LV11044B - Tanning process for chemical treatment of skins and pelts by using organic agent - Google Patents

Description

LV 11044 ciiocoK oupasotku ko* u μεχοβ

OnHcaHHe

IboopeTeinie othochtch κ npuMenemno Nr, N-^By3aMemeHHbi:c β-aMHHonpormo-HOBbl.\ KHCJIOT B KaHCCTBe 3MyJIbraHTOB, CMa^HBaTeaeH, nOBCpXHOCTHO-aKTHBHbIX Bemecra b cpejicTBax jum ooictkh h hjm npnjiaHiM BonoorraJEKHBaiomHK cbohctb KOJKaM h MexaM.

AJIKHnaMHHOnpOnHOHOBbie KHCJIOTbl, aJIKHJiaMHHOJIHnponHOHOBbie KHCJIOTbl H aminiipoBaHHbie anKHJiaMHHonpoiiHOHOBbie KHCJIOTbl cemh no ce6e H3Becmbi. Tax, b naTeirre CIJLIA N 2.468.012 onHCbiBaeTca noJiyqeHHe N-ajncHJiaMHHonponHOHOBbix kiicjiot h nx npHMCHeHne b KaqecTBe jieTepreHTOB, 3Myjn»raTopoB h craSHjnmTopoB neHbi. riojiy^eHHe ocymecTBJMK>T npHcoeaHHeHHeM περΒΗΗΗΒΐχ εμηηοβ κ 3φκρΕΜ aKpHJIOBOH KHCJIOTbl H OMbUICHHCM 06pa30BaHHbIX 3φκρ0Β N-ajJKHJiaMHHOnpOIIHOHOBOH KHCJIOTbl ko cooTBeTCTByiomHX khcjiot hjih cojiefl. B 3a«BKe Ha naTem ΦΡΓ N 20 54 649 onHCbiBaioTC» N-amui-N- aJiKHJiaMHHonponHOHOBoft KHCJIOTbl, KOTOpbie nojiyqaiOT npeBpameHHeM ΕΜΗΗΟΒ c npOH3BOHHbIMH aKpHJIOBOH KHCJIOTbl, K3K 3φπρΕΜΗ aKpHJIOBOH KHCJIOTbl, aKpjLTHHTpHjiOM, h nocjieuyiomefi peaKUHeft c aHnmpHnaMH. B nocjiejmeil crajiHH cHHTeaa ombumiot <pyHKwao 3φιιρα, Hinpiuia hjih aMHua ko khcjiotbi. ΠροΑ}τατ>ι nojiyqaior κεκ βοληβιη hjih Bojnio-crmpTOBOH pacreop. 3th H3Becmbie coemiHeHHJī hm&ot p*n HenocraiKOB:

Tpe6yeMa« no cnoco6y ri0JiyqeHiM crajiua OMbUieraM npHBOjurr κ TOMy, hto npojiyKTbi mojkho noJivnaTb kbk 100%-Hoe Bemecreo tojimco b pacreope η He 6e3 najibHeHinHx TexHOJioniqecKHX cranHfi. 06pa30BaHHeM 3KejiaTHHH3HpyroinHX cTpyicryp mojkho nojiyqaTb b Boae tojimco 20-30%-Hbie pacTBopbi nacroo6pa3HOH kohchctchhhh. Tojibko coBMecTHbiM npHMeHeHHeM cimpTOB, κοτοροε HeBbiroaHo, KomieHTpamM mohcct noBbimaTbca npH6jm3HTeJibHO Ha 50%. TaK KaK oMbuieHHe npoBOjnrr b CHJībHO mejioHHofi o6jiacrH, npojiyKTbt noaie peryjmpoBaHHH ko bcjihhhh pH ot 5 no 8, KOTOpbie Tpe6yioTca mia μηογηχ npHMCHCHHH, HanpnMep b oojiacra tckcthjm, hmciot BbicoKHc coaepJKaHHii cojih, KOTOpbie oimaKO qacro sbjmiotch HOKejiaTenbHbiMH. Πρκ npHMeHeHHH TBepai>ix ajnciuiaMHHOB npHcoejcHHeHHe κ npoH3Boano.My aKpmioBofi KHCJIOTbl cjieayer npoBOHHTb npn noBbimeHHbix TeMnepaTypax (Bbirne tohkh nrraBJieHJM amamaMUHa), bcjicjictbhc qero πρκ peaxmioHHOcnoco6Hbix ajcpmioBbix npoH3BoztHhix vcKopjnoT HOKCJiaTejibH^TEO no6oTOyro peaicmno oGpaaoBaHHH iniazuiyKTOB. Πριι rroii ποδο'ΐΗοΓι peaKUHH BTopyro MO/ieKyny aKpunoBoro npoHOBOzmoro npHcoejjiH.OOT κ y>Ke oopa30BaHHOMy npoH3BojHOMy N-ajncHJiaMHHonponHOHOBOH kiic.'iotli, npii'ieM oopa3yercji Tpenruibul a.MHH, KOTopbiii He Μθ>κετ oojibuie aipijDipoBaTbCH b c;ie,ayiomeH cTaznin cnHTe3a.

HaKOHeu, Bpejnioe BjmaiiHe OKaabiBaeT TaiOKe 3anax ocTaTOHHbix coziepMcaHHH aKpmioBoro 3φΗρβ hjih aKpHJiHHTpHjia b προζιγκτβ. Tajc, MOTKHO οτΗβτχαίΒΟ omymaTb ocTaTOTOoe coziepjKaHHe 0,1% aKproioBoro 3φπρα. H3o6pereHHe othochtch, cneaoBaTenbHO, κ cnoco6y jum npnjiaHHa BOJtOOTTaJHCHBaK>mHX CBOHCTB KO«e H MexaM ΓφΗ npHMeHeHHH HOBbIX COeHHHeHHH CaMHX no ce6e mm b cmcch c apyrHMH H3Becrm>iMH cpejicTBaMH jum npnaamm BoaoorrajiKiiijaiomnx cbohctb.

BoaoHenpoHHnaeMyio KOJKy noiryqaiOT, b ochobhom, no CJienjroimiM myu cnocoSaM: 1. HanojmeHHe KaimjiJijrponozio6Hbix, βπητβιββιοπιηχ BOicy BOJioKHHCTbix npo.Me>KyTKOB Bonojmjio'rajnomHMH BeinecTBaMH.

BoiīOHepaCTBOpHMbie BemeCTBa, ΚβΚ HanpHMep JKHpbl, ΠΒρΒφΗΗΜ, bock hjih onpezteneranjie nojniMepbi, noKa3bmaioT npn stom He>KeJiaTejibHoe convrcTBViomee iTBJieHiie, b qacTH0CTH, OKa3bmaioT oipraiaTejibHoe Bjramnie Ha BajKHbie zum yao6cTBa hockh cBoficTBa BO3,ayxonp0HHiiaeMOCTH h naponpoHHuaeMOCTH. BjiaronpHaiHee eeziyT ce6ii coe/nraeHHH, KOTOpbie Ha6yxaioT 6ji aroaapa noraomeHHio Bozibi h TeM caMbiM nozmepjKHBaioT 3φφβκτ coScTBeHHoro Ha6yxaHna h co6cTBeHHoro yruioTHeHHa bojiokoh ko>kh. IlpHMCHeHHbie no 3TOMy MeToziy npoayKTbi othochtcji k THny 3Myjn>raT0p0B boj& b Macne (WI0). 2. rīOĶpblTHe ΠΥΗΚΟΒ BOJIOKOH ΓΗΖφΟφοβΗΒΙΜΗ BemeCTBaMH. 3Myjn>raTopbi, KOTOpbie MoryT o6pa30BaTb KOMnneKCHbie coeūHHeHiifl c MHOrOBajieHTHbIMH HOHaMH MCTaTnOB (ΚΒΤΗΟΗΒΜΗ), MOiyr BO ΜΗΟΓΗΧ CJiyTJaaX BXOZIHTb Taioicc b īcoMiuieKcnoe coezomemie xpoMa-KOJinareHa ii Bbi3biBBTb b dtom cnynae πυροφοδΗ3αισπο. ΠοΛοδΗΒίε 3MynbraTopbr CBaabiBaioTca xiiMiraecKH c noOTeprHjrbiMH xpoMOBOMy hjih ajiioMHHHeBOMy ziy6;ieHHK) BOJioKHaMH kojkh h CHHJKaiOT Gnaioaapa ΓΗΛροφοόΗΟΜΥ nOKpblTHIO CMaHHBaCMOCTb H BOHOnorJIOmaeMOCTb. CHIDKeHHe paccrHJiaiomeH cnoco6HocTH Bbipa^aeTca b o6pa3oeaHHH mapoo6pa3Hbix Kanejib (3φφ«α· BOŪOOTTaJIKHBaHHJl). - 3 LV 11044

CmībHO noBbicHBUineca 3a nocjiezmee BpeMfl Tpe6oeaHH5i κ πο,ΠΒφΠψτοΗ ΠΙ.Τρθφθ6Η3,3ΙΙΗΙΙ KO>K? ΠΟ'ΙΤΪΙ Henb3H HOCTtirHVTb HJIH MOJKHO JOCTHrHVTb TOJIbKO B ymep6 jpvniM τακτκ? βαγκημμ οβοΓιοτβαμ πριι πομοιιιη H3BecTHbix MeTOiīOB nupc<ļ)Oūji3aujiix. Βφ.χιυιο κο>ιαι j,tsi noBcejnieBHofi hockh ζοίχιμ arojusi Bbinomixn> tokhč τρεδοΒΟΗΐΐΛ, KOTopbie HccKonbKo ner tomy Haaaa nņezbsanjimi το;π>κο κ (ļiopM>jiHpHOH kojkc (ko/kc jmsi BoeHHoro CHapsDKeHHa), He orKa3bmaHCb o/maico ot yno6cTBa hockh, μοληογο BHna h ap. Πο 3Toh npH^HHe npHaepJKHBanHCb, HanpHMep, aByxcraaH0HOH ΓΗΖφθφθ6Η3ΗΙΙΗΗ. Γ oTOBbie BbicymeHHBie hjih oTaejiaHHbie kohkh mojkho λοποπηητ«π>ηο o6pa6aTbraaTb pacTBopeHHBiMH b opraHHqecKHX pacrBopHTejwx οιπηκοηοβμμη MacnaMH. BpeaHoe Bjmamie OKa3bmaeT npH stom xpe6yeMaa jum CMaqHBaHH3 TeMnq)aTypa cynncH MOKny 90°C hjih 100°C, KOTopaa npHBoam: κ 3HaqHTejiBHbiM ποτερκΜ pa3MepoB. KpoMe τογο, npeacraBJiaer npo6jicMy BbicoKoe kojiotcctbo opraHiraecKHx pacTBopHTejieH, κοτοροβ c6pacbmaeTCJi b OKpjoKaiomvio q>eay.

Oco6eHHo H»KenaTejibHWM b cMbīcne paiiHOHanbHoro npoH3BoacTBa jranaercs tot φηκτ, ίτο aonojiHHTfJībHaa o6pa6oiKa CBjnaHa c nonojimrrejibHOH, HesfcejiaTejibHOH pa6oqen crajuien. rio3TOMy 3aaaqefi H3o6peremui aBJisuiocb TajoKe pa3pa6oxKa cnocooa jum ΠυφθφθβΗ33ΚΗΗ KOJKH H MCXOB, KOTOpbIH MO)KHO ΠρΟΒΟΛΗΠ» B OflHy pa6oqyiO CTaflHIO, b bozchom pacTBope h b 6apa6aHe, η npH πομοιιιη κοτοροτο mojkho nocraraTb OŪHOBpeMeHHO JKHpOBaHHH Η BbICOKOH Π«φθφθ6Η33ΙΙΗΗ. KpOMe ΤΟΓΟ, πρΗΜeHeHHblC BcnoMoraTCJībHbie cpejicTBa motkho nojiyqaib bo3mo>kho npome h ohh Hejtoporne, npHqeM jiocTHraioT nocraToqHoro «κροΒβΗΗΛ h nocraToqHofi ΓΗΐιροφο6Η33ΠΗΗ He TOJIbKO B CTaJDffl OTUCJIKH, HOHC OJOHHM npoayKTOM. 3Ty 3ajaqy pemaioT npHMeHeHHeM coennHeHHH o6mefl φopMyJπ>I 1: R3 /

R, — N - CHiCH — COOX

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I R, BAD 01 - - ν · β κοτοροΗ Ri o6o3HaqaeT HacbniieHHtii! hjih HeHacbimeHHtifi arncHJībHbiH ocraTOK hjih ajrKOKCHajiKHjrbHbiii οοτατοκ c 1-22 aTOMEMH yrjiepona, npennoqTHTeJibHO c 12-18 aTOMa.Mii vrnepojia, R: oooaua'iaeT arnauibHbUi ocraTOK c 1-18 aTOMaMii yrjiepoaa, HacbimeHHbrii mni HeHacbimeHHbm κ ap 6 ok chamaun.Hbrfi ocraTOK c 3-4 aT om3mh yrnepoaa, καρβοκαιφε-HH-lbHblii OCTaTOK HJIH KapSOKCHJIbHblH OCTaTOK (-COOH),

Rj o5o3HaqaeT Bonopoji hjih CHj h

X o6o3HaqaeT Bojiopon, mejioraofi MeTarui, mejioHHOseMejibHbift Mērāmi, emmohhh, aJUCHJiaMMOHHH HJIH ΕΠΚΕΗΟΠΕΜΟΗΗΗ H

P A o6o3HaqaeT >0=0, >SC>2, sq

NH hjih anKHJieHOBbiH ocraTOK c 0-3 ετομεμη yraepojia. ΠροΛγκτΒΐ no H3o6peTeHino nphmemnoT hjih HenocpejicTBCHHo b hx no MeHbmefi Mepe gacTiraio HeHTpajnnoeaimoH φορΜε Kaκ cojiepacammi HeMHoro bojuj npoajrcr b 6ojn>inHHCTBe cjiynaeB nacToo6pa3HOH kohchctchiihh juul ΓΗαροφο6Η3βιΐΗΗ, hjih HCH€HipajiH30BaHHbie, b 6ojibiuHHCTBe cjiyqaeB nacToo6pa3Hbie npojiyKTbi pacrBopaioT b yriieBoziopoaax h/hjih b xjiopnpoH3Bojmbix jTJieBonopoaoB, b cjiynae Heo6xonHMOCTH nocpencTBOM areiiTOB pacreopemni, h 3aTeM no Mem>meH Mepe nacnnmo HefirpanH3yiOT. J\wt 3τογο Hcnojn.3yror ocHOBamnr, oco6chho opraHHHecKHe nepBHHHbie, BTopHTObie h TpeTH'iHbie βμηηβι h β,πκβηοπβμηηβι, a τβισκε Boj0Q>ie pacTBopbi βμμηβκβ h niapooKHceH mejio«nn>ix MerajrioB. 3Myjn>rHpyiomee jieScTBHe HefrrpanH30BaHHbix npoayKTOB nooBOJiacr noJiyqaTL Taione BoaocoaepHcamHe npojijKTbi.

CoeHHHeHHM ΠΟ H306pereHHK) ΒΒΟΛΜΤ B KOJIHHCCTBC OT 0,1 ĶO 25, upezuīoHTHTejibHO οτ I no 15 Bec.% b nepecnere Ha crporaHHbiH eec kotkh hjih MOKpbiH Bec MexoB πρκ pH-Bejm*nmax Μοκζιγ 4 h 9, nocjie qero BejnnmHa pH cHHHcaerca ķo 3,5-5,0, h b cjiyqae Heo6xonHMocTH 3aKpenjiaiOT πρκ πομοπιη 2-, 3- hjih 4-BaJierHoil cojih MeTaJDia. ripHMeHeHHbifi jum ΓΗίτροφοδΗααιΐΗΗ COCTaB no Η3θ6ρβΤεΗΗΚ) CO/iepJKHT nejiecoo6pa3Ho 5-80 Bec.%, npennoTnrrenbHo - 10-70 Bec.% coejnmeHHH no H3o6peTemno o6men φορ\ψ;π>ι I, b ciiyqae Heo6xojiHMOCTH 20-70 Bec,%, npcimoTTHTejibHO 30-60 Bec.% yrneBo^opoa:oB hAuih xjiopnpoH3BOOTwx yrjicBonopoaoB, b c:iyqae hco6xo,uhmocth c arenraMM pacTBopeHHM, κοκ BbicoKOKHrumiHe npoayKTbi H3 OKcoctiHTeaa, h oeranbHoe jio 100% βο;π>ι. LV 11044 Χοτ« ywe πρκ πομοιιιη οαηιιχ coeziHHemra no H3o6peTeHmo /iocmraiOT οτ.τπμηογο >KiipoBaiiH5i h otjdihhoh ΓΠ/φοφοοιπαιχΗΗ, cpeacTBa ΓΗίΐροφοδίηαηΗΗ no ιηοδρετεΗίπο mohcho npiiMemiTb BMecre c inBecrabiMii epencTBa.MH jjm /KirpoeaHmi 11/11.ui cpe^CTBaMii πυφοφο6Η3αηηπ, κοκ 'iacrinubie οφιιρΜ φοοφορΗοπ κιιογιοτη,

CnJDIKOHOBblH 0apKO3lU OJieiIHOBOH KHCJIOTBI h/hjih (ΧΙΙθρ-)-ΠαρΕφΐΙΗΒΙ. riūCKonbKy npHMeHaioT qacTHiiHbie οφηρΒΐ φοοφορΗοη khcjiotbi, npeunomiTaioT Henomībie 3φηρί>ι cnnpTOB c λπηηοη nenn ot C4 no C20, πρβΛΠΟΏΉΤοπι,ΗΟ Cie-is, KOTopbie b cjiyqae ΗεοδχοΛΗΜοσίΉ OKcamcHjmpoBaHbi, b KOjmqecTBax ot 0,5 ņ.o 30 Bec.%, npeOToqTHT&m>HO 1-20 Bec.% (b nepecneTe Ha 100 r cpe^CTBa ΓΗΖιροφο6Η3βιΐΗΗ).

CoBMecTHoe npHMeHeHHe κηοιβιχ 3φηροΒ φοοφορΗοη khcjiotbi mojkho ocymecTBJi5m> tbkhm o6pa30M, ητο hx bbojdit BMecre c coeuHHeHjniMH no H3o6pereHmo, paaSaBJiinoT η οατβΜ neirrpajiH3yioT BMecre c nocJiemniMH. ΘφιιρΒΐ φοοφορΗοη khcjiotbi Moryr npHMeH^TbCH τβισκε b ρκε HeirrpajiH30BaHHOH φορΜε. npHMeHemie 3φκροβ φοοφορΗοη khcjiotbi npenjiaracrcji, HanpHMep, jum CHiDKemts 3KcrpanipyeMoro conep>KaHH^ JKHpa; 3TO npencraBJiHer rrpeHMjmecTBo ocoGemio y ko>k jum oaeHCZIbi BCJieacTBHe ynyTmieHHOH Sjiaronapu 3TOMy ctohkocth k jchmhhcckoh ohhctkc. riocKOJiBKy ΛοποπΗΗΤβΠΒΗΟ κ coe®meHHJiM no H3o6pereHHio πρΗΜβΗΗΐοτ CHJiHKOHOBBie Macjia, nocjiezurae HcnonB3yioT b KOjmqecTBax ot 0,5 jjo 80 Bec.%, npeflnoqTHTeJiBHo 1-20 Bec.% (b nepecneTe Ha 100 r cocraBa cpencrea jum ΓΗΖφθφθ6ΐΙ3ΒΙΙΗΗ). B Kanecrae chjihkohobbix Maceii mojkho npHMeHaTb KOMMepnecKHe nojDicHJiOKcaHBi, KaK hhmcthji- hjih Mejnu^eHHJinojiHCHJioKcaH. ΠρειιποΗΗΤβιοτ o6jiacrH B5T3KOCTH OT 100 JJO 500 MHJIHHnya3/ceK. ΠρΗ 3TOM CHHHKOHOBOe MaCJIO C COeflHHeHHeM no H3o6pereHHio bbozwt b cjiyqae hco6xoi[hmocth BMecre c yrjieBOūopo^aMH h/hjih c XJIOpnpOH3BOaHBIMH JTJieBOJIOpOflOB HJffl ΒΓβΗΤΒΜΗ paCTBOpeHHH. ΠρΗΜβΗεΗΗε chjihkohob cjijokht npennoHTHTejibHO juisi nocnDKeHHH onpenejieHHBix HcejiaTejiBHBix nOBep.XHOCTHBIX 3φφθΟΌΒ, KaK HarrpHMep HOKHOCTH juma KOJKH. Jķm iumbiiemnero yjiyqmeHiia mstkocth h hto6bi aocmrHyTb 6onee jiaipHoro Γρκφ3 mojkho iīpHMeHirrB TaioKe capK03tm ojieHHOBoft khcjiotbi. 'IroGbi λοογηγητπ» onpenejieHHBix 3φφεκτοΒ, mojkho BOo6me npuMemm» jno6yio KOMČHHamno in HenojiHBix 3φΐΐρθΒ φθϋφθρΗΟΗ KHCJIOTBI, CHJIHKOHOBOro MaCJia H CapK03Hūa OJieHHOBOfl KHCJIOTbl c coezcHHeHHsiMH no H3o6pereHHK>. - ε

CapKcmm ojichhoboh KHCJIOTbl mojkho npHMeHSTb nonojiHHTejibHo κ coejimeHHHM no rnoopoTeHino b KOJm»iecTBax ot 0,5 jo 50 Bec.% npenno'mnejihno 2-20 Bcc. r ) (b πορεοηετε Ha 100 r BBejeHHoro cocraea).

Cočjjihchhc oomon φορΜ)τπ>[ I no;iyiiaīOT tcm, ητο ajiKiiJiaumībi upu 40-130°C npejnommejiBHO npn 70-100°C, npHCoejHHinor κ (Mer)aicpHJioBOH khcjiotc. Xotji KOMnoHeHTbi peajcmiH nocjie CMemHBaHHa cymecTBy»>T κβκ opraHKraecKaa com., npHcoejHHeHne 3aKaHHHBaeTCH nepe3 1-4 naca h jomiraeT ποπηογο npeBpameHHH. 06pa30BaHHH jHajmyKTOB πρπ 3thx ycnoBHax peaKiniH He HaGjnojaioT. He Tpe6yeTca TaioKe npuMeHeraie pacreopirrenji. ΠρΗ aMHHax c tohkoS Kraiemta HiDKe Taκ Ha3biBaeMbix TeMnepaTyp pearamH npeBpameHHe npOBozurr rrpejnoīTHTejibHO noj jaBJieHHeM, HanpHMep b aBTOKJiaBe. npeBpameHHe ajnouiaMHHa c (MeT)aKpHJioBoft κκαιοτοίί npoHcxojHT npe/moMTHTeJTbHO κ 3KBHMOJurpHbix KOJinnecTBax. B KaqecTBe επκηπβμηηοβ ģopMynbi R1-NH2 MoryT npHMeHHTbca, HanpHMep, arejvToniHe nepBHHHbie aMHHbi: MeTHJiaMHH, nponHnaMHH, 6yTHJiaMHH, reKCHJiaMHH, HOHimaMim, jeimnaM hh , jojemuiaMiiH, TpHjerinnaMHH, H30TpHjeiiHJiaMHH, neKcajeiZHJiaMHH, OKrajemuiaMim, nponoKcnnponnjiaMHH, oKTHJiOKCHnponHJiaMHH, oneiuiaMHH, oJicnjioKCHiipomuiaMHH, JiaypHJiaMHH, βμηη kokocoboto Macna, creaptuiaMHH, bmhh cana hjih cMecH BbinieHa3BaHHbix βμηηοβ. OcooeHHo npeanonTHTejibHbiMH βμηηβμη jibjijiīotcs JiaypHJiaMHH, βμηη kokocoboto Macna, bmhh cana h oneHnaMHH. JļajībHeinuee npeBpameHHe N-amora-N-(2 -Kap6oKCH3ran)-aMHHOB npoBOjurr c ΒΗΓΗΖφΗΚΒΜΗ, Η30ΙΙΗΒΗΒΤΒΜΗ, XJIOpaHTHJpHJiaMH Kap6oHOBOit KHCJIOTbl ΗΠΗ xjiopaHrHjpHjaMH cyjn^OKHcnoTbi, eam pem> HjeT 06 amuiHpoBaHHH. ΠρΗ TCMneparypax 50-100°C amuiHpyiomee cpejcTBo πρΗΜειυποτ b 3KBHMOJiapHbix KOjnrqecTBax jo HeSontmoro H36bmca (οκοπο 5%).

PeaKUHj c aHTHjipHjaMη ηπη η30ιιηηηβτβμη 3aKaHqHBaeTc« qepe3 1-2 naca h mer Tpe6yeMbie N-amcHn-N-(2-Kap6oKCH3THn)-aMHjbi b 100% φορΜε. ΠρΗ npHMeHeHHH aiinutpHjoB ΜΟΗΟκηρβοΗΟΒοίί KHCJIOTbl, HanpHMep yKcycHoro aHTHjpHja, ncn>qaiomyioca b 3KBHBaneHTHOM KOjnmecrBe MOHOKap6oHoeyio KHcnoTy οτπε.τηιοτ neperoiiKon ium ripoMLiBKofi bojoh. B KanecTBe aHnmpnjoB Moryr 6bm> Ha3Bam>i KaK rrpHMepbi: yKcycHbiii aHnmpHj, aHnurpnj nporoioHOBOH κηοιοτμ, aHnmpHn MacjumoH κκαιοτω, aHrmrpHj ManemiOBOH KHCJIOTbl, aHnmpHJ 5īHTapHOi! KHCJIOTbl, annupuzi φτα/ΙϋΒΟίί KHCJIOTbl. LV 11044 B KanecTBe inounaHaTOB ripHHHMaioT bo BHHMaHHe, HanpHMep. 6yTHjnt30fiHaHaT( rojivH.THSoLuianaT, tnonponHmnouHonaT. II Βτορ)το crajuno peaKmiH, t. e. peaKmno anHJmpoBaHHJi, npOBOjun· npcarro'iTnTe.Ti>iio c oKBiīMOJiapubiMii KOJnmecTBaMii KOMnoHeHTOB peaKuini.

Ecjdi peaKLuao amunipoBamia npoBOjurr c xJiopaHrHztpn,aaMH καρδοΗΟΒοΓι Kiic;iorbi hjhi c xjiopaHrHūpnaaMH cyjH^oKHCJioTbi, το b Ka^ecTBe CBK3biBaK>imix KiicjioTy cpejtcTB npHMeHinoT noponncooopaBHjno co.ny hjhi Tpenratbie aMHHbi. 06pa30BaHHyK> BO BpeMa peajCUHH COJIb MOJKHO OT(ļ>HJIbTpOBbIBaTb HHH BbIMbIBaTb ΒΟΛΟίί. B Ka^ecTBe npHMepoe jpia JūiopaimiiīpmioB Kap6oHow>H KHcnoTbi mo>kho Ha3Ban>: xjiopaHrnapna yKcycHOH KHCJioTbi, xjiopaHrajipHn προπποΗΟΒΟΗ khcjiotbi, XJIOpaHTHJipH^i MaCJUfflOH KHCJIOTbl Η ΠΟΛΧΟΛΗΠΤΗβ XJI0paHTHflpHZEbI CyJΠ>φ0KHCJI0TbI, HanpHMCp XJIOpaHTHJīpHH MeTaHCyHbφoKHCJ^OTbI) XJ10paHTHZipHa 3TaHCyjn^OKHCJIOTbI, xjiopaHnurpnn napa-Tonvojicvjn^oKHCJioTbi. ^anBHemiiee rrpeBpameHHe o6pa30BaHHOH N-ajncHJiaMHHonponHOHOBOH khcjiotm MOJKHO npOBOiUITb TaiOKe C raJTOHiPaMemeHHbIMH Kap6oHOBblMH KHCJIOTaMH, npejļTTO'mrrem.HO c xjiop3aMemeHHOH KapGoHOBOH khcjiotoh, (HanpHMep c XJIOpMypaBm>HHOH KHCJIOTOH, XJIOpyKCyCHOH KHCJIOTOH, ΧΠΟρηρΟΠΗΟΗΟΒΟΗ KHCJIOTOH H XJIOpMaC.TaHOH KHCJIOTOfl), ium C (Mer)-aKpHJIOBOH KHCJIOTOfl.

BjiarozcapH HOBowy cnoco6y yaaerca noJiyqaTb N,N-ztByx3aMemeHHbie npOH3BOZUn>ie β-ΒΜΗΗΟΠρΟΠΗΟΗΟΒΟΗ KHCJIOTbl ΠΟ H3o6peTeHHK> B ΠΟΠΗΟΜ CnOCOGe B JD©e CTajtHH CHHTe3a 6ea o6pa30BaHHa πο6οηηογο nponyKTa. npoayKTbi nojiy^aic>T b 100%-hoh φορΜβ 6e3 paCTBOpHTeJIH. Jļnz HeinpanH3aiiHH N,N-,ziByx3aMeineHHbie npoH3BOūHbie p-aMHHonporoioHOBofi KHCJIOTbl CMeiHHBaJKJT C BOHHblM paCTBOpOM THjīpOOKHCH ΠΙ&ΊΟΗΗΟΓΟ MeTaJEia, rHnpooKHCH mejioHHoaeMejibHoro MeTaJtoa hjih rajīpooKHCH aMMHaKa. B 3aBHCHMOcra ot KOHiieHTpaiiHH h HeflrpaiiH3yK>inero cpeacrBa nojiyHaioT BojiHbie pacTBopbi οτ βα3κογο ko nacToo6pa3Horo. B npejmoTTHTejibHOM HcnojmeHHH ηεπτρaranaurao npoBojurr c opratuinecKHMH ocHORammMH. B KanecTRe opraHwqecKHx ocHOBamiH npHHHMaioT bo BHHMaHHe ocofieHHO nepDH'IIIbie, BTOpHHHbie H TpeTHHHbie aMHHbl. ĪTpHMepOM JUM 3ΤΟΓΟ SBJISIOTCJI ajnauiaMHHbr n ariKaHOJiaMiiHbi. Oco6chho npejinoHHTaiOT DTaHonaMHHbi n inonponaHoJiaMHHbr. HefiTpajTH^iomee cpezicTBO mojkho aodaBJism, Kaκ b KO-nnecTBe, OKBiiBajiefrrHOM Ko.T3iqecTBy κηοιοτμ, τακ ir b necļmuirre. Κοκ vTcaaaHO Bbime, corjiacuo ιποδρετείππο npoH3BO,mibre n,n-.iByx3aMeiueHHofi *-uMiinonpomionoBofi iciīcnoTbi π hx conii na\omrr npiiMeiieime b Ka’iecTBc DMy;rLraiiTOB η cMamīBaTenefi hjih b Ka^ecTBe πιαχπιηιχ κο>κν noBepXHOCTHO-ajcniBHbix BemecTB b cpeacrBa.v mm omhctkh. /ļpyraa o6jiacTb npuMeHemm npe/icraBiiiieT cocrasbi mm rrpnjaHHii BOHoorraJiKHBaiomHX cboMctb κο>κβ. B ocHOBy H3o6peTeHHJi noJioaceHa uenb, pa3pa6oTaTb cnoco6 jum npmiaHiiH πι,αροφοδΗΟίΠΉ κο>κε h nncypaM, KOToptifl mo*ho ocjmecTBiMTb oflHocTajiHiiHO, b bojehoh BaHHe h b 6apa6aHe h c πομοππ,ιο κοτοροΓο mojkho jiocraraTb ozmoBpeMeHHoro yM5imeHHa h cnnoraHoro ΓΗΒροφο6Η3ΗροΒΒΗΗΛ. Ceepx τογο, Hcnojn>3yeMbie BcnoMoraTeiibHBie cpeacrBa λο;ι>κηη no bo3Mohchocth npocro npHroToBiniTbcs, λοιγκηβι 6bITb HeaOpOrOCTOinitHMH H aOCTaTOnHOe CMa3btBaHHe Η ΓΗΧρθφθ6ΗρθΒ3ΗΗε HOJDKHbl aocraraTbca He tojibko b ojmy crajuno o6pa6oTKH, ho h TaioKe c noMombio οχηογο-eanHCTBeHHoro npojryKTa. ΠροτοτΗποm H3o6pereHH5i HBJiaercii HeaioienTOBaHHaa 3aaBKa Ha naTeHT ΦΡΓ 35 29 869 c npHopHTeroM ot 21.08.85 r. BnponeM, λοιεκηο 6brrb hcho, hto yKa3aHHoe onHcaHHe ιποδρβτεΗΗΛ κ HeajcnerrnipoBaHHOH 3anBKe Ha narem ΦΡΓ, κοτοροε KacaeTca CnOCo6bI ΓΉΙφθφθ6Η3ΗρθΒ3ΗΙΙΗ KOJKH H mKyp, He Hy>KHO IlOHHMaTb B KaneCTBe npoTOTima nacToamero H3o6peTemia b tom cMbicire, uto OTUHTHTenbHbie πριπΗΒΚΗ CBbimc y>Ke yKasaHHbix b orpaHHHHTejibHOH qacm n.l φopMyJIbI H3o6peTemm cMonm Gbirb iipnBJie4eHbi b Kanecrae H3BecTHbix mm φορΜγηΗροΒβΗΗ» φopMyJIbI H300peTeHHH. IlpaBfla, b cjiynae cnoco6a Hcnojn>3yerc5i com» N-(C9-C2o-auHJi)-aMHHOKHCJioTbi, oimaKo, 3to HecpaBHHMO co cnoco6oM coraacHO HacroiiineH 3aaBKe, τβκ KaK b cjryqae BbUiOHceHHoro onHcaHHH H3o6pereHH5i κ HeaiaieirroBaHHofi 3agBKe Ha naTeHT ΦΡΓ yKa3aHHaa cora> oijokht b Kanecrae 3Mym>raTopa nnsi οηληκοηοβογο Macjia, b to BpeMJi κβκ b cnyqae HacTOinnero H3o6pereHHa npexriaraeMbie b Η3οδρετεΗΗΗ nponyienbi coniacHO o6mefl φορΜγπε I caMii npencraBJunor co6ofl Πϊ,προφοδ^Ηρ^ιπββ cpencTBO. npeHMymecrrBa npejmaraeMoro cnoco6a no cpaBHeHino co cnoco6oM BbUĪO>KCHHOrO OHHCaHH.H H306pCTeHHH Κ Η€3ΚΙΐεΠΤΟΒ8ΗΗΟΗ 3anBKe Ha naTeHT ΦΡΓ 35 29 869 yKa3aHbi Bbirne: npocroe, HenoporocToamee noxtyqeHHe, nocraromoe CMa3biBaHHe h ΠϋφοφοδΗρΟΒΒΗΗβ B OūHy CTBiUflO οδρβδΟΊΚΗ C nOMOIUbfO ΟΛΗΟΓΟ-βΖΠΙΗΟΤΒβΗΗΟΓΟ npoztvicra. /īanbHeHiiiHe npenMVinecTBa cne^yioT TaioKe H3 nooieiiyioinero TeKcra OnifCaHHH O B03MO?KHOCTHX ΠρΗΜ€ΗεΗΙΜ Η ΚΟΜβΗΗΗρΟΒΟΗΗΛ. -9 LV 11044 H:io6peTemie noacHiieTCJi cnenyioinHMH npHMepaMH: ΠρΗΜερ 1. B Kon6y c MeinanKOH, TepMOMerpoM h χοπο,πιυπ>ΗΗΚοm 3aKJianbiBaioT 534 r (2 μοπ) ojieiuiaMUHa h HarpeBaioT ķo 60*C. B TeqeHHC 30 mhhjh 3axara>iBaK)T 144 r (2 moji) aKpHJioBOM khcjiotm, npmeM TeMnq>aTypa noBbmiacrca npn6jiH3HTejibHo no 90°C. 3aTeM nepeMemHBaioT eme ocrarnbHbie 2,5 nāca npn 90°C. OnpeneneroieM nepBHHHbix ocHOBamii! ycTaHaBJniBaioT nojiHoe npeBpameHHe. ΠροΛγκτ ρεακχχΗΗ oxjia5Knajeox no 70°C h cMcuiHBaEOT HacraMH b 196 r (2 moji) ManenHOBoro aHirmpH/ia. /Ļim aaBepmeHiui peaKiiroi nepeMeuiHBaioT 2 naca πρκ 70-80°C. nojiyqaiOT μοηοβμηα N-onemi-N-(2-Kap6oKcii3THJi) MajieHHOBofl khcjiotm kbk cBeTJioKopinHeByio nacTy.

KiīcnoTHoe nncno: 250 μγ KOH/t

OcTaTO'moe conepnamne ociioBiioro a30Ta: 0,2 mmoji/t JļjiM Hefi'ipajiH3aiiHH 3aKanbiBaJiH ripu 80°C πρκ nepeMeiUHBanHH 122 r (2 moji) M0H03TaH0JiaMHHa. rīoHMgp 2. B cooTBeTcrBHH c npHMepoM 1 npHCoenHHJnor 269 r (1 μοπ) creapHJiaMHHa κ 72 r (1 μοπ) aKpanoBOH KHCJioTbi h npeBpamaiOT peaKiiHOHHjTO CMecb c 98 r (1 moji) ManenHOBoro aHnmpHna. MoHoaMHji N-CTeapHn-N-(2-Kap6oKCH3ran) MaJiCHHOBOH KHCJiOTbi 3aTBep/ieBaeT npH κομηβτηοη xeMnepaType b CBCTJioKOpHTOeBjio nacxy. KncnoTHoe πηοιο: 251 μγ KOH/r

OcraToraoe conepJKaHHe οοηοβηογο a3oxa: 0,32 mmoji/γ

HeihpiajnTaoBajĪH rrpu 100°C c 37,5 r (0,5 μοπ) HaonponaHOJiaMHHa. ITpHMep 3. B COOTBeTCTBHH c npHMepoM 1 npHcoenHHJHOT 486 r (2,0 μοπ) naypHnoKCHnponHJiaMHHa κ 144 r aKpHnoBoft κιιοποτμ (2,0 μοπ) h npeBpamaiOT peaKiinoHHyio CMecb c 196 r (2 μοπ) ManeHHOBoro aHranpHna. Μοηοβμηπ N-jiaypHnoKCHiiponHn-N-(2-Kap6oKCH3THji)ManeHHOBoft κηοποτβι 3aTBepneBaex npH KOMHaTHOH TeMnepaType b TeMHOKopHHHeBjTo, cnenca mjthjto nacTy. KHcnoTHoe «nīcno: 265 μγ KOH/r

OcraToiiHoe co/iepncamie οοηοβηογο aaoTa: 0.3 mmoji/t. npHMCp 4. B cootbctctbiih c npiiMepoM 1 npiicoennHJnoT 785 r aMHHa KOKoeoBoro Macna (3,72 μοπ) conepncamie οοηοβηογο aaoīa: 4.74 mmoji/γ k 268 r aKpunoBOH khcjioti>i (3,72 moji) h npeBpamaioT rrponyKT peaKHHH c 364,8 r (3,72 μοπ) MancHHOBoro aHTHHpHjia. iIojiyqaiOT KpacHOKopHnHeeoe, BbicoicoBKncoe Macno. KHcnoTHoe πηοπο: 290 μγ KOH/r

OcraTOTOoe conepacaioie οοηοβηογο a3oTa: 0,25 μμοπ/γ. JĻīsi HefiTpanjrcaiiHH 3aKam,majiH npH 80°C npH nepeMenmBaHHH 554 r (3,72 μοπ) TpīDTanojiaMmia. ΠρΗΜορ 5. B cooTBeTCTBHH c npHMepoM 1 npHCoenHHjnoT 101 r (1,0 μοπ) reKCHnaMHHa κ 72 r aKpimoBOH KHcnoTbi (1,0 μοπ) h npeepainaiOT προπγκτ peaKHHH c 98 r (1,0 μοπ) ManeimoBoro aHTHiipHna. ΓΤοπνππιοτ MOHoaMHn N-reKCHn-N(2-icap6oKCH3THn)-ManeH-ΙΙΟΒΟΗ KHCnOTbl K'dK CBeTnOKOpHHHeBOe Macno.

KiīcnoTHoe racno: 418 μγ KOH/r

OcTaTonnoe conepncaime ocnoBiioro a30xa: 0,15 mmoji/γ. riPHMg? 6. 534 r (2 μοπ) oneHJiaMHHa HarpeBaiOT no 60°C b KOJi6e, KOTopaa cHaSjKena Meinamcoft, τερΜΟΜβτροΜ η κοποπηπβηηκομ. B Teneraie 30 mhhjtt 3aKanhiBaiOT 172 r (2 μοπ) MeraKpraiOBoft KHcnoTbi, πρκπεΜ TeMnepaTypa noBbimaeTca πρη6πη3ητοπ>ηο no 85°C. Jļnsi nojiyneHHn 3aBepraemLq peaKHHH CMecb nepeMeimīBajOT 3 naca ripu 100°C. OnpeneneHHeM nepBHnHbix οοηοβπηηΑ ycTaHaBJnrBaiOT nonHoe npeepameHHe. 3aīeM oxna>KZiaK)T no 70°C η 3aKanbiBaioT npH 70-80°C 204 r ( 2 μοπ) yKcyyHoro aHninpHna. ΓΤο rrpomecTBini eme 2 nacoB o6pa30BaHHyio yKcycHyio khcjtotv οτγοηηιοτ npH BaKvvMe 20 M6ap. IlonyqaioT N-onenn-N(2-Kap6okch-2-mcTHJDKTHn)aiieTaMHn KaK KopHHHeBoe, npo3panHoe Macno.

KiīcnoTiioe *mcno: 139 μγ KOH/r

OcraTOHHoe conepacamie οοηοβηογο aaoTa: 0,1 μμοπ/γ.

Heflipajnt30BaJtH rrpu 80°C πρκ πομοιπη 112,2 r (2 μοπ) KOH, pacTBOpeHHofl b 2492 r Bonbi· nonyqaioT BonHbai pacrBop c 25% TBepnoro BemecTBa. -//- LV 11044 1'lpnMep 7. Ληοποπιηηο npuMepy 1 267 r (1,0 moji) ojienjiaMHHa npHcoezotHjnoi κ 72 r (1,0 μοπ) ακρπποΒΟΗ KiīcnoTbi. 3axeM npn 90°C ββολητ 148 r (1,0 moji) aHniztpuja φχβπβΒΟΗ KHCJioTbi qacTHMH h nepeMeraHBaioT 3 qaca npn 1003C. MoHoa.vmn N-ojieici-N(2-Kap6oKCH3THJi)<ļ)TajieBOH KHCJioTbi npencTaBJineT JKenroKopOTHeBjio nacrv. 225 μγ KOH/r 0,5 mmoji/γ.

KtrcnoxHoe mhcjio:

Ocxaxoqnoe coaepaKaHHe οοηοβηογο a30Ta: ΠρΗΜΟΡ 8. AHajioraTOo npHMq>y 1 rrpHcoeaJiHjnoT 267 r OJicHJiaMHHa κ 72 r aicpHJioBOH khcjiotm. ripoiiyKT rrpHcoeztHHeHHJī cMeinneator c 55 r 6e3Bomioro Kap6oHaxa Haipna h npH 100° C 3aKam>iBaioT 301 r (1,0 moji) χπορaHTHupH£a ojieHHOBofi khcjiotm npH6.TH3HTejitHo 3a 2 qaca. Eme qepe3 2 qaca acuHjnipoBaHHe 3axaHqHBaioT. O6pa30BaHHyio noBapeHHyio cojn> npoMbiBaioT Boaofi.

KiiciioiHoe qHcno: 94 μγ KOH/r

OcraToqHoe coacpHcaHiie οοηοβηογο a30xa: 0,1 mmoji/γ. ripHMeo 9 AHarionniHO npHMepy 6 npHcoezmHinoT 267 r (1,0 moji) oneHJiaMHHa κ 86 r (1,0 MOJi) ΜβΤaKpHJIOBOfl KHCJIOTbl. nocne npHcoezcHHeHHa ,ao6aBJiaiox κ peaiamoHHoS cmcch 101 r (1,0 moji) TpH3THJiaMHHa h qacTJiMH npn 70-90°C 190,5 r (1,0 moji) xjiopaHnuipHjia napa-χoJIyoJIcyJIbφoκHCJIoτL·I. Flocjie 3axyxaHHH 3K30xepMHqecK0H peajaiHH nepeMemHBaior 2 qaca npH 90°C h 3aTeM npoMbiBaiox cojh> βολοη. Αμηλ N-0Jiemi-N-(2- Kap6oKCH-2-ΜετΗΐΓ3ΤΗΐι)-πΒρΒ-τοπνοπονιΐΒφοκΗοποχι>ι nojiyqaioT ksk TCMHOKopwqHeBoe BH3Koe Macjio. ΚιιοποχΗοε hhcjio: 99 μγ KOH/r

OcxaxoxHoc co^epJKaHiic οοηοβηογο a30xa: 0 mmoji/γ. H^ļjpaicpacHbiH cneiap IĪK: C = 0 1720 cm'1 C = C 1620 0M'*(apoMaxHqccKHH jTJieBOjiopoa) SO2-N 1330 cm-‘h 1170 cm*1 H-iUiepHbm MarHHTHbm penoHaHc: δ 7-8 ππμ apoMaxHqecKHX προτοΗΟΒ. Jļm HeHTpanH3amiH aoāaBJDOOT rrpH 90°C npH ncpcMeuiHBaHHH 105 r ( 1,0 moji) znisTAHonaNuma. nptfAiep 10.

AfuuioainHo ripHMq>y 1 npHcoenHHjnoT 267 (1,0 moji) ojieHJiaMHHa κ 72 r (1,0 MOJI) aKpHJIOBOH KHCJIOTbl.

IlocJie npHCoezmHeHHH iio6aBJiHK>T 53 r (0,5 moji) noponncoo6pa3Horo Kap6oHaTa naipiia ii aaKantraaioT npn 1I0°C 114,5 r (1,0 moji) χπορaHnmpmia μ«ήη-Υιιι>Φοκηοιοώ.ι. JJ/m aonojiHHTCJībHofi peaiaiHH nepeMemHBaiox «ne 2 qaca ρκ 110°C. 06pa30BaHHyio coJib npoMbiBaior eofloft. īlonymaoT aunu N-onewi-N-(2-Kap6o-KCH3THJl)-MeTaHOCyjn^OKHCJIOTĪ>I KSOC TeMHOKOpHqHeByiO nacTy. KHcjioTHoe tocjio: 129 mt KOH/t

OcTaTOTOoe conepjKaHHe οοηοβηογο a30Ta: 0 mmoji/t. HK: C = 0 1730 CM’1 SO2-N 1320 cm'h 1160 cm1. IīpHuep 11. AHajionraHO npHMepy 1 npHcoejmHiiiOT 267 (1,0 moji) oneHJiaMHHa κ 72 r (1,0 MOJI) aKpHJIOBOH KHCnOTbl. nocjie npHcoenHHeHHJi no6aBJi5noT 115 r (1,0 moji) Ν-3ΤΗπΜορφοπΗΗΒ h npn 40-50°C 3aKara>iBaioT 133 r (1,0 moji) TOJiyHJiH30imaHaTa. OcraBJunoT min aonojiHHTejn>HOH peaicuiiH 11a 1 qac h noJiyqaiOT N-oJieHji-N-(2-Kap6oKciiomji)-N- TOJiyiuiMoqeBHHy kek KOpirraeBoe Macjio.

Khcjiothoc hhcjio: 89 μγ KOH/r HK:C = 0 1720 cm’1 N - C= 0 1660 cm·' h 1560 cm·1. C = C (apOMaunca) 1590 cm-1 h 1610 cm1. npHMep 12 AHaJionrao npHMepy 1 npHcoenHHjnor 267 (1,0 moji) 0JieHJiaMHHa κ 72 r (1,0 MOJl) aKpHJIOBOH KIICJIOTBI. flocjie npucoe/omemiH ηοθωιυαοτ 115 r (0,5 moji) N-3THJ^opMaiDiHa h 3aKanbiBaioT npn 40-50°C 99 r (1,0 moji) n-6ymjm3oiiHaHaTa. OcraBJunor Ha 1 qac min . /- LV 11044 nonojiHHTejibHOH peaKHHH h nojiyqaioT Ν-οπεΜΠ-Ν-(2-κΕρ6οκχΗ3·πυι>Ν'-6}ατυι-MoqeBHny κβκ CBemoKopHHHeBoe Macjio.

KncnoTHoe hhcjio: 96,4 μγ KOH/r ΓΙΚ: C = 0 (κιιαιοτα) 1720 cm-1 N - C = 0 1620 cm1 H 1540 cm1. ripHMgp 13 AHanora^Ho npHMepy 1 3arpy>KajEOT 204 r ojieHJiaMHHonporiHOHOBOH KHCJioTbi (0,6 moji) 70 r xjiopyKcycHofi KCHJioTbi (HaTpneBaa cojib, 0,6 moji) 54 r βολμ h 108 r inonponaHOJia h HarpeBaiOT no 80°C, 3aTeM nonyqaioT np03paqHbm pacreop. K 3TOMy pacniopy aaicanbrnaioT 106,6 r 45:-ηογο naipoBoro mejioica (1,2 moji) b Tenemie 45 MHHyT, npiraeM βμκοοπ» peaiaiHOHHoii cmcch noBbnnaeTca. /1οποπηητοπ>ηο nepeMemHBaiOT 4 qaca npH 82°C, 3aieM HeHTpajiH3yiOT KOHiļeHTpHpoBaHHOH cojmhoh khcjiotoh h BbinHBaioT b η36βπόκ BOiibi, npOTeM npoayKT ocaJKZiaeTCii. nponyicr (N-oneHtt-N-Kap6oKCHMeTHJT-aMHHonpoTTHOHOByK>KHCJiOTy) OTjiejijnor h cymaT. KHcnoTHoe hhcjio: 245 μγ KOH/r. BBezceHHbrii b KaqecxBe ηοχοληογο nponjTcra npo^yicr npucoezpmeHHa nojiyqaior anajiont^HO npHMcpy 1 H3 rrpeBpameHH» oneHJiaMHHa c aKpHJioBOH khcjiotoh b 3KBHMOJWpHbIX KOJim6CTBaX. npHMep 14.

Hcnojn>3yioT 267,5 r ojieHJiaMHHa (1,0 moji) h 0,2 r HQME (ΓΗΤφΟΧΗΗΟΗΜΟΗΟΜβΤΗπΟΒΟΓΟ 3<ļ)Hpa). ClOJia 33Κ3ΠΒΓΒ3Κ)Τ ΓφΗ OTUiajKZieHHH JļO TeMnepaTypbi MaKaiMajībHO 70°C 144 r aKpHJioBOH KiicjioTbi (2,0 moji), nocjie qero HarpeBaiOT 3aTeM zto 140°C. HaHHHaa ot 80°C, peaKmm npOTeKaeT 3K30TepMHqecKH η b»3koctt> CHJTbHO noBbnnaeTc». npH6jni3HTejibHO qepe3 10 mhhjt πρκ 120°C cMecb cTanoBHTCJi nacToo6pa3Hoil. 3aieM nepeMemHBaiOT eme 3 qaca πρκ 140°C. npojyi<T (N-0JieHn-N(2-Kap60KCH3THJiaMHJHnp0nH0H0Baa KHCJIOTbl) HMeeT KHCJIOTHOe hhcjio 253 ΜΓ KOH/r. ripHMep 15.

a) B annapaT c MemajncoH 3arpy7KaioT 13,6 r Boan h 22,7 r HaipoBoro mejiona (45%- ηογο) h HarpeeaK>T IIpH6JIH3HτeJIL·Ho no 50*C. ΓΤοτομ πρκ nepeMennfflajiH _ t ,io6aBJunoT 63,7 r MOHoaMH,aa-N-oneHJī-N-(2-Kap6oKCH3THJi)ManeHHOBofī KHCJioTbi rrpilMepHO 1, nOCJie 3ΤΟΓΟ paiMeiIIHBaiOT ϋΟ ΟΛΗΟρΟΛΗΟΓΟ C0CT05IHH5Ī. 6) ripojyKT ii3 φ) ηοποηβιοβο-ήι b HiiHcec.rie;iyK>meii penenType jum H3roTOBJieHHa DūĪtoiionpūuimaeMori icojkii ii ncc^e/ioBami Bū^oorrajnciiBaioiuee ^eiicTBiie:

Ko-aca H3 πικνρ κρνπΗΟΓΟ ooraroro CKOTa:

Τηπ: BoaoHenpoHHuaeMaH

MaTepnaji: KopoBbH raKypbi, MOKpbie, craero UBera, Toramma nocjie CTporaima: 2,0 mm. ripoueHTHbie oaHHbie b nepec^eTe Ha ciporaHHbm Bec. ripoMbiBKa: 300% bozcm 35°C + 0,5% yKcycHOH khcjiotm 1:51 15 mhhjt. *1 οβιβΜΗ. qacxb κοΗκεκιρκροΒβΗΗοδ yKcycHofi khcjiotm h 5 oSbeMH. HaoTefl βολβι. Moionmfi pacreop cnyciHTb. npOMbiBKa: 300% Boztbi 35°C 10 mhhjt. Μοιοιπηη pacTBop CnVCTHTb.

HeHrpajiH3amw: 150% soņbi 35°C

Kpameroie: 2% HepacTBOpeHHoro Na^opMHara 90 mhh. /ļoay5jiHBaHHc: +2% HepacTBopcHHoro KpacHTCJia 15 mhh. +4% HepacTBOpeHHoro TaHHHraHa QF2 30 mhh. + 12% HepacTBOpeHHoro KanrraHa N 60 mhh. npH 8 o6opoTax/MHH b TeqeHHe ηοίη + 250% BO«bi 60°C 10 mhh.

Moiomral pacreop cnycTHTb. FlDOMbiBKa: 300% BOffbl 60° C 10 mhh ΜοιοπϊηΑ pacreop cnycnm>. Γ Himo<bo6H3aroī«: 100% BOflbi 60°C +0,5% aMMHajea 1:51 2 mhh. 1 1 o6beMH. qacTb KOHneHTpHpoBaHHoro βμμηβκβ h 5 o6beMH. nacTefl βοβηι + 6,3% cpeacTBa hjih ΓΗιιροφοδΗΒβηΗΗ no Η3οβρβτεΗΗΐο no npHMepy 15 a 1:51 60 mhh. *1 o6beMH. qacTb npojyKTa h 5 o6i>eMH. qacreH bo^bi. 2 + 0,5% MypaBbHHOH KHcnoTbi 1:5 15 mhh. pH: 3,6-4,0. LV 11044

MoiOimn'i pacTBop CnVCTHTb. 2 X ITDOMblBKH: 300% bobījI 40° C ΠΟ 10 MHHyT. Moiouuīn pacraop crijcniTL. 3aicpcnJiemie: 1 50% BOAbi 40‘C 3% EayxpoM A**, HepacTBopeHHoro, 60 mhh. pH: 4,2-4,8 Μοϊοπτηη pacTRop cnycTīrrb. 3-x noMbiBKH: 300%BOj[bi 20°C πο10μη)τ.

Moioumfi pacTBop cnycTHTb.

Ko>Ky 3a Hoqi> nojtcynmTb Ha K03Jiax, pacT«Hynb, noacynmxb b BaKyyMc (80°C/2 mhh), npoBeTpHTb Ha B03Ztyxe, KOHjHHIHOHHpoBarL·, paaMūTHHTt, pa3rjiazom> (80°C/0,5 mhh). xx) npoziyn>i φηρΜΜ ΒΑΜΕΡ ΑΓ, JleBepKy3CH. ΠεΗβΊροΜβτρ Eamm: (10% ocajncH)

BpeMH rrpoMOKaeMOCTH: >7/>7 qacoB.

BnaronorJiomaeMocTt b %: noore 7 qacoR 9,9/10,4.

Me3ep npoaonLHtie η3Γη6μ: 21924/19207

BjiaronornomaeMOCTb b % nocne npoHOJibHi>ix η3Γη6οβ 8,0/7,1. ΠρΗΜερ 16. Πρhm eHAnii nonyqeHHi.ra no npHMepy 1 βμηπ. B aimapaT c Memamcofi noMemaiOT 30 r bo/p>i h 7 i(HH3onponHJiaMHHa npH xeMnepaxype okojio 50°C, npe^e qeM npH nepeMenmBaHHH bboiuīt opraHHqecKyio φa3y, cocToamyio H3 14 r aMHūa no H306peTeHHK>, 3,5 r aMHHOBOH COim 3<f)Iipa φοοφορΗΟΗ KHCJIOTBI (nOJiyqCHHOH nneRpaiTļemTeM a.Th<ļioji(T 16-18, CMecH >κηρηβιχ crmpTOB tn cHHTe3a I_(Hrirq>a, c P2O5, Mo.iapHoc oTHomerme 3:1, zunnonpominaMraioM zcia Heiripamnaiimi) h 45,5 r χπορπαραφιηια c 40% uenHoro xnopa h pa3MenniBaiox λο ozCHopoaHoro οοοτοληηη. 3xox cocraB npuMCHara b HiDKecjieayiomcH pcucriType juia Η3γοτοβηοηη$ι kotkh

AiIM bOCHHOl'O CHHp>DKeHllH: -/€-

Ko?Ka H3 nncvp κρνπΗΟΓΟ poraToro cKOTa Τηπ: KO>Ka jum eoeHHoro CHapjraceHHa

MaTepnan: KopoBbH uncypbi, Moicpbie cHHero HBera, TOJUHHHa nocne CTporamta: 2,0 mm npoueHTHbie aajiabie b nepecqeTe Ha ciporaHHbii! Bec.

IlpoMbiBKa: 300% βοφι 35°C 0,5% Mj'paBbHHoit khcjiotbi 1:5* 15mhh. X1 oābeMH. qacn» KOHueHipHpoBaHHoft κηοιοίέι c 5 ο6τ>βΜΗ. qacr»MH Boabi.

Moiomral pacreop cnycTHTb.

HefiTpajpnaimg: 100%βολμ 35°C 3% Na-<ļ>opMHara, HepacTBopeHHoro, 15 mhh pH: 4,4 + 0,5% 6HKap6oHaTa HaTpasi 1:10 90 mhh. pH: 4,8

Motoram! pacrreop cnycTHTb. npOMbiBKa: 300% Boati 30°C 10 mhh.

Moioamfi pacreop cnycTHTb.

ūoirvOnHBaHHe: 200% BOffbi 30°C 1 % KpacHTejia 1:20 20 mhh + 4% HepacTBopeHHoro TaimraHa ^ 30 mhh. (QP) + 12%KBe6paxo, HepacTBopeHHoro 60 mhh. ABTOMairnca b xeqeHHe HoqH noKofi/BpameHHe 15 mhh/1 mhh. +200% BOjībi 60°C 20 mhh.

MotoiiīHif pacreop cnycrHTb. npoMbEBKa: 300%Boabi 60°C 10 mhh.

Moionmfi pacTBop cnycnrn>.

ΓΗΐτροφο6Η3ΒΐπΐΗ: 200% ΒΟφΐ 60°C 10% cpeacTBa ota nmpo<ļ>o6H3aHHH no npHMepy 16, paaSaBJieHHoe βολοη b OTHomeHHH 1:5 (o6i>eM/o6beM) 60 mhh. + 1% MypaBbimoH KHCJiOTbi 1:5“ 15 mhh. -//- LV 11044 + l% 06beMH. qacn> KOHIlCHTpHpOBaHHOft KHCJIOTbl H 5 o6"beMH. qa<rreH Bonbi + 3% EafixpoMa MF, HepacTBopeHHoro, 60 Mira. pH: 3,6-3,7.

Moiouhih pacrBop cnycTim>. 3 x npoMbiBKii: Moiounul pacrBop cnycTHTb. rTpononacKHBaHHe: 300% BOūbi

Bona

25°C no 10 MHHyT.

20°C

10 MHHyT

Ko*y 3a ηοηβ noncynnm> Ha K03Jiax, pacTXHyrb, noncynnrn» b BaKyyMe (80°C/3 mhh), ripoBeTpiiTb Ha B03nyxe, pa3MnrqHTb, pa3rjianjrn> (80°C/0,5 mhhjt). **rīponyKTbi φκρΜΗ EAH3P ΑΓ, JīeBepKy3eH. neiieipoMeTp Baroni (10% ocanrai)

BpeMH npoMOKaeMocra: >420/>420 mhhjt.

BnaronornomaeMocTb b %: 12/14, 29785/25971 nocne 7 qacoB:

Me3ep rrpononbHbie H3ra6bi

BnaronorjioinaeMOCTb b %: nocne npononbHbix η3Γη6οβ 10/12. rtpHMep 17. а) 3arpyacaioT 30,5 r Bojcbi h 5,5 r HaTpoBoro menoica 45% b armapar c MeraajncoH npn reMnepaxype okojio 50°C. Πρκ nepeMeuiHBaHHH Me/oieHHO ββολητ opraHHqecKyio φa3y) cocToqmyK> H3 18 r aMHna npHMepa 1, 40 r BbicoKOianwmero MHHepanbHoro Macna η 6 r HHMeTHjmojiHCHJiOKcaHa c bjokoctmo 350 Mnya3.ceK, 3aTeM paaMeiraroaioT no Ο,ΤΗΟρΟ^ΗΟΓΟ COCTOHHHJI. б) Cocrae H3 a) Hcnonb30BajiH b peneirrype no npHMepy 16 h oh naBan cne,nyiomHe pe3yjn>TaTbi: ncHeTpoMerp Baroni (10% ocanKH)

BpeMS npoMOKaeMocTH: >420/>420 mhhjt.

BnaronornomaeMocTb b %: nocne 7 qacoe: 7/8,

Meaep 48123/48316 9/8. npOJOniHtie H3ni6bl B;tnrononroinaeMOCTb b %: riOCie npOJO-ThHb!X Η3ΓΗ6θΒ

IlpHMep 18. ΠρHMeH5WH aMHH no H3o6pCTeHHK> H3 npHMepa 1. B aimapaT c Memamcofi 3arpyacaioT 39 r βολμ c 3 γ 45%-ηογο HaTpoBoro menoKa npH TeMnepaīype οκοπο 50°C. Flocnc 3Toro ββολητ opramnccKyK> H3 6 r aMima npHMepa 1, 6 r capK03ima oneHHOBofi khoiotu, 40 r BticoKOKHnamero MHHepajītHoro Macna h 5 r OTMeTHJinoJiHCHJioKcaHa c βλ3ΚΟ£γπ>κ> 350 m nya3.ceK MenjieHHo npH nepeMenmBaiiHH h roMoreHH3HpyiOT. riojiyHeHHBiH TaKHM nyTCM ηροπγκτ πρΗΜαηποτ b pcueirrype BOiioHeiipoHHuaeMofi kohch no npHMepy 16 6), npHHeM 6bum nonyqeHi>i cneiiyiomHe BeJDTHHHBi:

HeHeipoMeip Bamra (10% ocajucH) >420/>420 mhhjt. 9/10, 29885/30147 14/11,6.

Bpe.Ma npoMOKamur BnarononiomaeMOCTb b %: nocrce 7 *iacoB:

Me3q> npoztojibHBie η3Γη6βι BnaronoraomaeMOcrb b %: īlOCJie ΠρΟΛΟΠΒΗΒΙΧ Η3ΓΗ60Β ripHMep 19. а) B aimapaT c Memamcofi 3arpjoKaioT 39 r bozo>i h 4 r HaipoBoro menoKa, 45%-iioro, npn TeMnepaxype οκοπο 50°C. ΠρΗ nepeMetUHBaHHH bboaht opraroineocjio φβ3^ cocrojnnyio H3 12 r aMima no npHMepy 4, 35 r BbicoKOKHnjnnero yrneBoaopo^a, 5 r itHMCTHJmOJDICHJIOKCaHa H C BJI3KOCTbIO 100 Mnya3.CGK H 5 Γ ΗβΠΟΠΗΟΓΟ 3<j)Hpa φοοφορΗοκ khcjiotbi (am^ona 12-18, npeBpameHHoro c P2O5, MonapHoe oraonieHHe 3: 1) h nepeMeiiMBaioT no onHoponnoro cociosaum. б) B peuenType, npHMeHeHHofi no npHMepy 16, 6βιπη £0CTHTHyn>i cnezcvronme BemraiHbi: ΠίΗίτροΜβτρ Baroni (10% ocazocn)

BpeMa npoMOKaHHa: >70/>7 mhhvt. LV 11044 13,3/12,0. 15849/16717 12/8.

RnaronorjiomaeMocrb b %: nocrre 7 qacoB:

Me3ep npOiiO.TUIIjIC Η3Πΐ6ίΛ BnaronornomaeMocTb b %: nocne ΓφΟΛΟΗΒΗΒΙΧ Η3ΠΐβθΒ ΠρΗΜφ 20. npHMeHsjm ormcaHHbifi b npHMepe npo«yicr. 20 r 3τογο Bemecraa 3arpy*anH b annapaT c MemanKoft, c 68,4 r xjiopnapa4>HHa c 40% ueimoro XJiopa h nepeMemHBanH npH 100- 105°C RO ΟΛΗΟρΟΛΗΟΓΟ COCTOBHHfl. ΠθΟΚ OXJia>KaCHHiī npH6nH3HTCJIbHO RO 70°C κ cMecH ^oOaBJismi 11,6 r 2HH3onponaHOJiaMHHa juir HefiTpanH3diiHH. 3tot cocraB npHMenajiH b HiDKeciie^yiomeH peuerrrype ®ia mroTOBJieHHa BoztoHenpoHHiiaeMOH ko>kh h HccīrezīOBajiH Ha ero neficraHe:

MaTepnan: κοροΒΜΐ nncypbi, MOKpbie, cHHero izpēra, TonmHHa nocJie crporaima: οκοπο 2,0 MM. ripoueHTHfaie ztaHHbie b nepec«ere Ha crporaHbifi Bec.

HpoMbiBKa: 300% βοπβι 35°C 0,5% yKcycHofi KHcnoTbi 1:5 15 mhh.

Moionmfi pacTBop cnycTHTb.

Hcfiip ami3 aoM: 100% Bonbi 35°C 2% φορΜΗΒτπ Harpnn, HepacTBopeHHoro, 15 mhhjt, + 0,5% 6HKap6oHaTa Haipna 1:10 90 mhh.

Moiomjie pacTBOpbi - pH: 5,3. rionepenHbiH pa3pe3 kojkh προτΗΒ 6poMKpe3on3eneHoro rony6oro.

Moionmfi pacTBop cnycTHTb

ITpoMbiBKa: 300% BOHbl 30°C 10 MHH. Moioiiihh pacTBop cnycTHTb. KpanieHHe: 100% BO£bI 30° C /ļony6nHBamie: 1% nepHofi KpacKH nna xpoMoeofi kotkh TU 141%

1:20 20 MHHyT + 4% TaunraHa QF** HepacTBopeHHoro, 30 mhhjt + 12% HepacTBopeHHoro KBe6paxo npn 6 o6opoTax/MHHyTy b tc^chhc Homi, -j.0- rTpojy6jieHHe + 200°/obohi>i MoioimiK pacTBOp cnycniTL>. npOMblBKa: 300% ΒΟΛΜ Morommi pacreop cnycTHTb. Γ ιντροφοδιηβιρτίτ: 100% βοληι 3aicpcn:iemie:

60° C

60° C

60° C 8% cpeaciBa min ΓΠ£ροφο6Η3αιιιπι + 1 % MypaBbHHofl KiicjioTbi 1:5 20 MHHyr. 10 MHH. 1:4 60 MimyT 15 MHH.

+ 3% EafixpoMa F 60 MHHyT

Moionme pacreopbi - pH: 3,6-3,7.

Moiomra! pacreop cnycTHTb. 3 x npoMbiBKH: 300%BOflw 25°C no 10 mhhjt.

MoromHfi pacTBop cnycTHTb.

Ko>Ky 3a Hom> noa:cyinHBaioT Ha K03Jiax, pacTSTHBaiOT, noacymHBaioT b BaKyyMe (80-85°C, 2 MHHyrbi), προβετρΗΒβιοτ Ha B03ayxe, yBjia*HinoT, pa3MHTHaioT, pa3rjiaHCHBaioT πρκ BaKyyMe (80-8 5° C, 30 ceKyua). Bo epeM# pa6oT b ΜοκροΜ coctojihhh He 6bmo c^ejiaHo ηηκβκηχ HCKjnoqirrejibHbix Ha6niojeHHH. neneipoMeip Bajum (10% ocazīKH)

BpeMa npoMOKaeMocra: >7/>7 qacoB

BjiaronornomaeMOCTb b %: nocne 7 qacoB: 13,1/8,2.

Maeser: npoaojn>Hbie H3ra6bi 15407/14320

BjiarononiomaeMocTb b %: nOCJie ΠρΟΛΟΗΒΗΒΙΧ Η3ΠΐβθΒ 7,7/5,0.

IlpHMepbi 21-25 25 r cocaHHCHHa o6mefi φopMyπbI 1, 25 r BbicoKOKHnamcro MHHcpanbHoro Maora h Heo6xoztHMbie zdih HeftTpajiH3aiiHH κηοιοτηοΑ rpvnnbi KomraecTBO TpH3TāHOJiaMHHa CMeiiTHBaioT η πρκ 60°C 3MynbrHpyioT b 200 r βοχο>ι. 3th cocraBbi Hcnonb3yioT b Ka^ecTBe ηυχροφοβΗρνιοπιβΓΟ cpeacTBa b peuenType xexHHqecKoro πρΗΜβΗβΗΗΛ cornacHO npHMepy 16. Pe3yjrbTaTbr HcribrTaHHH npe/icTaBjreHbi b Ta6jnme 1: -ΛΛ LV 11044

Ta6jnnia 1 ripHMep IIcnoOT>3yeMoe coe^nHeHire BaIIy- πβΗετροΜετρ BpeMa ΠρΟΧΟΜζΗεΗΗΛ BOflbI (MHH) 10% cnDKarae nornonzeHHe BOJQ>I, % n. 4aC0B 21 aMHa H3 npHMepa 6 okojio 360 8 6 22 cyjn><ļ)OHaMim H3 npHMq>a 9 23 55 1 23 cyjn><ļ)OHaMna H3 rrpHMepa 10 135 13 1 24 ITpOH3BO,ZXHOe MOqeBHHBI H3 npHMepa 11 48 58 2 25 IipOH3BOflHOe MO^eBHHhl H3 npHMepa 12 10 67 2

/» /V LV 11044 ΦΟΡΜΥΤΙΑ H30BPETEHHŪ l. Cnoco6 ana npunamia BonooTrajiKHBaioniHX cbohctb KoacaM h MexaM, OTnunaioimiHca xeM, qrro coennHeHiia o6mefi φορΜγπΒΐ 1:

R, - Ņ - CH2CH — COOX

A

I R2 b κοτοροβ Ri o6o3Haqaer HacbnneHHbiH mra HeHacbnneHHbifi anKHJDbHBni ocraTOK hjih ajncoKOCHamcHJīBHtifi ocraTOK c 1-22 ετομεμη yrnepoaa, npeanoTnrrejibHO c 12-18 ετομεμη yraepoaa, R2 o6o3Haqaer ajnauibHbifi ocraTOK c 1-18 aTOMaMH yrjiepona, HacbimeHHbifl hjih HeHacbimeHHbrii κερ6οκ<:ηειιε>κηιπ>ηι>ι8 octetok c 3-4 ετομεμη yrnepoaa, hjih ΚΕρ6οκαιφβΗΐηπ>ΗΒΐΗ ocraTOK, hjih Kap6oKCHJitHBiH ocraTOK (-COOH),

Rj o6o3HaqaeT Bonopon hjih CH3 η

X o6o3HaqaeT Bonopon, meaoraoH Mcrajui, mejioHH03eMejn>HtiH Mcrajin, emmohhh, aJIKHJiaMMOHHH HJIH βϋΚΕΗΟΗΗΜΟΗΗΗ H ,p A o6o3HaHaeT >C=0, >SC>2, sq

NH mm ajHauienoBLiH ocraTOK c 0-3 ετομεμη yniepona. b KOJnraecrBe 0,1-25 Bec.%, npeanoarHTejibHO 1-15 bcc.%,: b iiqpec4cre Ha crpoiaHHbm Bec kojkh hjih MOKpbiH eec Mexoe, πρΗ β£εηηηηεχ pH ot 4 ao 9 rrpHBojurr bo B3aHMoneHCTBHe c o6pa6anbiBaeMbiMH kojkemh hjih mcjcemh bo BpeMfl noay6jiHBaHHH hjih nocjie aoay6JiHBaHHa, 3aTeM ycraHaBJiHBaioT ao bcjihhhh pH b o6jiacra ot 3,5 no 5,0 h nocjie o6pa6oTKH 3aKpemwioT b cjiy^ae Heo6xonHMOCTH πρκ noMomH 2-, 3- hjih 4-BajieHTHOH cojiH Merajuia, npennoHTHTeiībHo b bothom pacreope. 2. Cnoco6 πο π. 1 oTJmnaioimīHca TeM, hto msi npunaHHa BonooTTajiKHBaiomHX CBOHCTB npHMeH5E£0T npOnyKT, KOTOpbrii COnepJKHT 5-80, ΠρβηΠΟΉΉΤε.ΤΒΗΟ 10-70 Bec.% coenHHeHHH o6ihch φopMyπbl I, npeanoHTHTejibHo no MCHbmcfi Mepc h aacnniHO HeRipajiH30BaHH0H φορΜε, b cjivnae Heo6xonHMOCTH 20-70, npennoqTHTeJibHO 30-60

Bec.% vTJieBoaopozioB, b cnyqae Heo6xoAHMocni areHTbi pacrBopeHHa h ocraTOK zto 100% BOTU. 3. Cnoco6 no 0AH0My m n.1-2, oTnnnaiominicii TeM, «ito BBeAeHHoe cpeACTBO jsjīsi npimaHiia BojiooTTajiKiiBaiomiix cbohctb coacp>kht HenonHbie οφπρΜ φοοφορΗοι! KIICJIOTbl CIlHpTOB C ZŪDIHOH UenH OT C4 ΛΟ C20, ΠρΟΛΠΟΉΉΤεΠΒΗΟ Ci6-Ci8, KOTOpbie B cnyqae hco6xoahmocth oKcajncHjajīpoBaHbi, b KOjnmecTBax ot 0,5 ao 30, npeOTotrrHTenbHO οτ 1 η,ο 20 eec.%, b nepeqceTe Ha 100 r BBeAeHHoro cpeacraa ajw ΠρΗΛβΗΗΗ BOZtOOiraJIKHBaiOmHX CBOHCTB.

4. Cnoco6 no oaHOMy H3 n.1-3, oTmraaionmfica TeM, ato cpeacTBO jum npHAaHHS

BoaoorrajiKHBaiomHX CBoftcrB coflep)KHT cHHHKOHOBbie Macjia, npejmoqTHTejn>HO OTMeTHJi- hjih μ βτΗπφ eHHimojiHCHJioKcaHbi b KomnecTBax οτ 0,5 no 80, npe.zmoqTHTejn.Ho 1-10 Bec.%, b nepecnere Ha 100 r BBeAeHHoro cpeACTBa jum npHjtaHHa b o ao o rrajiKHB aK»mnx cbohctb. 5. Cnocos ΠΟ OAHOMy H3 n. 1-4, OTJZHHaiOIHHHCH TeM, ΤΓΟ CpCACTBO jum ΠρΗΑΒΗΗΛ BOAooTTajiKHBaionīHX cboIIctb coAep»arr ot 0,5 ao 50, πρβΑΠΟΏΉΤβπΒΗΟ οτ 2 ao 20 Bce.% capK03HAa onenHOBOH khcjiotm b nepenceTe Ha 100 r cpeACTBa jum npHAaHHS BOAOOTTaJIKHBaiOniHX CBOfiCTB. 6. Cnoco6 no OAHOMy H3 n.1-5, oTirHsaioniHHCs TeM, hto cpeACTBO jum npnAaima ΒΟΑΟΟΤΤβΑΚΗΒΕΙΟΠϊΗΧ CBOHCTB COAepHOīT Πβρ3φΗΗΒΙ Η/HJIH ΧΑΟρΠβρΒφΗΗΒΙ. LV 11044 AHHOTAURfl

PfaoopereHHe othochtcs k npHMCHemnocoejiHHeHHH oGuiefl φορΜγ/Ήΐ I /

R,- Ņ- CH2CH — COOX

A

I R2 b κοτοροΗ Ri o6o3Haqaer HacbimeHHbiū hjih HCHacbimeHHHia ajnarabHBie ocraTOK hjih ajiKOKOCHajncHjrbHbiH ocraTOK c 1-22 axoMaMH yrnepojca, npeano^THTejibHo c 12-18 aTOMaMH jrnepozca, R2 o6o3Haqaer arrKHJībHiiH ocraTOK c 1-18 βτομβμη yniepojia, HacbimeHin>m hjih ΗεΗΒΟΒίπιεΗΗΒίδ ΚΕρβοκεΗβϋΒΚΗπΒΗϋβ ocraTOK c 3-4 aTOMaMH yrjiepo.ua, καρ6οκοκφεΗΗ3ΐΒΗΒΐδ ocraTOK hjih KapGoKCHJībHbifi ocraTOK (-COOH),

Rj o6o3Haqacr βολορολ hjih CH3 η

X o6o3Haqaer Bonopon, mejio'iHOH McranJi, menoqH03eMejibHbiH Mcrajui, βμμοηηη, aJUCHJiaMMOHHfi HJIH aJIKaHOJiaMMOHHH, H

A o6o3HaqaeT >C=0, >S02 hjih ajncHJieHOBbril ocraTOK c 0-3 aTOMaMH C, b Ka^ecrae 3MyjibraTopoB, CMaHHBaTCJiefi, noBepxnocTHO-aKTHBHbix BemecTB b cpencTBax ohhcikh, a TaioKe jpia nojiyqeHH« cpencrB, npHnaiomHX BonooTTarncHBaiomHe cBOHcrea κοτκε.

Claims (6)

1. LV 11044 IZGUDROJUMA FORMULA 1. Hidrofobo īpašību piešķiršanas paņēmiens ādām un kažokādām, kas atšķiras ar to, ka savienojumu ar vispārējo formulu I R3 R, — N — CH2CH — COOX I A R2 kurā R-ļ apzīmē piesātinātu vai nepiesātinātu alkilatlikumu vai alkoksilatlikumu ar 1-22 oglekļa atomiem, ieteicams ar 12-18 oglekļa atomiem, R2 apzīmē alkilatlikumu ar 1-18 oglekļa atomiem, piesātinātu vai nepiesātinātu karboksilalkilatlikumu ar 3-4 oglekļa atomiem, vai karboksilfenilatlikumu, vai karboksilatlikumu (-COOH), R3 apzīmē ūdeņraža atomu vai CH3-grupu un X apzīmē ūdeņraža atomu, sārmu metāla, sārmzemju metāla atomus, amonija, alkilamonija, vai alkanolamonija grupu, un A apzīmē > C=0, > SO2, — c vai alkilenatlikumu ar 0-3 C-atomiem, 0,1-25 masas %, ieteicams 1-15 masas %, rēķinot uz nošķeltās ādas masu vai mitrās kažokādas masu, pie pH vērtības no 4 līdz 9 pakļauj mijiedarbībai ar apstrādājamām ādām vai kažokādām miecēšanas laikā vai pēc tās, pēc tam noregulē pH robežās no 3,5 līdz 5,0 un pēc apstrādes nostiprina vajadzības gadījumā ar 2-, 3- vai 4-vērtīga metāla sāli, ieteicams ūdens šķīdumā.
2. 2. Paņēmiens pēc 1 .p-ta, kas atšķiras ar to, ka lai piedotu hidrofobas īpašības, pielieto produktu, kas satur 5-80 masas %, vēlams 10-70 masas %, savienojumu ar vispārējo formulu I, vēlams vismaz daļēji neitralizētā formā, nepieciešamības gadījumā 20-70 masas %, vēlams 30-60 masas % ogļūdeņražu, nepieciešamības gadījumā šķīdināšanas aģentus un pārējo līdz 100% ūdeni.
3. 3. Paņēmins pēc 1. vai 2. p-ta, kas atšķiras ar to, ka hidrofobo īpašību veidošanai ievadītais līdzeklis satur fosforskābes mono- vai diesterus ar spirtiem ar ķēžu garumu no C4 līdz C2o> vēlams C-|6*Cl8> kuras nepieciešamības gadījumā ir oksialkilētas, apjomā no 0,5 līdz 30 masas %, vēlams no 1 līdz 20 masas %, rēķinot uz 100g ievadītā līdzekļa hidrofobo īpašību veidošanai.
4. 4. Paņēmiens pēc viena no 1 .-3. p-tiem, kas atšķiras ar to, ka hidrofobo īpašību veidošanas līdzeklis satur silikonu eļļas, ieteicams dimetil- vai metilfenilpolisiloksānus apjomā no 0,5 līdz 80 masas %, vēlams 1-10 masas %, rēķinot uz 10Og hidrofobo īpašību veidošanai ievadītā līdzekļa.
5. 5. Paņēmiens pēc viena no 1 .-4.p-tiem, kas atšķiras ar to, ka hidrofobo īpašību veidošanas līdzeklis satur no 0,5 līdz 50 masas %, vēlams no 2 līdz 20 masas % oleīnskābes sarkozīdu, rēķinot uz 100g hidrofobo īpašību veidošanai ievadītā līdzekļa.
6. 6. Paņēmiens pēc viena no 1 .-5. p-tiem, kas atšķiras ar to, ka hidrofobo īpašību veidošanas līdzeklis satur parafīnus un/vai hlorparafīnus.