MX341179B - Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. - Google Patents

Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.

Info

Publication number
MX341179B
MX341179B MX2013010134A MX2013010134A MX341179B MX 341179 B MX341179 B MX 341179B MX 2013010134 A MX2013010134 A MX 2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A MX 341179 B MX341179 B MX 341179B
Authority
MX
Mexico
Prior art keywords
styrene
preparation
methods
polymer
butadiene rubber
Prior art date
Application number
MX2013010134A
Other languages
English (en)
Other versions
MX2013010134A (es
Inventor
Valenti Silvia
Hamann Evemarie
Schmiedel Karin
Original Assignee
Styron Europe Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styron Europe Gmbh filed Critical Styron Europe Gmbh
Publication of MX2013010134A publication Critical patent/MX2013010134A/es
Publication of MX341179B publication Critical patent/MX341179B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Un polímero tiene al menos las siguientes características: (a) un contenido de estireno en bloque que contiene 4 a 6 unidades de estireno de aproximadamente 27 a aproximadamente 50 por ciento en peso basado en el contenido de estireno total en el polímero; (b) un contenido de vinilo de aproximadamente 30 a aproximadamente 80 por ciento en peso basado en la cantidad total de 1,3-butadieno polimerizado; y (c) un contenido de estireno de aproximadamente 40 a aproximadamente 70 por ciento en peso basado en el peso total del polímero. Se describen procesos para la polimerización de un polímero de este tipo, composiciones que contienen dicho polímero, y artículos que contienen al menos un componente formado a partir de dicha composición.
MX2013010134A 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. MX341179B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11156987A EP2495266A1 (en) 2011-03-04 2011-03-04 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
PCT/EP2012/053524 WO2012119918A1 (en) 2011-03-04 2012-03-01 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof

Publications (2)

Publication Number Publication Date
MX2013010134A MX2013010134A (es) 2014-03-26
MX341179B true MX341179B (es) 2016-08-10

Family

ID=44147899

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013010134A MX341179B (es) 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.

Country Status (10)

Country Link
US (1) US8981000B2 (es)
EP (1) EP2495266A1 (es)
JP (1) JP6077470B2 (es)
KR (1) KR20140003584A (es)
CN (1) CN103443152B (es)
BR (1) BR112013022511A2 (es)
MX (1) MX341179B (es)
RU (1) RU2606129C2 (es)
SG (1) SG192912A1 (es)
WO (1) WO2012119918A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2537872B1 (en) * 2011-06-22 2015-08-12 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
EP2746300B1 (en) 2012-12-21 2016-12-07 Borealis AG Process for producing a ziegler natta procatalyst for ethylene polymerisation
ES2653868T3 (es) 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
ES2709631T3 (es) 2013-04-30 2019-04-17 Borealis Ag Catalizadores de Ziegler-Natta soportados modificados con donador
CN103672218A (zh) * 2013-12-23 2014-03-26 苏州市依星橡塑有限公司 一种新型橡胶管
TWI531605B (zh) * 2014-12-30 2016-05-01 奇美實業股份有限公司 共軛二烯－乙烯基芳香烴共聚物及橡膠組成物
WO2018016980A1 (en) * 2016-07-19 2018-01-25 Public Joint Stock Company "Sibur Holding" (Pjsc "Sibur Holding") Random copolymers of vinyl aromatic compounds and conjugated dimers and method for preparing the same
WO2018016986A1 (en) * 2016-07-22 2018-01-25 Public Joint Stock Company "Sibur Holding" A method of producing a rubber, a rubber composition comprising the rubber obtained by said method, and also use of the rubber composition
US11525049B2 (en) 2017-03-29 2022-12-13 Synthos S.A. Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents
CN109485791B (zh) * 2017-09-13 2021-10-19 中国石油化工股份有限公司 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法
CN109627382B (zh) * 2017-10-06 2022-03-18 台橡股份有限公司 共轭二烯聚合物及其组合物及制造方法
KR102154046B1 (ko) * 2017-10-26 2020-09-09 주식회사 엘지화학 연속식 중합에 의한 공액디엔계 중합체의 제조방법
JP6961826B2 (ja) * 2017-12-26 2021-11-05 株式会社ブリヂストン 低分子量テーパードスチレン−ブタジエンコポリマーの合成、及びタイヤにおけるその使用

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JPS58142901A (ja) 1982-02-19 1983-08-25 Nippon Zeon Co Ltd ゴムの変性方法
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EP2537872B1 (en) * 2011-06-22 2015-08-12 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof

Also Published As

Publication number Publication date
BR112013022511A2 (pt) 2016-12-06
KR20140003584A (ko) 2014-01-09
JP2014506951A (ja) 2014-03-20
WO2012119918A1 (en) 2012-09-13
SG192912A1 (en) 2013-09-30
RU2606129C2 (ru) 2017-01-10
RU2013144577A (ru) 2015-04-10
CN103443152B (zh) 2016-01-13
US20140024767A1 (en) 2014-01-23
JP6077470B2 (ja) 2017-02-08
EP2495266A1 (en) 2012-09-05
CN103443152A (zh) 2013-12-11
US8981000B2 (en) 2015-03-17
MX2013010134A (es) 2014-03-26

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