MD842G2 - Method of preparing of 4-aminodiphenylamine - Google Patents

Method of preparing of 4-aminodiphenylamine

Info

Publication number
MD842G2
MD842G2 MD94-0303A MD940303A MD842G2 MD 842 G2 MD842 G2 MD 842G2 MD 940303 A MD940303 A MD 940303A MD 842 G2 MD842 G2 MD 842G2
Authority
MD
Moldova
Prior art keywords
adpa
produce
substituted derivatives
aminodiphenylamine
preparing
Prior art date
Application number
MD94-0303A
Other languages
Romanian (ro)
Russian (ru)
Other versions
MD842F2 (en
Inventor
Malcolm Allman James
Keane Bashkin James
Keranen Rains Roger
Keith Stern Michael
Original Assignee
Monsanto Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24891732&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MD842(G2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Monsanto Company filed Critical Monsanto Company
Publication of MD842F2 publication Critical patent/MD842F2/en
Publication of MD842G2 publication Critical patent/MD842G2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/38—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitroso groups

Abstract

The invention relates to the method of producing of 4-aminodiphenylamine (4-ADPA), intermediate compounds, as well as to the p-phenylendiamine alkylation products applicable as antioxidants.The method is disclosed wherein aniline or substituted aniline derivatives and nitrobenzene are reacted under suitable conditions to produce 4-nitro- or 4-nitrozodiphenylamine and substituted derivatives thereof and/or their salts, either or both of which are subsequently reduced to produce 4-ADPA or substituted derivatives thereof which can be reductively hydroalkylated to produce p-phenylenediamine products or substituted derivatives thereof which are useful as antiozonants.The technical results of the inventions is the increase of the yield of preparing 4-ADPA.
MD94-0303A 1991-06-21 1994-07-29 Method of preparing of 4-aminodiphenylamine MD842G2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/719,876 US5117063A (en) 1991-06-21 1991-06-21 Method of preparing 4-aminodiphenylamine

Publications (2)

Publication Number Publication Date
MD842F2 MD842F2 (en) 1997-09-30
MD842G2 true MD842G2 (en) 1998-12-31

Family

ID=24891732

Family Applications (1)

Application Number Title Priority Date Filing Date
MD94-0303A MD842G2 (en) 1991-06-21 1994-07-29 Method of preparing of 4-aminodiphenylamine

Country Status (19)

Country Link
US (4) US5117063A (en)
EP (1) EP0590053B2 (en)
JP (1) JP3167029B2 (en)
KR (1) KR0132514B1 (en)
AT (1) ATE158567T1 (en)
AU (1) AU653249B2 (en)
BR (1) BR9206180A (en)
CA (1) CA2065056A1 (en)
CZ (1) CZ281972B6 (en)
DE (1) DE69222417T3 (en)
EE (1) EE03043B1 (en)
ES (1) ES2110001T5 (en)
HU (1) HU214296B (en)
MD (1) MD842G2 (en)
PL (3) PL168938B1 (en)
RU (1) RU2102381C1 (en)
SK (1) SK283999B6 (en)
UA (1) UA26851C2 (en)
WO (1) WO1993000324A1 (en)

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US5331099A (en) * 1992-05-22 1994-07-19 Monsanto Company Process for preparing p-nitroaromatic amides and products thereof
US5252737A (en) * 1992-05-22 1993-10-12 Monsanto Company Process for preparing N-aliphatic substituted p-phenylenediamines
US5552531A (en) * 1992-05-22 1996-09-03 Monsanto Company Process for preparing substituted aromatic azo compounds
US5233010A (en) * 1992-10-15 1993-08-03 Monsanto Company Process for preparing isocyanate and carbamate ester products
DE69316825T2 (en) * 1992-10-28 1998-09-10 Mitsui Toatsu Chemicals Process for the production of diphenylamine or core-substituted derivatives
US5451702A (en) * 1993-04-26 1995-09-19 Monsanto Company Process for preparing substituted aromatic amines
US5380946A (en) * 1993-07-30 1995-01-10 Monsanto Company Process for preparing p-nitroaromatic amides and products thereof
JPH07149695A (en) * 1993-09-30 1995-06-13 Seiko Kagaku Kk Production of 4-aminodiphenylamine
US5382691A (en) * 1993-11-05 1995-01-17 Monsanto Company Process for preparing substituted aromatic amines
DE4427248A1 (en) * 1994-08-02 1996-02-08 Bayer Ag Process for the preparation of nitro-substituted arylamides and arylamines
DE4427249A1 (en) * 1994-08-02 1996-02-08 Bayer Ag Process for the preparation of nitro-substituted arylamines
DE4432556A1 (en) * 1994-09-13 1996-03-14 Bayer Ag Process for the preparation of nitro-substituted arylamines
DE19600722A1 (en) * 1996-01-11 1997-07-17 Bayer Ag Process for the preparation of optionally substituted 4-aminodiphenylamines
US5728882A (en) * 1996-04-04 1998-03-17 Uniroyal Chemical Company, Inc. Preparation of substituted aromatic amines
DE19709124A1 (en) * 1997-03-06 1998-09-10 Bayer Ag Process for the preparation of 4-aminodiphenylamine
US5925790A (en) * 1997-03-13 1999-07-20 Uniroyal Chemical Company, Inc. Preparation of substituted aromatic amines
US5977411A (en) * 1997-06-10 1999-11-02 Flexsys America L.P. Catalytic hydrogeneration of nitrobenzene to 4-aminodiphenylamine in the presence of a hydroxyl compound and a solvent
TW500712B (en) * 1997-08-06 2002-09-01 Bayer Ag Process for the preparation of 4-aminodiphenylamine
DE19810929A1 (en) * 1998-03-13 1999-09-16 Bayer Ag Process for the preparation of 4-aminodiphenylamine
US6140538A (en) * 1998-05-18 2000-10-31 Flexsys America L.P. Process for preparing 4-aminodiphenylamines
US5840982A (en) * 1998-06-04 1998-11-24 Uniroyal Chemical Company, Inc. Process for preparing para-phenylenediamine derivatives
SK283209B6 (en) * 1998-12-11 2003-03-04 Duslo, A. S. Preparation method for 4-aminodiphenylamine
US6069279A (en) * 1999-06-14 2000-05-30 Simon; Mark W. Preparation of substituted aromatic amines
US6229035B1 (en) 1999-06-16 2001-05-08 Uniroyal Chemical Company, Inc. Preparation of substituted aromatic amines
KR100302862B1 (en) * 1999-07-08 2001-09-13 박찬구 Method of preparing 4-nitrodiphenylamine and 4-nitroaniline from phenylurea
KR100298572B1 (en) * 1999-08-19 2001-09-22 박찬구 The method for preparing 4-nitrodiphenylamine and 4-nitrosodiphenylamine from carbanilide
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Also Published As

Publication number Publication date
EP0590053A1 (en) 1994-04-06
DE69222417T3 (en) 2006-11-16
EP0590053B1 (en) 1997-09-24
JP3167029B2 (en) 2001-05-14
PL168393B1 (en) 1996-02-29
SK145293A3 (en) 1994-07-06
JPH06508630A (en) 1994-09-29
US5117063A (en) 1992-05-26
CA2065056A1 (en) 1992-12-22
UA26851C2 (en) 1999-12-29
DE69222417T2 (en) 1998-04-16
EP0590053B2 (en) 2006-04-12
EE03043B1 (en) 1997-10-15
RU2102381C1 (en) 1998-01-20
DE69222417D1 (en) 1997-10-30
MD842F2 (en) 1997-09-30
WO1993000324A1 (en) 1993-01-07
ATE158567T1 (en) 1997-10-15
ES2110001T3 (en) 1998-02-01
AU2224592A (en) 1993-01-25
AU653249B2 (en) 1994-09-22
KR0132514B1 (en) 1998-04-13
ES2110001T5 (en) 2006-11-16
PL168917B1 (en) 1996-05-31
US5453541A (en) 1995-09-26
CZ281972B6 (en) 1997-04-16
PL168938B1 (en) 1996-05-31
SK283999B6 (en) 2004-07-07
US5623088A (en) 1997-04-22
BR9206180A (en) 1995-04-25
CZ248493A3 (en) 1994-03-16
HUT66362A (en) 1994-11-28
US5608111A (en) 1997-03-04
HU9303686D0 (en) 1994-04-28
HU214296B (en) 1998-03-02

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