MX341179B - Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. - Google Patents
Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.Info
- Publication number
- MX341179B MX341179B MX2013010134A MX2013010134A MX341179B MX 341179 B MX341179 B MX 341179B MX 2013010134 A MX2013010134 A MX 2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A MX 341179 B MX341179 B MX 341179B
- Authority
- MX
- Mexico
- Prior art keywords
- styrene
- preparation
- methods
- polymer
- butadiene rubber
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 2
- QOVWSDOHZFBJSO-UHFFFAOYSA-N C=CC=C.C=CC=CC1=CC=CC=C1 Chemical compound C=CC=C.C=CC=CC1=CC=CC=C1 QOVWSDOHZFBJSO-UHFFFAOYSA-N 0.000 title 1
- 229920003048 styrene butadiene rubber Polymers 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Un polímero tiene al menos las siguientes características: (a) un contenido de estireno en bloque que contiene 4 a 6 unidades de estireno de aproximadamente 27 a aproximadamente 50 por ciento en peso basado en el contenido de estireno total en el polímero; (b) un contenido de vinilo de aproximadamente 30 a aproximadamente 80 por ciento en peso basado en la cantidad total de 1,3-butadieno polimerizado; y (c) un contenido de estireno de aproximadamente 40 a aproximadamente 70 por ciento en peso basado en el peso total del polímero. Se describen procesos para la polimerización de un polímero de este tipo, composiciones que contienen dicho polímero, y artículos que contienen al menos un componente formado a partir de dicha composición.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11156987A EP2495266A1 (en) | 2011-03-04 | 2011-03-04 | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
| PCT/EP2012/053524 WO2012119918A1 (en) | 2011-03-04 | 2012-03-01 | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013010134A MX2013010134A (es) | 2014-03-26 |
| MX341179B true MX341179B (es) | 2016-08-10 |
Family
ID=44147899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013010134A MX341179B (es) | 2011-03-04 | 2012-03-01 | Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8981000B2 (es) |
| EP (1) | EP2495266A1 (es) |
| JP (1) | JP6077470B2 (es) |
| KR (1) | KR20140003584A (es) |
| CN (1) | CN103443152B (es) |
| BR (1) | BR112013022511A2 (es) |
| MX (1) | MX341179B (es) |
| RU (1) | RU2606129C2 (es) |
| SG (1) | SG192912A1 (es) |
| WO (1) | WO2012119918A1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2537872T3 (pl) * | 2011-06-22 | 2015-11-30 | Trinseo Europe Gmbh | Kauczuk styrenowo-butadienowy wysokostyrenowy wysokowinylowy o wąskim rozkładzie masy cząsteczkowej oraz metody jego przygotowania |
| ES2653868T3 (es) | 2012-12-21 | 2018-02-09 | Borealis Ag | Procatalizador de Ziegler Natta soportado para la polimerización de etileno |
| EP2746300B1 (en) | 2012-12-21 | 2016-12-07 | Borealis AG | Process for producing a ziegler natta procatalyst for ethylene polymerisation |
| EP2799456B1 (en) | 2013-04-30 | 2018-11-21 | Borealis AG | Supported donor modified Ziegler-Natta catalysts |
| CN103672218A (zh) * | 2013-12-23 | 2014-03-26 | 苏州市依星橡塑有限公司 | 一种新型橡胶管 |
| TWI531605B (zh) * | 2014-12-30 | 2016-05-01 | 奇美實業股份有限公司 | 共軛二烯-乙烯基芳香烴共聚物及橡膠組成物 |
| WO2018016980A1 (en) * | 2016-07-19 | 2018-01-25 | Public Joint Stock Company "Sibur Holding" (Pjsc "Sibur Holding") | Random copolymers of vinyl aromatic compounds and conjugated dimers and method for preparing the same |
| RU2709530C1 (ru) * | 2016-07-22 | 2019-12-18 | Публичное акционерное общество "СИБУР Холдинг" | Способ получения каучука, резиновая композиция, содержащая полученный данным способом каучук, а также применение резиновой композиции |
| BR112019020104A2 (pt) * | 2017-03-29 | 2020-05-05 | Synthos Dwory 7 Spolka Z Ograniczona Odpowiedzialnoscia Spolka Jawna | aditivo polar para síntese de copolímeros de monômero de vinilaromático e monômero de dieno conjugado tendo alto teor de vinilaromático e baixo teor de vinila |
| CN109485791B (zh) * | 2017-09-13 | 2021-10-19 | 中国石油化工股份有限公司 | 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法 |
| CN109627382B (zh) * | 2017-10-06 | 2022-03-18 | 台橡股份有限公司 | 共轭二烯聚合物及其组合物及制造方法 |
| KR102154046B1 (ko) * | 2017-10-26 | 2020-09-09 | 주식회사 엘지화학 | 연속식 중합에 의한 공액디엔계 중합체의 제조방법 |
| JP6961826B2 (ja) * | 2017-12-26 | 2021-11-05 | 株式会社ブリヂストン | 低分子量テーパードスチレン−ブタジエンコポリマーの合成、及びタイヤにおけるその使用 |
| KR20250135291A (ko) | 2023-03-20 | 2025-09-12 | 닛뽕 엘라스토마 가부시끼가이샤 | 공액 디엔계 중합체 및 공액 디엔계 중합체 조성물 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3496154A (en) * | 1965-10-15 | 1970-02-17 | Phillips Petroleum Co | Random copolymerization |
| JPS58142901A (ja) | 1982-02-19 | 1983-08-25 | Nippon Zeon Co Ltd | ゴムの変性方法 |
| JPS5936144A (ja) | 1982-08-23 | 1984-02-28 | Sumitomo Rubber Ind Ltd | ジエン系ゴム組成物及び該組成物をトレツドに用いたタイヤ |
| US4616069A (en) | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
| DE3776565D1 (de) | 1987-01-14 | 1992-03-12 | Bridgestone Corp | Reifen. |
| DE3724870A1 (de) * | 1987-07-28 | 1989-02-09 | Huels Chemische Werke Ag | Verfahren zur herstellung von polymerisaten auf basis von konjugierten dienen und ggf. monovinylaromatischen verbindungen |
| CA1338317C (en) | 1988-02-25 | 1996-05-07 | Akio Imai | Modified diene polymer rubbers |
| DE69119125T3 (de) | 1990-03-02 | 2001-01-11 | Bridgestone Corp., Tokio/Tokyo | Luftreifen |
| US5066729A (en) | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
| US5070150A (en) | 1990-07-02 | 1991-12-03 | The Goodyear Tire & Rubber Company | Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan |
| US5227431A (en) | 1991-04-12 | 1993-07-13 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine |
| US5210145A (en) | 1991-12-20 | 1993-05-11 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds |
| US5532327A (en) | 1991-12-30 | 1996-07-02 | Xerox Corporation | Random copolymers made by anionic polymerization, toners incorporating these copolymers and method for the manufacture thereof |
| JP3319639B2 (ja) * | 1992-12-24 | 2002-09-03 | 株式会社ブリヂストン | 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物 |
| EP0622381B1 (en) | 1993-04-30 | 1998-07-29 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefrom |
| FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
| ES2174183T3 (es) * | 1996-03-29 | 2002-11-01 | Bridgestone Corp | Copolimero de estireno-butadieno y composicion de caucho que contiene este copolimero. |
| US6274680B1 (en) | 1998-12-31 | 2001-08-14 | Bridgestone/Firestone Research, Inc. | Sulfenyl halide polymerization terminators |
| ES2400176T3 (es) | 2001-12-03 | 2013-04-08 | Bridgestone Corporation | Proceso para producir polímero modificado, polímero modificado obtenido mediante el proceso y composición de caucho |
| RU2377258C2 (ru) * | 2008-01-09 | 2009-12-27 | Открытое акционерное общество "Воронежский синтетический каучук" | Способ получения полимеров бутадиена и сополимеров бутадиена со стиролом |
| BRPI0907687A2 (pt) | 2008-04-30 | 2019-09-10 | Styron Europe Gmbh | processo para polimerizar um polímero compreendendo unidades monoméricas derivadas de estireno e 1,3- butadieno, polímero, composição e artigo |
| JP5653344B2 (ja) * | 2009-04-16 | 2015-01-14 | 株式会社ブリヂストン | チオール含有液状ゴム組成物 |
| JP5596174B2 (ja) * | 2009-12-22 | 2014-09-24 | 株式会社ブリヂストン | 改良されたビニル変性剤組成物および当該組成物の利用方法 |
| TW201211083A (en) * | 2010-06-15 | 2012-03-16 | Styron Europe Gmbh | Low vinyl styrene-butadiene polymers and methods of making the same |
| PL2537872T3 (pl) * | 2011-06-22 | 2015-11-30 | Trinseo Europe Gmbh | Kauczuk styrenowo-butadienowy wysokostyrenowy wysokowinylowy o wąskim rozkładzie masy cząsteczkowej oraz metody jego przygotowania |
-
2011
- 2011-03-04 EP EP11156987A patent/EP2495266A1/en not_active Withdrawn
-
2012
- 2012-03-01 US US14/001,605 patent/US8981000B2/en not_active Expired - Fee Related
- 2012-03-01 JP JP2013555874A patent/JP6077470B2/ja not_active Expired - Fee Related
- 2012-03-01 WO PCT/EP2012/053524 patent/WO2012119918A1/en not_active Ceased
- 2012-03-01 RU RU2013144577A patent/RU2606129C2/ru not_active IP Right Cessation
- 2012-03-01 CN CN201280011611.5A patent/CN103443152B/zh not_active Expired - Fee Related
- 2012-03-01 SG SG2013063805A patent/SG192912A1/en unknown
- 2012-03-01 KR KR1020137023147A patent/KR20140003584A/ko not_active Ceased
- 2012-03-01 MX MX2013010134A patent/MX341179B/es active IP Right Grant
- 2012-03-01 BR BR112013022511A patent/BR112013022511A2/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| MX2013010134A (es) | 2014-03-26 |
| CN103443152B (zh) | 2016-01-13 |
| RU2606129C2 (ru) | 2017-01-10 |
| EP2495266A1 (en) | 2012-09-05 |
| SG192912A1 (en) | 2013-09-30 |
| CN103443152A (zh) | 2013-12-11 |
| WO2012119918A1 (en) | 2012-09-13 |
| BR112013022511A2 (pt) | 2016-12-06 |
| RU2013144577A (ru) | 2015-04-10 |
| US20140024767A1 (en) | 2014-01-23 |
| JP6077470B2 (ja) | 2017-02-08 |
| US8981000B2 (en) | 2015-03-17 |
| KR20140003584A (ko) | 2014-01-09 |
| JP2014506951A (ja) | 2014-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |