MX344267B - Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo. - Google Patents
Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo.Info
- Publication number
- MX344267B MX344267B MX2013010135A MX2013010135A MX344267B MX 344267 B MX344267 B MX 344267B MX 2013010135 A MX2013010135 A MX 2013010135A MX 2013010135 A MX2013010135 A MX 2013010135A MX 344267 B MX344267 B MX 344267B
- Authority
- MX
- Mexico
- Prior art keywords
- styrene
- preparation
- methods
- butadiene rubber
- group
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/06—Pectin; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
Un proceso para la polimerización de un polímero que contiene unidades monoméricas derivadas de un monómero de estireno y un monómero de 1,3-butadieno incluye polimerizar las unidades monoméricas en presencia de un iniciador, un primer agente polar, y un segundo agente polar. El primer agente polar incluye una estructura (1): R1'R2'N-Q-NR3'R4' y el segundo agente polar comprende una estructura (II): R1', R2', R3', y R4' son cada uno independientemente seleccionados del grupo que consiste de un grupo alquilo e hidrógeno; Q contiene un grupo alquileno; R1 y R2 son cada uno independientemente un grupo alquilo; y R3, R4, R5, R6, R7 y R8 son cada uno independientemente seleccionados del grupo que consiste de un grupo alquilo e hidrógeno. Se describen polímeros preparados por los procesos anteriores, así como composiciones que contienen dicho polímero, y artículos que contienen al menos un componente formado a partir de tal composición.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11156988.5A EP2495267B1 (en) | 2011-03-04 | 2011-03-04 | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
PCT/EP2012/053523 WO2012119917A1 (en) | 2011-03-04 | 2012-03-01 | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2013010135A MX2013010135A (es) | 2014-02-27 |
MX344267B true MX344267B (es) | 2016-12-09 |
Family
ID=44121525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013010135A MX344267B (es) | 2011-03-04 | 2012-03-01 | Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo. |
Country Status (13)
Country | Link |
---|---|
US (1) | US9000109B2 (es) |
EP (1) | EP2495267B1 (es) |
JP (1) | JP5873112B2 (es) |
KR (1) | KR101908155B1 (es) |
CN (1) | CN103476814B (es) |
BR (1) | BR112013022513A2 (es) |
ES (1) | ES2598035T3 (es) |
HU (1) | HUE031642T2 (es) |
MX (1) | MX344267B (es) |
PL (1) | PL2495267T3 (es) |
RU (1) | RU2626320C2 (es) |
SG (1) | SG192909A1 (es) |
WO (1) | WO2012119917A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2537871T3 (pl) | 2011-06-22 | 2019-03-29 | Trinseo Europe Gmbh | Kauczuk styrenowo-butadienowy o dużej zawartości styrenu i o dużej zawartości winylu o wąskim rozkładzie masy cząsteczkowej i sposoby jego otrzymywania |
KR101721635B1 (ko) * | 2015-07-20 | 2017-03-30 | 공요찬 | 스피커 엣지 및 스피커 |
WO2018081799A1 (en) * | 2016-10-31 | 2018-05-03 | Bridgestone Corporation | Methods for producing polydienes |
US11525049B2 (en) | 2017-03-29 | 2022-12-13 | Synthos S.A. | Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents |
US10358430B2 (en) | 2017-08-25 | 2019-07-23 | Thomas Swan & Co. Ltd | Oligomeric (TH)FP, production and uses therefor |
WO2020066561A1 (ja) * | 2018-09-27 | 2020-04-02 | 富士フイルム株式会社 | 重合体の製造方法、及び重合体を製造するフロー式反応システム |
Family Cites Families (39)
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JPS57100112A (en) * | 1980-12-16 | 1982-06-22 | Asahi Chem Ind Co Ltd | Perfectly random styrene-butadiene copolymer rubber |
JPS58142901A (ja) | 1982-02-19 | 1983-08-25 | Nippon Zeon Co Ltd | ゴムの変性方法 |
JPS5936144A (ja) | 1982-08-23 | 1984-02-28 | Sumitomo Rubber Ind Ltd | ジエン系ゴム組成物及び該組成物をトレツドに用いたタイヤ |
US4616069A (en) | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
JPH0641488B2 (ja) * | 1985-05-09 | 1994-06-01 | 旭化成工業株式会社 | 耐屈曲性に優れたスチレン−ブタジエン共重合ゴムの製造方法 |
JPH0621123B2 (ja) * | 1986-07-30 | 1994-03-23 | 住友化学工業株式会社 | ジエン系重合体およびその製造法 |
EP0299074B1 (en) | 1987-01-14 | 1992-01-29 | Bridgestone Corporation | Tire |
JPS6438402A (en) * | 1987-08-04 | 1989-02-08 | Asahi Chemical Ind | Selectively partially hydrogenated polymer and composition thereof |
CA1338317C (en) | 1988-02-25 | 1996-05-07 | Akio Imai | Modified diene polymer rubbers |
EP0447066B2 (en) | 1990-03-02 | 2000-08-16 | Bridgestone Corporation | Pneumatic tyres |
US5066729A (en) | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
US5070150A (en) | 1990-07-02 | 1991-12-03 | The Goodyear Tire & Rubber Company | Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan |
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JPH0674353B2 (ja) * | 1991-05-17 | 1994-09-21 | 旭化成工業株式会社 | 選択部分水添重合体組成物 |
US5210145A (en) * | 1991-12-20 | 1993-05-11 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds |
US5532327A (en) * | 1991-12-30 | 1996-07-02 | Xerox Corporation | Random copolymers made by anionic polymerization, toners incorporating these copolymers and method for the manufacture thereof |
JP3290469B2 (ja) * | 1992-08-17 | 2002-06-10 | ジェイエスアール株式会社 | ゴム組成物 |
JP3319639B2 (ja) | 1992-12-24 | 2002-09-03 | 株式会社ブリヂストン | 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物 |
US5405903A (en) * | 1993-03-30 | 1995-04-11 | Shell Oil Company | Process for the preparation of a block copolymer blend |
DE69411984T2 (de) * | 1993-04-30 | 1998-12-10 | Bridgestone Corp., Tokio/Tokyo | Anionische Polymerisationsinitiatoren und Produkte mit niedriger Hysteresis |
FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
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US6008295A (en) * | 1997-07-11 | 1999-12-28 | Bridgestone Corporation | Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds |
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WO2004065478A1 (fr) * | 2003-01-20 | 2004-08-05 | Societe De Technologie Michelin | Composition de caoutchouc pour bande de roulement de pneumatique et procede de preparation |
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KR100992324B1 (ko) | 2005-09-22 | 2010-11-05 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 공액 디엔계 중합체 및 그의 제조 방법 |
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US8053542B2 (en) | 2008-04-30 | 2011-11-08 | Styron Europe Gmbh | Styrene-butadiene polymers with styrene gradient and methods of making the same |
JP5521698B2 (ja) * | 2009-03-31 | 2014-06-18 | 日本ゼオン株式会社 | 防振ゴム部材、架橋物、防振ゴム用組成物、ならびに防振ゴム用共役ジエンゴム組成物およびその製造方法 |
JP5692067B2 (ja) * | 2009-05-11 | 2015-04-01 | 日本ゼオン株式会社 | 末端変性放射状共役ジエン重合体の製造方法 |
JP6074353B2 (ja) * | 2013-11-12 | 2017-02-01 | 京楽産業.株式会社 | 遊技機 |
-
2011
- 2011-03-04 ES ES11156988.5T patent/ES2598035T3/es active Active
- 2011-03-04 EP EP11156988.5A patent/EP2495267B1/en not_active Not-in-force
- 2011-03-04 PL PL11156988T patent/PL2495267T3/pl unknown
- 2011-03-04 HU HUE11156988A patent/HUE031642T2/en unknown
-
2012
- 2012-03-01 BR BR112013022513A patent/BR112013022513A2/pt not_active IP Right Cessation
- 2012-03-01 KR KR1020137023145A patent/KR101908155B1/ko active IP Right Grant
- 2012-03-01 SG SG2013063771A patent/SG192909A1/en unknown
- 2012-03-01 JP JP2013555873A patent/JP5873112B2/ja not_active Expired - Fee Related
- 2012-03-01 MX MX2013010135A patent/MX344267B/es active IP Right Grant
- 2012-03-01 WO PCT/EP2012/053523 patent/WO2012119917A1/en active Application Filing
- 2012-03-01 CN CN201280011615.3A patent/CN103476814B/zh not_active Expired - Fee Related
- 2012-03-01 US US14/001,612 patent/US9000109B2/en not_active Expired - Fee Related
- 2012-03-01 RU RU2013144551A patent/RU2626320C2/ru not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HUE031642T2 (en) | 2017-07-28 |
RU2626320C2 (ru) | 2017-07-26 |
RU2013144551A (ru) | 2015-04-10 |
SG192909A1 (en) | 2013-09-30 |
PL2495267T3 (pl) | 2017-08-31 |
US20130345379A1 (en) | 2013-12-26 |
EP2495267B1 (en) | 2016-10-12 |
JP2014506950A (ja) | 2014-03-20 |
CN103476814B (zh) | 2016-06-01 |
EP2495267A1 (en) | 2012-09-05 |
US9000109B2 (en) | 2015-04-07 |
MX2013010135A (es) | 2014-02-27 |
CN103476814A (zh) | 2013-12-25 |
KR20140003583A (ko) | 2014-01-09 |
JP5873112B2 (ja) | 2016-03-01 |
KR101908155B1 (ko) | 2018-10-15 |
WO2012119917A1 (en) | 2012-09-13 |
ES2598035T3 (es) | 2017-01-24 |
BR112013022513A2 (pt) | 2016-12-06 |
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