MX2015014592A - Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno. - Google Patents
Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno.Info
- Publication number
- MX2015014592A MX2015014592A MX2015014592A MX2015014592A MX2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A
- Authority
- MX
- Mexico
- Prior art keywords
- graft
- moulding materials
- thermoplastic moulding
- acrylonitrile
- butadiene
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La invención se refiere a materiales de moldeo termoplásticos a base de acrilonitrilo-butadieno-estireno, que comprende una matriz de polímero-SAN y un copolímero de injerto, estructurado a partir de una base de hule de injerto-aglomerada y una cubierta de injerto SAN. La base del sustrato de injerto es un hule diénico que tiene una proporción de vinilo aromático de 10.5 a 24.5% en peso. El sustrato de injerto aglomerado tiene una distribución de tamaño de partícula bimodal de una fracción x) de partículas no aglomeradas que tienen valor de d50 en el intervalo de 80 a 120 nm y una fracción y) de partículas aglomeradas que tienen un valor d50 en el intervalo de 350-550 nm y una polidispersidad U de menos de 0.28. La invención se refiere además a un proceso para producir el copolímero de injerto, en el que un copolímero de acrilato que tiene una polidispersidad U de menos de 0.27 y un valor de d50 de 100 a 150 nm se utiliza para la aglomeración. La invención se refiere además al uso de materiales de moldeo termoplásticos para la producción de partes moldeadas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13164275 | 2013-04-18 | ||
PCT/EP2014/057823 WO2014170406A1 (de) | 2013-04-18 | 2014-04-16 | Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2015014592A true MX2015014592A (es) | 2016-04-28 |
Family
ID=48128185
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015014592A MX2015014592A (es) | 2013-04-18 | 2014-04-16 | Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno. |
Country Status (7)
Country | Link |
---|---|
US (1) | US9624333B2 (es) |
EP (1) | EP2986650B1 (es) |
KR (1) | KR102179358B1 (es) |
CN (1) | CN105164166B (es) |
ES (1) | ES2685809T3 (es) |
MX (1) | MX2015014592A (es) |
WO (1) | WO2014170406A1 (es) |
Families Citing this family (42)
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US9708483B2 (en) * | 2013-04-18 | 2017-07-18 | Ineos Styrolution Group Gmbh | Thermoplastic moulding materials based on acrylonitrile, styrene and butadiene |
EP3080201B1 (en) * | 2013-12-11 | 2018-11-28 | INEOS Styrolution Group GmbH | Abs product with improved fire retardancy |
US10138364B2 (en) * | 2014-01-28 | 2018-11-27 | Ineos Styrolution Group Gmbh | Thermoplastic molding compounds with optimized flowability-toughness ratio |
ES2685302T3 (es) | 2014-04-30 | 2018-10-08 | Ineos Styrolution Group Gmbh | Masas moldeadas termoplásticas con contenido optimizado de monómeros residuales |
US10683372B2 (en) * | 2015-03-05 | 2020-06-16 | Ineos Styrolution Group Gmbh | Efficient copolymers having an agglomerating effect |
US10815342B2 (en) | 2016-06-06 | 2020-10-27 | Ineos Styrolution Group Gmbh | Process for producing a stabilizer dispersion and process for producing a thermoplastic composition stabilized with the stabilizer dispersion |
ES2860198T5 (es) * | 2017-04-24 | 2024-04-26 | Ineos Styrolution Group Gmbh | Procedimiento mejorado para la preparación de copolímeros de injerto de ABS |
EP3710492B1 (en) | 2017-11-13 | 2021-08-11 | INEOS Styrolution Group GmbH | Thermoplastic molding composition and articles made thereof having improved surface quality |
KR102324050B1 (ko) * | 2017-12-06 | 2021-11-09 | 주식회사 엘지화학 | 그래프트 공중합체의 제조 방법, 이로부터 제조된 내충격성이 우수한 그래프트 공중합체 및 이를 포함하는 열가소성 수지 조성물 |
KR102626347B1 (ko) | 2017-12-19 | 2024-01-16 | 이네오스 스티롤루션 그룹 게엠베하 | 취입 성형을 위한 abs 열가소성 성형 조성물 |
EP3728462B1 (en) | 2017-12-19 | 2023-05-24 | INEOS Styrolution Group GmbH | High fatigue resistance abs |
KR102278035B1 (ko) | 2018-02-07 | 2021-07-15 | 주식회사 엘지화학 | 그라프트 공중합체의 제조방법 및 열가소성 수지 성형품 |
US11603464B2 (en) | 2018-02-16 | 2023-03-14 | Ineos Styrolution Group Gmbh | High heat resistant ABS molding composition |
KR102282816B1 (ko) * | 2018-02-26 | 2021-07-29 | 주식회사 엘지화학 | Abs계 그라프트 공중합체의 제조방법 및 열가소성 수지 조성물의 제조방법 |
WO2019201784A1 (en) | 2018-04-16 | 2019-10-24 | Ineos Styrolution Group Gmbh | Ultra-high flow acrylonitrile butadiene styrene copolymer compositions |
US20210139698A1 (en) | 2018-06-20 | 2021-05-13 | Ineos Styrolution Group Gmbh | High heat resistant impact modified polycarbonate blend |
WO2020064594A1 (en) | 2018-09-25 | 2020-04-02 | Ineos Styrolution Group Gmbh | Heat resistant abs composition with reduced odor for automotive interior application |
KR102468058B1 (ko) * | 2018-09-28 | 2022-11-17 | 주식회사 엘지화학 | 인-시츄 바이모달 비닐시안 화합물-공액 디엔 고무-방향족 비닐 화합물 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
KR102543169B1 (ko) * | 2018-11-29 | 2023-06-14 | 주식회사 엘지화학 | 디엔계 그라프트 공중합체의 제조방법 |
KR102511537B1 (ko) * | 2018-12-17 | 2023-03-17 | 주식회사 엘지화학 | 비닐시안 화합물-공액디엔 화합물-방향족 비닐 화합물 그라프트 공중합체의 제조방법 |
KR102465134B1 (ko) * | 2018-12-19 | 2022-11-10 | 주식회사 엘지화학 | 그라프트 공중합체의 제조방법 |
WO2020168180A1 (en) * | 2019-02-14 | 2020-08-20 | Sabic Global Technologies B.V. | Method of forming articles from acrylonitrile-butadiene-styrene |
WO2021032827A1 (en) | 2019-08-21 | 2021-02-25 | Ineos Styrolution Group Gmbh | Abs molding composition for sheet extrusion and thermoforming with high escr, high color and thermal stability and low tendency to delamination |
EP4225819A1 (en) | 2020-10-08 | 2023-08-16 | INEOS Styrolution Group GmbH | Preparation of diene polymer latex of high gel content and controlled cross linking |
CN115028782B (zh) * | 2021-03-08 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种乳液聚合法制备含氟高耐候性热塑性树脂的方法及制得的热塑性树脂 |
CN115043991B (zh) * | 2021-03-08 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种乳液聚合法制备含氟热塑性弹性体的方法及制得的热塑性弹性体 |
CN115043996B (zh) * | 2021-03-08 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种乳液聚合法制备高耐候性热塑性树脂的方法及制得的含硅热塑性树脂 |
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CN115043993B (zh) * | 2021-03-08 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种乳液聚合法制备含羧基热塑性树脂的方法及制得的含羧基热塑性树脂 |
CN115043994B (zh) * | 2021-03-08 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种提高耐热性的热塑性树脂的乳液聚合制备方法及得到的热塑性树脂 |
CN117321135A (zh) | 2021-03-16 | 2023-12-29 | 英力士苯领集团股份公司 | Abs模塑组合物可改善电镀应用的表面质量 |
WO2022229335A1 (en) | 2021-04-30 | 2022-11-03 | Ineos Styrolution Group Gmbh | Improved process for producing thermoplastic abs molding compositions |
WO2022229347A1 (en) | 2021-04-30 | 2022-11-03 | Ineos Styrolution Group Gmbh | Improved processes for producing thermoplastic abs molding compositions |
WO2023083936A1 (en) | 2021-11-12 | 2023-05-19 | Ineos Styrolution Group Gmbh | Thermoplastic abs molding compositions with improved surface |
WO2023222674A1 (en) | 2022-05-18 | 2023-11-23 | Ineos Styrolution Group Gmbh | Method to improve surface gloss stability of acrylonitrile-butadiene-styrene copolymer compositions |
KR20230172109A (ko) * | 2022-06-15 | 2023-12-22 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이로부터 제조된 성형품 |
WO2024013294A1 (de) | 2022-07-15 | 2024-01-18 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung von asa- oder abs-pfropfcopolymeren mit verminderter verfärbung |
WO2024013297A1 (de) | 2022-07-15 | 2024-01-18 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung von asa- oder abs-pfropfcopolymeren mit verminderter verfärbung |
WO2024046959A1 (en) | 2022-08-30 | 2024-03-07 | Ineos Styrolution Group Gmbh | Process for the preparation of abs graft copolymers |
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Publication number | Priority date | Publication date | Assignee | Title |
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FR1580834A (es) | 1968-01-04 | 1969-09-12 | ||
CH578138A5 (es) | 1973-02-28 | 1976-07-30 | Jylland Gummivarefabriken As | |
DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
DE2427960B1 (de) | 1974-06-10 | 1975-06-19 | Basf Ag | Verfahren zur Herstellung von schlagfesten thermoplastischen Formmassen |
DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
DE2927572A1 (de) | 1979-07-07 | 1981-01-22 | Basf Ag | Themoplastische formmassen |
DE3114875A1 (de) | 1981-04-13 | 1982-11-04 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von schlagfesten thermoplastischen formmassen |
CA1193036A (en) | 1981-10-09 | 1985-09-03 | Kazuo Kishida | Process for producing impact resistant graft resins including an agglomerated rubber |
DE4223202A1 (de) * | 1992-07-15 | 1994-01-20 | Basf Ag | Teilchenförmiges Pfropfcopolymerisat |
DE19752394A1 (de) * | 1997-11-19 | 1999-05-20 | Basf Ag | Verfahren zur Herstellung von Pfropfpolymerisaten |
DE19907136A1 (de) | 1999-02-19 | 2000-08-24 | Basf Ag | Verfahren zum Trocknen koagulierter wasserhaltiger Kautschukpartikel |
DE10037280A1 (de) | 2000-07-28 | 2002-02-07 | Basf Ag | Verfahren zur Agglomeration dispergierter Kautschuke |
DE102005022635B4 (de) * | 2005-05-11 | 2018-05-30 | Ineos Styrolution Europe Gmbh | Thermoplastische Formmassen mit verbesserter Anfärbbarkeit |
DE102005022632B4 (de) | 2005-05-11 | 2022-05-25 | Ineos Styrolution Europe Gmbh | Teilchenförmiger Kautschuk, Verfahren zu dessen Herstellung und Verwendung, sowie Pfropfcopolymerisat, thermoplastische Formmasse und Verfahren zu deren Herstellung |
WO2008020012A2 (de) | 2006-08-18 | 2008-02-21 | Basf Se | Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien |
-
2014
- 2014-04-16 CN CN201480022041.9A patent/CN105164166B/zh active Active
- 2014-04-16 EP EP14718577.1A patent/EP2986650B1/de active Active
- 2014-04-16 ES ES14718577.1T patent/ES2685809T3/es active Active
- 2014-04-16 US US14/784,660 patent/US9624333B2/en active Active
- 2014-04-16 WO PCT/EP2014/057823 patent/WO2014170406A1/de active Application Filing
- 2014-04-16 MX MX2015014592A patent/MX2015014592A/es unknown
- 2014-04-16 KR KR1020157033015A patent/KR102179358B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
US20160075813A1 (en) | 2016-03-17 |
WO2014170406A1 (de) | 2014-10-23 |
CN105164166A (zh) | 2015-12-16 |
KR20150144795A (ko) | 2015-12-28 |
US9624333B2 (en) | 2017-04-18 |
ES2685809T3 (es) | 2018-10-11 |
EP2986650B1 (de) | 2018-08-08 |
CN105164166B (zh) | 2017-12-22 |
KR102179358B1 (ko) | 2020-11-18 |
EP2986650A1 (de) | 2016-02-24 |
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