MD842G2 - Procedeu de obţinere a 4-aminodifenilaminei - Google Patents
Procedeu de obţinere a 4-aminodifenilamineiInfo
- Publication number
- MD842G2 MD842G2 MD94-0303A MD940303A MD842G2 MD 842 G2 MD842 G2 MD 842G2 MD 940303 A MD940303 A MD 940303A MD 842 G2 MD842 G2 MD 842G2
- Authority
- MD
- Moldova
- Prior art keywords
- adpa
- produce
- substituted derivatives
- aminodiphenylamine
- preparing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/38—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitroso groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Input From Keyboards Or The Like (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
- User Interface Of Digital Computer (AREA)
Abstract
Invenţia se referă la procedeele de obţinere a 4-aminodifenilaminei (4-ADFA), a compuşilor intermediari, precum şi la produsele alchilării p-fenilendiaminei, utilizate în calitate de antioxidanţi.Procedeul constă în interacţiunea anilinei sau derivaţilor ei substituiţi cu nitrobenzenul, în condiţii optime pentru obţinerea 4-nitro- sau a 4-nitrozodifenilaminei şi a derivaţilor lor substituiţi, şi/sau a sărurilor lor. Prin reducerea ulterioară se obţine 4-ADFA sau derivaţii ei substituiţi, care pot fi hidroalchilaţi cu formarea p-fenilendiaminelor, sau a derivaţilor substituiţi, utili pentru aplicare în calitate de antiozonanţi.Rezultatul tehnic al invenţiei constă în majorarea randamentului de obţinere a 4-ADFA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/719,876 US5117063A (en) | 1991-06-21 | 1991-06-21 | Method of preparing 4-aminodiphenylamine |
Publications (2)
Publication Number | Publication Date |
---|---|
MD842F2 MD842F2 (ro) | 1997-09-30 |
MD842G2 true MD842G2 (ro) | 1998-12-31 |
Family
ID=24891732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MD94-0303A MD842G2 (ro) | 1991-06-21 | 1994-07-29 | Procedeu de obţinere a 4-aminodifenilaminei |
Country Status (19)
Country | Link |
---|---|
US (4) | US5117063A (ro) |
EP (1) | EP0590053B2 (ro) |
JP (1) | JP3167029B2 (ro) |
KR (1) | KR0132514B1 (ro) |
AT (1) | ATE158567T1 (ro) |
AU (1) | AU653249B2 (ro) |
BR (1) | BR9206180A (ro) |
CA (1) | CA2065056A1 (ro) |
CZ (1) | CZ281972B6 (ro) |
DE (1) | DE69222417T3 (ro) |
EE (1) | EE03043B1 (ro) |
ES (1) | ES2110001T5 (ro) |
HU (1) | HU214296B (ro) |
MD (1) | MD842G2 (ro) |
PL (3) | PL168393B1 (ro) |
RU (1) | RU2102381C1 (ro) |
SK (1) | SK283999B6 (ro) |
UA (1) | UA26851C2 (ro) |
WO (1) | WO1993000324A1 (ro) |
Families Citing this family (93)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5117063A (en) † | 1991-06-21 | 1992-05-26 | Monsanto Company | Method of preparing 4-aminodiphenylamine |
EP0566783A1 (en) * | 1992-04-21 | 1993-10-27 | Akzo N.V. | Process for the production of nitrodiarylamines |
US5252737A (en) * | 1992-05-22 | 1993-10-12 | Monsanto Company | Process for preparing N-aliphatic substituted p-phenylenediamines |
US5331099A (en) * | 1992-05-22 | 1994-07-19 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
US5552531A (en) * | 1992-05-22 | 1996-09-03 | Monsanto Company | Process for preparing substituted aromatic azo compounds |
US5233010A (en) * | 1992-10-15 | 1993-08-03 | Monsanto Company | Process for preparing isocyanate and carbamate ester products |
EP0595332B1 (en) * | 1992-10-28 | 1998-02-04 | MITSUI TOATSU CHEMICALS, Inc. | Process for the preparation of diphenylamine or nucleus-substituted derivative thereof |
US5451702A (en) * | 1993-04-26 | 1995-09-19 | Monsanto Company | Process for preparing substituted aromatic amines |
US5380946A (en) * | 1993-07-30 | 1995-01-10 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
JPH07149695A (ja) * | 1993-09-30 | 1995-06-13 | Seiko Kagaku Kk | 4−アミノジフェニルアミン類の製造方法 |
US5382691A (en) * | 1993-11-05 | 1995-01-17 | Monsanto Company | Process for preparing substituted aromatic amines |
DE4427249A1 (de) * | 1994-08-02 | 1996-02-08 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamine |
DE4427248A1 (de) * | 1994-08-02 | 1996-02-08 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamide und Arylamine |
DE4432556A1 (de) * | 1994-09-13 | 1996-03-14 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamine |
DE19600722A1 (de) * | 1996-01-11 | 1997-07-17 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls substituierten 4-Aminodiphenylaminen |
US5728882A (en) * | 1996-04-04 | 1998-03-17 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
DE19709124A1 (de) * | 1997-03-06 | 1998-09-10 | Bayer Ag | Verfahren zur Herstellung von 4-Aminodiphenylamin |
US5925790A (en) * | 1997-03-13 | 1999-07-20 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
US5977411A (en) * | 1997-06-10 | 1999-11-02 | Flexsys America L.P. | Catalytic hydrogeneration of nitrobenzene to 4-aminodiphenylamine in the presence of a hydroxyl compound and a solvent |
TW500712B (en) * | 1997-08-06 | 2002-09-01 | Bayer Ag | Process for the preparation of 4-aminodiphenylamine |
DE19810929A1 (de) * | 1998-03-13 | 1999-09-16 | Bayer Ag | Verfahren zur Herstellung von 4-Aminodiphenylamin |
US6140538A (en) * | 1998-05-18 | 2000-10-31 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamines |
US5840982A (en) * | 1998-06-04 | 1998-11-24 | Uniroyal Chemical Company, Inc. | Process for preparing para-phenylenediamine derivatives |
SK283209B6 (sk) * | 1998-12-11 | 2003-03-04 | Duslo, A. S. | Spôsob prípravy 4-aminodifenylamínu |
US6069279A (en) * | 1999-06-14 | 2000-05-30 | Simon; Mark W. | Preparation of substituted aromatic amines |
US6229035B1 (en) | 1999-06-16 | 2001-05-08 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
KR100302862B1 (ko) * | 1999-07-08 | 2001-09-13 | 박찬구 | 페닐유레아로부터 4-니트로디페닐아민 및 4-니트로아닐린을 제조하는 방법 |
KR100298572B1 (ko) * | 1999-08-19 | 2001-09-22 | 박찬구 | 카바아닐라이드로부터 4-니트로디페닐아민과 4-니트로소디페닐아민의 제조방법 |
KR100331490B1 (ko) | 1999-12-03 | 2002-04-09 | 박찬구 | 요소와 니트로벤젠으로 부터 4,4'-디니트로디페닐아민을제조하는 방법 |
US6156932A (en) * | 2000-02-23 | 2000-12-05 | Korea Kumho Petrochemical Co., Ltd. | Preparation of 4,4'-dinitrodiphenylamine from urea and nitrobenzene |
US6495723B1 (en) * | 2000-06-21 | 2002-12-17 | Flexsys America | Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene |
WO2002033026A1 (en) | 2000-10-16 | 2002-04-25 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors |
US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
CA2454603A1 (en) * | 2001-07-23 | 2003-02-06 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamine |
US6395933B1 (en) | 2001-07-23 | 2002-05-28 | Flexsys America, L.P. | Process for preparing 4-aminodiphenylamine intermediates |
WO2003033121A1 (en) * | 2001-10-12 | 2003-04-24 | Flexsys B.V. | Process for improving the purity of quaternary ammonium hydroxides by electrolysis in a two-compartment cell |
KR20030035343A (ko) * | 2001-10-31 | 2003-05-09 | 금호석유화학 주식회사 | 4-니트로소 치환 방향족아민 화합물의 제조방법 |
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- 1991-06-21 US US07/719,876 patent/US5117063A/en not_active Expired - Lifetime
-
1992
- 1992-03-27 AU AU22245/92A patent/AU653249B2/en not_active Expired
- 1992-03-27 HU HU9303686A patent/HU214296B/hu not_active IP Right Cessation
- 1992-03-27 RU RU93058557A patent/RU2102381C1/ru active
- 1992-03-27 WO PCT/US1992/002232 patent/WO1993000324A1/en active IP Right Grant
- 1992-03-27 ES ES92914179T patent/ES2110001T5/es not_active Expired - Lifetime
- 1992-03-27 KR KR1019930703471A patent/KR0132514B1/ko not_active IP Right Cessation
- 1992-03-27 JP JP50144693A patent/JP3167029B2/ja not_active Expired - Lifetime
- 1992-03-27 US US08/157,120 patent/US5453541A/en not_active Expired - Lifetime
- 1992-03-27 BR BR9206180A patent/BR9206180A/pt not_active IP Right Cessation
- 1992-03-27 UA UA93003978A patent/UA26851C2/uk unknown
- 1992-03-27 DE DE69222417T patent/DE69222417T3/de not_active Expired - Lifetime
- 1992-03-27 AT AT92914179T patent/ATE158567T1/de not_active IP Right Cessation
- 1992-03-27 CZ CS932484A patent/CZ281972B6/cs not_active IP Right Cessation
- 1992-03-27 PL PL92301799A patent/PL168393B1/pl unknown
- 1992-03-27 PL PL92307116A patent/PL168938B1/pl unknown
- 1992-03-27 PL PL92307117A patent/PL168917B1/pl unknown
- 1992-03-27 EP EP92914179A patent/EP0590053B2/en not_active Expired - Lifetime
- 1992-03-27 SK SK1452-93A patent/SK283999B6/sk not_active IP Right Cessation
- 1992-04-03 CA CA002065056A patent/CA2065056A1/en not_active Abandoned
-
1994
- 1994-07-29 MD MD94-0303A patent/MD842G2/ro active IP Right Grant
- 1994-11-23 EE EE9400390A patent/EE03043B1/xx unknown
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1995
- 1995-05-05 US US08/435,607 patent/US5608111A/en not_active Expired - Lifetime
- 1995-05-10 US US08/438,603 patent/US5623088A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3847990A (en) * | 1971-09-28 | 1974-11-12 | Bayer Ag | Process for the production of nitrodiphenyl amine derivatives |
US4404401A (en) * | 1979-02-23 | 1983-09-13 | Akzona Incorporated | Process for the preparation of para-amino-diphenylamine |
US4479008A (en) * | 1982-09-30 | 1984-10-23 | Uniroyal, Inc. | Preparation of p-nitrosodiphenylamine |
DE3501698A1 (de) * | 1985-01-19 | 1986-07-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
US4683332A (en) * | 1985-05-20 | 1987-07-28 | The Goodyear Tire & Rubber Company | Para-nitrodiphenylamine synthesis |
US4760186A (en) * | 1986-09-15 | 1988-07-26 | Monsanto Company | Preparation of substituted aromatic amines |
Non-Patent Citations (1)
Title |
---|
Tetrahedron Letters, vol.31, no.22, 1990 ( Oxford, GB. N.R. Ayyangar et al., p. 3217-3220). * |
Also Published As
Publication number | Publication date |
---|---|
AU653249B2 (en) | 1994-09-22 |
US5117063A (en) | 1992-05-26 |
MD842F2 (ro) | 1997-09-30 |
PL168393B1 (pl) | 1996-02-29 |
ES2110001T3 (es) | 1998-02-01 |
SK145293A3 (en) | 1994-07-06 |
EP0590053B1 (en) | 1997-09-24 |
US5608111A (en) | 1997-03-04 |
PL168938B1 (pl) | 1996-05-31 |
US5623088A (en) | 1997-04-22 |
CZ281972B6 (cs) | 1997-04-16 |
ATE158567T1 (de) | 1997-10-15 |
WO1993000324A1 (en) | 1993-01-07 |
EE03043B1 (et) | 1997-10-15 |
PL168917B1 (pl) | 1996-05-31 |
DE69222417D1 (de) | 1997-10-30 |
KR0132514B1 (ko) | 1998-04-13 |
HU214296B (hu) | 1998-03-02 |
UA26851C2 (uk) | 1999-12-29 |
HU9303686D0 (en) | 1994-04-28 |
JP3167029B2 (ja) | 2001-05-14 |
CZ248493A3 (en) | 1994-03-16 |
BR9206180A (pt) | 1995-04-25 |
ES2110001T5 (es) | 2006-11-16 |
HUT66362A (en) | 1994-11-28 |
AU2224592A (en) | 1993-01-25 |
EP0590053A1 (en) | 1994-04-06 |
EP0590053B2 (en) | 2006-04-12 |
RU2102381C1 (ru) | 1998-01-20 |
CA2065056A1 (en) | 1992-12-22 |
US5453541A (en) | 1995-09-26 |
JPH06508630A (ja) | 1994-09-29 |
SK283999B6 (sk) | 2004-07-07 |
DE69222417T3 (de) | 2006-11-16 |
DE69222417T2 (de) | 1998-04-16 |
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Legal Events
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IF99 | Valid patent on 19990615 |
Free format text: EXPIRES: 20140729 |