NO319283B1 - Fremgangsmate for fremstilling av en latex bestaende av to populasjoner av partikler, plastisoler oppnadd ved hjelp av latexen og skum basert pa plastisolene - Google Patents
Fremgangsmate for fremstilling av en latex bestaende av to populasjoner av partikler, plastisoler oppnadd ved hjelp av latexen og skum basert pa plastisolene Download PDFInfo
- Publication number
- NO319283B1 NO319283B1 NO19973914A NO973914A NO319283B1 NO 319283 B1 NO319283 B1 NO 319283B1 NO 19973914 A NO19973914 A NO 19973914A NO 973914 A NO973914 A NO 973914A NO 319283 B1 NO319283 B1 NO 319283B1
- Authority
- NO
- Norway
- Prior art keywords
- latex
- particles
- graft polymer
- water
- polymerization
- Prior art date
Links
- 239000004816 latex Substances 0.000 title claims description 36
- 229920000126 latex Polymers 0.000 title claims description 36
- 239000002245 particle Substances 0.000 title claims description 30
- 239000006260 foam Substances 0.000 title claims description 15
- 229920001944 Plastisol Polymers 0.000 title claims description 14
- 239000004999 plastisol Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 10
- 239000003999 initiator Substances 0.000 claims description 40
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 27
- 229920000578 graft copolymer Polymers 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000003638 chemical reducing agent Substances 0.000 claims description 11
- 239000012874 anionic emulsifier Substances 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 5
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical group [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 description 27
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 235000010323 ascorbic acid Nutrition 0.000 description 9
- 229960005070 ascorbic acid Drugs 0.000 description 9
- 239000011668 ascorbic acid Substances 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 6
- -1 vinylidene halides Chemical class 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000012875 nonionic emulsifier Substances 0.000 description 4
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 4
- 235000010263 potassium metabisulphite Nutrition 0.000 description 4
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
- 235000019395 ammonium persulphate Nutrition 0.000 description 3
- 230000001413 cellular effect Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 3
- 235000019796 monopotassium phosphate Nutrition 0.000 description 3
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 3
- 239000004297 potassium metabisulphite Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 239000004160 Ammonium persulphate Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 239000004262 Ethyl gallate Substances 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- AQSPWOCSGZUTBB-UHFFFAOYSA-N carbonic acid;1-hexadecylperoxyhexadecane Chemical compound OC(O)=O.CCCCCCCCCCCCCCCCOOCCCCCCCCCCCCCCCC AQSPWOCSGZUTBB-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 125000003074 decanoyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C(*)=O 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229940043349 potassium metabisulfite Drugs 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- KXYJPVZMZBJJBZ-UHFFFAOYSA-N tert-butyl 2-ethylbutaneperoxoate Chemical compound CCC(CC)C(=O)OOC(C)(C)C KXYJPVZMZBJJBZ-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9610492A FR2752846B1 (fr) | 1996-08-27 | 1996-08-27 | Latex bipopule a base de polymeres de chlorure de vinyle, ayant un taux eleve de population de fines particules, ses procedes de fabrication et ses applications |
| US08/917,896 US6245848B1 (en) | 1996-08-27 | 1997-08-27 | Bipopulated latex based on vinyl chloride polymers having a high population level of fine particles, processes for the manufacture thereof and applications thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO973914D0 NO973914D0 (no) | 1997-08-26 |
| NO973914L NO973914L (no) | 1998-03-02 |
| NO319283B1 true NO319283B1 (no) | 2005-07-11 |
Family
ID=26232931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19973914A NO319283B1 (no) | 1996-08-27 | 1997-08-26 | Fremgangsmate for fremstilling av en latex bestaende av to populasjoner av partikler, plastisoler oppnadd ved hjelp av latexen og skum basert pa plastisolene |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6245848B1 (pt) |
| EP (1) | EP0826702B1 (pt) |
| JP (2) | JP3145665B2 (pt) |
| KR (2) | KR100252532B1 (pt) |
| CN (1) | CN1282675C (pt) |
| BR (1) | BR9704526A (pt) |
| CA (1) | CA2213701C (pt) |
| DE (1) | DE69726072T2 (pt) |
| ES (1) | ES2210472T3 (pt) |
| FR (1) | FR2752846B1 (pt) |
| NO (1) | NO319283B1 (pt) |
| PT (1) | PT826702E (pt) |
| TW (1) | TW513455B (pt) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2787794B1 (fr) * | 1998-12-29 | 2004-09-10 | Atochem Elf Sa | Polymeres a base de chlorure de vinyle, aptes a donner des plastisols de proprietes particulieres et leur procede d'obtention |
| KR100343544B1 (ko) * | 2000-03-13 | 2002-07-20 | 한솔케미언스 주식회사 | 이중구조의 스틸렌 부타디엔계 라텍스의 제조방법 |
| MXPA01008532A (es) * | 2000-09-03 | 2002-08-06 | Rohm & Haas | Sistema de acitivos funcionales de liquidos-solidos; sus composiciones, procesos y productos. |
| MXPA01008706A (es) * | 2000-09-03 | 2004-08-12 | Rohm & Haas | Sistemas aditivos polimericos altos en solidos: composiciones, procesos y productos de los mismos. |
| MXPA01008705A (es) | 2000-09-03 | 2004-08-12 | Rohm & Haas | Sistemas de aditivos polimericos multiples: composiciones, procesos y productos derivados. |
| EP1702936A1 (de) * | 2005-03-18 | 2006-09-20 | VESTOLIT GmbH & Co. KG | Verfahren zur Herstellung von verpastbaren Polymeren |
| JP2006306963A (ja) * | 2005-04-27 | 2006-11-09 | Kaneka Corp | 塩化ビニル系ペースト樹脂 |
| KR100762838B1 (ko) * | 2005-08-11 | 2007-10-04 | 주식회사 엘지화학 | 고탄성 폴리염화비닐 조성물 및 이를 이용하여 제조된 성형체 |
| JP5118396B2 (ja) * | 2007-06-22 | 2013-01-16 | 新第一塩ビ株式会社 | ペースト用塩化ビニル系樹脂及びペースト用塩化ビニル系樹脂組成物 |
| KR101154469B1 (ko) * | 2008-06-13 | 2012-06-13 | 주식회사 엘지화학 | 저점도 특성이 우수한 염화비닐계 수지 및 그 제조 방법 |
| US20090311531A1 (en) | 2008-06-13 | 2009-12-17 | Lg Chem, Ltd. | Large-sized vinyl chloride seed, method of preparing the seed, vinyl chloride resin prepared using the seed, and method of preparing the vinyl chloride resin |
| KR101236652B1 (ko) * | 2009-06-10 | 2013-02-22 | 주식회사 엘지화학 | 저점도 특성이 우수한 발포용 염화비닐계 수지 및 이의 제조방법 |
| KR101293377B1 (ko) * | 2009-12-24 | 2013-08-05 | 주식회사 엘지화학 | 발포 물성이 우수한 염화비닐계 수지 페이스트 제조 방법 |
| KR101445240B1 (ko) | 2012-11-02 | 2014-09-29 | 한화케미칼 주식회사 | 염화비닐계 수지 및 이의 제조방법 |
| KR101424891B1 (ko) * | 2012-12-10 | 2014-08-04 | 주식회사 엘지화학 | 저점도 특성이 우수한 발포용 염화비닐계 수지 및 이의 제조방법 |
| KR101721295B1 (ko) * | 2014-06-11 | 2017-04-10 | 주식회사 엘지화학 | 염화비닐계 수지의 제조방법 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1318956A (fr) * | 1961-03-24 | 1963-02-22 | Montedison Spa | Procédé pour obtenir des polymères vinyliques halogénés aptes à donner des plastisols de stabilité durable |
| FR2286152A1 (fr) * | 1974-09-24 | 1976-04-23 | Plastimer | Polymerisation du chlorure de vinyle en emulsion |
| FR2309569A1 (fr) * | 1975-04-30 | 1976-11-26 | Rhone Poulenc Ind | Procede de polymerisation du chlorure de vinyle en microsuspension ensemencee |
| HU173513B (hu) * | 1975-04-30 | 1979-05-28 | Rhone Poulenc Ind | Sposob polimerizacii vinilkhlorida v sshitojj mikrosuspensii |
| FR2344579A2 (fr) * | 1976-03-19 | 1977-10-14 | Rhone Poulenc Ind | Procede de polymerisation du chlorure de vinyle en microsuspension ensemencee |
| DE2937223A1 (de) * | 1979-09-14 | 1981-04-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur diskontinuierlichen polymerisation von vinylchlorid in emulsion |
| KR840000466B1 (ko) * | 1980-10-24 | 1984-04-09 | 끌로메 쉬미 | 레올로지 성질이 향상된 플라스티졸을 얻기에 적합한 염화비닐의 단일-또는 공-중합체의 제조방법 |
| US4461869A (en) * | 1981-12-30 | 1984-07-24 | The B. F. Goodrich Company | Process for making low fusion dispersion resins |
| FR2607138B1 (fr) * | 1986-11-24 | 1990-05-04 | Atochem | Procede de preparation en microsuspension ensemencee d'homo- et copolymeres du chlorure de vinyle |
| US5151476A (en) * | 1987-08-31 | 1992-09-29 | The Goodyear Tire & Rubber Company | Micro-suspension polymerization of vinyl chloride with ascorbic acid and water-soluble metal salts |
| BE1004570A3 (fr) * | 1990-09-17 | 1992-12-15 | Solvay | Procede pour la production de latex plurimodaux de polymeres du chlorure de vinyle. |
| JPH05271313A (ja) * | 1992-03-30 | 1993-10-19 | Mitsubishi Kasei Vinyl Co | 塩化ビニル系重合体の製造法 |
-
1996
- 1996-08-27 FR FR9610492A patent/FR2752846B1/fr not_active Expired - Fee Related
-
1997
- 1997-08-19 ES ES97401950T patent/ES2210472T3/es not_active Expired - Lifetime
- 1997-08-19 PT PT97401950T patent/PT826702E/pt unknown
- 1997-08-19 EP EP97401950A patent/EP0826702B1/fr not_active Expired - Lifetime
- 1997-08-19 DE DE69726072T patent/DE69726072T2/de not_active Expired - Lifetime
- 1997-08-26 NO NO19973914A patent/NO319283B1/no not_active IP Right Cessation
- 1997-08-26 JP JP24466997A patent/JP3145665B2/ja not_active Expired - Fee Related
- 1997-08-27 CN CNB971186065A patent/CN1282675C/zh not_active Expired - Fee Related
- 1997-08-27 CA CA002213701A patent/CA2213701C/fr not_active Expired - Fee Related
- 1997-08-27 BR BR9704526A patent/BR9704526A/pt not_active IP Right Cessation
- 1997-08-27 KR KR1019970041649A patent/KR100252532B1/ko not_active IP Right Cessation
- 1997-08-27 US US08/917,896 patent/US6245848B1/en not_active Expired - Lifetime
- 1997-09-27 TW TW086114139A patent/TW513455B/zh not_active IP Right Cessation
-
1999
- 1999-08-27 KR KR1019990035872A patent/KR100253686B1/ko not_active IP Right Cessation
-
2000
- 2000-03-29 JP JP2000091073A patent/JP2000290307A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69726072T2 (de) | 2004-08-19 |
| FR2752846A1 (fr) | 1998-03-06 |
| KR19980019077A (ko) | 1998-06-05 |
| ES2210472T3 (es) | 2004-07-01 |
| US6245848B1 (en) | 2001-06-12 |
| CN1282675C (zh) | 2006-11-01 |
| BR9704526A (pt) | 1999-03-09 |
| CN1177600A (zh) | 1998-04-01 |
| NO973914L (no) | 1998-03-02 |
| DE69726072D1 (de) | 2003-12-18 |
| CA2213701A1 (fr) | 1998-02-27 |
| PT826702E (pt) | 2004-03-31 |
| JP2000290307A (ja) | 2000-10-17 |
| KR100253686B1 (en) | 2000-04-15 |
| NO973914D0 (no) | 1997-08-26 |
| JPH1087731A (ja) | 1998-04-07 |
| FR2752846B1 (fr) | 1998-10-30 |
| EP0826702A1 (fr) | 1998-03-04 |
| CA2213701C (fr) | 2002-05-07 |
| JP3145665B2 (ja) | 2001-03-12 |
| TW513455B (en) | 2002-12-11 |
| KR100252532B1 (ko) | 2000-04-15 |
| EP0826702B1 (fr) | 2003-11-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO319283B1 (no) | Fremgangsmate for fremstilling av en latex bestaende av to populasjoner av partikler, plastisoler oppnadd ved hjelp av latexen og skum basert pa plastisolene | |
| US4352916A (en) | Use of hydrophobically modified water soluble polymers in suspension polymerization | |
| US4458057A (en) | Process for producing spherical and porous vinyl resin particles | |
| SU656531A3 (ru) | Способ получени (со)полимеров винилхлорида | |
| US4093581A (en) | Emulsion polymerization of vinyl chloride using prehomogenized mixed emulsifier system | |
| NO319904B1 (no) | Fremgangsmate for fremstilling av en lateks av polymerer basert pa vinylklorid | |
| KR100259206B1 (ko) | 염화 비닐 공중합체의 2원 입자 라텍스 및 그것에 관한 제조 방법과 적용 | |
| US3882195A (en) | Pre-emulsification-delayed initiation suspension pearl polymerization process | |
| NO151010B (no) | Fremgangsmaate for fremstilling av vinylkloridhomo- eller -ko-polymerisater inneholdende minst 50 vekt% vinylklorid-enheter | |
| US6433060B1 (en) | Vinyl chloride-based polymers capable of giving plastisols having specific properties, and process for obtaining them | |
| NO145661B (no) | Fremgangsmaate for fremstilling av vinylkloridhomo- eller -ko-polymerer ved polymerisering i mikrosuspensjon | |
| US5872155A (en) | Latex based on vinyl chloride copolymers with a specific structure, process for the manufacture thereof and applications thereof | |
| EP0052632B1 (en) | Process for preparing spherical and porous vinyl resin particles | |
| US3891723A (en) | Emulsion polymerization of vinyl chloride, and a copolymer of {60 -methyl styrene and acrylic acid ester | |
| KR930003103B1 (ko) | 파종된 미소현탁액 내에서 비닐클로라이드 단일 - 및 공중합체의 제조방법 | |
| US4833180A (en) | Process for polymerizing vinyl chloride in emulsion or in microsuspension | |
| JP3563234B2 (ja) | 塩化ビニル系重合体ラテックスの製造方法 | |
| KR800000344B1 (ko) | 시이드 첨가한 미세 현탁액 중에서의 염화비닐의 중합법 | |
| EP0051678B1 (en) | Process for producing spherical and porous vinyl resin particles | |
| JPH11263817A (ja) | 塩化ビニルポリマ― | |
| AU540016B2 (en) | Process for preparing spherical and porous vinyl resin particles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CHAD | Change of the owner's name or address (par. 44 patent law, par. patentforskriften) |
Owner name: KEM ONE, FR |
|
| MM1K | Lapsed by not paying the annual fees |