MX342671B - Fibras de carbono recubiertas con agente de encolado, proceso para producir fibras de carbono recubiertas con agente de encolado, preimpregnado y material compuesto reforzado con fibra de carbono. - Google Patents

Fibras de carbono recubiertas con agente de encolado, proceso para producir fibras de carbono recubiertas con agente de encolado, preimpregnado y material compuesto reforzado con fibra de carbono.

Info

Publication number
MX342671B
MX342671B MX2014007830A MX2014007830A MX342671B MX 342671 B MX342671 B MX 342671B MX 2014007830 A MX2014007830 A MX 2014007830A MX 2014007830 A MX2014007830 A MX 2014007830A MX 342671 B MX342671 B MX 342671B
Authority
MX
Mexico
Prior art keywords
carbon fiber
sizing agent
fiber coated
prepreg
coated
Prior art date
Application number
MX2014007830A
Other languages
English (en)
Other versions
MX2014007830A (es
Inventor
Endo Makoto
Ichikawa Tomoko
Taiko Hiroshi
Kobayashi Masanobu
Arai Nobuyuki
Misumi Jun
Original Assignee
Toray Industries
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries filed Critical Toray Industries
Publication of MX2014007830A publication Critical patent/MX2014007830A/es
Publication of MX342671B publication Critical patent/MX342671B/es

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55Epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/248Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using pre-treated fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/14Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11Compounds containing epoxy groups or precursors thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40Fibres of carbon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249942Fibers are aligned substantially parallel
    • Y10T428/249944Fiber is precoated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2918Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Inorganic Fibers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Se proporcionan fibras de carbono recubiertas con agente de encolado que logran excelente adherencia entre las fibras de carbono y una resina de matriz y producen un preimpregnado que tiene excelente estabilidad de propiedades físicas del material compuesto después de almacenamiento a largo plazo y que tienen excelente capacidad de procesamiento de alto orden, un proceso para producir las fibras de carbono recubiertas con agente de encolado, un preimpregnado y un material compuesto reforzado con fibras de carbono. La presente invención proporciona fibras de carbono recubiertas con un agente de encolado que incluye un compuesto epóxico alifático (A) y un compuesto aromático (B) que contiene al menos un compuesto epóxico aromático (B1). Las fibras de carbono tienen una relación (a)/(b) de 0.50 a 0.90 en donde (a) es la altura (cps) de un componente a una energía de unión (284.6 eV) asignada a CHx, C-C y C=C y (b) es la altura (cps) de un componente a una energía de unión (286.1 eV) asignada a C-O en un espectro central de C1s de la superficie del agente de encolado analizado por espectroscopia fotoelectrónica de rayos X usando AIKa1,2 como la fuente de rayos X a un ángulo de despegue de fotoelectrones de 15°.
MX2014007830A 2011-12-27 2012-12-18 Fibras de carbono recubiertas con agente de encolado, proceso para producir fibras de carbono recubiertas con agente de encolado, preimpregnado y material compuesto reforzado con fibra de carbono. MX342671B (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2011285052 2011-12-27
JP2012166594 2012-07-27
JP2012203377 2012-09-14
PCT/JP2012/082823 WO2013099707A1 (ja) 2011-12-27 2012-12-18 サイジング剤塗布炭素繊維、サイジング剤塗布炭素繊維の製造方法、プリプレグおよび炭素繊維強化複合材料

Publications (2)

Publication Number Publication Date
MX2014007830A MX2014007830A (es) 2014-08-21
MX342671B true MX342671B (es) 2016-10-07

Family

ID=48697199

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014007830A MX342671B (es) 2011-12-27 2012-12-18 Fibras de carbono recubiertas con agente de encolado, proceso para producir fibras de carbono recubiertas con agente de encolado, preimpregnado y material compuesto reforzado con fibra de carbono.

Country Status (11)

Country Link
US (1) US10138593B2 (es)
EP (1) EP2799616B1 (es)
JP (1) JP6011345B2 (es)
KR (1) KR101863990B1 (es)
CN (1) CN104011288B (es)
BR (1) BR112014015754A8 (es)
CA (1) CA2861235A1 (es)
MX (1) MX342671B (es)
RU (1) RU2014131002A (es)
TW (1) TWI570298B (es)
WO (1) WO2013099707A1 (es)

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CN104011288B (zh) 2016-11-02
EP2799616A4 (en) 2015-09-30
KR101863990B1 (ko) 2018-07-04
CN104011288A (zh) 2014-08-27
TW201333296A (zh) 2013-08-16
CA2861235A1 (en) 2013-07-04
JPWO2013099707A1 (ja) 2015-05-07
TWI570298B (zh) 2017-02-11
EP2799616A1 (en) 2014-11-05
US10138593B2 (en) 2018-11-27
EP2799616B1 (en) 2018-07-11
JP6011345B2 (ja) 2016-10-19
BR112014015754A2 (pt) 2017-06-13
KR20140109391A (ko) 2014-09-15
RU2014131002A (ru) 2016-02-20
BR112014015754A8 (pt) 2017-07-04
MX2014007830A (es) 2014-08-21
WO2013099707A1 (ja) 2013-07-04

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