MX2016012774A - Proceso para producir caucho de acrilato con formacion reducida de coagulos. - Google Patents
Proceso para producir caucho de acrilato con formacion reducida de coagulos.Info
- Publication number
- MX2016012774A MX2016012774A MX2016012774A MX2016012774A MX2016012774A MX 2016012774 A MX2016012774 A MX 2016012774A MX 2016012774 A MX2016012774 A MX 2016012774A MX 2016012774 A MX2016012774 A MX 2016012774A MX 2016012774 A MX2016012774 A MX 2016012774A
- Authority
- MX
- Mexico
- Prior art keywords
- weight
- graft
- preparation
- reduced
- acrylate rubber
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C08F212/10—Styrene with nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Un proceso para producir una composición termoplástica de moldeo que comprende: de 10% a 40% en peso de un copolímero de injerto A que comprende de 50% a 70% en peso, con base en A, de una base de injerto A1 formada de un polímero elastomérico de éster acrílico reticulado y de 30% a 50% en peso de una cubierta de injerto A2, 50% a 90% en peso de una matriz dura B formada de copolímeros de estireno o a-metilestireno y acrilonitrilo, de 0% a 50% en peso de un copolímero de injerto C adicional, de 0% a 15% en peso de aditivos D, en donde la reacción para la preparación del polímero de éster acrílico A y/o la reacción para la preparación de C se lleva a cabo en presencia de 0.01 a 4 veces la cantidad molar de carbonato de sodio, con base en la suma total de la cantidad molar del iniciador utilizada en la preparación de la base de injerto y la cubierta de injerto, que lleva a una menor formación de coágulos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14162554 | 2014-03-31 | ||
PCT/EP2015/056570 WO2015150223A1 (de) | 2014-03-31 | 2015-03-26 | Verfahren zur herstellung von acrylat-kautschuk mit reduzierter koagulatbildung |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016012774A true MX2016012774A (es) | 2016-12-14 |
Family
ID=50433972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016012774A MX2016012774A (es) | 2014-03-31 | 2015-03-26 | Proceso para producir caucho de acrilato con formacion reducida de coagulos. |
Country Status (6)
Country | Link |
---|---|
US (1) | US10280296B2 (es) |
EP (1) | EP3126400B1 (es) |
KR (1) | KR102329711B1 (es) |
ES (1) | ES2665644T3 (es) |
MX (1) | MX2016012774A (es) |
WO (1) | WO2015150223A1 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10870747B2 (en) | 2015-09-30 | 2020-12-22 | Ineos Styrolution Group Gmbh | Method for producing acrylate rubber at reduced emulsifier concentration |
KR102397210B1 (ko) | 2016-09-06 | 2022-05-11 | 이네오스 스티롤루션 그룹 게엠베하 | 아크릴레이트를 중합하는 방법 및 시스템 |
ES2817825T3 (es) | 2016-09-27 | 2021-04-08 | Ineos Styrolution Group Gmbh | Procedimiento mejorado para la preparación de plásticos de ASA |
CN111247205A (zh) | 2017-07-26 | 2020-06-05 | 英力士苯领集团股份公司 | 含有耐磨性能改善的聚硅氧烷添加剂的抗冲改性的苯乙烯共聚物组合物 |
ES2930761T3 (es) | 2017-07-26 | 2022-12-21 | Ineos Styrolution Group Gmbh | Composición de copolímero de estireno modificado al impacto que comprende un aditivo de polisiloxano que tiene características de abrasión mejoradas |
WO2019092237A1 (en) | 2017-11-13 | 2019-05-16 | Ineos Styrolution Group Gmbh | Thermoplastic molding composition and articles made thereof having improved surface quality |
ES2886928T3 (es) | 2017-12-11 | 2021-12-21 | Ineos Styrolution Group Gmbh | Procedimiento para la producción de una composición de moldeo termoplástica modificada al impacto con procesamiento y resistencia al impacto mejorados |
CN112566977A (zh) | 2018-06-18 | 2021-03-26 | 英力士苯领集团股份公司 | 具有改善的抗紫外线性的热塑性组合物 |
WO2022175283A1 (de) | 2021-02-16 | 2022-08-25 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung einer thermoplastischen formmasse enthaltend ein thermoplastisches copolymer a und ein pfropfcopolymer b |
CN113307903B (zh) * | 2021-07-07 | 2022-10-18 | 邢台学院 | 一种聚(苯乙烯-丙烯腈)共聚微球及其制备方法 |
CN117999314A (zh) | 2021-09-14 | 2024-05-07 | 英力士苯领集团股份公司 | 透光率增加的asa-共聚物组合物及其制备方法 |
WO2023209007A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate (asa) copolymer composition having good uv resistance with reduced uv absorber content |
WO2023209004A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate copolymer composition with improved uv resistance |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1911882B2 (de) | 1969-03-08 | 1975-04-17 | Basf Ag, 6700 Ludwigshafen | Schlagfeste thermoplastische Massen |
DE3149358A1 (de) | 1981-12-12 | 1983-06-16 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
DE3331010A1 (de) | 1983-08-27 | 1985-03-14 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
DE4011162A1 (de) | 1990-04-06 | 1991-10-10 | Basf Ag | Thermoplastische formmasse |
DE4235976A1 (de) * | 1992-10-24 | 1994-04-28 | Basf Ag | Thermoplastische Formmasse |
DE4446896A1 (de) * | 1994-12-27 | 1996-07-04 | Basf Ag | Schlagzähne, thermoplastisch verarbeitbare Mischung aus Elastomeren und Thermoplasten |
DE19503545A1 (de) | 1995-02-03 | 1996-08-08 | Basf Ag | Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit |
US6054531A (en) | 1998-11-23 | 2000-04-25 | General Electric Company | Emulsion polymerized polyacrylate rubber, impact modifiers and blends obtained therefrom, and method for making |
DE10206557A1 (de) | 2002-02-18 | 2003-08-28 | Polymerlatex Gmbh & Co Kg | Verfahren zur Herstellung von Schutzkolloidstabilisierten wässrigen Dispersionen |
KR100815995B1 (ko) | 2006-06-08 | 2008-03-21 | 제일모직주식회사 | 저온 및 상온 내충격성과 착색성 및 내후성이 우수한asa 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물 |
US8440764B2 (en) | 2010-05-07 | 2013-05-14 | Styrolution GmbH | Molding composition with reduced light scattering |
WO2014187803A1 (en) * | 2013-05-23 | 2014-11-27 | Styrolution Group Gmbh | Thermoplastic moulding composition with water-repellent properties |
WO2015078751A1 (de) * | 2013-11-26 | 2015-06-04 | Styrolution Group Gmbh | Thermoplastische formmassen mit angepasster pfropfhülle |
US9982123B2 (en) * | 2014-04-02 | 2018-05-29 | Ineos Styrolution Group Gmbh | Process for producing thermoplastic moulding compositions with improved mechanical properties |
-
2015
- 2015-03-26 US US15/300,037 patent/US10280296B2/en active Active
- 2015-03-26 WO PCT/EP2015/056570 patent/WO2015150223A1/de active Application Filing
- 2015-03-26 EP EP15713856.1A patent/EP3126400B1/de active Active
- 2015-03-26 MX MX2016012774A patent/MX2016012774A/es active IP Right Grant
- 2015-03-26 KR KR1020167030174A patent/KR102329711B1/ko active IP Right Grant
- 2015-03-26 ES ES15713856.1T patent/ES2665644T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
WO2015150223A1 (de) | 2015-10-08 |
ES2665644T3 (es) | 2018-04-26 |
EP3126400A1 (de) | 2017-02-08 |
KR20160139021A (ko) | 2016-12-06 |
EP3126400B1 (de) | 2018-03-21 |
US10280296B2 (en) | 2019-05-07 |
KR102329711B1 (ko) | 2021-11-19 |
US20170145201A1 (en) | 2017-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2016012774A (es) | Proceso para producir caucho de acrilato con formacion reducida de coagulos. | |
BR112015028368A2 (pt) | elastômeros termoplásticos por meio de polimerização de triglicerídeos por transferência de cadeia de fragmentação-adição reversível | |
MY176208A (en) | Block copolymer and adhesive composition | |
MY181194A (en) | Thermoplastic resin composition and molded product thereof | |
CU20180032A7 (es) | Polímeros de cloruro de vinilo y composiciones para la fabricación de aditivos | |
WO2013129709A3 (ja) | ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物及び成形体 | |
MY178743A (en) | Thermoplastic resin composition | |
MX2016012526A (es) | Composicion de resina termoplastica y articulo moldado de la misma. | |
MY178756A (en) | Block copolymer composition and adhesive composition | |
MX2016005089A (es) | Fluorocopolimero curable formado a partir de tetrafluoropropeno. | |
BR112016021574A2 (pt) | Monômeros etilenicamente insaturados, copolímeros, composição aquosa e método para espessar emulsão aquosa | |
MX2016003369A (es) | Caucho de copolimero de nitrilo y metodo de produccion del mismo. | |
MX2017004771A (es) | Emulsiones y productos de polímero de etilvinilacetato/acrílico y métodos relacionados con estos. | |
MX2019003876A (es) | Composicion de resina termoplastica y su articulo moldeado. | |
SA518400220B1 (ar) | تركيبة بوليمر تشتمل على بولي (ميثيل ميثاكريلات) وتركيبة معدلة التأثير | |
MX2015011761A (es) | Polioles polimericos modificados con polibutadieno, espumas preparadas a partir de polioles polimericos modificados con polibutadieno, y procesos para su produccion. | |
MX2017013897A (es) | Composiciones polimericas que comprenden poliuretano termoplastico y poliolefina. | |
MX2018005321A (es) | Metodos alternativos para controlar el entrecruzamiento en poliestireno de alto impacto. | |
MX2017010238A (es) | Composicion de copolimero de bloques, material moldeado, composicion de resina y producto moldeado. | |
MY182050A (en) | Thermoplastic resin composition and resin molded article | |
TW201613997A (en) | Thermoplastic resin composition, manufacturing method thereof and molded body | |
MY187040A (en) | Thermoplastic resin composition, method for producing same, and molded article of same | |
BR112017012913A2 (pt) | um modificador de impacto e uma composição de polímero com o mesmo | |
MX2016004356A (es) | Cemento con polimero de latex elastico. | |
MX2016002382A (es) | Composiciones de copolimero de estireno que tienen un brillo mejorado. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration |