MX2016007292A - Hidroxilamina de nitroxido y combinaciones de fenilendiamina como inhibidores de polimerizacion para procesos de monomero etilenicamente insaturado. - Google Patents
Hidroxilamina de nitroxido y combinaciones de fenilendiamina como inhibidores de polimerizacion para procesos de monomero etilenicamente insaturado.Info
- Publication number
- MX2016007292A MX2016007292A MX2016007292A MX2016007292A MX2016007292A MX 2016007292 A MX2016007292 A MX 2016007292A MX 2016007292 A MX2016007292 A MX 2016007292A MX 2016007292 A MX2016007292 A MX 2016007292A MX 2016007292 A MX2016007292 A MX 2016007292A
- Authority
- MX
- Mexico
- Prior art keywords
- phenylenediamine
- ethylenically unsaturated
- combinations
- unsaturated monomer
- monomers
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/22—Separation; Purification; Stabilisation; Use of additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/32—Separation; Purification; Stabilisation; Use of additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/86—Use of additives, e.g. for stabilisation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Se proporcionan composiciones de inhibidor de polimerización. Las composiciones de inhibidor de polimerización pueden incluir al menos una hidroxilamina de un nitróxido y al menos una fenilendiamina. También se proporcionan métodos para inhibir la polimerización no deseada de monómeros. Los métodos incluyen la adición de las composiciones de inhibidor de polimerización descritas en la presente a un fluido que contiene los monómeros. Los monómeros pueden ser monómeros etilénicamente insaturados, tales como ácido acrílico, ácido metacrílico, acrilonitrilo, metacrilonitrilo, acroleína, metacroleína, acrilato, metacrilato, acrilamida, metacrilamida, acetato de vinilo, butadieno, etileno, propileno y estireno.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/095,606 US9399622B2 (en) | 2013-12-03 | 2013-12-03 | Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes |
PCT/US2014/068154 WO2015084843A1 (en) | 2013-12-03 | 2014-12-02 | Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016007292A true MX2016007292A (es) | 2016-09-07 |
Family
ID=53264422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016007292A MX2016007292A (es) | 2013-12-03 | 2014-12-02 | Hidroxilamina de nitroxido y combinaciones de fenilendiamina como inhibidores de polimerizacion para procesos de monomero etilenicamente insaturado. |
Country Status (13)
Country | Link |
---|---|
US (4) | US9399622B2 (es) |
EP (1) | EP3077420B1 (es) |
JP (1) | JP6594877B2 (es) |
KR (2) | KR102245153B1 (es) |
CN (2) | CN105793292B (es) |
BR (1) | BR112016012507B1 (es) |
CA (1) | CA2932254C (es) |
MX (1) | MX2016007292A (es) |
MY (1) | MY176038A (es) |
RU (1) | RU2725895C2 (es) |
SA (1) | SA516371230B1 (es) |
SG (2) | SG11201604520VA (es) |
WO (1) | WO2015084843A1 (es) |
Families Citing this family (12)
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SG11201703031PA (en) | 2014-10-14 | 2017-05-30 | Ecolab Usa Inc | Reducing polymer fouling and agglomeration in acrylate/methacrylate processes |
RU2715559C2 (ru) | 2015-03-18 | 2020-03-02 | ЭКОЛАБ ЮЭсЭй ИНК. | Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров |
US9957209B2 (en) | 2015-03-31 | 2018-05-01 | Ecolab Usa Inc. | Use of quinone methides as antipolymerants for vinylic monomers |
TWI624480B (zh) | 2015-04-20 | 2018-05-21 | 藝康美國公司 | 供不飽和單體用作防污劑之受阻對苯二酚 |
JP2020509126A (ja) | 2017-02-27 | 2020-03-26 | エコラブ ユーエスエイ インク | 圧縮機のための防汚剤配合物 |
CN111100001B (zh) * | 2018-10-25 | 2024-01-23 | 中国石油化工股份有限公司 | 一种乙酸乙烯酯精馏用复配型阻聚剂及其使用方法 |
CN109503306B (zh) * | 2019-01-07 | 2021-06-11 | 安徽卓远化工科技有限公司 | 一种苯乙烯精馏阻聚剂及其生产方法 |
CN111233612B (zh) * | 2020-03-13 | 2021-03-12 | 淄博鲁华同方化工有限公司 | 用于dmf法萃取分离碳五的高效阻聚剂及其应用方法 |
KR20220080909A (ko) | 2020-12-08 | 2022-06-15 | 에스케이이노베이션 주식회사 | 플러깅 억제용 윤활 조성물 및 이를 이용한 플러깅 억제방법 |
TW202348787A (zh) * | 2022-04-01 | 2023-12-16 | 美商藝康美國公司 | 用於乙烯系單體流之高苛刻度加工的防汙劑組成物 |
TW202404930A (zh) * | 2022-04-01 | 2024-02-01 | 美商藝康美國公司 | 在共軛二烯單體之萃取蒸餾期間減少非所要之乳化聚合 |
TW202406889A (zh) * | 2022-04-01 | 2024-02-16 | 美商藝康美國公司 | 蒸氣空間聚合之抑制劑 |
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US8691994B2 (en) * | 2011-02-03 | 2014-04-08 | Nalco Company | Multi-component polymerization inhibitors for ethylenically unsaturated monomers |
CN103030590A (zh) | 2011-10-10 | 2013-04-10 | 南通市振兴精细化工有限公司 | 一种高品位阻聚剂及其制造工艺 |
CN103012250A (zh) * | 2013-01-07 | 2013-04-03 | 南通惠康国际企业有限公司 | 一种受阻胺类阻聚剂2,2,6,6-四甲基-4-羟基哌啶氮氧自由基的制备方法 |
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