MX344267B - Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo. - Google Patents

Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo.

Info

Publication number
MX344267B
MX344267B MX2013010135A MX2013010135A MX344267B MX 344267 B MX344267 B MX 344267B MX 2013010135 A MX2013010135 A MX 2013010135A MX 2013010135 A MX2013010135 A MX 2013010135A MX 344267 B MX344267 B MX 344267B
Authority
MX
Mexico
Prior art keywords
styrene
preparation
methods
butadiene rubber
group
Prior art date
Application number
MX2013010135A
Other languages
English (en)
Other versions
MX2013010135A (es
Inventor
Valenti Silvia
Hamann Evemarie
Schmiedel Karin
Original Assignee
Styron Europe Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styron Europe Gmbh filed Critical Styron Europe Gmbh
Publication of MX2013010135A publication Critical patent/MX2013010135A/es
Publication of MX344267B publication Critical patent/MX344267B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C08L5/06Pectin; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Un proceso para la polimerización de un polímero que contiene unidades monoméricas derivadas de un monómero de estireno y un monómero de 1,3-butadieno incluye polimerizar las unidades monoméricas en presencia de un iniciador, un primer agente polar, y un segundo agente polar. El primer agente polar incluye una estructura (1): R1'R2'N-Q-NR3'R4' y el segundo agente polar comprende una estructura (II): R1', R2', R3', y R4' son cada uno independientemente seleccionados del grupo que consiste de un grupo alquilo e hidrógeno; Q contiene un grupo alquileno; R1 y R2 son cada uno independientemente un grupo alquilo; y R3, R4, R5, R6, R7 y R8 son cada uno independientemente seleccionados del grupo que consiste de un grupo alquilo e hidrógeno. Se describen polímeros preparados por los procesos anteriores, así como composiciones que contienen dicho polímero, y artículos que contienen al menos un componente formado a partir de tal composición.
MX2013010135A 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo. MX344267B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11156988.5A EP2495267B1 (en) 2011-03-04 2011-03-04 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
PCT/EP2012/053523 WO2012119917A1 (en) 2011-03-04 2012-03-01 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof

Publications (2)

Publication Number Publication Date
MX2013010135A MX2013010135A (es) 2014-02-27
MX344267B true MX344267B (es) 2016-12-09

Family

ID=44121525

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013010135A MX344267B (es) 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo.

Country Status (13)

Country Link
US (1) US9000109B2 (es)
EP (1) EP2495267B1 (es)
JP (1) JP5873112B2 (es)
KR (1) KR101908155B1 (es)
CN (1) CN103476814B (es)
BR (1) BR112013022513A2 (es)
ES (1) ES2598035T3 (es)
HU (1) HUE031642T2 (es)
MX (1) MX344267B (es)
PL (1) PL2495267T3 (es)
RU (1) RU2626320C2 (es)
SG (1) SG192909A1 (es)
WO (1) WO2012119917A1 (es)

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PL2537871T3 (pl) 2011-06-22 2019-03-29 Trinseo Europe Gmbh Kauczuk styrenowo-butadienowy o dużej zawartości styrenu i o dużej zawartości winylu o wąskim rozkładzie masy cząsteczkowej i sposoby jego otrzymywania
KR101721635B1 (ko) * 2015-07-20 2017-03-30 공요찬 스피커 엣지 및 스피커
WO2018081799A1 (en) * 2016-10-31 2018-05-03 Bridgestone Corporation Methods for producing polydienes
US11525049B2 (en) 2017-03-29 2022-12-13 Synthos S.A. Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents
US10358430B2 (en) 2017-08-25 2019-07-23 Thomas Swan & Co. Ltd Oligomeric (TH)FP, production and uses therefor
WO2020066561A1 (ja) * 2018-09-27 2020-04-02 富士フイルム株式会社 重合体の製造方法、及び重合体を製造するフロー式反応システム

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Also Published As

Publication number Publication date
HUE031642T2 (en) 2017-07-28
RU2626320C2 (ru) 2017-07-26
RU2013144551A (ru) 2015-04-10
SG192909A1 (en) 2013-09-30
PL2495267T3 (pl) 2017-08-31
US20130345379A1 (en) 2013-12-26
EP2495267B1 (en) 2016-10-12
JP2014506950A (ja) 2014-03-20
CN103476814B (zh) 2016-06-01
EP2495267A1 (en) 2012-09-05
US9000109B2 (en) 2015-04-07
MX2013010135A (es) 2014-02-27
CN103476814A (zh) 2013-12-25
KR20140003583A (ko) 2014-01-09
JP5873112B2 (ja) 2016-03-01
KR101908155B1 (ko) 2018-10-15
WO2012119917A1 (en) 2012-09-13
ES2598035T3 (es) 2017-01-24
BR112013022513A2 (pt) 2016-12-06

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