NO300274B1 - Katalysatorbestanddeler og katalysatorer, og anvendelse av disse ved polymerisasjon av olefiner - Google Patents
Katalysatorbestanddeler og katalysatorer, og anvendelse av disse ved polymerisasjon av olefiner Download PDFInfo
- Publication number
- NO300274B1 NO300274B1 NO930348A NO930348A NO300274B1 NO 300274 B1 NO300274 B1 NO 300274B1 NO 930348 A NO930348 A NO 930348A NO 930348 A NO930348 A NO 930348A NO 300274 B1 NO300274 B1 NO 300274B1
- Authority
- NO
- Norway
- Prior art keywords
- compound
- components according
- alkyl
- spherical components
- cycloalkyl
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 43
- 238000006116 polymerization reaction Methods 0.000 title claims description 30
- 150000001336 alkenes Chemical class 0.000 title claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 48
- 239000005977 Ethylene Substances 0.000 claims description 48
- 239000010936 titanium Substances 0.000 claims description 42
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 26
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 150000003609 titanium compounds Chemical class 0.000 claims description 20
- -1 alkyl radical Chemical class 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 17
- 239000011777 magnesium Substances 0.000 claims description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 229910052749 magnesium Inorganic materials 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 11
- 150000005840 aryl radicals Chemical group 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 7
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 6
- 230000002140 halogenating effect Effects 0.000 claims description 6
- 230000001603 reducing effect Effects 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000002459 porosimetry Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- CBBVHSHLSCZIHD-UHFFFAOYSA-N mercury silver Chemical compound [Ag].[Hg] CBBVHSHLSCZIHD-UHFFFAOYSA-N 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 1
- 150000008378 aryl ethers Chemical class 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 84
- 229920000642 polymer Polymers 0.000 description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 29
- 238000003756 stirring Methods 0.000 description 16
- 239000007787 solid Substances 0.000 description 13
- 229910003910 SiCl4 Inorganic materials 0.000 description 10
- 229920000092 linear low density polyethylene Polymers 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 239000004707 linear low-density polyethylene Substances 0.000 description 9
- 235000011147 magnesium chloride Nutrition 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 230000000877 morphologic effect Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000011949 solid catalyst Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007429 general method Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- ROSQVPGTZCDBOC-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,4-dimethylpentane Chemical compound COCC(C)(COC)CC(C)C ROSQVPGTZCDBOC-UHFFFAOYSA-N 0.000 description 1
- VDSMRHLGJLFQEQ-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,5-dimethylhexane Chemical compound COCC(C)(COC)CCC(C)C VDSMRHLGJLFQEQ-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- BAQNULZQXCKSQW-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4] BAQNULZQXCKSQW-UHFFFAOYSA-N 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI920194A IT1262934B (it) | 1992-01-31 | 1992-01-31 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO930348D0 NO930348D0 (no) | 1993-02-01 |
| NO930348L NO930348L (no) | 1993-08-02 |
| NO300274B1 true NO300274B1 (no) | 1997-05-05 |
Family
ID=11361767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO930348A NO300274B1 (no) | 1992-01-31 | 1993-02-01 | Katalysatorbestanddeler og katalysatorer, og anvendelse av disse ved polymerisasjon av olefiner |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US5585317A (fr) |
| EP (1) | EP0553806B1 (fr) |
| JP (1) | JP3285637B2 (fr) |
| KR (1) | KR100250336B1 (fr) |
| CN (2) | CN1036461C (fr) |
| AT (1) | ATE165843T1 (fr) |
| AU (1) | AU655526B2 (fr) |
| BR (1) | BR9300391A (fr) |
| CA (1) | CA2088525A1 (fr) |
| DE (1) | DE69318318T2 (fr) |
| DK (1) | DK0553806T3 (fr) |
| ES (1) | ES2117061T3 (fr) |
| FI (1) | FI106310B (fr) |
| IL (1) | IL104562A (fr) |
| IT (1) | IT1262934B (fr) |
| MX (1) | MX9300533A (fr) |
| MY (1) | MY109025A (fr) |
| NO (1) | NO300274B1 (fr) |
| RU (1) | RU2118330C1 (fr) |
| TW (1) | TW222652B (fr) |
| ZA (1) | ZA93664B (fr) |
Families Citing this family (164)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1256648B (it) * | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| ITMI922919A1 (it) * | 1992-12-21 | 1994-06-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269194B (it) * | 1994-01-21 | 1997-03-21 | Spherilene Srl | Composizioni polimeriche ad elevata processabilita' basate su lldpe |
| IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269837B (it) * | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| US5455303A (en) | 1994-06-20 | 1995-10-03 | Montell North America Inc. | Linear low density polyethylene based compositions with improved optics |
| IT1270070B (it) | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1273660B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propilene |
| IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
| IT1274469B (it) * | 1995-05-11 | 1997-07-17 | Spherilene Spa | Composizioni poliolefiniche vulcanizzabili dinamicamente |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| IT1276120B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili basati su lldpe |
| IT1276121B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili |
| IT1281198B1 (it) | 1995-12-18 | 1998-02-17 | Montell Technology Company Bv | Film termoretraibili basati su composizioni poliolefiniche comprendenti un copolimero lineare dell'etilene con alfa-olefine |
| CN1108312C (zh) * | 1996-12-06 | 2003-05-14 | 旭化成株式会社 | 烯烃聚合催化剂和使用该催化剂制备聚烯烃的方法 |
| IT1292107B1 (it) * | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292108B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292109B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292138B1 (it) * | 1997-06-12 | 1999-01-25 | Montell Technology Company Bv | Film multistrato estensibili |
| US5952423A (en) * | 1997-07-18 | 1999-09-14 | Baxter International Inc. | Plastic compositions for medical containers and methods for providing such containers and for storing red blood cells |
| US6468258B1 (en) | 1997-07-18 | 2002-10-22 | Baxter International Inc. | Plastic compositions including vitamin E for medical containers and methods for providing such compositions and containers |
| EP0938509B1 (fr) * | 1997-09-03 | 2002-11-20 | Basell Poliolefine Italia S.p.A. | Constituants et catalyseurs pour la polymerisation d'olefines |
| JP3406488B2 (ja) * | 1997-09-05 | 2003-05-12 | 東京エレクトロン株式会社 | 真空処理装置 |
| AU744327B2 (en) | 1998-03-05 | 2002-02-21 | Montell Technology Company B.V. | Polybutene-1 (co)polymers and process for their preparation |
| ES2198098T3 (es) | 1998-03-09 | 2004-01-16 | Basell Poliolefine Italia S.P.A. | Procedimiento multietapas para la polimerizacion de olefinas. |
| SG73622A1 (en) | 1998-03-11 | 2000-06-20 | Sumitomo Chemical Co | Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer |
| ID23021A (id) * | 1998-03-23 | 1999-12-30 | Montell Technology Company Bv | Komponen-komponen katalis prapolimerisasi untuk polimerisasi olefin |
| KR100334165B1 (ko) | 1998-04-17 | 2002-11-27 | 삼성종합화학주식회사 | 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법 |
| BR9906424A (pt) | 1998-05-06 | 2000-07-11 | Montell Technology Company Bv | Composições poliolefìinicas e filmes obtidos a partir delas |
| ATE258192T1 (de) | 1998-05-06 | 2004-02-15 | Basell Poliolefine Spa | Katalysatorbestandteile für die olefinpolymerisation |
| IT1301990B1 (it) | 1998-08-03 | 2000-07-20 | Licio Zambon | Catalizzatori per la polimerizzazione delle olefine. |
| WO2000026259A1 (fr) | 1998-11-04 | 2000-05-11 | Montell Technology Company Bv | Composants et catalyseurs de polymerisation d'olefines |
| DE60006082T2 (de) | 1999-03-09 | 2004-07-22 | Basell Polyolefine Gmbh | Mehrstufiges verfahren zur (co)polymersation von olefinen |
| CA2331732A1 (fr) | 1999-03-15 | 2000-09-21 | Basell Technology Company B.V. | Composants et catalyseurs pour la polymerisation d'olefines |
| EP1088009B1 (fr) | 1999-04-15 | 2006-08-02 | Basell Poliolefine Italia S.r.l. | Constituants et catalyseurs de polymerisation d'olefines |
| US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
| KR100546499B1 (ko) | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| ATE376560T1 (de) * | 1999-06-18 | 2007-11-15 | Basell Poliolefine Srl | Katalysatorkomponenten für die polymerisation von olefinen und daraus erhaltene katalysatoren |
| KR20020037355A (ko) | 1999-09-10 | 2002-05-18 | 간디 지오프레이 에이치. | 올레핀의 중합 촉매 |
| CN1167715C (zh) | 1999-10-23 | 2004-09-22 | 三星阿托菲纳株式会社 | 用于烯烃均聚和共聚反应的改进的催化剂 |
| KR100361224B1 (ko) | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
| JP4574934B2 (ja) | 2000-02-02 | 2010-11-04 | バセル テクノロジー カンパニー ビー．ブイ． | オレフィン重合用成分及び触媒 |
| KR20020007419A (ko) | 2000-03-22 | 2002-01-26 | 간디 지오프레이 에이치. | 이소택틱 프로필렌 중합체 및 감소된 이소택틱성을 갖는유연성 프로필렌 중합체의 열가소성 조성물 및 그 제조방법 |
| KR100351386B1 (ko) | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법 |
| KR100353960B1 (ko) | 2000-05-31 | 2002-09-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체의 제조방법 |
| KR100359932B1 (ko) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100387734B1 (ko) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | 올레핀 중합용 촉매 및 중합방법 |
| HUP0204041A3 (en) | 2000-10-13 | 2004-08-30 | Basell Poliolefine Spa | Catalyst components for the polymerization of olefins |
| KR100389477B1 (ko) | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
| EP1358223A4 (fr) * | 2000-12-22 | 2005-01-05 | Samsung General Chemicals Co | Catalyseur de chelate pour polymerisation olefinique et procede de polymerisation olefinique utilise |
| US20040082696A1 (en) * | 2000-12-22 | 2004-04-29 | Sok-Won Kim | Polypropylene resin composition with improved surface hardness and scratch resistance properties |
| ATE305490T1 (de) * | 2000-12-22 | 2005-10-15 | Samsung General Chemicals Co | Polyolefinharzzusammensetzung |
| US7067576B2 (en) * | 2000-12-22 | 2006-06-27 | Samsung Atofina, Co., Ltd. | Flame retardant polypropylene resin composition |
| KR100421553B1 (ko) | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | 알파 올레핀 중합 방법 |
| WO2002074818A1 (fr) | 2001-03-15 | 2002-09-26 | Basell Poliolefine Italia S.P.A. | Procede de (co)polymerisation d'ethylene |
| ATE328912T1 (de) * | 2001-06-20 | 2006-06-15 | Borealis Tech Oy | Herstellung eines katalysatorbestandteils zur olefinpolymerisation |
| KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100496776B1 (ko) | 2001-06-21 | 2005-06-22 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| EP1406969A1 (fr) | 2001-07-17 | 2004-04-14 | Basell Polyolefine GmbH | Procede multi-etape de (co)polymerisation d'olefines |
| KR20040028674A (ko) | 2001-09-13 | 2004-04-03 | 바셀 폴리올레핀 이탈리아 에스.피.에이. | 올레핀 중합용 성분 및 촉매 |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| EP1323747A1 (fr) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Procédé pour la préparation des catalyseurs pour la polymérisation oléfinique |
| KR100530795B1 (ko) * | 2001-12-26 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
| JP2005519172A (ja) | 2002-03-08 | 2005-06-30 | バセル ポリオレフィン イタリア エス．ピー．エー． | オレフィンの重合方法 |
| KR100892901B1 (ko) | 2002-05-29 | 2009-04-15 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 부텐-1 (공)중합체 및 이의 제조방법 |
| US9352308B2 (en) | 2002-06-19 | 2016-05-31 | Braskem S.A. | Solid catalyst component for polymerization and copolymerization of ethylene and process for obtaining the same |
| EP1515995B1 (fr) * | 2002-06-19 | 2010-05-05 | Braskem S.A. | Composant catalyseur solide destine a la polymerisation et a la copolymerisation d'ethylene, et procede d'obtention associe |
| MXPA04012699A (es) | 2002-06-26 | 2005-03-23 | Basell Poliolefine Spa | Composiciones de poliolefina resistentes a impactos. |
| US7572859B2 (en) | 2002-06-26 | 2009-08-11 | Basell Polyolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
| CN1290874C (zh) * | 2002-07-23 | 2006-12-20 | 巴塞尔聚烯烃意大利有限公司 | 氯化镁－醇加合物及由其获得的催化剂组分 |
| CN100436491C (zh) | 2002-10-09 | 2008-11-26 | 巴塞尔聚烯烃意大利有限公司 | 烯烃的气相催化聚合 |
| JP4971633B2 (ja) | 2002-11-28 | 2012-07-11 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ブテン−１共重合体およびそれらの製造方法 |
| US20090131593A1 (en) * | 2003-05-21 | 2009-05-21 | Basell Poliolefine Italia S.R.L | Polyethylene films for packaging |
| CA2526574A1 (fr) * | 2003-05-21 | 2004-12-02 | Basell Poliolefine Italia S.R.L. | Films d'emballage etirables |
| EP1678218A1 (fr) | 2003-10-28 | 2006-07-12 | Basell Poliolefine Italia S.r.l. | Composants et catalyseurs pour la polymerisation d'olefines |
| EP1680468B1 (fr) | 2003-11-06 | 2011-08-17 | Basell Poliolefine Italia S.r.l. | Composition de polypropylene |
| EP1564226A1 (fr) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Système catalytique à base de titanocène |
| RU2006138604A (ru) | 2004-04-02 | 2008-05-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Компоненты и катализаторы для полимеризации олефинов |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| JP4920587B2 (ja) | 2004-06-08 | 2012-04-18 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 剛性、衝撃強さおよび破断点伸び率の良好なバランスならびに低い熱収縮を有するポリオレフィン組成物 |
| DE602005017489D1 (de) | 2004-06-16 | 2009-12-17 | Basell Poliolefine Srl | Komponenten und katalysatoren zur olefinpolymerisation |
| ATE463517T1 (de) | 2004-06-18 | 2010-04-15 | Basell Poliolefine Srl | Verfahren zur herstellung von katalysatorkomponenten für die olefinpolymerisation |
| US7776986B2 (en) | 2004-10-18 | 2010-08-17 | Basell Poliolefine Italia S.R.L. | Butene-1 (Co)Polymers having low isotacticity |
| WO2006045687A1 (fr) | 2004-10-21 | 2006-05-04 | Basell Polyolefine Gmbh | Polymere 1-butene et processus de preparation de celui-ci |
| JP2008528779A (ja) | 2005-02-03 | 2008-07-31 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 射出成形用プロピレンポリマー組成物 |
| KR20070118143A (ko) * | 2005-03-30 | 2007-12-13 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 |
| KR20070118150A (ko) * | 2005-03-30 | 2007-12-13 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 결정성 에틸렌 (공)중합체의 제조 방법 |
| KR20070118144A (ko) * | 2005-03-30 | 2007-12-13 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 |
| KR20080022101A (ko) | 2005-05-12 | 2008-03-10 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌-에틸렌 공중합체 및 그 제조 방법 |
| JP5178512B2 (ja) | 2005-07-01 | 2013-04-10 | サンアロマー株式会社 | 広い分子量分布を示すプロピレンポリマー |
| CN101287768A (zh) * | 2005-10-14 | 2008-10-15 | 巴塞尔聚烯烃股份有限公司 | 担载在卤化镁上的杂化催化剂系统 |
| CA2629788A1 (fr) * | 2005-11-15 | 2007-05-24 | Basell Poliolefine Italia S.R.L. | Copolymeres propylene-ethylene et leur procede de preparation |
| ATE556096T1 (de) * | 2006-08-08 | 2012-05-15 | Basell Poliolefine Srl | Buten-1-copolymere |
| JP2010017082A (ja) | 2006-10-10 | 2010-01-28 | Ajinomoto Co Inc | Ｌ−アミノ酸の製造法 |
| KR20090102802A (ko) * | 2006-12-20 | 2009-09-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매 |
| BRPI0721273A2 (pt) * | 2006-12-20 | 2014-04-01 | Basell Poliolefine Srl | Componentes catalisadores para a polimerização de olefinas e catalisadores obtidos das mesmas. |
| US8071499B2 (en) | 2006-12-22 | 2011-12-06 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| CN101583634B (zh) * | 2006-12-22 | 2012-12-05 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分以及由其获得的催化剂 |
| JP2010110216A (ja) | 2007-02-20 | 2010-05-20 | Ajinomoto Co Inc | Ｌ−アミノ酸または核酸の製造方法 |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| WO2008132035A1 (fr) | 2007-04-27 | 2008-11-06 | Basell Poliolefine Italia S.R.L. | Terpolymères de butène-1 et leur procédé de fabrication |
| JP5419871B2 (ja) | 2007-06-29 | 2014-02-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 非フェノール系安定剤を含む照射ポリオレフィン組成物 |
| JP5404646B2 (ja) * | 2007-12-24 | 2014-02-05 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
| JP2011067095A (ja) | 2008-01-10 | 2011-04-07 | Ajinomoto Co Inc | 発酵法による目的物質の製造法 |
| EP2248906A4 (fr) | 2008-01-23 | 2012-07-11 | Ajinomoto Kk | Procédé de fabrication de l-aminoacide |
| RU2010139855A (ru) | 2008-02-29 | 2012-04-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Полиолефиновые композиции |
| ES2399251T3 (es) | 2008-12-29 | 2013-03-27 | Basell Poliolefine Italia S.R.L. | Componentes de catalizador para la polimerización de olefinas y catalizadores obtenidos a partir de los mismos |
| US7935740B2 (en) | 2008-12-30 | 2011-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing high melt strength polypropylene |
| WO2010118962A1 (fr) | 2009-04-16 | 2010-10-21 | Basell Poliolefine Italia S.R.L. | Procédé pour la préparation de polymère du 1-butène |
| US8598285B2 (en) | 2009-07-14 | 2013-12-03 | Basell Poliolefine Italia, s.r.l. | Process for the preparation of polymer of 1-butene |
| CN102471790B (zh) | 2009-07-29 | 2014-10-29 | 味之素株式会社 | 产生l-氨基酸的方法 |
| JP2012223091A (ja) | 2009-08-25 | 2012-11-15 | Ajinomoto Co Inc | Ｌ−アミノ酸の製造法 |
| US9051400B2 (en) | 2009-12-22 | 2015-06-09 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| WO2011107371A1 (fr) | 2010-03-04 | 2011-09-09 | Basell Poliolefine Italia Srl | Composants de catalyseur pour la polymérisation d'oléfines |
| US8835578B2 (en) | 2010-03-04 | 2014-09-16 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| US20130102744A1 (en) | 2010-06-24 | 2013-04-25 | Basell Poliolefine Italia, s.r.l. | Catalyst Systems for the Polymerization of Olefins |
| GB201012273D0 (en) * | 2010-07-22 | 2010-09-08 | Ineos Mfg Belguim Nv | Polymer compositon |
| US20130131293A1 (en) | 2010-08-05 | 2013-05-23 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| BR112013002873A2 (pt) | 2010-08-05 | 2016-05-31 | Basell Poliolefine Srl | componentes de catalisador para a polimerização de olefinas |
| BR112013008900A2 (pt) | 2010-10-19 | 2016-06-28 | Basell Poliolefine Srl | "sistema da catalisação para a polimerização de olefinas" |
| US20130203948A1 (en) | 2010-10-19 | 2013-08-08 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high purity propylene polymers |
| EP2630169A1 (fr) | 2010-10-19 | 2013-08-28 | Basell Poliolefine Italia S.r.l. | Procédé de polymérisation d'oléfines |
| WO2012052429A1 (fr) | 2010-10-21 | 2012-04-26 | Basell Poliolefine Italia S.R.L. | Adhésif sensible à la pression à base de copolymères de butène-1 |
| CN102558398B (zh) * | 2010-12-30 | 2013-11-06 | 中国石油化工股份有限公司 | 一种氯化镁球形载体的制备方法 |
| US9034783B2 (en) | 2011-06-24 | 2015-05-19 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| EP2583983A1 (fr) | 2011-10-19 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Composant de catalyseur pour la polymérisation d'oléfines |
| EP2583985A1 (fr) | 2011-10-19 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation des oléfines |
| EP2607384A1 (fr) | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Système de catalyseur pour la polymérisation des oléfines |
| EP2636687A1 (fr) | 2012-03-07 | 2013-09-11 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation d'oléfines |
| EP2666792A1 (fr) | 2012-05-23 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Composant catalytique pour la polymérisation d'oléfines |
| EP2671894A1 (fr) | 2012-06-08 | 2013-12-11 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation de butène-1 |
| EP2712874A1 (fr) | 2012-09-26 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation des oléfines |
| EP2712875A1 (fr) | 2012-09-28 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation des oléfines |
| EP2757114A1 (fr) | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation d'oléfines |
| EP2787014A1 (fr) | 2013-04-05 | 2014-10-08 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation d'oléfines |
| EP2803678A1 (fr) | 2013-05-14 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation des oléfines |
| EP2803679A1 (fr) | 2013-05-17 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation des oléfines |
| JP2016165225A (ja) | 2013-07-09 | 2016-09-15 | 味の素株式会社 | 有用物質の製造方法 |
| JP5958653B2 (ja) | 2013-10-02 | 2016-08-02 | 味の素株式会社 | アンモニア制御装置およびアンモニア制御方法 |
| EP3061828B1 (fr) | 2013-10-23 | 2024-08-28 | Ajinomoto Co., Inc. | Procédé de production d'une substance cible |
| EP3268397B1 (fr) | 2015-03-10 | 2019-04-17 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur pour la polymérisation d'oléfines |
| US10246532B2 (en) | 2015-03-12 | 2019-04-02 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| WO2016156473A1 (fr) | 2015-04-01 | 2016-10-06 | Basell Poliolefine Italia S.R.L. | Constituants de catalyseur pour la polymérisation d'oléfines |
| US10221256B2 (en) | 2015-05-19 | 2019-03-05 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CN109071711B (zh) * | 2016-04-29 | 2021-03-26 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的催化剂组分 |
| TWI735673B (zh) | 2016-10-03 | 2021-08-11 | 日商東邦鈦股份有限公司 | 烯烴類聚合用固體觸媒成分、烯烴類聚合用固體觸媒成分之製造方法、烯烴類聚合用觸媒、烯烴類聚合體之製造方法、丙烯系共聚合體之製造方法及丙烯系共聚合體 |
| CN109890852B (zh) | 2016-11-18 | 2020-10-20 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的催化剂组分 |
| JP7066977B2 (ja) | 2017-04-03 | 2022-05-16 | 味の素株式会社 | Ｌ－アミノ酸の製造法 |
| WO2018210665A1 (fr) | 2017-05-18 | 2018-11-22 | Basell Poliolefine Italia S.R.L. | Composants catalytiques destinés à la polymérisation d'oléfines |
| WO2020069847A1 (fr) | 2018-10-01 | 2020-04-09 | Basell Poliolefine Italia S.R.L. | Précurseurs et constituants de catalyseur pour la polymérisation d'oléfines |
| WO2020071538A1 (fr) | 2018-10-05 | 2020-04-09 | Ajinomoto Co., Inc. | Procédé de production d'une substance cible par fermentation bactérienne |
| BR112021008495A2 (pt) | 2018-12-04 | 2021-08-03 | Basell Poliolefine Italia S.R.L. | processo para a preparação de um polímero de polipropileno. |
| EP3894448B1 (fr) | 2018-12-14 | 2023-01-18 | Basell Poliolefine Italia S.r.l. | Composants de catalyseur de polymérisation d'oléfines |
| BR112021017834A2 (pt) | 2019-04-11 | 2021-11-30 | Basell Poliolefine Italia Srl | Processo para a preparação de um polímero de propileno |
| JP7100775B2 (ja) | 2019-07-03 | 2022-07-13 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合のための触媒成分 |
| US12012476B2 (en) | 2019-12-04 | 2024-06-18 | Basell Poliolefine Italia S.R.L. | Catalyst for the polymerization of olefins |
| WO2024194125A1 (fr) | 2023-03-17 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Composants catalyseurs pour la polymérisation d'oléfines |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| IT1078995B (it) * | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| IT1169291B (it) * | 1981-12-24 | 1987-05-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione dell'etilene e sue miscele con olefine ed i soui catalizzatori da essi ottenuti |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| DE3366573D1 (en) * | 1982-06-24 | 1986-11-06 | Bp Chimie Sa | Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed |
| IT1212698B (it) * | 1983-02-10 | 1989-11-30 | Sir Soc Italiana Resine Spa | In sospensione di etilene con procedimento di copolimerizzazione alfa-olefine lineari perl'ottenimento di copolimeri a bassa densita'. |
| IT1190319B (it) * | 1986-04-17 | 1988-02-16 | Enichem Polimeri | Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo |
| US4710482A (en) * | 1986-06-18 | 1987-12-01 | Shell Oil Company | Olefin polymerization catalyst component |
| US4727051A (en) * | 1986-12-15 | 1988-02-23 | Stauffer Chemical Company | Production of halide-and alkoxy-containing magnesium compositions |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| US5204303A (en) * | 1988-12-30 | 1993-04-20 | Neste Oy | Preparation and use of a new ziegler-natta catayst component |
| IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| US5221651A (en) * | 1989-04-28 | 1993-06-22 | Himont Incorporated | Component and catalysts for the polymerization of olefins |
| IT1231768B (it) * | 1989-08-02 | 1991-12-21 | Himont Inc | Composizioni polipropileniche adatte alla modifica di bitumi. |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
| IT1236509B (it) * | 1989-10-06 | 1993-03-11 | Francesco Masi | Procedimento per la preparazione di copolimeri etilene-butene-1 con densita' ultra-bassa. |
| CN1022170C (zh) * | 1990-06-08 | 1993-09-22 | 河北机电学院 | 滚挤异型钢管装置 |
| US5229342A (en) * | 1990-10-18 | 1993-07-20 | Shell Oil Company | Olefin polymerization catalyst |
| US5141910A (en) * | 1990-10-18 | 1992-08-25 | Shell Oil Company | Olefin polymerization catalyst |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1245249B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1992
- 1992-01-31 IT ITMI920194A patent/IT1262934B/it active IP Right Grant
-
1993
- 1993-01-28 DE DE69318318T patent/DE69318318T2/de not_active Expired - Lifetime
- 1993-01-28 AT AT93101284T patent/ATE165843T1/de not_active IP Right Cessation
- 1993-01-28 ES ES93101284T patent/ES2117061T3/es not_active Expired - Lifetime
- 1993-01-28 EP EP93101284A patent/EP0553806B1/fr not_active Expired - Lifetime
- 1993-01-28 DK DK93101284T patent/DK0553806T3/da active
- 1993-01-29 IL IL10456293A patent/IL104562A/en not_active IP Right Cessation
- 1993-01-29 JP JP01420393A patent/JP3285637B2/ja not_active Expired - Lifetime
- 1993-01-29 FI FI930403A patent/FI106310B/fi not_active IP Right Cessation
- 1993-01-29 RU RU93004501A patent/RU2118330C1/ru not_active IP Right Cessation
- 1993-01-29 BR BR9300391A patent/BR9300391A/pt not_active IP Right Cessation
- 1993-01-29 ZA ZA93664A patent/ZA93664B/xx unknown
- 1993-01-30 MY MYPI93000152A patent/MY109025A/en unknown
- 1993-01-30 TW TW082100610A patent/TW222652B/zh active
- 1993-01-30 CN CN 95115110 patent/CN1036461C/zh not_active Expired - Fee Related
- 1993-01-30 KR KR1019930001257A patent/KR100250336B1/ko not_active IP Right Cessation
- 1993-01-30 CN CN93102504A patent/CN1032063C/zh not_active Expired - Fee Related
- 1993-02-01 AU AU32157/93A patent/AU655526B2/en not_active Ceased
- 1993-02-01 CA CA002088525A patent/CA2088525A1/fr not_active Abandoned
- 1993-02-01 MX MX9300533A patent/MX9300533A/es not_active IP Right Cessation
- 1993-02-01 NO NO930348A patent/NO300274B1/no unknown
-
1995
- 1995-07-10 US US08/500,032 patent/US5585317A/en not_active Expired - Lifetime
-
1996
- 1996-09-11 US US08/712,425 patent/US5726261A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU3215793A (en) | 1993-08-05 |
| ITMI920194A1 (it) | 1993-07-31 |
| MY109025A (en) | 1996-11-30 |
| CN1036461C (zh) | 1997-11-19 |
| JP3285637B2 (ja) | 2002-05-27 |
| US5726261A (en) | 1998-03-10 |
| KR100250336B1 (ko) | 2000-04-01 |
| ZA93664B (en) | 1993-09-02 |
| US5585317A (en) | 1996-12-17 |
| DE69318318D1 (de) | 1998-06-10 |
| KR930016443A (ko) | 1993-08-26 |
| NO930348D0 (no) | 1993-02-01 |
| FI106310B (fi) | 2001-01-15 |
| IL104562A (en) | 1995-10-31 |
| CA2088525A1 (fr) | 1993-08-01 |
| IT1262934B (it) | 1996-07-22 |
| CN1075485A (zh) | 1993-08-25 |
| AU655526B2 (en) | 1994-12-22 |
| ATE165843T1 (de) | 1998-05-15 |
| ES2117061T3 (es) | 1998-08-01 |
| TW222652B (fr) | 1994-04-21 |
| ITMI920194A0 (it) | 1992-01-31 |
| DK0553806T3 (da) | 1998-10-07 |
| CN1032063C (zh) | 1996-06-19 |
| FI930403A (fi) | 1993-08-01 |
| BR9300391A (pt) | 1993-08-03 |
| MX9300533A (es) | 1994-07-29 |
| RU2118330C1 (ru) | 1998-08-27 |
| DE69318318T2 (de) | 1998-11-19 |
| EP0553806A1 (fr) | 1993-08-04 |
| CN1117499A (zh) | 1996-02-28 |
| EP0553806B1 (fr) | 1998-05-06 |
| FI930403A0 (fi) | 1993-01-29 |
| NO930348L (no) | 1993-08-02 |
| JPH0665314A (ja) | 1994-03-08 |
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