LV11044B - Tanning process for chemical treatment of skins and pelts by using organic agent - Google Patents

Abstract

A process for the preparation of compounds of the formula I <IMAGE> in which R1 denotes a saturated or unsaturated alkyl radical or alkoxyalkyl radical having 1 - 22 carbon atoms, preferably 12 - 18 carbon atoms, R2 denotes an alkyl radical having 1 - 18 carbon atoms, a saturated or unsaturated carboxyalkyl radical having 3 - 4 carbon atoms, a carboxyphenyl radical or a carboxyl radical (-COOH), R3 denotes hydrogen or CH3 and X denotes hydrogen, alkali metal, alkaline earth metal, ammonium, alkylammonium or alkanolammonium and A represents <2bL>C=O, <2bL>SO2, <IMAGE> or an alkylene radical having 0-3 C atoms, which is characterised in that alkylamines of the formula R1-NH2, in which R1 has the meaning described above, are added to (meth)acrylic acid and the resulting N-alkylaminopropionic acids are reacted with carboxylic anhydrides, carbonyl chlorides, sulphonyl chlorides, isocyanates, halocarboxylic acids or (meth)acrylic acids and are then optionally at least partially neutralised. Novel N-alkyl-N-(2-carboxyethyl)sulphonamides and N-alkyl-N-(2-carboxyethyl)ureas are additionally described.

Description

LV 11044 ciiocoK oupasotku ko * u μεχοβ

OnHcaHHe

IboopeTeinie othochtch κ npuMenemno Nr, N ^ By3aMemeHHbi c β-aMHHonpormo-HOBbl. \ KHCJIOT B KaHCCTBe 3MyJIbraHTOB, CMA ^ HBaTeaeH, nOBCpXHOCTHO-aKTHBHbIX Bemecra b cpejicTBax jum ooictkh h HJM npnjiaHiM BonoorraJEKHBaiomHK cbohctb KOJKaM h MexaM.

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Tpe6yeMa «from cnoco6y ri0JiyqeHiM crajiua OMbUieraM npHBOjurr κ TOMy, hto npojiyKTbi mojkho noJivnaTb kbk 100% -Hoe Bemecreo munimco b pacreope η He 6e3 najibHeHinHx TexHOJioniqecKHX cranHfi. 06pa30BaHHeM 3KejhTHHH3HpyroinHX cTpyicryp mojkho nojiyqaTb b Boae munimco 20-30% Hbie pacTBopbi nacro6pa3HOH kohchctchhhh. Tojibko coBMecTHbiM npHMeHeHHeM cimpTOB, κοτοροε HeBbiroaHo, KomieHTpamM mohcct noBbimaTbca npH6jm3HTeJibHO Ha 50%. TAK KAK oMbuieHHe npoBOjnrr b CHJībHO mejioHHofi o6jiacrH, npojiyKTbt noaie peryjmpoBaHHH the bcjihhhh pH ot 5 of 8, KOTOpbie Tpe6yioTca mia μηογηχ npHMCHCHHH, HanpnMep b oojiacra tckcthjm, hmciot BbicoKHc coaepJKaHHii cojih, KOTOpbie oimaKO qacro sbjmiotch HOKejiaTenbHbiMH. Πρκ npHMeHeHHH TBepai &gt; ix ajnciuiaMHHOB npHcoejcHHeHHe κ npoH3Boano.My aKpmioBofi KHCJIOTbl cjieayer npoBOHHTb npn noBbimeHHbix TeMnepaTypax (Bbirne tohkh nrraBJieHJM amamaMUHa) bcjicjictbhc qero πρκ peaxmioHHOcnoco6Hbix ajcpmioBbix npoH3BoztHhix vcKopjnoT HOKCJiaTejibH ^ TEO no6oTOyro peaicmno oGpaaoBaHHH iniazuiyKTOB. Πριι rroii ποδο'ΐΗοΓι peaKUHH BTopyro MO / ieKyny aKpunoBoro npoHOBOzmoro npHcoejjiH.OOT κ y &gt; Ke oopa30BaHHOMy npoH3BojHOMy N-ajncHJiaMHHonponHOHOBOH kiic.'iotli, npii'ieM oopa3yercji Tpenruibul a.MHH, KOTopbiii He Μθ &gt; κετ oojibuie aipijDipoBaTbCH bc, ie, ayiomeH cTaznin cnHTe3a.

HaKOHeu, Bpejnioe BjmaiiHe OKaabiBaeT TaiOKe 3anax ocTaTOHHbix coziepMcaHHH aKpmioBoro 3φΗρβ hjih aKpHJiHHTpHjia b προζιγκτβ. Tajc, MOTKHO οτΗβτχαίΒΟ omymaTb ocTaTOTOoe coziepjKaHHe 0.1% aKproioBoro 3φπρα. H3o6pereHHe othochtch, cneaoBaTenbHO, κ cnoco6y jum npnjiaHHa BOJtOOTTaJHCHBaK &gt; MHX CBOHCTB KO 'e H MexaM ΓφΗ npHMeHeHHH HOBbIX COeHHHeHHH CaMHX of ce6e mm b cmcch c apyrHMH H3Becrm &gt; jum IMH cpejicTBaMH npnaamm BoaoorrajiKiiijaiomnx cbohctb.

BoaoHenpoHHnaeMyio KOJKy noiryqaiOT, b ochobhom, no CJienjroimiM myu cnocoSaM: 1.

BoiīOHepaCTBOpHMbie BemeCTBa, ΚβΚ e.g. JKHpbl, ΠΒρΒφΗΗΜ, Bock hjih onpezteneranjie nojniMepbi, noKa3bmaioT npn stom He &gt; KeJiaTejibHoe convrcTBViomee iTBJieHiie, b qacTH0CTH, OKa3bmaioT oipraiaTejibHoe Bjramnie Ha BajKHbie zum yao6cTBa hockh cBoficTBa BO3, ayxonp0HHiiaeMOCTH h naponpoHHuaeMOCTH. BjiaronpHaiHee eeziyT ce6ii coefficients / nraeHHH, KOTOpbie Ha6yxaioT 6ji arabic norhHHio Bozibi h teM caMbiM iMeCeBeHHORO HaHyxaHna h co6cTBeHHoro yruioTHeHHa bojiokoh ko &gt; kh. IlpHMCHeHHbie from 3TOMy MeToziy npoayKTbi othochtcji k THny 3Myjn & rat0p0B boil &amp; b Macne (WI0). 2.OrganicBeCeBeMoBeMe. 3Myjn &gt; raTopbi, KOTOpbie MoryT o6pa30BaTb KOMnneKCHbie coeūHHeHiifl c MHOrOBajieHTHbIMH HOHaMH MCTaTnOB (ΚΒΤΗΟΗΒΜΗ) MOiyr BO ΜΗΟΓΗΧ CJiyTJaaX BXOZIHTb Taioicc b īcoMiuieKcnoe coezomemie xpoMa-KOJinareHa ii Bbi3biBBTb b dtom cnynae πυροφοδΗ3αισπο. ΠοΛοδΗΒίε 3MynbraTopbr CBaabiBaioTca xiiMiraecKH c NoHyRHMH xpoMOBOMy hjih aJioMHHHeBOMy ziy6; HHKKHaMHaMH kojkh h CHHJKaiOT Gnaioaapa ΓΗΛροφοόΗΟΜΥ nOKpblTHIO CMaHHBaCMOCTb H BOHOnorJIOmaeMOCTb. CHIDKeHH pacHrHYHyH cnoco6HocTH Bbipa ^ aeTca b o6pa3oeaHHH mapoo6pa3Hbix Kanejib (3φφ α · BOUOTOJIKHBaHHJl). - 3 LV 11044

CmībHO fromBbicHBUineca 3a nocjiezmee BpeMfl Tpe6oeaHH5i κ πο, ΠΒφΠψτοΗ ΠΙ.Τρθφθ6Η3,3ΙΙΗΙΙ KO &gt; K? ΠΟ'ΙΤΪΙ Henb3H HOCTtirHVTb HJIH MOJKHO JOCTHrHVTb TOJIbKO B enep6 jpvniM τακτκ? βαγκημμ οβοΓιοτβαμ πριι πομοιιιη H3BecTHbix MeTOiBi &lt; l) Oūji3aujiix. Βφ.χιυιο κο &gt; ιαι j, tsi noBcejnieBHofi hockh ζοίχιμ wrote Bbinomixn &gt; tokhč τρεδοΒΟΗΐΐΛ, KOTopbie HccKonbKo ner tomy haaai nņezbsanjimi το; π &gt; κο κ (ļiopM &gt; jiHpHOH kojkc (the / kc jmsi BoeHHoro CHapsDKeHHa) He orKa3bmaHCb o / MAICO ot yno6cTBa hockh, μοληογο BHna h ap. Πο 3Toh NPH ^ HCE npHaepJKHBanHCb, e.g. aByxcraaH0HOH ΓΗΖφθφθ6Η3ΗΙΙΗΗ. Γ oTOBbie BbicymeHHBie hjih oTaejiaHHbie kohkh mojkho λοποπηητ "π &gt; ηο o6pa6aTbraaTb pacTBopeHHBiMH b opraHHqecKHX pacrBopHTejwx οιπηκοηοβμμη MacnaMH. BpeaHoe Bjmamie OKa3bmaeT NPH stom xpe6yeMaa jum CMaqHBaHH3 TeMnq) ATYP cynncH MOKny 90 ° C hjih 100 ° C, KOTopaa npHBoam: κ 3HaqHTejiBHbiM ποτερκΜ pa3MepoB. KpoMe τογο, npeacraBJiaer npo6jicMy BbicoKoe kojiotcctbo opraHiraecKHx pacTBopHTJieH, κοτοροβ c6pacbmaeTCJi b OKpjoComment q &gt; eay.

Oco6eHHo H »KenaTejibHWM b cCommon paHHOHanbHoro npoH3BoacTBa jranaercs tot φηκτ, ίτο aonojiHHTfJībHaa o6pa6oiKa CBjnaHa c nonojimrrejibHOH, HesfcejiaTejibHOH pa6oqen crajuien. rio3TOMy 3aaaqefi H3o6peremui aBJisuiocb TajoKe pa3pa6oxKa cnocooa jum ΠυφθφθβΗ33ΚΗΗ KOJKH H MCXOB, KOTOpbIH MO) KOH ΠρΟΒΟΛΗΠ "B OflHy pa6oqyiO CTaflHIO, b bozchom solution of h b 6apa6aHe, η NPH πομοιιιη κοτοροτο mojkho nocraraTb OŪHOBpeMeHHO JKHpOBaHHH Η BbICOKOH Π« φθφθ6Η33ΙΙΗΗ. KpOMe ΤΟΓΟ, πρΗΜeHeHHblC BcnoMoraTCJibHbie cpejicTBa motkho nojiyqaib bo3mo & kt ndome h ohh Hejtoporne, npHqeM taocTHraioT nocraToqHoro «κροΒβΗΗΛ h nocraToqHofi ΓΗΐιροφο6Η33ΠΗΗ He TOJIbKO B CTaJDffl OTUCJIKH, HOHC OJOHHM npoayKTOM. 3Ty 3ajaqy pEngMeHeHHeM coennHeHHH o6mefl φopMyJπ &gt; I 1: R3 /

R, - N - CHiCH - COOX

I

A

I R, BAD 01 - - ν · β κοτοροΗ Ri o6o3HaqaeT HacbniieHHtii! hjih HeHacbimeHHtifi arncHJībHbiH ocraTOK hjih ajrKOKCHajiKHjrbHbiii οοτατοκ c 1-22 aTOMEMH yrjiepona, npennoqTHTeJibHO c 12-18 aTOMa.Mii vrnepojia, R: oooaua'iaeT arnauibHbUi ocraTOK c 1-18 aTOMaMii yrjiepoaa, HacbimeHHbrii tab in HeHacbimeHHbm κ about 6 ok chamaun.Hbrfi ocraTOK c 3-4 aT om3mh yrnepoaa, καρβοκαιφε-HH-1bHblii OCTaTOK HJIH KapSOKCHJIbHblH OCTaTOK (-COOH),

Rj o5o3HaqaeT Bonopoji hjih CHj h

X o6o3HaqaeT Bojiopon, Meijoraofi MeTarui, mejioHHOseMejibHbift Measured, emmohhh, aJUCHJiaMMOHHH HJIH ΕΠΚΕΗΟΠΕΜΟΗΗΗ H

P A o6o3HaqaeT &gt; 0 = 0, &gt; SC &gt; 2, sq

NH hjih anKHJieHOBbiH ocraTOK c 0-3 ετομεμη is an epoote. ΠροΛγκτΒΐ of H3o6peTeHino nphmemnoT hjih HenocpejicTBCHHo b hx of MeHbmefi mepe gacTiraio HeHTpajnnoeaimoH φορΜε Kaκ cojiepacammi HeMHoro bojuj npoajrcr b 6ojn &gt; inHHCTBe cjiynaeB nacToo6pa3HOH kohchctchiihh Juul ΓΗαροφο6Η3βιΐΗΗ, hjih HCH € HipajiH30BaHHbie, b 6ojibiuHHCTBe cjiyqaeB nacToo6pa3Hbie npojiyKTbi pacrBopaioT b yriieBoziopoaax h / hjih b xjiopnpoH3Bojmbix jTJieBonopoaoB b cjiynae Heo6xonHMOCTH nocpencTBOM areiiTOB pacreopemni, h 3aTeM from Mem &gt; Mepe nacnnmo HefirpanH3yiOT. Wt 3τογο Hcnojn.3yror ocHOBamnr, oco6chho opraHHecKHe nepBHHHbie, BTopHTObie h TpeTH'iHbie βμηηβι h β, πκβηοπβμηηβι, τβισκε Boj0Q &lt; tb &gt; 3Myjn &gt; rHpyiomee theyScTBHe HefrrpanH30BaHHbix npoayKTOB nooJJJrrJiyqaTL Taione BoaocoaepHcamHe npojijKTbi.

CoeHHHeHHM ΠΟ H306pereHHK) ΒΒΟΛΜΤ B KOJIHHCCTBC OT 0.1 KO 25, OTHHYJHHO οτ I of 15 Become% b nepecnere Ha crporaHHHiH eCkHhHHHHH MOKpbiH Bec MexoB πρκ pH-Bem * nmax Μοκζιγ 4 h 9, nocjie qero BejnnmHa pH cHHHcaerca 3 , 5-5.0, hb cjiyqae Heo6xonHMocTH 3aKpenjiaiOT πρκ πομοπιη 2-, 3- hjih 4-BaJierHoil cojih MeTaJDia. ripHMeHeHHbifi jum ΓΗίτροφοδΗααιΐΗΗ COCTaB of Η3θ6ρβΤεΗΗΚ) CO / iepJKHT nejiecoo6pa3Ho 5-80 Bec.% npennoTnrrenbHo - 10-70 Bec.% of coejnmeHHH H3o6peTemno o6men φορ \ ψ; π &gt; I ι, b ciiyqae Heo6xojiHMOCTH 20-70 Bec%, npcimoTTHTejibHO 30-60 Become% yrneBo ^ opo: oB hAuih xjiopnpoH3BOOTwx yrjicBonopoaoB, bc: iyqae hco6xo; EN 11044 Χοτ "YWE πρκ πομοιιιη οαηιιχ coeziHHemra of H3o6peTeHmo / iocmraiOT οτ.τπμηογο &gt; KiipoBaiiH5i h otjdihhoh ΓΠ / φοφοοιπαιχΗΗ, cpeacTBa ΓΗίΐροφοδίηαηΗΗ of ιηοδρετεΗίπο mohcho npiiMemiTb BMecre c inBecrabiMii epencTBa.MH JJM / KirpoeaHmi 11 / 11.ui cpe ^ CTBaMii πυφοφο6Η3αηηπ, κοκ 'iacrinubie οφιιρΜ φοοφορΗοπ κιιογιοτη,

CnJDIKOHOBblH 0apKO3lU OJieiIHOBOH KHCJIOTBI h / hjih (ΧΙΙθρ -) - ΠαρΕφΐΙΗΒΙ. riūCKonbKy npHMeHaioT qacTHiiHbie οφηρΒΐ φοοφορΗοη khcjiotbi, npeunomiTaioT Henomībie 3φηρί &gt; ι cnnpTOB c λπηηοη Nenni ot C4 of C20 πρβΛΠΟΏΉΤοπι, ΗΟ Cie-is, KOTopbie b cjiyqae ΗεοδχοΛΗΜοσίΉ OKcamcHjmpoBaHbi, b KOjmqecTBax ot 0.5 nº 30 Bec.% npeOToqTHT &amp; m &gt; HO 1-20 Bec%% (unreached Ha 100 rs ct CTBa ΓΗΖιροφο6Η3βιΐΗΗ).

CoBMecTHoe npHMeHeHHe κηοιβιχ 3φηροΒ φοοφορΗοη khcjiotbi mojkho ocymecTBJi5m &gt; tbkhm o6pa30M, ητο hx bbojdit BMecre c coeuHHeHjniMH no H3o6pereHmo, roeBJinTi η ταατΜΜajiiiii3333333333 BM BMec BMecre c nocJiemniMH. ΘφιιρΒΐ φοοφορΗοη khcjiotbi Moryr npHMeH ^ TbCH τβισκε b ρκε HeirrpajiH30BaHHOH φορΜε. npHMeHemie 3φκροβ φοοφορΗοη khcjiotbi npenjiaracrcji, HanpHMep, jum CHiDKemts 3KcrpanipyeMoro conep &gt; KaHH ^ JKHpa; 3TO npencraBJiHer rrpeHMjmecTBo ocoGemio y ko &gt; kh oyHCZIbi BCJieacTBHe ynyTmieHHOH Sjiaronapu 3TOMy ctohkocth k jchmhhcckoh ohhctkc. riocKOJiBKy ΛοποπΗΗΤβΠΒΗΟ κ coe®meHHJiM no H3o6pereHHio πρΗΜβΗΗΐοτ CHJiHKOHOBBie Macjia, nocjiezurae HcnonB3yioT b KOjmqecTBax 0,5 0.5 jo 80 Bec. B Kanecrae chjihkohobbix Maceii mojkho npHMeHaTb KOMMepnecKHiHiHiIiKcaHBi, KaK hhmcthj-hjih Mejnu ^ eHHJinojiHCHJioKcaH. ΠρειιποΗΗΤβιοτ o6jiacrH B5T3KOCTH OT 100 JJO 500 MHJIHHnya3 / ceK. ΠρΗ 3TOM CHHHKOHOBOe MaCJIO C COef1HHeHHeM No H3O6HereiBbozwt b cjiyqae hco6xoi [hmocth BMecre cjjOuOuOuMH h / hiH cYJJpOpOH3BOaHBIMH JTJieBOJIOpOflOB HJffl ΒΓβΗΤΒΜΗ paCTBOpeHHH. ΠρΗΜβΗεΗΗε chjihkohob cjijokht npennoHTHTejibHO yisi nocnDKeHHH onpenejieHHBix HcejiaTejiBHBix nOBep.XHOCTHBIX 3φφθΟΌΒ, KaK HarrpHMep HOKHOCTH juma KOJKH. Yi iumbiiemnero yjiyqmeHiia mstkocth h hto6bi aocmrHyTb 6onee jiaipHoro Γρκφ3 mojkho iipHMeHirrB TaioKe capK03tm ojieHHOBoft khcjiotbi. 'IroGbi λοογηγητπ »onpenejieHHBix 3φφεκτοΒ, mojkho BOo6me npuMemm» jno6yio KOMČHHamno in HenojiHBix 3φΐΐρθΒ φθϋφθρΗΟΗ KHCJIOTBI, CHJHKOHOBOro MaCJia H CapK03Hu OJieHHOBOfl KHCJIOTbl c coezcHHeHHsiMH no H3o6pereHHK &gt;. - ε

CapKcmm ojichhoboh KHCJIOTbl mojkho npHMeHSTb nonojiHHTejibHo κ coejimeHHHM no rnoopoTeHINO b KOJm »izTBax ot 0.5 Already 50 Bec.% Npenno'mnejihno 2-20 Bcc. r) (b πορεοηετε Ha 100 r BBejeHHoro cocraea).

Cočjjihchhc oomon φορΜ) τπ &gt; [I no; iyyiaīot tcm, ητο ajiKiiJiumibi river 40-130 ° C npejnommejiBHO npn 70-100 ° C, npHCoejHHinor κ (Mer) callsHJioBOH khcjiotc. Xotji ComnoHeHTbIt is a CMemHBaHHa cymecTBy »&gt; T κβκ opraHKraecKaa com., NpHcoejHHeHne 3aKaHHHBaeTCH nepe3 1-4 naca h jomiraeT ποπηογο npeBpameHHH. 06pa30BaHHH jHajmyKTOB πρπ 3thx ycnoBHax headKiniH He HaGjnojaioT. They Tpe6yeTca TaioKe npuMeHeraie pacreopirrenji. ΠρΗ aMHHax c slogan Scratch HiDKe Taκ Ha3biBaeMbix TeMnepaTyp pearamH npeBpameHHe npOBozurr rrpejnoīTHTejibHO noj jaBJieHHeM, HanpHMep b aBTOKJiaBe. npeBpameHHe ajnouiaMHHa c (MeT) aKpHJioBoft κκαιοτοίί npoHcxojHT npe / moMTHTeJTbHO κ 3KBHMOJurpHbix KOJinnecTBax. B KaqecTBe επκηπβμηηοβ ģopMynbi R1-NH2 MoryT npHMeHHTbca, e.g. arejvToniHe nepBHHHbie aMHHbi: MeTHJiaMHH, nponHnaMHH, 6yTHJiaMHH, reKCHJiaMHH, HOHimaMim, jeimnaM hh jojemuiaMiiH, TpHjerinnaMHH, H30TpHjeiiHJiaMHH, neKcajeiZHJiaMHH, OKrajemuiaMim, nponoKcnnponnjiaMHH, oKTHJiOKCHnponHJiaMHH, oneiuiaMHH, oJicnjioKCHiipomuiaMHH, JiaypHJiaMHH, βμηη Cocoboto Macna, creaptuiaMHH, bmhh cana hjih cMecH BbinieHa3BaHHbix βμηηοβ. OcooeHHo npeanonTHTejibHbiMH βμηηβμη jibjijiotcs JiaypHJiaMHH, βμηη kokocoboto Macna, bmhh cana h oneHnaMHH. JayjieHeinue npeBpameHHe N-Amora-N- (2 -Kap6oKCH3ran) -MHHOB npoBOjurr c ΒΗΓΗΖφΗΚΒΜΗ, Η30ΙΙΗΒΗΒΤΒΜΗ, XJIOpaHTHJpHJiaMH Kap6oHOBOit KHCJIOTbl ΗΠΗ xjiopaHrHjpHjaMH cyjn ^ OKHcnoTbi, eam pem &gt; HjeT 06 amuiHpoBaHHH. MρΗ TCMneparypax 50-100 ° C amuiHpyiomee cpejcTBo πρΗΜειυποτ b 3KBHMOJiapHbix KOjnrqecTBax already HeSontmoro H36bmca (οκοπο 5%).

HEALTHCASE aHTHjipHjaMη ηπη η30ιιηηηβτβμη 3aKaHqHBaeTc «qepe3 1-2 naca h mer Tpe6yeMbie N-amcHn-N- (2-Kap6oKCH3THn) -MHjb b 100% φορΜε. ΠρΗ npHMeHeHHH κηρβοΗΟΒοίί KHCJIOTbl, HanpHMep yKcycoro aHTHjpHja, ncn qaiomyioca b 3KBHBaneHTHOM KOjnmecrBe MOHOKap6oHoeyio KHcnoTy οτπε.τηιοτ neperoiiKon io ripoMLiBKofi boozo. B KanecTBe aHnmpnjoB Moryr 6bm &gt; Ha3Bam &gt; KaK rrpHMepbi: yKcycHbiii aHnmpHj, aHnurpnj nporoioHOBOH κηοιοτμ, aHnmpHn MacjumoH κκαιοτω, aHrmrpHj ManemiOBOH KHCJIOTbl, aHnmpHJ 5iHTapHOi! KHCJIOTbl, annupuzi φτα / ΙϋΒΟίί KHCJIOTbl. LV 11044 B KanecTBe InHaBeRHHHMMaoB BHHMaHHe, HanpHMep. 6yTHjnt30iHaHaT (rojivH.THSoLuianaT, tnonponHmnouHonaT. II Βτορ) το crajuno peaKmiH, t. e. headKmno anHJmpoBaHHJi, npOBOjun · npcarro'iTnTe.Ti iio c oKBiMiMiBiMiKOJnmecTBaMii KOMnoHeHTOB headKIN.

Ecjdi's headKLuao amunipoBam npoBOjurr c xJiopaHrHztpn, aaMH καρδοΗΟΒοΓι Kiy; iorbi hjhi c xjiopaHrHobbnMH cyJH ^ oKHCJioTbi, το b Ka ^ ecTBe CBK3bBaK &im; 06pa30BaHHyK &gt; BO BpeMa peajCUHH COJIb MOJKHO OT (L &gt; HJIbTpOBbIBaTb HHH BbIMbIBaTb ΒΟΛΟίί. B Ka ^ ecTBe npHMepoe jpia JūiopaimiiīpmioB Kap6oHow &gt; H KHcnoTbi mo &gt; kho Ha3Ban &gt;: xjiopaHrnapna yKcycHOH KHCJioTbi, xjiopaHrajipHn προπποΗΟΒΟΗ khcjiotbi, XJIOpaHTHJipH ^ i MaCJUfflOH KHCJIOTbl Η ΠΟΛΧΟΛΗΠΤΗβ XJI0paHTHflpHZEbI CyJΠ &gt; φ0KHCJI0TbI , HanpHMCp XJIOpaHTHJypHH MeTaHCyHbφoKHCJ ^ OTbI) XJ10paHTHZipHa 3TaHCyjn ^ OKHCJIOTbI, xjiopHnurpnn napa-Tonvojicvjn ^ oKHCJioTbi. ^ AnBHemiiee rrpeBpameHHe o6pa30BaHHOH N-ajncHJiaMHHonponHOHOBOH khcjiotm MOJKHO npOBOiUITb TaiOKe C raJTOHiPaMemeHHbIMH Kap6oHOBblMH KHCJIOTaMH, npejļTTO'mrrem.HO c xjiop3aMemeHHOH KapGoHOBOH khcjiotoh (e.g. XJIOpMypaBm c &gt; HHOH KHCJIOTOH, XJIOpyKCyCHOH KHCJIOTOH, ΧΠΟρηρΟΠΗΟΗΟΒΟΗ KHCJIOTOH H XJIOpMaC.TaHOH KHCJIOTOfl) ium C (Mer ) -aKpHJIOBOH KHCJIOTOfl.

BjiarozcapH HOBowy cnoco6 yaaerca noJiqaTb N, N-ztByx3aMemeHHbie npOH3BOZUn ie ie β-ΒΜΗΗΟΠρΟΠΗΟΗΟΒΟΗ KHCJIOTbl ΠΟ H3o6peTeHHK &gt; B n CnOCOGe B JD © e CTiHH CHHTe3a 6ea o6pa30BaHHa πο6οηηογο nponyKTa. npoayKTbi nojiy ^ ur Tb 100% -hoh φορΜβ 6e3 paCTBOpHTeJIH. Jnn HeinpanH3aiiHH N, N-, ziByx3aMeineHHbie npoH3BOūHbie p-aMHHonporoioHOBofi KHCJIOTbl CMeiHHBaJKJT C BOHHblM paCTBOpOM THYPOOKHCH ΠΙ & B 3aBHCHMOcra ot COPHYHHHH HHFlrpaiiH3yK inero cpeacrBa nojiyHaioT BojiHbie pacTBopbi οτ βα3κογο by nacToo6pa3Horo. B npejmoTTHTejibHOM HcnojmeHHH ηεπτρaranaurao npoBojurr c opratuinecKHMH ocHORammMH. B KanecTRe opraHwqecKHx ocHOBamiHpHHHMaioT BHHMaHHe ocofieHHO nepDH'IIIbie, BTOpHHHbie H TpeTHHHbie aMHHbl. TCPHMepOM JUM 3ΤΟΓΟ SBJISIOTCJIUnHaMiHiHiMiHiMiHi. Oco6chho npejinoHHTaiOTa DTaHonaMHHbi's inonponaHoJiaMHHbr. HefiTpajTH ^ iomee cpezicTBO mojkho aodaBJism, Kaκ b KO-nnecTBe, OKBiiBajiefrrHOM Ko.T3iqecTBy κηοιοτμ, τακ are b nonspeeds. Κοκ vTcaaaHO Bbime, corjiacuo ιποδρετείππο npoH3BO, MIBRO n, n-.iByx3aMeiueHHofi * -uMiinonpomionoBofi iciīcnoTbi π hx CONI na \ omrr npiiMeiieime b Ka'iecTBc DMY; rLraiiTOB η cMamīBaTenefi hjih b Ka ^ ecTBe πιαχπιηιχ κο &gt; κν noBepXHOCTHO-ajcniBHbix BemecTB b cpeacrBa .v mm omhctkh. / buttercup o6jiacTb npuMeMeNe / icraBiIt cocrasbi mm rrpnjaHHii BOHoorraJiKHBaiomHX cboMctb κο &gt; κβ. B ocHOBy H3o6peTeHHJi noJioaceHa uenb, pa3pa6oTaTb cnoco6 jum npmiaHiiH πι, αροφοδΗΟίΠΉ κο &gt; κε h nncypaM, KOToptifl mo * ho ocjmecTBiMTb oflHocTajiHiiHO, b bojehoh BaHHe h b h c 6apa6aHe πομοππ, ιο κοτοροΓο mojkho jiocraraTb ozmoBpeMeHHoro yM5imeHHa h cnnoraHoro ΓΗΒροφο6Η3ΗροΒΒΗΗΛ. Ceepx τογο, Hcnojn &gt; 3yeMbie BcnoMoraTeiibHBie cpeacrBa λο; ι &gt; κηη of bo3Mohchocth npocro npHroToBiniTbcs, λοιγκηβι 6bITb HeaOpOrOCTOinitHMH H aOCTaTOnHOe CMa3btBaHHe Η ΓΗΧρθφθ6ΗρθΒ3ΗΗε HOJDKHbl aocraraTbca He tojibko b ojmy crajuno o6pa6oTKH, ho h TaioKe c noMombio οχηογο-eanHCTBeHHoro npojryKTa. ΠροτοτΗποm H3o6pereHH5i HBJiaercii HeaioienTOBaHHa 3aaBKa Ha naTeHT ΦΡΓ 35 29 869 c npHopHTeroM ot 21.08.85 r. BnponeM, λοιεκηο 6brrb HCHO, whereby to yKa3aHHoe onHcaHHe ιποδρβτεΗΗΛ κ HeajcnerrnipoBaHHOH 3anBKe Ha narėms ΦΡΓ, κοτοροε KacaeTca CnOCo6bI ΓΉΙφθφθ6Η3ΗρθΒ3ΗΙΙΗ KOJKH H mKyp, He Hy &gt; KOH IlOHHMaTb B KaneCTBe npoTOTima nacToamero H3o6peTemia b tom cMbicire, uto OTUHTHTenbHbie πριπΗΒΚΗ CBbimc y &gt; Ke yKasaHHbix b orpaHHHHTejibHOH qacm nl φopMyJIbI H3o6peTem cMonm Gbirb iipnBJie4eHbi b Kanecrae H3BecTHbix mm φορΜγηΗροΒβΗΗ »φopMyJIbI H300peTeHHH. IlpaBfla, b cjiynae cnoco6a Hcnojn &gt; 3yerc5i com "N- (C9-C2o-auHJi) -aMHHOKHCJioTbi, oimaKo, 3to HecpaBHHMO co cnoco6oM coraacHO HacroiiineH 3aaBKe, τβκ CEC b cjryqae BbUiOHceHHoro onHcaHHH H3o6pereHH5i κ HeaiaieirroBaHHofi 3agBKe Ha naTeHT ΦΡΓ yKa3aHHaa Cora &gt; oijokht b Kanecrae 3Mym &gt; raTopa nnsi οηληκοηοβογο Macjia, b to BpeMJi κβκ b cnyqae HacTOinnero H3o6pereHHa npexriaraeMbie b Η3οδρετεΗΗΗ nponyienbi coniacHO o6mefl φορΜγπε I Cami npencraBJunor co6ofl Πϊ, προφοδ ^ ^ Ηρ ιπββ cpencTBO. npeHMymecrrBa npejmaraeMoro cnoco6a of cpaBHeHino co cnoco6oM BbUĪO &gt; KCHHOrO OHHCaHH.H H306pCTeHHH Κ Η € 3ΚΙΐεΠΤΟΒ8ΗΗΟΗ 3anBKe Ha naTeHT ΦΡΓ 35 29869 yKa3aHbi Bbirne: npocroe, HenoporocToamee noxtyqeHHe, nocraromoe CMa3biBaHHe h ΠϋφοφοδΗρΟΒΒΗΗβ B OūHy CTBiUflO οδρβδΟΊΚΗ C nOMOIUbfO ΟΛΗΟΓΟ-βΖΠΙΗΟΤΒβΗΗΟΓΟ npoztvicra. / IanbHeHiIHiNeMeVinecTBa cNiOiTiOke H3 nOiIiYiNiOn TeKcra OnifCaHHH O B03MO? KHOCTHX ΠρΗΜ € ΗεΗΙΜ Η ΚΟΜβΗΗΗρΟΒΟΗΗΛ. -9 LV 11044 H: io6peTemie noacHiHiCiNiNiNHH npHMEPMH: ΠρΗΜερ 1. B Kon6y c MeinanKOH, TepMOMerpoM h χοπο, πιυπ &gt; B TeqeHHC 30 mhhhh 3axara &gt; iBaK) T 144 r (2 moji) aKpHJioBOM khcjiotm, npmeM TeMnq &gt; aTypa noBbmiacrca npn6jiH3HTejibHo no 90 ° C. 3aTeM nepeMemHBaioT eme ocrarnbHbie 2.5 came npn at 90 ° C. OnpeneneroieM nepBHHHbix ocHOBamii! ycTaHaBJniBaioT nojiHoe npeBpameHHe. JiaροΛγκτ ρεακχχΗΗ oxjia5Knajeox no 70 ° C h cMcuiHBaEOT HacraMH b 196 r (2 moji) ManenHOBoro aHirmpH / ia. / Liim aaBepmeHiui headContact nepeMeuiHBaioT 2 naca πρκ 70-80 ° C. nojiyqaiOT μοηοβμηα N-onemi-N- (2-Kap6oKcii3THJi) MajieHHOBofl khcjiotm kbk cBeTJioKopinHeByio nacTy.

KiīcnoTHoe nncno: 250 μγ KOH / t

OcTaTO'moe conepnamne ociioBiori a30The following: 0.2 mmoji / t JijiM Hefi'ipajiH3aiiHH 3aKanbiBaJiH Pipe 80 ° C πρκ nepeMeiUHBanHH 122 r (2 moji) M0H03TaH0JiaMHHa. royalHMgp 2. B cooTBeTcrBHH c npHMepoM 1 npHCoenHHJnor 269 r (1 μοπ) creapHJiaMHHa κ 72 r (1 μοπ) aKpanoBOH KHCJioTbi h npeBpamma headKiiHOHHYTO CMecb c 98 r (1 moji) ManenHOBoro aHnmpHna. MoHoaMHji N-CTeapHn-N- (2-Kap6oKCH3ran) MaJiCHHOBOH KHCJiOTbi 3aTBep / eBaeT npH κομηβτηοη xeMnepaType b CBCTJioKOpHTOeBjio nacxy. KncnoTHoe πηοιο: 251 μγ KOH / r

OcraToraoe conepJKaHHe οοηοβηογο a3oxa: 0.32 mmoji / γ

HeihpiajnTaoBajĪH rUrr 100 ° C c 37.5 r (0.5 μοπ) HaonponaHOJiaMHHa. ITpHMep 3. B COOTBeTCTBHH c npHMepoM 1 npHcoenHHJHOT 486 r (2.0 μοπ) naypHnoKCHnponHJMHH κ 144 r aKpHnoBoft κιιοποτμ (2.0 μοπ) h npeBpamaiOT headChinaHHyio CMecb c 196 r (2 μοπ) ManeHHOBoro aHranpHna. Μοηοβμηπ N-jiaypHnoKCHiPonHn-N- (2-Kap6oKCH3THji) ManeHHOBoft κηοποτβι 3aTBepneBaex npH KOMHaTHOH TeMnepaType b TeMHOKopHHHeBjTo, cnenca mjthjto nacTy. KHcnoTHoe «nicno: 265 μγ KOH / r

OcraToiiHoe co / camcorder οοηοβηογο aaoTa: 0.3 mmoji / t. npHMCp 4. B cootbctctbiih c npiiMepoM 1 npiicoennHJnoT 785 r aMHHa KOKoeoBoro Macna (3,72 μοπ) conepncamie οοηοβηογο aaoīa: 4.74 mmoji / γ k 268 r aKpunoBOH khcjioti &gt; (3.72 μοπ) MancHHOBoro aHTHHpHjia. iIojiyqaiOT KpacHOKopHnHeeoe, BbicoicoBKncoe Macno. KHcnoTHoe πηοπο: 290 μγ KOH / r

OcraTOTOoe conepacaioie οοηοβηογο a3oTa: 0.25 μμοπ / γ. Will HepiTanjrcaii HH 3aKam, MajiH npH 80 ° C npH nepeMenmBaHHH 554 r (3.72 μοπ) TpīDTanojiaMmia. ΠρΗΜορ 5. B cooTBeTCTBHH c npHMepoM 1 nPHCoHHYNT 101 r (1,0 μοπ) reKCHnaMHHa κ 72 r aPeBOH KHcnoTbi (1,0 μοπ) OT OT OTρ προπγκτ headKHHH c 98 r (1,0 μοπ) ManeimoBoro aHTHiipHna. ΓΤοπνππιοτ MOHoaMHn N-reKCHn-N (2-icap6oKCH3THn) -ManeH-KHCnOTbl K'dK CBeTnOKOpHHHeBOe Macno.

Quitthoe racno: 418 μγ KOH / r

OcTaTonnoe conepncaime ocnoBiorior a30xa: 0.15 mmoji / γ. riPHMg? 6. 534 r (2 μοπ) oneHJiaMHHa HarpeBaiOT from 60 ° C b KOJi6e, KOTopaa cHaSjKena Meinamcoft, τερΜΟΜβτροΜ η κοποπηπβηηκομ. B Teneraie 30 mhhjtt 3aKanhiBaiOT 172 r (2 μοπ) MeraKpraiOBoft KHcnoTbi, πρκπεΜ TeMnepaTypa noBbimaeTca πρη6πη3ητοπ &gt; ηο no 85 ° C. Yelts nojiyneHHn 3aBepraemLq peaKHHH CMecb LESS THROUGH 3 naca pips 100 ° C. OnpeneneHHeM nepBHnHbix οοηοβπηηΑ ycTaHaBJnrBaiOT nonHoe npeepameHHe. 3aEmM Oxna &gt; KZiaK) T 70 ° C η 3aKanbiBaioT npH 70-80 ° C 204 r (2 μοπ) yKcyyHoro aHninpHna. ΓΤο rrpomecTBin em 2 nacoB o6pa30BaHHyio yKcycHyio khcjtotv οτγοηηιοτ npH BaKvvMe 20 M6ap. IlonyqaioT N-onenn-N (2-Kap6okch-2-mcTHJDKTHn) THEME KaK KopHHHeBoe, npo3panHoe Macno.

KiīcnoTiioe * mcno: 139 μγ KOH / r

OcraTOHHoe conepacamie οοηοβηογο aaoTa: 0,1 μμοπ / γ.

Heflipajnt30BaJtH Rust 80 ° C πρκ πομοιπη 112.2 r (2 μοπ) KOH, pacTBOpeHHofl b 2492 r Bonbi · nonyqaioT BonHbai pacrBop c 25% TBepnor BemecTBa. - // - EN 11044 1'lpnMep 7. Ληοποπιηηο npuMepy 1 267 r (1,0 moji) ojiajiaMHHa npHcoezotHjnoi κ 72 r (1,0 μοπ) ακρπποΒΟΗ KiīcnoTbi. 3axeM npn 90 ° C ββολητ 148 r (1.0 moji) αβπβΒΟΗ KHCJioTbi qacTHMH h nepeMeraHBaioT 3 qaca npn 1003C. MoHoa.vmn N-Ojieici-N (2-Kap6oKCH3THJi) &lt; t) TajieBOH KHCJioTbi npencTaBJineT JKenroKopOTHeBjio nacrv. 225 μγ KOH / r 0.5 mmoji / γ.

KtrcnoxHoe mhcjio:

Ocxaxoqnoe coaepaKaHHe οοηοβηογο a30Ta: ΠρΗΜΟΡ 8. AHajiorao npHMq &gt; y 1 rrpHcoeaJiHjnoT 267 r OJicHJiaMHHa κ 72 r ppHJioBOH khcjiotm. ripoiiyKT rrpHcoezHHeHHJi cMeinneator c 55 r 6e3Bomioro Kap6oHaxa Good h npH 100 ° C 3aKam &gt; iBaioT 301 r (1.0 moji) χπορaHTHupH £ a oHieHHofof khcjiotm npH6.TH3HTejHo 3a 2 qaca. Eme qepe3 2 qaca acuHjnipoBaHHe 3axaHqHBaioT. O6pa30BaHHyio noBapeHHyio cojn &gt; npoMbiBaioT Boaofi.

KichiiiHoe qHcno: 94 μγ KOH / r

OcraToqHoe coacpHcaHiie οοηοβηογο a30xa: 0,1 mmoji / γ. ripHMeo 9 AHarionniHO npHMepy 6 npHcoezmHinoT 267 r (1.0 moji) oneHJiaMHHa κ 86 r (1.0 MOJi) ΜβΤaKpHJIOBOfl KHCJIOTbl. nocne npHcoezcHHeHHa, α6aBJiaiox κ mainHHoS cmcch 101 r (1.0 moji) TpH3THJiaMHHa h qacTJiMH npn 70-90 ° C 190.5 r (1.0 moji) xjiopHnuipHjia napa-χoJIyoJIcyJIbφoκHCJIoτL · I. Flocjie 3axyxaHHH 3K30xepMHqecK0H HeadsHH nepeMemHBaior 2 qaca npH 90 ° C h 3aTeM npoMbiBaiox cojh &gt; βολοη. Αμηλ N-0Jiemi-N- (2- Kap6oKCH-2-ΜετΗΐΓ3ΤΗΐι) -πΒρΒ-τοπνοπονιΐΒφοκΗοποχι &gt; nojiyqaio ksk TCMHOKopwqHeBoe BH3Koe Macjio. ΚιιοποχΗοε hhcjio: 99 μγ KOH / r

OcxaxoxHoc co ^ epJKaHiic οοηοβηογο a30xa: 0 mmoji / γ. H1JpicpacHbiH cneiap ILK: C = 0 1720 cm -1 C = C 1620 0M '* (apoMaxHqccKHH jTJieBOjiopo) SO2-N 1330 cm-1h 1170 cm * 1 H -UuepHbm MarHHTHbm penHaHc: δ 7-8 ππμ apoMaxHqecKHX προτοΗΟΒ. YH HePpanH3amiHoAaBJDOOT rrpH 90 ° C npH ncpcMeuiHBaHHH 105 r (1.0 moji) znisTAHonaNuma. nptfAiep 10.

AfuainHo ripHMq &gt; y 1 npHcoenHHjNT 267 (1.0 moji) oJieHHaMHH κ 72 r (1.0 MOJI) aKpHJIOBOH KHCJIOTbl.

IlocJie npHCoezmHeHHH iio6aBJiHK T 53 r (0.5 moji) noponncoo6pa3Horo Kap6oHaTi niii aa aaChannel npn 1I0 ° C 114.5 r (1.0 moji) χπορaHnmpmia μ «ήη-Υιιι &gt; Φοκηοιοώ.ι. JJ / m aHonGHHTCJibHofi mainHH nepeMemHBaiox «ne 2 qaca ρκ 110 ° C. 06pa30BaHHyio coJib npoMbiBaior eofloft. NON-ONEWI-N- (2-CAP6O-KCH3THJL) -MeTaHOCYJNO OKHCJIOTY &gt; KSOC TeMHOKOpHqHeByiO nacTy. KHcjioTHoe tocjio: 129 mt KOH / t

OcTaTOTOoe conepjKaHHe οοηοβηογο a30Ta: 0 mmoji / t. HK: C = 0 1730 CM'1 SO2-N 1320 cm @ -1 1160 cm @ -1. IipHuep 11. AHajionraHO npHMepy 1 npHcoejmHiiiOT 267 (1.0 moji) oneHJiaMHHa κ 72 r (1.0 MOJI) aKpHJIOBOH KHCnOTbl. nocjie npHcoenHHHHJJ no6aBJi5noT 115 r (1.0 moji) Ν-3ΤΗπΜορφοπΗΗΒ h npn 40-50 ° C 3aKara &gt; iBaioT 133 r (1.0 moji) TOILET H30iHaTa. OcraBJunoT min aHaCe &gt; HOH produCa 11a 1 qac h noJiyqaiOT N-ye Hji-N- (2-Kap6oCiomy) -N- TOJiyiuiMoqeBHHykek KOpirraeBoe Macjio.

Khcjiothoc hhcjio: 89 μγ KOH / r HK: C = 0 1720 cm'1 N - C = 0 1660 cm · 'h 1560 cm · 1. C = C (apOMaunca) 1590 cm-1 h 1610 cm -1. npHMep 12 AHaJionrao npHMepy 1 npHcoenHHjnor 267 (1.0 moji) 0JieHJMHHa κ 72 r (1.0 MOJl) aKpHJIOBOH KIICJIOTBI. flocjie npucoe / omemiH ηοθωιυαοτ 115 r (0.5 moji) N-3THJ ^ opDaHa h 3aKanbiBaioT npn 40-50 ° C 99 r (1.0 moji) n-6 µmol / mlHaHaT. OcraBJunor Ha 1 qac min. / - LV 11044 nonojiHHTejibHOHHKHHH nojiyqaioTH pea-οπεΜΠ-Ν- (2-κΕρ6οκχΗ3 · πυι &gt; Ν'-6} ατυι-MoqeBHny κβκ CBemoKopHHHeBoe Macjio.

KncnoTHoe hhcjio: 96.4 μγ KOH / r ΓΙΚ: C = 0 (κιιαιοτα) 1720 cm-1 N - C = 0 1620 cm @ -1 H 1540 cm @ -1. ripHMgp 13 AHanora ^ Ho npHMepy 1 3arpy &gt; KajEOT 204 rijieHJMHHonporiHOHOBOH KHCJioTbi (0.6 moji) 70 r xjiopyKcycHofi KCHJioTbi (HaTpneBaa cojib, 0.6 moji) 54 r βολμ h 108 r inonponaHOJia h HarpeBaiOT from 80 ° C, 3aTeM nonyqaio np03paqHbm pacreop. K 3TOMy pacniopy aaicanbrnaioT 106.6 r 45: -ηογο naipoBoro mejioica (1.2 moji) b Tenemie 45 MHHyT, npiraeM βμκοοπ »MainlyHOHHoii cmcch noBbnnaeTca. / 1οποπηητοπ &gt; ηο nepeMemHBaiOT 4 qaca npH 82 ° C, 3aeM HHYHYOH KOHItHpHpoBaHHOH cojmhoh khcjiotoh h BbinHBaioT b η36βπόκ BOiibi, npOTeM npoayKT ocaJKZiaeTCii. nponyicr (N-oneHtt-N-Kap6oKCHMeTHJT-aHHonpoTTHOHOByK &gt; KHCJiOTy) OTjiejijnor h cymaT. KHcnoTHoe hhcjio: 245 μγ KOH / r. BBezceHHbrii b KaqecxBe ηοχοληογο nponjTcra npo o yicr npucoezpmeHHa nojiyqaior anajion ^ HO npHMcpy 1 H3 rrpeBpameHH »oneHJiaMHHa c aKpHJioBOH khcjiotoh b 3KBHMOJWpHbIX KOJim6CTBaX. npHMep 14.

Hcnojn &gt; 3yioT 267.5 rHiMHHMa (1.0 moji) h 0.2 r HQME (ΓΗΤφΟΧΗΗΟΗΜΟΗΟΜβΤΗπΟΒΟΓΟ 3 &lt; l) Hpa). ClOJia 33Κ3ΠΒΓΒ3Κ) Τ ΓφΗ OTUiajKZieHHH O M M n n n epa epa epa y y y y y 70 ° 70 ° ° ° ° ° ° ° ° ° 144 144 144 144 144 144 144 r r r r r r r 144 144 OH OH OH bi HaHHHaa 80 ° C, headKmm npOTeKaeT 3K30TepMHqecKH η b »3koctt &gt; CHJTbHO noBbnnaeTc ». npH6jni3HTejibHO qepe3 10 mhhjt πρκ 120 ° C cMecb cTanoBHTCJ nacToo6pa3Hoil. 3aieM nepeMemHBaiOT eme 3 qaca πρκ 140 ° C. npojyi &lt; T (N-0JieHn-N (2-Kap60KCH3THJiaMHJHnp0nH0H0Baa KHCJIOTbl) HMeeT KHCJIOTHOe hhcjio 253 ΜΓ KOH / r.

a) B to let c c MemajncoH 3arpy7KaioT 13.6 r Boan h 22.7 r HaipoBoro mejion (45% - ηογο) h HarpeeaK &gt; T IIpH6JIH3HτeJIL · Ho no 50 * C. ΓΤοτομ πρκ nepeMennfflajiH_t, io6aBJunoT 63.7 r MOHoaMH, aa-N-oneHJ-N- (2-Kap6oKCH3THJi) ManeHHOBofi KHCJioTbi rrpilMepHO 1, nOCJie 3ΤΟΓΟTheMiHiBiOt ϋΟ ΟΛΗΟρΟΛΗΟΓΟ C0CT05IHH5I. 6) ripojyKT ii3 φ) ηοποηβιοβο-ήι b HiiHcec.rie; iyK &mt; meni penenType um H3roTOBJieHHaïtoitoi ïuū ï ï ïori Mori icojkii ii ncc ^ e / ioBami Bee ^ oorrajnciiBaioiuee ^ neicTBiie:

Ko-aca H3 πικνρ κρνπΗΟΓΟ ooraroro CKOTa:

Τηπ: BoaoHenpoHHuaeMaH

MaTepnaji: KopoBbH raKypbi, MOKpbie, craero UBera, Toramma nocjie CTporaima: 2.0 mm. ripoueHTHbie oaHHbie b nepec ^ eTe Ha shoeHHbm Bec. RIPMbiBKa: 300% bccm 35 ° C + 0.5% yCcHHOH khcjiotm 1:51 15 ml / ml. * 1 οβιβΜΗ. qacxb κοΗκεκιρκροΒβΗΗοδ yKcycHofi khcjiotm h 5 oSbeMH. HaoTefl βολβι. Moionmfi pacreop cnyciHTb. nPOMbiBKa: 300% Boztbi at 35 ° C for 10 ml. Μοιοιπηη pacTBop CnVCTHTb.

HeHrpajiH3amw: 150% stroke at 35 ° C

Kpameroie: 2% HepacTBOpeHHoro Na ^ opMHara 90 ml. [alpha] 1HBaHHc: + 2% HepacTBopcHHoro KpacHTCJ and 15 [mu] mhh. + 4% HepacTBOpeHHoro TaHHHraHa QF2 30 ml. + 12% HepacTBOpeHHoro KanrraHa N 60 ml. npH 8 o6opoTax / MHH b TeqeHHe ηοίη + 250% BO «bi 60 ° C 10 ml.

Moiomral pacreop cnycTHTb. FlDOMbiBKa: 300% BOffbl 60 ° C 10 mhh ΜοιοπϊηΑ pacreop cnycnm &gt;. Imo Himo &lt; bo6H3aroi «: 100% BOFB 60 ° C + 0.5% aMMHayea 1:51 2 ml. 1 1 o6beMH. qacTb COPPERHPHpoBaHHoro βμμηβκβ h 5 o6beMH. nacTefl βοβηι + 6.3% cpeacTBa hjih ΓΗιιροφοδΗΒβηΗΗ of Η3οβρβτεΗΗΐο from npHMepy 15 a 1:51 to 60 mhh. * 1 o6beMH. qacTb npojyKTa h 5 o6i &gt; eMH. qacreH bo ^ bi. 2 + 0.5% MypaBbHHOH KHcnoTbi 1: 5 15 mL. pH: 3.6-4.0. LV 11044

MoiOimn pacTBop CnVCTHTb. 2 X ITDOMblBKH: 300% bob 40 ° C ΠΟ 10 MHHyT. Moiouuin pacraop crijcniTL. 3aicpcnJiemie: 1 50% BOAbi 40'C 3% EayxpoM A **, HepacTBopeHHoro, 60hhh. pH: 4.2-4.8 Μοϊοπτηη pacTRop cnycTyrrb. 3-x noMbiBKH: 300% BOj [bi 20 ° C πο10μη) τ.

Moioumfi pacTBop cnycTHTb.

Ko &gt; Ky 3a Hoqi &gt; nojtcynmTb Ha K03Jiax, pacT «Hynb, noacynmxb b BaKyyMc (80 ° C / 2hhh), npoBeTpHTb Ha B03Ztyxe, KOHjHHIHOHHpoBarL ·, roMeHHTH, pa3rjiazom &gt; (80 ° C / 0.5 mL). xx) npoziyn &gt; i φηρΜΜ ΒΑΜΕΡ ΑΓ, JleBepKy3CH. ΠεΗβΊροΜβτρ Eamm: (10% ocajncH)

BpeMH rrpoMOKaeMOCTH: &gt; 7 / &gt; 7 qacoB.

BnaronorJiomaeMocTt b%: Young 7 qacoR 9.9 / 10.4.

Me3ep npoaonLHtie η3Γη6μ: 21924/19207

BjiaronornomaeMOCTb b% nocne npoHOJibHi &gt; ix η3Γη6οβ 8.0 / 7.1. ΠρΗΜερ 16. Πρhm eHAnii nonyqeHHi.ra no npHMepy 1 βμηπ. B mocking c m MemamcofiMemaiOT 30 r bo / p &gt; ih 7 i (HH3onponHJMHHa npH xeMnepaxype okojio 50 ° C, npe ^ e qeM npH nepeMenmBaHHH bboiuit opraHHqecKyio φa3y, cocToamyio H3 14 r aMHu no H306peTeHHK &gt; 3.5 r aHHOBOH COim 3 &lt; (f) Iipa φοοφορΗΟΗ KHCJIOTBI (nOJiyqCHHOH nNRpAtMeTh &lt; t (lt 16-18, CMecH κηρηβιχ crmpTOB t cHHTe3a I (Hrirq &gt; a, c P2O5, Mo.iapHoc oTHomerme 3: 1, expressed by MouloM z 5 r χπορπαραφιηια c 40% uenHoro xnopa h pa3MenniBaiox λο ozCHopoaHoro οοοτοληηη 3xox cocraB npuMCHara b HiDKecjieayiomcH pcucriType juia Η3γοτοβηοηη $ ι kotkh

AiIM bOCHHOl'O CHHp &gt; DKeHllH: - / € -

What is H3 nncvp κρνπΗΟΓΟ poraToro cKOTa Τηπ: KO &gt; Ka jum eoeHHoro CHapjraceHHa

MaTepnan: KopoBbH uncypbi, Moicpbie cHHero HBera, TOJUHHHa nocne CTporamta: 2.0 mm npoueHTHbie aajiabie b nepecqeTe If yourHHbii! Bec.

IlpoMbiBKa: 300% βοφι 35 ° C 0.5% Mj'paBbHHydrocyte 1: 5 * 15mhh. X1 oabeMH. qacn »KOHUEHipHpoBaHHoft κηοιοίέι c 5 ο6τ &gt; βΜΗ. qacr »MH Boabi.

Moiomral pacreop cnycTHTb.

HefiTpypymax: 100% βολμ 35 ° C 3% Na &lt; s &gt; opMHara, HepacTBopeHHoro, 15mhh pH: 4.4 + 0.5% 6HKap6oHaTa HaTpase 1:10 90 ml. pH: 4.8

Motor! pacrreop cnycTHTb. nPOMbiBKa: 300% Boat at 30 ° C for 10 ml.

Moioamfi pacreop cnycTHTb.

ūoirvOnHBaHHe: 200% BOffbi 30 ° C 1% KpacHT? 1:20 20 mhh + 4% HepacTBopeHHoro TimeHa? (QP) + 12% KBe6paxo, HepacTBopeHHoro 60hhhh. ABTOMairnca b xeqeHHe HoqH noKofi / BpameHHe 15 mhh / 1 mhh. + 200% BOJib 60 ° C 20 ppm.

MotoiiiHif pacreop cnycrHTb. npoMbEBKa: 300% Boabi 60 ° C 10 ml.

Moionmfi pacTBop cnycnrn &gt;.

%Τροφο6Η3ΒΐπΐΗ: 200% ΒΟφΐ 60 ° C 10% cpeacTBa Take a look at &nbsp; &gt; 6H3aHHH no npHMepy 16, SILVER HHOE βολοη b OTHomeHHH 1: 5 (o6i &gt; eM / o6beM) 60Mhh. + 1% MypaBbimoH KHCJiOTbi 1: 5 ' - // - LV 11044 + 1% 06beMH. qacn &gt; KOHIlCHTpHpOBaHHOft KHCJIOTbl H 5 o6 &quot; beMH. qa &lt; rreH Bonbi + 3% EafixpoMa MF, HepacTBopeHHoro, 60 Mira. pH: 3.6-3.7.

Moiouhih pacrBop cnycTim &gt;. 3 x npoMbiBKii: Moiounul pacrBop cnycTHTb. rTpononacKHBaHHe: 300% Boolean

Bona

25 ° C from 10 MHHyT.

20 ° C

10 MHHyT

Ko * y 3a ηοηβ noncynnm &gt; Ha K03Jiax, pacTXHyrb, noncynnrn »b BaKyyMe (80 ° C / 3hhh), RippingBeTpiiTb Ha B03nyxe, pa3MnrqHTb, pa3rjianjrn &gt; (80 ° C / 0.5 ml). ** Toolpiece biκρΜΗ EAH3P ΑΓ, JeeBepKy3eH. No Barrel (10% octane)

BpeMH npoMOKaeMocra: &gt; 420 / &gt; 420 mhhjt.

BnaronornomaeMocTb b%: 12/14, 29785/25971 nocne 7 qacoB:

Me3ep rrpononbHbie H3ra6bi

BnaronorjioinaeMOCTb b%: nocne npononbHbix η3Γη6οβ 10/12. rtpHMep 17. а) 3arpyacaioT 30.5 r Bojcbi h 5.5 r HaTpoBoro menoica 45% b armapar c Seafish npn reMnepaxype okojio 50 ° C. Πρκ nepeMeuiHBaHHH Me / oieHHO ββολητ opraHHqecKyio φa3y) cocToqmyK &gt; H3 18 r aMHna npHMepa 1, 40 r BbicoKianwmero MHHepanbHoro Macna η 6 r HHMeTHjmojiHCHJiOKcaHa c bjokoctmo 350 Mnya3.ceK, 3aTeM mAiraraioT no Ο, ΤΗΟρΟ ^ ΗΟΓΟ COCTOHHHJI. б) Cocrae H3 a) Hcnonb30BajiH b peneirrype no npHMepy 16 h oh naBan cne, nyiomHe pe3yjn &gt; TaTbi: ncHeTpoMerp Baroni (10% ocanKH)

BpeMS npoMOKaeMocTH: 420 g &lt; / RTI &gt;

BnaronornomaeMocTb b%: nocne 7 qacoe: 7/8,

Meaep 48123/48316 9/8. npOJOniHtie H3ni6bl B; tnrononroinaeMOCTb b%: riOCie npOJO-ThHb! X Η3ΓΗ6θΒ

IlpHMep 18. ΠρHMeH5WH aMHH from H3o6pCTeHHK &gt; H3 npHMepa 1. B A ct c m Memamcofi 3arpyacaioT 39 r βολμ c 3 γ 45% -ηογο HaTpoBoro exp. NpH TeMnPypype οκοπο 50 ° C. Flocnc 3Toro ββολητ opramnccKyK &gt; H3 6 r aMima npHMepa 1, 6 r capK03ima oneHHOBofi khoiotu, 40 r BticoKOKHnamero MHHepiHoro Macna h 5 r OTMeTHJinoJiHCHJioKcaHa c βλ3ΚΟ £ γπ &gt; κ &gt; 350 m nya3.ceK Go to HHo npH nepeMenmBaiiHH h roMoreHH3HpyiOT. chiHyHeHHBiH TaKHM nyTCM ηροπγκτ πρΗΜαηποτ b pcueirrype BOioHeiipoHHuaeMofi kohch no nPHMepy 16 6), npHHeM 6bum nonyqeHi &gt; i cneiiyiomHe BeJDTHHHBi:

HeHeipoMeip Bamra (10% ocajucH) &gt; 420 / &gt; 420 mhhjt. 9/10, 29885/30147 14 / 11.6.

Bpe.Ma npoMOKamur BnarononiomaeMOCTb b%: nocrce 7 * iacoB:

Me3q &gt; npoztojibHBie η3Γη6βι BnaronoraomaeMOcrb b%: WRC ieρΟΛΟΠΒΗΒΙΧ Η3ΓΗ60Β ripHMep 19. а) B mocking c Memamcofi 3pcsKoo 39 r boso i h 4 r HaipoBoro expense, 45%, npn TeMnepaxype οκοπο 50 ° C. ΠρΗ nepeMetUHBaHHH bboaht opraroineocjio φβ3 ^ cocrojnnyio H3 12 r codend of npHMepy 4, 35 r BbicoKOKHnjnnero yrneBoaopo ^ a, 5 r itHMCTHJmOJDICHJIOKCaHa HC BJI3KOCTbIO 100 Mnya3.CGK H 5 Γ ΗβΠΟΠΗΟΓΟ 3 &lt; j) Hpa φοοφορΗοκ khcjiotbi (s ^ ona 12-18, npeBpameHHoro c P2O5, MonapHoe oraonHHe 3: 1) h nepeMeiiMBaioT no onHoponnoro cociosaum. б) B peuenType, npHMeHeHHofi no nPHMepy 16, 6βιπη £ 0CTHTHyn &gt; i cnezcvronme BemraiHbi: ΠίΗίτροΜβτρ Baroni (10% ocazocn)

BpeMa npoMOKaHHa: &gt; 70 / &gt; 7 mhhvt. LV 11044 13.3 / 12.0. 15849/16717 12/8.

RnaronorjiomaeMocrb b%: nocrre 7 qacoB:

Me3ep npOiiO.TUIIjIC Η3Πΐ6ίΛ BnaronornomaeMocTb b%: nocne ΓφΟΛΟΗΒΗΒΙΧ Η3ΠΐβθΒ ΠρΗΜφ 20. npHMeHsjm ormcaHHbifi b npHMepe npo «yicr. 20 r 3τογο Bemecraa 3arpy * anH b annapT c MemanKoft, c 68.4 r xjiopnapa4 &gt; HHa c 40% ueimor XJiop h nepeMemHBanH npH 100- 105 ° C RO ΟΛΗΟρΟΛΗΟΓΟ COCTOBHHfl. X OXJia &gt; KaCHHi nPH6nH3HTCJIbHO RO 70 ° C κ cMecH 2 OObBismism 11.6 r 2HH3onponaHOJiaMHHa Juir HefiTpanH3diiHH. 3tot cocraB npHMenajiH b HiDKeciie ^ yiomeH peuerrrype ® mroTOBJieHHa BoztoHenpoHHiiaeMOH what &gt; kh h HccīrezīOBajiH Ha Difference neficraHe:

MaTepnan: κοροΒΜΐ nncypbi, MOKpbie, cHHero explores, TonmHHa nocJie crporaima: οκοπο 2.0 MM. ripoueHTHfaie ztaHHbie b nepec ere Ha crporaHbifi Bec.

HpoMbiBKa: 300% βοπβι 35 ° C 0.5% yCycHofi KHcnoTbi 1: 5 15 mL.

Moionmfi pacTBop cnycTHTb.

Hcfiip am3: 100% Bonbi 35 ° C 2% φορΜΗΒτπ Harpnn, HepacTBopeHHoro, 15 ml, + 0.5% 6HKap6oHaA 1:10 90 ml.

Moiomjie pacTBOpbi - pH: 5.3. rionepenHbiH pa3pe3 kojkh προτΗΒ 6poMKpe3on3eneHoro rony6oro.

Moionmfi pacTBop cnycTHTb

ITpoMbiBKa: 300% BOHb 30 ° C 10 MHH. Moioiiihh pacTBop cnycTHTb. KpanieHHe: 100% BO bis 30 ° C / sat6nHBamie: 1% nepHofi KpacKH nna xpoMoeofi kotkh TU 141%

1:20 20 MHHyT + 4% TaunraHa QF ** HepacTBopeHHoro, 30mhp + 12% HepacTBopeHHoro KBe6paxo npn 6 o6opoTax / MHHyTy b tc ^ chhc Homi, -j.0- rTpojy6jieHHe + 200 ° / obohi MoioimiK pacTBOp cnycniTL &gt;. npOMblBKa: 300% omm Morommi pacreop cnycTHTb. Γ ιντροφοδιηβιρτίτ: 100% βοληι 3aicpcn: goose:

60 ° C

60 ° C

60 ° C 8% cpeaciBa min ρ £ ροφο6Η3αιιιπι + 1% MypaBbHHofl KiicjioTbi 1: 5 20 MHHyr. 10 MHH. 1: 4 60 MimyT 15 MHH.

+ 3% EafixpoMa F 60 MHHyT

Moionme pacreopbi - pH: 3.6-3.7.

Moiomra! pacreop cnycTHTb. 3 x npoMiBKH: 300% BOflw at 25 ° C from 10 ml.

MoromHfi pacTBop cnycTHTb.

Ko &gt; Ky 3a Hom &gt; noa: cyinHBaioT Ha K03Jiax, pacTSTHBaiOT, noacymHBaiOt b BaKyyMe (80-85 ° C, 2 MHHyrbi), προβετρΗΒβιοτ Ha B03ayxe, yBjia * HinoT, pa3MHTHaioT, pa3rjiaHCHBaioT πρκ BaKyyMe (80-8 5 ° C, 30 ceKyu). Bo epeM # pa6oT b ΜοκροΜ coctojihhh He 6bmo c ^ ejiaHo ηηκβκηχ HCKjnoqirrejibHbix in HHHHH. do not tapMeip Bajum (10% ocaziKH)

BpeMa npoMOKaeMocra: &gt; 7 / &gt; 7 qacoB

BjiaronornomaeMOCTb b%: nocne 7 qacoB: 13.1 / 8.2.

Maeser: npoaojn &gt; Hbie H3ra6bi 15407/14320

BjiarononiomaeMocTb b%: nOCJie ΠρΟΛΟΗΒΗΒΙΧ Η3ΠΐβθΒ 7.7 / 5.0.

IlpHMepbi 21-25 25 r cocaHHCHHa o6mefi φopMyπbI 1, 25 r BbicoKOKHnamcro MHHcpanbHoro Maori h Heo6xoztHMbie zdih HeftTpajiH3aiiHH κηοιοτηοΑ rpvnnbi KomraecTBO TpH3TāHOJiaMHHa CMeiiTHBaioT η πρκ 60 ° C 3MynbrHpyioT b 200 r βοχο &gt; ι. 3th cocraBbi Hcnonb3yioT b Ka ^ ecTBe ηυχροφοβΗρνιοπιβΓΟ cpeacTBa b peuenType xexHHqecKoro πρΗΜβΗβΗΗΛ cornacHO npHMepy 16. Pe3yjrbTaTbr HcribrTaHHH npe / icTaBjreHbi b Ta6jnme 1: -ΛΛ LV 11044

Ta6jnnia 1 ripHMep IIcnoOT 3yeMoe coefficient ^ nHeHire BaIIy πβyετροΜετρ BpeMa ΠρΟΧΟΜζΗεΗΗΛ BOflbI (MHH) 10% cnDKarae nornonzeHHe BOJQ &gt; I,% n. 4aC0B 21 aMHa H3 npHMepa 6 okojio 360 8 6 22 cyjn &gt; &lt; t &gt; OHaMim H3 npHMq &gt; 2 25 IipOH3BOflHOe MO ^ eBHHhl H3 npHMepa 12 10 67 2

/ »/ V LV 11044 ΦΟΡΜΥΤΙΑ H30BPETEHHU l. Cnoco6 ana npunamia BonooTrajiKHBaioniHX cbohctb KoacaM h MexaM, OTnunaiiimi Hca xeM, qrro coennHeIi6mefi φορΜγπΒΐ 1:

R, - N - CH2CH - COOX

A

I R 2 b κοτοροβ Ri o6o3Haqaer HacbnneHHbiH the target HeHacbnneHHbifi anKHJDbHBni ocraTOK hjih ajncoKOCHamcHJīBHtifi ocraTOK c 1-22 ετομεμη yrnepoaa, npeanoTnrrejibHO c 12-18 ετομεμη yraepoaa, R2 o6o3Haqaer ajnauibHbifi ocraTOK c 1-18 aTOMaMH yrjiepona, HacbimeHHbifl hjih HeHacbimeHHbrii κερ6οκ &lt;: ηειιε &gt; κηιπ &gt; ηι &gt; ι8 octetok c 3-4 ετομεμη yrnepoaa, hjih ΚΕρ6οκαιφβΗΐηπ &gt; ΗΒΐΗ ocraTOK, hjih Kap6oKCHJitHBiH ocraTOK (-COOH),

Rj o6o3HaqaeT Bonopon hjih CH3 η

Xo6o3HaqaeT Bonopon, meaoraoH Mcrajui, mejioHH03eMejn & HtH Mcrajin, emmohhh, aJIKHJiaMMOHHHHJIH βϋΚΕΗΟΗΗΜΟΗΗΗH, pA6O3HaTe &gt; C = 0, &gt; SC &gt; 2, sq

NH mm ajHiBuH ocraTOK c 0-3 ετομεμη yniepona. b KOJnraecrBe 0.1-25 Bec%%, npeanoarHTJHHOHO 1-15 bcc.%, b iiqpec4cre Ha crpoiaHHbm Bec koj hhih MOKpbiH eE Mexoe, πρΗ β £ εηηηηεχ pH ot 4 ao 9 rrpHBojurr bo B3aHMoneHCTBHe noay6jiHBaHHH hjih nocjie aoay6JiHBaHHa, 3aTeM ycraHaBJiHBaioT ao bcjihhhh pH b o6jiacra ot 3.5 of 5.0 h nocjie o6pa6oTKH 3aKpemwioT b cjiy ^ ae Heo6xonHMOCTH πρκ noMomH 2-, 3-, 4-hjih BajieHTHOH cojiH Merajuia, npennoHTHTeiībHo b bothom pacreope. 2. Cnoco6 πο π. 1 oTJmnaioimīHca TEM, whereby to msi npunaHHa BonooTTajiKHBaiomHX CBOHCTB npHMeH5E £ 0T npOnyKT, KOTOpbrii COnepJKHT 5-80, 10-70 ΠρβηΠΟΉΉΤε.ΤΒΗΟ Bec.% CoenHHeHHH o6ihch φopMyπbl I, npeanoHTHTejibHo of MCHbmcfi MEPC h aacnniHO HeRipajiH30BaHH0H φορΜε, b cjivnae Heo6xonHMOCTH 20-70, npennoqTHTeJibHO 30-60

% VTJieBooposioB, b cnyqae Heo6xoAHMocni areHTbi pacrBopeHHa h ocraTOK zto 100% BOTU. 3. Cnoco6 from 0AH0My m n.1-2, oTnnnaiominicii TeM, «ito BBeAeHHoe cpeACTBO jsjisi npimaHiia BojiooTajiKiiBaiomiix cbohctb coacp &gt; HenonHbie οφπρΜ φοοφορΗοι! KIICJIOTbl CIlHpTOB C ZŪDIHOH UenH OT C4 ΛΟ C20, Ci6-Ci8 ΠρΟΛΠΟΉΉΤεΠΒΗΟ, KOTOpbie B cnyqae hco6xoahmocth oKcajncHjajīpoBaHbi, b KOjnmecTBax ot ao 0.5 30 npeOTotrrHTenbHO οτ 1 η, ο 20 eec.%, B nepeqceTe H 100 r BBeAeHHoro cpeacraa AJW ΠρΗΛβΗΗΗ BOZTOOIRJIKHBaiOmHX CBOHCTB.

4. Cnoco6 no oaHOMy H3 n.1-3, oTmraaionmfica TeM, ato cpeacTBO jum npHAaHHS

BoaerKHBaiomHX CBoftcrB coflep) CPA cHHHKOHOBbie Maci, npejmoqTHTejn &HO; rrajiKHB aK »mnx cbohctb. 5. Cnocos ΠΟ OAHOMy H3 n. 1-4, OTJZHHaiOIHHHCH TeM, ΤΓΟ CpCACTBO jum ΠρΗΑΒΗΗΛ BOAOOTTajiKHBaioniHX cboIIctb coAep »ar a 0.5 ao 20, πρβΑΠΟΏΉΤβπΒΗΟ οτ 2 ao 20 Bce. 6. Cnoco6 no OAHOMy H3 n.1-5, oTirHaHionHHCs TeM, hto cpeACTBO jum npnAa βΑΚΗΒΕΙΟΠϊΗΧ CBOHCTB COAepHO Tβρ3φΗΗΒΙ Η / HJIH ΧΑΟρΠβρΒφΗΗΒΙ. LV 11044 AHHOTAURfl

PfaoopereHHe othochtcs k npHMCHemnocoejiHHHHH oGuiefl φορΜγ / Ήΐ I /

R, - N- CH2CH - COOX

A

I R 2 b R κοτοροΗ o6o3Haqaer HacbimeHHbiū hjih HCHacbimeHHHia ajnarabHBie ocraTOK hjih ajiKOKOCHajncHjrbHbiH ocraTOK c 1-22 axoMaMH yrnepojca, npeano ^ c THTejibHo 12-18 aTOMaMH jrnepozca, R2 o6o3Haqaer arrKHJībHiiH ocraTOK c 1-18 βτομβμη yniepojia, HacbimeHin &gt; m hjih ΗεΗΒΟΒίπιεΗΗΒίδ ΚΕρβοκεΗβϋΒΚΗπΒΗϋβ ocraTOK c 3-4 aTOMaMH yrjiepo.ua, καρ6οκοκφεΗΗ3ΐΒΗΒΐδ ocraTOK hjih KapGoKCHJibHbifi ocraTOK (-COOH),

Rj o6o3Haqacr βολορολ hjih CH3 η

XO6O3Haqaer Bonopon, mejioHOH McranJi, menoqH03eMejibHbiH Mcrajui, βμμοηηη, aJUCHJiaMMOHHH HJIH AJIKAHOJiaMMOHHH, H

A o6o3HaqaeT &gt; C = 0, &gt; S02 hjih ajncHJieHOBbril ocraTOK c 0-3 aTOMaMH C, b ^ That ecrae 3MyjibraTopoB, CMaHHBaTCJiefi, noBepxnocTHO-aKTHBHbix BemecTB b cpencTBax ohhcikh, a TaioKe jpia nojiyqeHH "cpencrB, npHnaiomHX BonooTTarncHBaiomHe cBOHcrea κοτκε.

Claims (6)

A method for assigning hydrophobic properties to skins and furskins, characterized in that the compound of the general formula I R3 R, - N - CH2CH - COOX IA R2 wherein R1 represents a saturated or unsaturated alkyl radical or alkoxy radical with 1- 22 carbon atoms, preferably 12-18 carbon atoms, R2 represents an alkyl moiety of 1-18 carbon atoms, saturated or unsaturated carboxylic alkyl with 3-4 carbon atoms, or carboxylphenyl radical, or carboxylic acid (-COOH), R3 denotes hydrogen atom or CH3- and X represents a hydrogen atom, an alkali metal, an alkaline earth metal atom, an ammonium, alkylammonium, or an alkanolammonium group, and A represents &gt; C = 0, &gt; For SO2, - c or alkylenic acid with 0-3 C atoms, 0.1-25% by weight, preferably 1-15% by weight based on the weight of the cut skin or wet fur mass, interact with the workpiece at pH 4 to 9 for skins or fur during or after tanning, then adjusted to a pH of between 3.5 and 5.0 and, after treatment, fixed, if necessary, with a 2, 3 or 4-valent metal salt, preferably in aqueous solution. Method according to claim 1, characterized in that a product containing from 5 to 80% by weight, preferably from 10 to 70% by weight, of the compound of the general formula I is used in order to release the hydrophobic properties, preferably in at least partially neutralized form. , if necessary, 20-70 wt.%, preferably 30-60 wt.% of hydrocarbons, if necessary dissolving agents and other water up to 100%. 3. A method according to claim 1 or 2, wherein the agent administered to form the hydrophobic properties comprises mono- or diesters of phosphoric acid with alcohols having chain lengths of C4 to C2o &gt; preferably C? 6 * Cl8 &gt; which are, if necessary, oxyalkylated, in an amount of from 0.5 to 30% by weight, preferably from 1 to 20% by weight, based on 100g of hydrophobic properties of the administered agent. 4. The method of one of claims 1 to 3. characterized in that the hydrophobic property forming agent comprises silicone oils, preferably dimethyl or methylphenylpolysiloxanes in an amount of from 0.5 to 80% by weight, preferably from 1 to 10% by weight, based on the agent injected to form 10Og of hydrophobic properties. Method according to one of Claims 1 to 4, characterized in that the hydrophobic forming agent comprises from 0.5 to 50% by weight, preferably from 2 to 20% by weight of oleic acid sarcoside, on a 100g hydrophobic property of the product injected. Method according to one of claims 1 to 5. characterized in that the hydrophobic forming agent comprises paraffins and / or chloroparaffins.