fluorine-containing elastomer with cold and alcohol resistance
DE3135598A1 (de) 1981-09-09 1983-03-17 Hoechst Ag, 6000 Frankfurt "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver"
JPS5869213A (ja) 1981-09-21 1983-04-25 Daikin Ind Ltd 含フツ素共重合体
US4525305A (en) * 1982-10-25 1985-06-25 Minnesota Mining And Manufacturing Company Leather with fluorochemical finish
US4977219A (en) 1983-02-24 1990-12-11 Union Carbide Chemicals And Plastics Company, Inc. Low temperature crosslinking of water-borne resins
US4587301A (en) 1983-02-24 1986-05-06 Union Carbide Corporation Method of using mixed aliphatic/aromatic polycarbodiimides
US4487964A (en) 1983-02-24 1984-12-11 Union Carbide Corporation Method of making mixed aliphatic/aromatic polycarbodiimides
US4668726A (en) 1984-03-30 1987-05-26 Minnesota Mining And Manufacturing Company Cationic and non-ionic fluorochemicals and fibrous substrates treated therewith
US4588796A (en) 1984-04-23 1986-05-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using fluoroxy compound solution as initiator
EP0186186B1 (en) 1984-12-27 1991-07-24 Asahi Glass Company Ltd. Curable resin composition
JPS61201078A (ja) 1985-02-28 1986-09-05 ダイキン工業株式会社 新規な含浸物品
US5110385A (en) 1985-05-31 1992-05-05 The Dow Chemical Company Method for forming polymer composite films using a removable substrate
JPS6289713A (ja) 1985-10-12 1987-04-24 Daikin Ind Ltd 新規フルオロエラストマー
IL82308A (en) * 1986-06-26 1990-11-29 Ausimont Spa Microemulsions containing perfluoropolyethers
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
JPS6356532A (ja) 1986-08-27 1988-03-11 Daikin Ind Ltd 変性ポリテトラフルオロエチレンファインパウダ−及びその製造方法
US4861845A (en) 1988-03-10 1989-08-29 E. I. Du Pont De Nemours And Company Polymerization of fluoroolefins
US4929471A (en) 1989-04-13 1990-05-29 The Balson-Hercules Group Ltd. Method of treating polyester fabric
JP2796385B2 (ja) 1989-12-22 1998-09-10 ミネソタ マイニング アンド マニユフアクチユアリング カンパニー 撥水撥油処理剤
DE4124134A1 (de) 1991-07-20 1993-01-21 Hoechst Ag Konzentrierte, waessrige dispersionen von tetrafluorethylen-polymeren, verfahren zu deren herstellung und deren verwendung
DE4213154C1 (ru) 1992-04-22 1993-06-17 Hoechst Ag, 6230 Frankfurt, De
US5352400A (en) 1992-04-29 1994-10-04 E. I. Du Pont De Nemours And Company Carbodiimides and processes therefor
US5453477A (en) 1992-05-01 1995-09-26 Alliedsignal Inc. Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite
US5285002A (en) * 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
IT1264125B1 (it) 1993-03-30 1996-09-16 Ausimont Spa Fluoroelastomeri dotati di elevata resistenza ai solventi polari ed alle basi
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
DE4402694A1 (de) 1993-06-02 1995-08-03 Hoechst Ag Verfahren zur Rückgewinnung von fluorierten Carbonsäuren
WO1995010541A1 (fr) 1993-10-12 1995-04-20 Asahi Kasei Kogyo Kabushiki Kaisha Copolymere de perfluorocarbone ayant des groupes fonctionnels et procede pour sa production
DE4335705A1 (de) 1993-10-20 1995-04-27 Hoechst Ag Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung
US5447993A (en) * 1994-04-19 1995-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer curing
DE69424173T2 (de) 1994-11-24 2000-09-28 Minnesota Mining & Mfg Carbodiimide-Verbindungen und dauerhafte wasserabweisende Zusammensetzungen, die diese Verbindungen enthalten
DE69511583T2 (de) 1995-01-18 2000-01-13 Gore & Ass Microemulsionspolymerisation-systeme für fluor-enthaltende monomere
US5478905A (en) 1995-02-06 1995-12-26 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene/hexafluoropropylene copolymers
EP0731081B1 (de) 1995-03-09 1998-04-15 Dyneon GmbH Rückgewinnung hochfluorierter Carbonsäuren aus der Gasphase
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5882466A (en) 1996-08-08 1999-03-16 Minnesota Mining And Manufacturing Company Aqueous bonding composition
US5981614A (en) 1996-09-13 1999-11-09 Adiletta; Joseph G. Hydrophobic-oleophobic fluoropolymer compositions
JPH10101740A (ja) 1996-10-01 1998-04-21 Nippon Mektron Ltd フルオロエラストマーおよびその架橋性組成物
US5877264A (en) * 1996-11-25 1999-03-02 E. I. Du Pont De Nemours And Company Fast-curing perfluoroelastomer composition
DE19824614A1 (de) 1998-06-02 1999-12-09 Dyneon Gmbh Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern
DE19824615A1 (de) 1998-06-02 1999-12-09 Dyneon Gmbh Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern
US6103844A (en) 1998-06-08 2000-08-15 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers in carbon dioxide
ITMI981520A1 (it) 1998-07-02 2000-01-02 Ausimont Spa Dispersioni di fluoropolimeri
CN1215085C (zh) 1998-10-13 2005-08-17 大金工业株式会社 含氟聚合物的制造方法
DE60016577T2 (de) 1999-03-02 2005-11-24 E.I. Du Pont De Nemours And Co., Wilmington Radikalische polymerisationsmethode für fluorierte copolymere
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
DE19932771A1 (de) 1999-07-14 2001-01-18 Dyneon Gmbh Verfahren zur Eluierung fluorierter Emulgatoren
IT1317847B1 (it) * 2000-02-22 2003-07-15 Ausimont Spa Processo per la preparazione di dispersioni acquose di fluoropolimeri.
IT1318596B1 (it) * 2000-06-23 2003-08-27 Ausimont Spa Copolimeri termoprocessbili del tfe.
AU2001294391A1 (en) 2000-09-07 2002-03-22 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappijk Onderzoek Tno Coating compositions containing perfluoropolyether surfactants
US6737489B2 (en) 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
BR0212308A (pt) 2001-09-05 2004-10-13 3M Innovative Properties Co Dispersão de fluoropolìmero, e, método para prover uma dispersão de partìculas de fluoropolìmero
US6822059B2 (en) 2002-04-05 2004-11-23 3M Innovative Properties Company Dispersions containing bicomponent fluoropolymer particles and use thereof

Also Published As

Publication number Publication date
US7262246B2 (en) 2007-08-28
US7045571B2 (en) 2006-05-16
US20060160947A1 (en) 2006-07-20
US20030181572A1 (en) 2003-09-25
CN1742027A (zh) 2006-03-01
JP2006513303A (ja) 2006-04-20
AU2003300980A1 (en) 2004-08-23
EP1622949A1 (en) 2006-02-08
ZA200506758B (en) 2006-05-31
WO2004067588A1 (en) 2004-08-12

Similar Documents

Publication Publication Date Title
RU2005123338A (ru) Эмульсионная полимеризация фторированных мономеров
JP2006513303A5 (ru)
RU2007143627A (ru) Водоимульсионная полимеризация фторсодержащих мономеров в присутствии частично фторированного олигомера в качестве эмульгатора
CN1093142C (zh) 具有衍生自碘化烯烃的单体单元的氟化热塑性弹性体
KR980009299A (ko) V d f 중합방법
JP2010509441A5 (ru)
JP5223435B2 (ja) 含フッ素ブロック共重合体
EP0193370A2 (en) Fluorinated polyacrylates and polyacrylamides having a controlled cross-linking degree, and process for preparing same
JP2009517528A5 (ru)
KR100576586B1 (ko) 불화 친수성중합체
JPWO2019138680A1 (ja) 含フッ素共重合体分散液、その製造方法及び物品
JPH06329787A (ja) アクリル基含有ペルフルオロポリエーテル系塗料
JP2005522539A5 (ru)
KR910018555A (ko) 피혁 처리제 및 피혁 처리방법
KR950011485A (ko) 다른 과플루오르화 단량체에 의한 테트라플루오로에틸렌 공중합체 제조방법
EP0248383B1 (en) Surface modifier
CN1062736A (zh) 制备聚合物的方法
DE60121291D1 (de) Verbessertes Verfahren zur Polymerisation von Fluor enthaltenden Monomeren in wässriger Emulsion
EP2576716B1 (en) Fluoropolymer additive for coatings
RU2006118782A (ru) Новые фторированное соединения и фторполимер
JPS61148208A (ja) 含フツ素基を有するポリビニルエステル系重合体
KR920008090A (ko) 경화성 불소화 공중합체, 그의 제조방법 및 페인트 및 니스로서의 용도
JP2570827B2 (ja) 水性分散液の製造方法および水性塗料組成物
JP3341053B2 (ja) 含窒素フルオロカーボン共重合体及びその製造方法並びに用途
JP3887879B2 (ja) 含フッ素（メタ）アクリル系重合体の製造方法

Legal Events

Date Code Title Description
FA92 Acknowledgement of application withdrawn (lack of supplementary materials submitted)

Effective date: 20080807