MX362989B - Proceso para la epoxidacion de una olefina. - Google Patents

Proceso para la epoxidacion de una olefina.

Info

Publication number
MX362989B
MX362989B MX2018006438A MX2018006438A MX362989B MX 362989 B MX362989 B MX 362989B MX 2018006438 A MX2018006438 A MX 2018006438A MX 2018006438 A MX2018006438 A MX 2018006438A MX 362989 B MX362989 B MX 362989B
Authority
MX
Mexico
Prior art keywords
hydrogen peroxide
epoxidation
olefin
fixed bed
feed mixture
Prior art date
Application number
MX2018006438A
Other languages
English (en)
Other versions
MX2018006438A (es
Inventor
Pascaly Matthias
BÄRZ Manfred
Brendel Marc
Jahn Robert
Schemel Jürgen
Dopfer Michael
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=54782456&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX362989(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of MX2018006438A publication Critical patent/MX2018006438A/es
Publication of MX362989B publication Critical patent/MX362989B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2475Membrane reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0492Feeding reactive fluids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/0027Pressure relief
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/0068Means for controlling the apparatus of the process
    • B01J2219/00702Processes involving means for analysing and characterising the products
    • B01J2219/00707Processes involving means for analysing and characterising the products separated from the reactor apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32279Tubes or cylinders
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

En un proceso para la epoxidación de una olefina mediante reaccionar continua de la olefina con peróxido de hidrógeno en un solvente de metanol en un catalizador de epoxidación de lecho fijo que comprende una zeolita de titanio, el peróxido de hidrógeno se utiliza como una solución acuosa de peróxido de hidrógeno producida mediante un proceso de antraquinona, la solución acuosa de peróxido de hidrógeno se mezcla con metanol para dar una mezcla de alimentación y esta mezcla de alimentación se filtra antes de ponerse en contacto con el catalizador de epoxidación de lecho fijo.
MX2018006438A 2015-11-26 2016-11-01 Proceso para la epoxidacion de una olefina. MX362989B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15196528 2015-11-26
PCT/EP2016/076268 WO2017089074A1 (en) 2015-11-26 2016-11-01 Process for the epoxidation of an olefin

Publications (2)

Publication Number Publication Date
MX2018006438A MX2018006438A (es) 2018-09-28
MX362989B true MX362989B (es) 2019-02-28

Family

ID=54782456

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018006438A MX362989B (es) 2015-11-26 2016-11-01 Proceso para la epoxidacion de una olefina.

Country Status (13)

Country Link
US (1) US10428035B2 (es)
EP (1) EP3380459B1 (es)
KR (1) KR102642647B1 (es)
CN (2) CN112159369A (es)
AR (1) AR106814A1 (es)
EA (1) EA033968B1 (es)
ES (1) ES2769921T3 (es)
HU (1) HUE048938T2 (es)
MX (1) MX362989B (es)
MY (1) MY184843A (es)
PL (1) PL3380459T3 (es)
TW (1) TWI629269B (es)
WO (1) WO2017089074A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI707847B (zh) 2015-11-26 2020-10-21 德商贏創運營有限公司 丙烯之環氧化方法
EP3380459B1 (en) 2015-11-26 2020-01-01 Evonik Operations GmbH Process for the epoxidation of an olefin
EP3405460B1 (en) 2016-01-19 2020-06-24 Evonik Operations GmbH Process for the epoxidation of an olefin
HUE052019T2 (hu) 2016-03-21 2021-04-28 Evonik Operations Gmbh Eljárás propén epoxidálására
EP3246323A1 (en) 2016-05-17 2017-11-22 Evonik Degussa GmbH Integrated process for making propene oxide from propane
EP3406603A1 (en) 2017-05-22 2018-11-28 Evonik Degussa GmbH Process for the epoxidation of propene
KR20240006545A (ko) 2021-05-10 2024-01-15 에보닉 오퍼레이션스 게엠베하 프로펜 옥사이드를 제조하기 위한 통합 플랜트 및 통합 프로세스
EP4359394A1 (en) 2021-06-23 2024-05-01 Basf Se Process for the preparation of a liquid mixture comprising methanol, water and hydrogen peroxide

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4308409A (en) 1978-10-03 1981-12-29 Gulf Research & Development Company Preparation of propylene glycol from propylene
US5274140A (en) 1979-07-19 1993-12-28 Instituto Guido Donegani, S.P.A. Process for catalytically epoxidizing olefin with hydrogen peroxide
IT1152299B (it) 1982-07-28 1986-12-31 Anic Spa Procedimento per l'espossidazione di composti olefinici
ES2033693T3 (es) 1986-01-28 1993-04-01 Eniricerche S.P.A. Un procedimiento para la exposidacion de compuestos olefinicos.
CA2137310C (en) 1993-12-20 2004-02-17 John C. Jubin Jr. Catalytic converter and method for highly exothermic reactions
DE19507584C2 (de) 1995-03-04 1997-06-12 Geesthacht Gkss Forschung Strahlenchemisch modifizierte Silikonkompositmembran für die Ultrafiltration
US5591875A (en) 1995-08-02 1997-01-07 Chang; Te Epoxidation Process
US5599956A (en) 1996-02-22 1997-02-04 Uop Integrated process for the production of propylene oxide
DE19623608A1 (de) 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden
JP3405125B2 (ja) * 1996-06-14 2003-05-12 住友化学工業株式会社 オレフィン類のエポキシ化物の製造方法
DE19716412A1 (de) * 1997-04-18 1998-10-22 Linde Ag Verfahren zur Herstellung von Epoxiden aus Olefinen
BE1011577A3 (fr) 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur.
JP2001509821A (ja) 1998-03-26 2001-07-24 レプソル キミカ,ソシエダ アノニマ 溶媒の存在下での過酸化水素によるオレフィン性化合物のエポキシ化方法
CN1101334C (zh) 1998-12-21 2003-02-12 黎明化工研究院 一种蒽醌法过氧化氢的精制及浓缩方法
US6013834A (en) * 1999-03-04 2000-01-11 Celanese International Corporation Production of vinyl acetate in a catalytic reactor equipped with filter and distribution bed
DE19936547A1 (de) 1999-08-04 2001-02-15 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
DE19944839A1 (de) 1999-09-18 2001-03-22 Degussa Verfahren zur Herstellung von Epoxiden aus Olefinen
JP4126346B2 (ja) * 1999-10-20 2008-07-30 Dowaサーモテック株式会社 耐焼付き性に優れた摺動部材およびその製法
EP1122249A1 (fr) * 2000-02-02 2001-08-08 SOLVAY (Société Anonyme) Procédé de fabrication d'un oxiranne
DE10052323A1 (de) 2000-10-21 2002-05-02 Degussa Kontinierliches Verfahren zur Hydrierung
EP1247805A1 (en) 2001-03-05 2002-10-09 Degussa AG Process for the epoxidation of olefins
EP1258483A1 (en) * 2001-03-05 2002-11-20 Degussa AG Process for the epoxidation of olefins
EP1247806A1 (en) 2001-03-05 2002-10-09 Degussa AG Process for the epoxidation of olefins
EP1285915A1 (en) 2001-08-16 2003-02-26 Degussa AG Continuous process to make epoxide from olefins and hydrogen peroxide
EP1293505A1 (en) 2001-08-22 2003-03-19 Degussa AG Process for the epoxidation of olefins
US6596883B2 (en) 2001-08-23 2003-07-22 Degussa Ag Process for the epoxidation of olefins
EP1359148A1 (en) 2002-05-02 2003-11-05 Degussa AG Process for the epoxidation of olefins
DE10233385A1 (de) 2002-07-23 2004-02-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Propylenglykolen
US6914167B2 (en) 2002-08-26 2005-07-05 Arco Chemical Technology, L.P. Vent recovery system
DE10240129B4 (de) 2002-08-30 2004-11-11 Basf Ag Integriertes Verfahren zur Synthese von Propylenoxid
EP1403219A1 (en) * 2002-09-30 2004-03-31 Degussa AG Novel aqueous hydrogen peroxide solutions
DE10249378A1 (de) 2002-10-23 2004-05-06 Basf Ag Verfahren zur kontinuierlichen Rückführung des bei der Oxidation von Olefinen mit Hydroperoxiden nicht umgesetzten Olefins mittels Verdichtung und Druckdestillation
DE10249377A1 (de) * 2002-10-23 2004-05-06 Basf Ag Verfahren zu kontinuierlichen Herstellung von Epoxiden aus Olefinen und Hydroperoxiden an einem suspendierten Katalysator
TW200410921A (en) 2002-11-25 2004-07-01 Hoffmann La Roche Mandelic acid derivatives
EP1424331A1 (en) 2002-11-26 2004-06-02 Degussa AG Process for the epoxidation of olefins
EP1424332A1 (en) 2002-11-26 2004-06-02 Degussa AG Process for the purification of crude propene oxide
US7169945B2 (en) 2002-11-26 2007-01-30 Degussa Ag Process for the epoxidation of olefins
US7279145B2 (en) * 2003-03-10 2007-10-09 Lyondell Chemical Technology, L.P. Multiphase reactor design incorporating filtration system for fixed--bed catalyst
EP1489074A1 (en) 2003-06-18 2004-12-22 Degussa AG Process for the epoxidation of propene
DE10341896A1 (de) 2003-09-10 2005-04-14 Uhde Gmbh Mehrphasen-Flüssigkeitsverteiler für einen Rieselbettreaktor
DE102004003003A1 (de) 2004-01-20 2005-09-01 Basf Ag Verfahren und Vorrichtung zur kontinuierlichen Herstellung einer chemischen Verbindung
US7223876B2 (en) 2004-04-21 2007-05-29 Basf Aktiengesellschaft Method of separating an olefin from a gas stream
US20060001497A1 (en) * 2004-07-01 2006-01-05 Minteer Timothy M Magnetic actuator trip and close circuit and related methods
DE102004050506A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung
US20060161010A1 (en) * 2005-01-18 2006-07-20 Basf Aktiengesellschaft Process for the epoxidation of an olefin with improved energy balance
US20070004926A1 (en) * 2005-06-29 2007-01-04 Basf Aktiengesellschaft Process for producing propylene oxide
DE102005031703B3 (de) 2005-07-05 2007-01-11 Gkss-Forschungszentrum Geesthacht Gmbh Kompositmembran
DE102005050283A1 (de) * 2005-10-20 2007-04-26 Basf Ag Verteilervorrichtung für ein Gas-Flüssigphasengemisch für Apparate
DE102007024029A1 (de) 2007-05-22 2008-11-27 Evonik Degussa Gmbh Mehrphasen-Reaktorsumpf
CL2009000939A1 (es) 2008-04-30 2010-10-01 Evonik Degussa Gmbh Proceso para recuperar molibdato o tungstato desde una solucion acuosa que comprende a) contactar la solucion con un material portador inorganico cationizado e insoluble en agua, b) separar el material portador de molibdato o tungstato, c) contactarlo con una solucion acuosa con un ph entre 6 a 14 y d) separar el material saturado.
US20100174099A1 (en) * 2009-01-05 2010-07-08 Lyondell Chemical Technology, L.P. Propylene oxide reactor gas distribution system
EP2343288A1 (en) 2009-11-27 2011-07-13 Momentive Specialty Chemicals Research Belgium S.A. Process for the manufacture of propylene oxide
DE102009047351A1 (de) 2009-12-01 2011-06-09 Evonik Goldschmidt Gmbh Komposit-Siliconmembranen mit hoher Trennwirkung
WO2012076543A1 (en) 2010-12-07 2012-06-14 Basf Se Process for the production of propylene oxide
US8785670B2 (en) 2010-12-07 2014-07-22 Basf Se Process for the production of propylene oxide
CN103842288A (zh) 2011-09-30 2014-06-04 三菱瓦斯化学株式会社 过氧化氢水溶液的制造方法
CN102532063B (zh) * 2011-11-17 2014-02-05 大连理工大学 一种利用工业过氧化氢进行烯烃气相环氧化的装置及方法
DE102012200990A1 (de) 2012-01-24 2013-07-25 Evonik Industries Ag Verfahren zur Rückgewinnung von Molybdat bei einer mit Molybdat katalysierten Delignifizierung von Zellstoff mit Wasserstoffperoxid
CN103664831A (zh) * 2012-09-14 2014-03-26 中国科学院上海高等研究院 生产烯烃衍生物的系统及方法
CN103145102B (zh) 2013-03-11 2015-01-14 上海睿思化工科技有限公司 一种除去过氧化氢中有机杂质的方法
CN109970685A (zh) 2013-10-02 2019-07-05 索尔维公司 用于制造纯化的过氧化氢水溶液的方法
CN106795126B (zh) 2014-07-29 2018-10-26 赢创德固赛有限公司 烯烃的环氧化方法
WO2016113185A1 (en) 2015-01-14 2016-07-21 Evonik Degussa Gmbh Integrated process for making propene oxide and an alkyl tert-butyl ether
CN107428711A (zh) 2015-01-14 2017-12-01 赢创德固赛有限公司 制备环氧丙烯和烷基叔丁基醚的集成方法
EP3059229A1 (en) 2015-02-17 2016-08-24 Evonik Degussa GmbH Method for the epoxidation of an olefin with hydrogen peroxide
JP6707553B2 (ja) 2015-02-17 2020-06-10 エボニック オペレーションズ ゲーエムベーハー 過酸化水素を用いたオレフィンのエポキシ化方法
TW201700464A (zh) 2015-02-17 2017-01-01 贏創德固賽有限責任公司 使用過氧化氫之使烯烴環氧化方法
EP3059230A1 (en) 2015-02-17 2016-08-24 Evonik Degussa GmbH Method for the epoxidation of propene with hydrogen peroxide
US10125108B2 (en) 2015-04-28 2018-11-13 Evonik Degussa Gmbh Process for the epoxidation of propene
KR102648446B1 (ko) 2015-11-25 2024-03-15 에보닉 오퍼레이션스 게엠베하 프로펜 및 과산화수소로부터 프로필렌 글리콜의 제조 방법
KR102648943B1 (ko) 2015-11-26 2024-03-18 에보닉 오퍼레이션스 게엠베하 프로펜의 에폭시화를 위한 방법 및 반응기
TWI707847B (zh) 2015-11-26 2020-10-21 德商贏創運營有限公司 丙烯之環氧化方法
EP3380459B1 (en) 2015-11-26 2020-01-01 Evonik Operations GmbH Process for the epoxidation of an olefin
EP3405460B1 (en) 2016-01-19 2020-06-24 Evonik Operations GmbH Process for the epoxidation of an olefin

Also Published As

Publication number Publication date
KR102642647B1 (ko) 2024-02-29
ES2769921T3 (es) 2020-06-29
EP3380459B1 (en) 2020-01-01
CN108368073A (zh) 2018-08-03
MY184843A (en) 2021-04-26
EP3380459A1 (en) 2018-10-03
MX2018006438A (es) 2018-09-28
HUE048938T2 (hu) 2020-09-28
EA033968B1 (ru) 2019-12-16
TW201731829A (zh) 2017-09-16
CN112159369A (zh) 2021-01-01
WO2017089074A1 (en) 2017-06-01
KR20180086232A (ko) 2018-07-30
TWI629269B (zh) 2018-07-11
AR106814A1 (es) 2018-02-21
US10428035B2 (en) 2019-10-01
CN108368073B (zh) 2022-03-22
PL3380459T3 (pl) 2020-06-01
EA201891221A1 (ru) 2018-12-28
US20180354923A1 (en) 2018-12-13

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