MX2016017154A - Proceso para la preparacion de etilenglicol a partir de azucares. - Google Patents
Proceso para la preparacion de etilenglicol a partir de azucares.Info
- Publication number
- MX2016017154A MX2016017154A MX2016017154A MX2016017154A MX2016017154A MX 2016017154 A MX2016017154 A MX 2016017154A MX 2016017154 A MX2016017154 A MX 2016017154A MX 2016017154 A MX2016017154 A MX 2016017154A MX 2016017154 A MX2016017154 A MX 2016017154A
- Authority
- MX
- Mexico
- Prior art keywords
- preparation
- ethylene glycol
- sugars
- pyrolysing
- monosaccharide
- Prior art date
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 235000000346 sugar Nutrition 0.000 title 1
- 150000008163 sugars Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 150000002772 monosaccharides Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/202—Ethylene glycol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/205—1,3-Propanediol; 1,2-Propanediol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
- C07C45/60—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
- C07C47/12—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing more than one —CHO group
- C07C47/127—Glyoxal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
- C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/185—Saturated compounds containing keto groups bound to acyclic carbon atoms containing —CHO groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
Abstract
La presente invención se refiere a un proceso para la preparación de etilenglicol que comprende los pasos que consisten en pirolizar un monosacárido e hidrogenar una composición del producto en presencia de un catalizador y un solvente, en donde la presión de la reacción de hidrogenación es 40 bares o mayor.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14174972 | 2014-06-30 | ||
EP14174976 | 2014-06-30 | ||
PCT/EP2015/064741 WO2016001169A1 (en) | 2014-06-30 | 2015-06-29 | Process for the preparation of ethylene glycol from sugars |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016017154A true MX2016017154A (es) | 2017-05-03 |
Family
ID=53487377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016017154A MX2016017154A (es) | 2014-06-30 | 2015-06-29 | Proceso para la preparacion de etilenglicol a partir de azucares. |
Country Status (14)
Country | Link |
---|---|
US (1) | US10077222B2 (es) |
EP (1) | EP3160928B1 (es) |
JP (1) | JP6861032B2 (es) |
KR (1) | KR102044453B1 (es) |
CN (1) | CN106795079A (es) |
AU (1) | AU2015282666B2 (es) |
BR (1) | BR112016030694B1 (es) |
CA (1) | CA2952535C (es) |
ES (1) | ES2962507T3 (es) |
MX (1) | MX2016017154A (es) |
PL (1) | PL3160928T3 (es) |
TW (1) | TWI660936B (es) |
WO (1) | WO2016001169A1 (es) |
ZA (1) | ZA201608381B (es) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6959926B2 (ja) * | 2016-01-07 | 2021-11-05 | ハルドール・トプサー・アクチエゼルスカベット | 糖からエチレングリコールを製造する方法 |
EP3414218A1 (en) * | 2016-02-08 | 2018-12-19 | Shell International Research Maatschappij B.V. | Process for the hydrogenation of glycolaldehyde |
BR112018016284A2 (pt) * | 2016-02-09 | 2018-12-18 | Shell Int Research | processo para a produção de alquileno glicóis |
MY193158A (en) * | 2016-06-03 | 2022-09-26 | Iowa Corn Promotion Board | Continuous processes for the highly selective conversion of aldohexose-yielding carbohydrate to ethylene glycol |
EP3786145A1 (en) | 2016-06-16 | 2021-03-03 | Haldor Topsøe A/S | Thermolytic fragmentation of sugars |
EA036685B1 (ru) * | 2016-06-22 | 2020-12-08 | Хальдор Топсёэ А/С | Термолитическая фрагментация сахаров |
CN108070079A (zh) * | 2016-11-09 | 2018-05-25 | 可口可乐公司 | 生物基meg和pet组合物以及制造它们的方法 |
CN108070075A (zh) * | 2016-11-09 | 2018-05-25 | 可口可乐公司 | 生物基meg和聚酯纤维组合物以及制造它们的方法 |
EP3544947B1 (en) | 2016-11-24 | 2023-09-13 | Topsoe A/S | A method for producing glycolic acid and/or glycolate |
WO2018104508A1 (en) * | 2016-12-08 | 2018-06-14 | Haldor Topsøe A/S | Production of glycolaldehyde by thermolytic fragmentation |
CN109971803B (zh) * | 2017-12-28 | 2022-04-05 | 中国科学院天津工业生物技术研究所 | 一种l-赤藓酮糖和赤藓糖醇生产方法 |
CN108610244B (zh) * | 2018-06-13 | 2020-05-15 | 北京大学 | 一种从醛糖制备乙二醛的方法 |
WO2020016209A1 (en) | 2018-07-16 | 2020-01-23 | Haldor Topsøe A/S | Thermolytic fragmentation of sugars using resistance heating |
JP2022516972A (ja) * | 2019-01-11 | 2022-03-03 | アーチャー-ダニエルズ-ミッドランド カンパニー | カルボニル炭素原子を有する化合物の選択的水素化のためのプロセス及び触媒 |
CN111686747B (zh) * | 2019-03-15 | 2023-03-21 | 北京化工大学 | 葡萄糖氢解反应目标产物为二元醇的催化剂的制备方法 |
US20240270670A1 (en) | 2021-05-28 | 2024-08-15 | Topsoe A/S | Process for partial condensation of an oxygenate mixture |
TW202411183A (zh) | 2022-07-08 | 2024-03-16 | 丹麥商托普索公司 | 冷凝含氧化合物混合物之方法 |
WO2024133660A1 (en) | 2022-12-22 | 2024-06-27 | Topsoe A/S | Purified biomass based compositions comprising ethylene glycol and use thereof to produce a polyester |
WO2024133661A1 (en) | 2022-12-22 | 2024-06-27 | Topsoe A/S | Purified biomass based compositions comprising ethylene glycol and use thereof to produce a polyester |
WO2024133659A1 (en) | 2022-12-22 | 2024-06-27 | Topsoe A/S | Method of producing a polyester |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
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US4200765A (en) | 1976-09-17 | 1980-04-29 | National Distillers And Chemical Corporation | Glycol aldehyde and ethylene glycol processes |
EP0002908B1 (en) | 1977-12-16 | 1982-05-12 | Monsanto Company | Hydroformylation of formaldehyde with rhodium catalyst |
US4317946A (en) | 1980-06-27 | 1982-03-02 | The Halcon Sd Group, Inc. | Process for producing ethylene glycol via catalytic hydrogenation of glycolaldehyde |
US4321414A (en) * | 1980-08-26 | 1982-03-23 | The Halcon Sd Group, Inc. | Catalytic hydrogenation of glycolaldehyde to produce ethylene glycol |
US4476331A (en) * | 1982-02-11 | 1984-10-09 | Ethyl Corporation | Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage |
US4496781A (en) * | 1984-04-05 | 1985-01-29 | The Halcon Sd Group, Inc. | Process for the production of ethylene glycol through the hydroformylation of glycol aldehyde |
US5210337A (en) | 1988-12-15 | 1993-05-11 | Hoechst Celanese Corporation | Formaldehyde resistant catalyst for hydrogenation and hydrogenolysis of aldehydes, acetals, and esters |
US5252188A (en) | 1990-03-26 | 1993-10-12 | Red Arrow Products Company, Inc. | Process for producing hydroxyacetaldehyde |
DE4023255A1 (de) * | 1990-07-21 | 1992-01-23 | Basf Ag | Verfahren zur herstellung von glykolen, insbesondere propylenglykol aus formaldehyd |
FR2789683B1 (fr) | 1999-02-17 | 2002-02-15 | Roquette Freres | Procede continu de preparation d'un ose hydrogene de haute purete par hydrogenation catalytique |
CA2326471A1 (en) | 2000-11-20 | 2002-05-20 | Resource Transforms International Ltd. | Production of glycolaldehyde by hydrous thermolysis of sugars |
US6900361B2 (en) * | 2001-05-08 | 2005-05-31 | Battelle Memorial Institute | Process for lactose conversion to polyols |
CN1762938A (zh) | 2005-09-21 | 2006-04-26 | 徐昌洪 | 氢化裂解法生产乙二醇及低级多元醇的方法 |
WO2008051540A2 (en) | 2006-10-23 | 2008-05-02 | Archer-Daniels-Midland Company | Hydrogenolysis of glycerol and products produced therefrom |
US8177980B2 (en) | 2007-11-09 | 2012-05-15 | Archer Daniels Midland Company | Separation of a mixture of polyhydric alcohols |
CN101735014B (zh) | 2008-11-26 | 2013-07-24 | 中国科学院大连化学物理研究所 | 一种多羟基化合物制乙二醇的方法 |
CN102190562B (zh) | 2010-03-17 | 2014-03-05 | 中国科学院大连化学物理研究所 | 一种多羟基化合物制乙二醇的方法 |
CN101781168A (zh) | 2010-03-18 | 2010-07-21 | 西安近代化学研究所 | 二元醇和多元醇的合成方法 |
WO2012125276A2 (en) | 2011-03-14 | 2012-09-20 | Archer Daniels Midland Company | Improved methods for producing bioderived propylene glycol |
US8222463B2 (en) | 2011-07-28 | 2012-07-17 | Uop Llc | Process for generation of polyols from saccharide containing feedstock |
WO2013015996A2 (en) * | 2011-07-28 | 2013-01-31 | Uop Llc | Generation of polyols from saccharide containing feedstock |
US9767173B2 (en) | 2012-10-22 | 2017-09-19 | Workday, Inc. | Systems and methods for interest-driven data sharing in interest-driven business intelligence systems |
TWI630197B (zh) | 2013-02-27 | 2018-07-21 | 丹麥商哈爾德杜薩公司 | 從包含低分子量羰基化合物之組成物移除甲醛的方法 |
MY184090A (en) * | 2014-05-19 | 2021-03-17 | Iowa Corn Promotion Board | Process for the continuous production of ethylene glycol from carbohydrates |
-
2015
- 2015-06-29 EP EP15731382.6A patent/EP3160928B1/en active Active
- 2015-06-29 PL PL15731382.6T patent/PL3160928T3/pl unknown
- 2015-06-29 CN CN201580035793.3A patent/CN106795079A/zh active Pending
- 2015-06-29 BR BR112016030694-5A patent/BR112016030694B1/pt active IP Right Grant
- 2015-06-29 ES ES15731382T patent/ES2962507T3/es active Active
- 2015-06-29 MX MX2016017154A patent/MX2016017154A/es unknown
- 2015-06-29 WO PCT/EP2015/064741 patent/WO2016001169A1/en active Application Filing
- 2015-06-29 AU AU2015282666A patent/AU2015282666B2/en active Active
- 2015-06-29 KR KR1020177001266A patent/KR102044453B1/ko active IP Right Grant
- 2015-06-29 CA CA2952535A patent/CA2952535C/en active Active
- 2015-06-29 JP JP2016575912A patent/JP6861032B2/ja active Active
- 2015-06-29 US US15/322,680 patent/US10077222B2/en active Active
- 2015-06-30 TW TW104121106A patent/TWI660936B/zh active
-
2016
- 2016-12-05 ZA ZA2016/08381A patent/ZA201608381B/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU2015282666B2 (en) | 2019-04-18 |
CN106795079A (zh) | 2017-05-31 |
KR102044453B1 (ko) | 2019-11-13 |
JP6861032B2 (ja) | 2021-04-21 |
US10077222B2 (en) | 2018-09-18 |
KR20170027778A (ko) | 2017-03-10 |
EP3160928C0 (en) | 2023-10-25 |
US20170137354A1 (en) | 2017-05-18 |
AU2015282666A1 (en) | 2017-01-12 |
WO2016001169A1 (en) | 2016-01-07 |
CA2952535C (en) | 2019-03-19 |
BR112016030694B1 (pt) | 2020-12-15 |
TW201634433A (zh) | 2016-10-01 |
BR112016030694A2 (pt) | 2018-07-17 |
JP2017519792A (ja) | 2017-07-20 |
ES2962507T3 (es) | 2024-03-19 |
CA2952535A1 (en) | 2016-01-07 |
ZA201608381B (en) | 2020-05-27 |
TWI660936B (zh) | 2019-06-01 |
EP3160928A1 (en) | 2017-05-03 |
EP3160928B1 (en) | 2023-10-25 |
PL3160928T3 (pl) | 2024-03-04 |
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