LT3106B - Process for the polymerisation of epoxycompounds - Google Patents
Process for the polymerisation of epoxycompounds Download PDFInfo
- Publication number
- LT3106B LT3106B LTIP217A LTIP217A LT3106B LT 3106 B LT3106 B LT 3106B LT IP217 A LTIP217 A LT IP217A LT IP217 A LTIP217 A LT IP217A LT 3106 B LT3106 B LT 3106B
- Authority
- LT
- Lithuania
- Prior art keywords
- compound
- compounds
- metal
- weight
- epoxy
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 19
- 230000008569 process Effects 0.000 title claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 43
- 239000004593 Epoxy Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 21
- 239000002585 base Substances 0.000 claims description 20
- -1 metal complex compound Chemical class 0.000 claims description 13
- 239000002879 Lewis base Substances 0.000 claims description 11
- 239000003446 ligand Substances 0.000 claims description 11
- 150000007527 lewis bases Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 150000007522 mineralic acids Chemical group 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 3
- MLIREBYILWEBDM-UHFFFAOYSA-N cyanoacetic acid Chemical compound OC(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000000536 complexating effect Effects 0.000 claims description 2
- 150000005690 diesters Chemical class 0.000 claims description 2
- 238000004870 electrical engineering Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229910001437 manganese ion Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- QBWKPGNFQQJGFY-QLFBSQMISA-N 3-[(1r)-1-[(2r,6s)-2,6-dimethylmorpholin-4-yl]ethyl]-n-[6-methyl-3-(1h-pyrazol-4-yl)imidazo[1,2-a]pyrazin-8-yl]-1,2-thiazol-5-amine Chemical compound N1([C@H](C)C2=NSC(NC=3C4=NC=C(N4C=C(C)N=3)C3=CNN=C3)=C2)C[C@H](C)O[C@H](C)C1 QBWKPGNFQQJGFY-QLFBSQMISA-N 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229940125846 compound 25 Drugs 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000000565 sealant Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 description 29
- 150000002460 imidazoles Chemical class 0.000 description 11
- 229920000647 polyepoxide Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 239000003822 epoxy resin Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000977 initiatory effect Effects 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 2
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 1
- YRAJNWYBUCUFBD-UHFFFAOYSA-N 2,2,6,6-tetramethylheptane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(C)(C)C YRAJNWYBUCUFBD-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241001455214 Acinonyx jubatus Species 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 101710173835 Penton protein Proteins 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- VYGUBTIWNBFFMQ-UHFFFAOYSA-N [N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O Chemical compound [N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O VYGUBTIWNBFFMQ-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- SHGAZHPCJJPHSC-YCNIQYBTSA-N all-trans-retinoic acid Chemical compound OC(=O)\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C SHGAZHPCJJPHSC-YCNIQYBTSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- MJSNUBOCVAKFIJ-LNTINUHCSA-N chromium;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Cr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MJSNUBOCVAKFIJ-LNTINUHCSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000003055 glycidyl group Chemical class C(C1CO1)* 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229920000570 polyether Chemical class 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012262 resinous product Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD90338526A DD292468A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidverbindungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LTIP217A LTIP217A (en) | 1994-06-15 |
| LT3106B true LT3106B (en) | 1994-12-27 |
Family
ID=5616937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LTIP217A LT3106B (en) | 1990-03-09 | 1992-10-02 | Process for the polymerisation of epoxycompounds |
Country Status (2)
| Country | Link |
|---|---|
| DD (1) | DD292468A5 (de) |
| LT (1) | LT3106B (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4231680A1 (de) * | 1992-09-22 | 1994-03-24 | Ruetgerswerke Ag | Verfahren zur Herstellung von Metallkomplexen mit hoher Koordinationszahl und deren Verwendung |
Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US355166A (en) | 1886-12-28 | Separator for steam-generators | ||
| CH269230A (it) | 1948-08-13 | 1950-06-30 | Benaglio Osvaldo | Quadrante per orologi da polso e da tasca. |
| US3310602A (en) | 1962-07-26 | 1967-03-21 | Borden Co | Curing epoxide resins with aromatic amine-aldehyde coordination complexes |
| US3367913A (en) | 1966-09-09 | 1968-02-06 | Interchem Corp | Thermosetting epoxy resin composition containing a zinc chelate |
| DE2019816A1 (de) | 1969-04-24 | 1970-10-29 | Morton Internat Inc | Formmassen aus Epoxyharzen |
| US3553166A (en) | 1968-02-02 | 1971-01-05 | Ppg Industries Inc | Mixtures of imidazole complexes and nitrogenous compound as curing agents for epoxy resins |
| US3632427A (en) | 1970-05-15 | 1972-01-04 | Air Prod & Chem | Epoxy resin and imidazole alkyl acid phosphate fiber treatment |
| US3635894A (en) | 1969-11-06 | 1972-01-18 | Ppg Industries Inc | Curable epoxy resin compositions containing organoimidazolium salt |
| US3638007A (en) | 1969-08-05 | 1972-01-25 | Herbert B Brooks | Digital control simulator |
| US3642698A (en) | 1970-05-15 | 1972-02-15 | Air Prod & Chem | Epoxy resin curing with imidazole alkyl acid phosphate salt catalyst |
| US3677978A (en) | 1971-08-23 | 1972-07-18 | Ppg Industries Inc | Metal salt complexes of imidazoles as curing agents for one-part epoxy resins |
| US3746686A (en) | 1971-07-12 | 1973-07-17 | Shell Oil Co | Process for curing polyepoxides with polycarboxylic acid salts of an imidazole compound and compositions thereof |
| DE2300489A1 (de) | 1972-01-06 | 1973-07-19 | Minnesota Mining & Mfg | Verfahren zum haerten von massen mit einem gehalt an epoxygruppenhaltigen verbindungen |
| DE2334467A1 (de) | 1972-07-06 | 1974-02-14 | Mccall Corp | Metallorganische katalysatorzusammensetzungen und ihre verwendung in aushaertbaren massen |
| DE2525248A1 (de) | 1974-06-07 | 1976-01-02 | Aerojet General Co | Latente katalysatoren fuer epoxyharze |
| US4101514A (en) | 1970-07-17 | 1978-07-18 | Minnesota Mining And Manufacturing Company | Imidazole type curing agents and latent systems containing them |
| DE2810428A1 (de) | 1977-03-10 | 1978-09-14 | Loctite Corp | Haertbare epoxyharzzusammensetzung |
| DE2811764A1 (de) | 1977-03-18 | 1978-10-05 | Shikoku Chem | Neue imidazol-isocyanursaeure-addukte sowie verfahren zu deren herstellung und anwendung |
| US4137275A (en) | 1976-04-27 | 1979-01-30 | Westinghouse Electric Corp. | Latent accelerators for curing epoxy resins |
| US4473674A (en) | 1983-11-03 | 1984-09-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Process for improving mechanical properties of epoxy resins by addition of cobalt ions |
| US4487914A (en) | 1983-02-18 | 1984-12-11 | National Research Development Corporation | Curing agents for epoxy resins |
-
1990
- 1990-03-09 DD DD90338526A patent/DD292468A5/de not_active IP Right Cessation
-
1992
- 1992-10-02 LT LTIP217A patent/LT3106B/lt not_active IP Right Cessation
Patent Citations (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US355166A (en) | 1886-12-28 | Separator for steam-generators | ||
| CH269230A (it) | 1948-08-13 | 1950-06-30 | Benaglio Osvaldo | Quadrante per orologi da polso e da tasca. |
| US3310602A (en) | 1962-07-26 | 1967-03-21 | Borden Co | Curing epoxide resins with aromatic amine-aldehyde coordination complexes |
| US3367913A (en) | 1966-09-09 | 1968-02-06 | Interchem Corp | Thermosetting epoxy resin composition containing a zinc chelate |
| US3553166A (en) | 1968-02-02 | 1971-01-05 | Ppg Industries Inc | Mixtures of imidazole complexes and nitrogenous compound as curing agents for epoxy resins |
| DE2019816A1 (de) | 1969-04-24 | 1970-10-29 | Morton Internat Inc | Formmassen aus Epoxyharzen |
| US3638007A (en) | 1969-08-05 | 1972-01-25 | Herbert B Brooks | Digital control simulator |
| US3635894A (en) | 1969-11-06 | 1972-01-18 | Ppg Industries Inc | Curable epoxy resin compositions containing organoimidazolium salt |
| US3632427A (en) | 1970-05-15 | 1972-01-04 | Air Prod & Chem | Epoxy resin and imidazole alkyl acid phosphate fiber treatment |
| US3642698A (en) | 1970-05-15 | 1972-02-15 | Air Prod & Chem | Epoxy resin curing with imidazole alkyl acid phosphate salt catalyst |
| US4101514A (en) | 1970-07-17 | 1978-07-18 | Minnesota Mining And Manufacturing Company | Imidazole type curing agents and latent systems containing them |
| US3746686A (en) | 1971-07-12 | 1973-07-17 | Shell Oil Co | Process for curing polyepoxides with polycarboxylic acid salts of an imidazole compound and compositions thereof |
| US3677978A (en) | 1971-08-23 | 1972-07-18 | Ppg Industries Inc | Metal salt complexes of imidazoles as curing agents for one-part epoxy resins |
| US3792016A (en) | 1972-01-06 | 1974-02-12 | Minnesota Mining & Mfg | Metal imidazolate-catalyzed systems |
| DE2300489B2 (de) | 1972-01-06 | 1976-03-11 | Minnesota Mining And Manufacturing Co., St. Paul, Minn. (V.St.A.) | Verfahren zur herstellung von gehaerteten epoxidpolyaddukten |
| DE2300489A1 (de) | 1972-01-06 | 1973-07-19 | Minnesota Mining & Mfg | Verfahren zum haerten von massen mit einem gehalt an epoxygruppenhaltigen verbindungen |
| DE2334467A1 (de) | 1972-07-06 | 1974-02-14 | Mccall Corp | Metallorganische katalysatorzusammensetzungen und ihre verwendung in aushaertbaren massen |
| DE2525248A1 (de) | 1974-06-07 | 1976-01-02 | Aerojet General Co | Latente katalysatoren fuer epoxyharze |
| US4137275A (en) | 1976-04-27 | 1979-01-30 | Westinghouse Electric Corp. | Latent accelerators for curing epoxy resins |
| DE2810428A1 (de) | 1977-03-10 | 1978-09-14 | Loctite Corp | Haertbare epoxyharzzusammensetzung |
| DE2811764A1 (de) | 1977-03-18 | 1978-10-05 | Shikoku Chem | Neue imidazol-isocyanursaeure-addukte sowie verfahren zu deren herstellung und anwendung |
| US4487914A (en) | 1983-02-18 | 1984-12-11 | National Research Development Corporation | Curing agents for epoxy resins |
| US4473674A (en) | 1983-11-03 | 1984-09-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Process for improving mechanical properties of epoxy resins by addition of cobalt ions |
Non-Patent Citations (2)
| Title |
|---|
| FARKAS, A. AT AL: "J.Appl. Polym. Sci." |
| RICCIARDI, F. ET AL: "J. Polym. Sci. Polym. Chem. Ed" |
Also Published As
| Publication number | Publication date |
|---|---|
| LTIP217A (en) | 1994-06-15 |
| DD292468A5 (de) | 1991-08-01 |
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