MX2015014597A - Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno. - Google Patents

Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno.

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Publication number
MX2015014597A
MX2015014597A MX2015014597A MX2015014597A MX2015014597A MX 2015014597 A MX2015014597 A MX 2015014597A MX 2015014597 A MX2015014597 A MX 2015014597A MX 2015014597 A MX2015014597 A MX 2015014597A MX 2015014597 A MX2015014597 A MX 2015014597A
Authority
MX
Mexico
Prior art keywords
butadiene
moulding materials
thermoplastic moulding
acrylonitrile
styrene
Prior art date
Application number
MX2015014597A
Other languages
English (en)
Inventor
Norbert Niessner
Sangjun Ahn
Brian J Banaszak
Roland Walker
Michel Pepers
Johannes Barth
Gisbert Michels
Florian Patcas
Younghwa Hwang
Rudy Verstraeten
Original Assignee
Styrolution Group Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styrolution Group Gmbh filed Critical Styrolution Group Gmbh
Publication of MX2015014597A publication Critical patent/MX2015014597A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26Emulsion polymerisation with the aid of emulsifying agents anionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04Vinyl aromatic monomers and nitriles as the only monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

La invención se refiere a materiales de moldeo termoplásticos a base de acrilonitrilo-butadieno-estireno, que comprende una matriz de polímero-SAN y un copolímero de injerto, estructurado a partir de una base de hule de injerto-aglomerada y una cubierta de injerto SAN. La base del sustrato de injerto tiene una distribución de tamaño de partícula bimodal de una fracción x) de partículas no aglomeradas que tienen valor de d50 en el intervalo de 80 a 120 nm y una fracción y) de partículas aglomeradas que tienen un valor d50 en el intervalo de 350-550 nm y una polidispersidad U de menos de 0.28. La invención se refiere además a un proceso para producir el copolímero de injerto, en el que un copolímero de acrilato que tiene una polidispersidad U de menos de 0.27 y un valor de d50 de 100 a 150 nm se utiliza para la aglomeración. La invención se refiere además al uso de materiales de moldeo termoplásticos para la producción de partes moldeadas.
MX2015014597A 2013-04-18 2014-04-16 Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno. MX2015014597A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13164273 2013-04-18
PCT/EP2014/057824 WO2014170407A1 (de) 2013-04-18 2014-04-16 Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien

Publications (1)

Publication Number Publication Date
MX2015014597A true MX2015014597A (es) 2016-04-25

Family

ID=48128184

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014597A MX2015014597A (es) 2013-04-18 2014-04-16 Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno.

Country Status (7)

Country Link
US (1) US9708483B2 (es)
EP (1) EP2986649B1 (es)
KR (1) KR102179363B1 (es)
CN (1) CN105164167B (es)
ES (1) ES2685578T3 (es)
MX (1) MX2015014597A (es)
WO (1) WO2014170407A1 (es)

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KR101530150B1 (ko) * 2013-08-02 2015-06-19 주식회사 엘지화학 고무강화 열가소성 수지의 제조방법
ES2685302T3 (es) 2014-04-30 2018-10-08 Ineos Styrolution Group Gmbh Masas moldeadas termoplásticas con contenido optimizado de monómeros residuales
US10683372B2 (en) 2015-03-05 2020-06-16 Ineos Styrolution Group Gmbh Efficient copolymers having an agglomerating effect
WO2017093468A1 (de) 2015-12-02 2017-06-08 Ineos Styrolution Group Gmbh Verfahren zur herstellung von abs-kunststoffen mit verbesserten eigenschaften
US10815342B2 (en) 2016-06-06 2020-10-27 Ineos Styrolution Group Gmbh Process for producing a stabilizer dispersion and process for producing a thermoplastic composition stabilized with the stabilizer dispersion
ES2860198T5 (es) 2017-04-24 2024-04-26 Ineos Styrolution Group Gmbh Procedimiento mejorado para la preparación de copolímeros de injerto de ABS
CN109517286A (zh) * 2017-09-18 2019-03-26 中国石油天然气股份有限公司 Abs树脂及其制备方法
EP3710492B1 (en) 2017-11-13 2021-08-11 INEOS Styrolution Group GmbH Thermoplastic molding composition and articles made thereof having improved surface quality
KR102324050B1 (ko) * 2017-12-06 2021-11-09 주식회사 엘지화학 그래프트 공중합체의 제조 방법, 이로부터 제조된 내충격성이 우수한 그래프트 공중합체 및 이를 포함하는 열가소성 수지 조성물
EP3728462B1 (en) 2017-12-19 2023-05-24 INEOS Styrolution Group GmbH High fatigue resistance abs
KR102278035B1 (ko) 2018-02-07 2021-07-15 주식회사 엘지화학 그라프트 공중합체의 제조방법 및 열가소성 수지 성형품
US11603464B2 (en) 2018-02-16 2023-03-14 Ineos Styrolution Group Gmbh High heat resistant ABS molding composition
WO2019201784A1 (en) 2018-04-16 2019-10-24 Ineos Styrolution Group Gmbh Ultra-high flow acrylonitrile butadiene styrene copolymer compositions
US20210139698A1 (en) 2018-06-20 2021-05-13 Ineos Styrolution Group Gmbh High heat resistant impact modified polycarbonate blend
KR20210036939A (ko) 2018-07-24 2021-04-05 이네오스 스티롤루션 그룹 게엠베하 탈수가 개선된 그라프트 고무 조성물을 제조하는 공정
WO2020064594A1 (en) 2018-09-25 2020-04-02 Ineos Styrolution Group Gmbh Heat resistant abs composition with reduced odor for automotive interior application
KR102489409B1 (ko) * 2019-08-16 2023-01-17 주식회사 엘지화학 비닐시안 화합물-공액디엔 화합물-방향족 비닐 화합물 그라프트 공중합체의 제조방법 및 이 그라프트 공중합체를 포함하는 열가소성 수지 조성물
WO2021032827A1 (en) 2019-08-21 2021-02-25 Ineos Styrolution Group Gmbh Abs molding composition for sheet extrusion and thermoforming with high escr, high color and thermal stability and low tendency to delamination
CN117321135A (zh) 2021-03-16 2023-12-29 英力士苯领集团股份公司 Abs模塑组合物可改善电镀应用的表面质量
WO2024028311A1 (de) 2022-08-04 2024-02-08 Ineos Styrolution Group Gmbh Thermoplastische abs-formmasse mit guter eigenschaftskombination von verarbeitbarkeit und oberflächenqualität
WO2024046959A1 (en) * 2022-08-30 2024-03-07 Ineos Styrolution Group Gmbh Process for the preparation of abs graft copolymers

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Also Published As

Publication number Publication date
ES2685578T3 (es) 2018-10-10
EP2986649A1 (de) 2016-02-24
KR20160002972A (ko) 2016-01-08
US9708483B2 (en) 2017-07-18
EP2986649B1 (de) 2018-08-01
WO2014170407A1 (de) 2014-10-23
KR102179363B1 (ko) 2020-11-18
CN105164167B (zh) 2017-03-22
US20160083572A1 (en) 2016-03-24
CN105164167A (zh) 2015-12-16

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